title: Characterisation of pigments and corrosion patinas by means of micro-Raman spectroscopy.
abstract: New applications of micro-Raman spectroscopy are presented here for the investigation of colouring agents in a wax model of plant and of corrosion products on metal artworks. A late 1700 wax model of Camellia japonica L. was studied in order to characterise the nature of white, red and green colours of petals and leaves. White and red colours of petals were identified as pigments of baryte and a mixture of cinnabar and carmine lake, respectively. Fragments taken from leaves with different green hues were also studied; only yellow grains were isolated in this case which were identified as orpiment and yellow chrome. The applicability of micro-Raman spectroscopy to the study of corrosion products on metal objects is presented here for iron archaeological artefacts and for lead samples taken from the cupolas of the Consolata Sancturay in Turin. Analysis of blackish and reddish corrosion patinas entirely covering the archaeological iron objects led to the identification of magnetite and maghemite, goethite and lepidocrocite, respectively. As to lead fragments, the main corrosion product was lead sulphate, and minor amounts of lead carbonate, nitrate and oxide (litharge) were also found.
authors.affiliation: Laboratorio Europeo di Spettroscopie non Lineari (LENS), Università di Firenze, L.go E. Fermi 2, 50125 Firenze, Italy. ange@lens.unifi.it
authors.forename: A
authors.initials: A
authors.lastname: Zoppi
authors.forename: A
authors.initials: A
authors.lastname: Perardi
authors.forename: E
authors.initials: E
authors.lastname: Castellucci
mesh_terms: D003343:Corrosion; D049670:History, 17th Century; D049671:History, 18th Century; D007501:Iron / Q000737:chemistry*; D007558:Italy; D007854:Lead / Q000737:chemistry*; D010860:Pigments, Biological / Q000737:chemistry* / Q000266:history; D012613:Sculpture / Q000266:history*; D013059:Spectrum Analysis, Raman; D014885:Waxes / Q000032:analysis
chemical_list: D010860:Pigments, Biological; D014885:Waxes; D007854:Lead; D007501:Iron