title: Use of a Plackett-Burman design with multivariate calibration for the analysis of polycyclic aromatic hydrocarbons in micellar media by synchronous fluorescence.
abstract: This work describes the use of a multilevel Plackett-Burman design (PB) for the creation of a calibration set for partial least square regression (PLS). The PB calibration set was compared to a collinear analogue by testing these two PLS models for the analysis of six polycyclic aromatic hydrocarbons (PAHs). These compounds were analyzed in micellar media by synchronous fluorescence after determination of the experimental conditions (choice of surfactant, analytical conditions such as deltalambda, step, and scan range). The external validation shows that the collinear set is inappropriate to quantify PAH in real samples, but the PB calibration set affords optimal results.
authors.affiliation: Laboratoire de Chimie Moléculaire et Environnement, Ecole Supérieure d'Ingénieurs de Chambéry, Université de Savoie, Le Bourget du Lac, France. odevo@univ-savoie.fr
authors.forename: Olivier
authors.initials: O
authors.lastname: Devos
authors.forename: Bernard
authors.initials: B
authors.lastname: Fanget
authors.forename: Abdel-Ilah
authors.initials: AI
authors.lastname: Saber
authors.forename: Laurent
authors.initials: L
authors.lastname: Paturel
authors.forename: Emmanuel
authors.initials: E
authors.lastname: Naffrechoux
authors.forename: Jean
authors.initials: J
authors.lastname: Jarosz
mesh_terms: D002138:Calibration; D008823:Micelles; D011084:Polycyclic Aromatic Hydrocarbons / Q000032:analysis* / Q000592:standards; D013050:Spectrometry, Fluorescence; D013501:Surface-Active Agents; D014867:Water / Q000032:analysis; D014881:Water Supply / Q000032:analysis / Q000592:standards
chemical_list: D008823:Micelles; D011084:Polycyclic Aromatic Hydrocarbons; D013501:Surface-Active Agents; D014867:Water