title: Lysimeter study to investigate the effect of rainfall patterns on leaching of isoproturon.
abstract: The influence of five rainfall treatments on water and solute leaching through two contrasting soil types was investigated. Undisturbed lysimeters (diameter 0.25 m, length 0.5 m) from a sandy loam (Wick series) and a moderately structured clay loam (Hodnet series) received autumn applications of the radio-labelled pesticide isoproturon and bromide tracer. Target rainfall plus irrigation from the end of November 1997 to May 1998 ranged from drier to wetter than average (235 to 414 mm); monthly rainfall was varied according to a pre-selected pattern or kept constant (triplicate lysimeters per regime). Leachate was collected at intervals and concentrations of the solutes were determined. Total flow (0.27-0.94 pore volumes) and losses of bromide (3-80% of applied) increased with increasing inputs of water and were larger from the Wick sandy loam than from the Hodnet clay loam soil. Matrix flow appeared to be the main mechanism for transport of isoproturon through the Wick soil whereas there was a greater influence of preferential flow for the Hodnet lysimeters. The total leached load of isoproturon from the Wick lysimeters was 0.02-0.26% of that applied. There was no clear variation in transport processes between the rainfall treatments investigated for this soil and there was an approximately linear relationship (r2 = 0.81) between leached load and total flow. Losses of isoproturon from the Hodnet soil were 0.03-0.39% of applied and there was evidence of enhanced preferential flow in the driest and wettest treatments. Leaching of isoproturon was best described by an exponential relationship between load and total flow (r2 = 0.62). A 45% increase in flow between the two wettest treatments gave a 100% increase in leaching of isoproturon from the Wick soil. For the Hodnet lysimeters, a 35% increase in flow between the same treatments increased herbicide loss by 325%.
authors.affiliation: Cranfield Centre for EcoChemistry, Cranfield University, Silsoe, Bedford MK45 4DT, UK. s.beulke@cranfield.ac.uk
authors.forename: Sabine
authors.initials: S
authors.lastname: Beulke
authors.forename: Colin D
authors.initials: CD
authors.lastname: Brown
authors.forename: Christopher J
authors.initials: CJ
authors.lastname: Fryer
authors.forename: Allan
authors.initials: A
authors.lastname: Walker
mesh_terms: D000538:Aluminum Silicates / Q000032:analysis; D001965:Bromides / Q000737:chemistry; D000077215:Clay; D005618:Fresh Water / Q000032:analysis; D006540:Herbicides / Q000737:chemistry / Q000378:metabolism; D008782:Methylurea Compounds / Q000737:chemistry / Q000378:metabolism*; D008954:Models, Biological; D010573:Pesticide Residues / Q000032:analysis; D010671:Phenylurea Compounds; D016062:Porosity; D011891:Rain; D012621:Seasons; D012822:Silicon Dioxide / Q000032:analysis; D012987:Soil / Q000032:analysis; D012996:Solutions / Q000032:analysis; D014867:Water / Q000008:administration & dosage
chemical_list: D000538:Aluminum Silicates; D001965:Bromides; D006540:Herbicides; D008782:Methylurea Compounds; D010573:Pesticide Residues; D010671:Phenylurea Compounds; D012987:Soil; D012996:Solutions; D014867:Water; C028904:isoproturon; D012822:Silicon Dioxide; D000077215:Clay