Minor diterpenoids from Halimium viscosum.
Two new diterpenic acids with an ent-halimane skeleton have been isolated from the aerial parts of Halimium viscosum (Villarino de los Aires chemotype) and separated as methyl esters. These diterpenes were 13-oxo-14, 15-dinor-1(10),11E-ent-halimadien-18-oic acid and 15-hydroxy-1(10),13Z-ent-halimadien-18-oic acid.
Urones
J G
JG
Departamento de Química Orgánica, Universidad de Salamanca, Spain.
Sexmero
M J
MJ
Hernandez
F A
FA
Basabe
A B
AB
Diez
D
D
Marcos
I S
IS
D030601:Cistaceae / Q000737:chemistry*; D004224:Diterpenes / Q000737:chemistry / Q000302:isolation & purification*; D004952:Esters / Q000737:chemistry; D019906:Nuclear Magnetic Resonance, Biomolecular; D018547:Plant Stems / Q000737:chemistry; D010946:Plants, Medicinal / Q000737:chemistry*; D013030:Spain; D013055:Spectrophotometry, Infrared; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared; D013237:Stereoisomerism
C449242:13-oxo-14,15-dinor-1(10),11E-ent-halimadien-18-oate; C449239:13-oxo-14,15-dinor-1(10),11E-ent-halimadien-18-oic acid; C449240:15-hydroxy-1(10),13Z-ent-halimadien-18-oic acid; D004224:Diterpenes; D004952:Esters; C449243:methyl 15-hydroxy-1(10),13Z-ent-halimadien-18-oate