The first total synthesis of (corrected) ritterazine M.
Hecogenin acetate was converted to ritterazine M in 16 operations with an average yield per opearation of 87%. The overall linear yield was 12%. This confirmed 1 as the corrected structure for ritterazine M by total synthesis.
Lee
Seongmin
S
Department of Chemistry, Purdue University, West Lafayette, Indiana 47907, USA.
Fuchs
Philip L
PL
D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D010619:Phenazines; D013141:Spiro Compounds / Q000138:chemical synthesis*; D013256:Steroids / Q000138:chemical synthesis* / Q000737:chemistry*
D010619:Phenazines; D013141:Spiro Compounds; D013256:Steroids; C448328:ritterazine M