Unexpected remarkable stability of primary ozonides derived from alkenyl stannanes. One-pot synthesis of 1,2-diols from alkynes.
Primary ozonides derived from alkenyl stannanes display an unusual stability and can be transformed into 1,2-diols by treatment with dimethyl sulfide and borane-methyl sulfide complex. This observation has been incorporated into the development of a novel one-pot strategy for the conversion of alkynes into 1,2-diols.
Gómez
Ana M
AM
Instituto de Química Orgánica General (CSIC), Juan de la Cierva 3, 28006 Madrid, Spain. anago@iqog.csic.es
Company
María D
MD
Valverde
Serafín
S
López
J Cristóbal
JC