Interaction of metal ions with D-glucobenzothiazoline: isolation and characterization of the resultant products.
Six different metal-ion complexes of D-glucobenzothiazoline were synthesized and characterized by analytical and spectral techniques. Formation of different types of species (ML and ML(2)) were observed with Cu(2+), Ag(+), Cd(2+), Hg(2+), and Zn(2+) ions. Existence of an anomeric mixture in the case of the Cu(2+) complex is identified from the EPR spectra, and the results were further supported by the simulated spectra. The structures were proposed based on different studies.
Das
T Mohan
TM
Bioinorganic Laboratory, Department of Chemistry, Indian Institute of Technology Bombay, Powai, 400 076, Mumbai, India.
Rao
Chebrolu P
CP
Kolehmainen
Erkki
E
Kadam
Ramakant M
RM
Sastry
Medury D
MD
D052160:Benzothiazoles; D002104:Cadmium / Q000737:chemistry; D003300:Copper / Q000737:chemistry; D004578:Electron Spin Resonance Spectroscopy / Q000379:methods; D005947:Glucose / Q000031:analogs & derivatives / Q000737:chemistry; D008628:Mercury / Q000737:chemistry; D008670:Metals / Q000737:chemistry*; D012834:Silver / Q000737:chemistry; D013057:Spectrum Analysis / Q000379:methods; D013844:Thiazoles / Q000138:chemical synthesis / Q000737:chemistry*; D015032:Zinc / Q000737:chemistry
D052160:Benzothiazoles; D008670:Metals; D013844:Thiazoles; C456722:glucobenzothiazoline; D002104:Cadmium; D012834:Silver; C058836:benzothiazoline; D003300:Copper; D008628:Mercury; D005947:Glucose; D015032:Zinc