A rapid method for 90Sr determination in the presence of 137Cs in environmental samples.
A rapid method for the determination of 90Sr in the presence of 137Cs using the Cherenkov radiation technique is described. The contribution of 137Cs to gross Cherenkov radiation (90Y + 137Cs) was examined for 137Cs /90Sr ratios ranging from 0.09 to 2.50 for 137Cs activities ranging from 2 to 1,211 Bq. Results from direct Cherenkov radiation measurement and results after radiochemical separation of 90Y from 90Sr for samples containing both 90Sr and 137Cs were compared. Errors below 5% were obtained for 137Cs /90Sr ratios lower than 1, when no separation was performed, independently of the activity level. However, errors between 10% and 35% were obtained for 137Cs/90Sr ratios higher than 1. In order to determine 90Sr activity in the presence of 137Cs using the Cherenkov technique, a multiple linear regression analysis model was established to correct the data for 137Cs content. The mathematical correction proposed was validated using 66 artificially contaminated lettuce samples in a laboratory experiment by taking into account the activity levels of 137Cs and 90Sr and the radionuclide ratios. Comparison of mathematically corrected radionuclide ratios with the results obtained without correction shows that, for radionuclide ratios higher than 1, error values for measuring 90Sr activity using the mathematical model were much smaller than when no radiochemical separation was performed. On the other hand, for ratios lower than 1, error values when measuring 90Sr activity with radiochemical separation were smaller than when mathematical correction was performed. In spite of this, the mathematical correction is an appropriate way of reducing the time needed to determine radiostrontium using the Cherenkov radiation technique. The method proposed could be a powerful tool for environmental research whenever the contents of 90Sr and 137Cs have to be determined.
Torres
J M
JM
Department de Química Analítica, Universitat de Barcelona, Spain.
Tent
J
J
Llauradó
M
M
Rauret
G
G
D002588:Cesium Radioisotopes / Q000032:analysis; D004784:Environmental Monitoring / Q000379:methods; D008962:Models, Theoretical; D011848:Radioactive Pollutants / Q000032:analysis*; D012680:Sensitivity and Specificity; D013326:Strontium Radioisotopes / Q000032:analysis; D013997:Time Factors
D002588:Cesium Radioisotopes; D011848:Radioactive Pollutants; D013326:Strontium Radioisotopes