title: A facile C-C bond cleavage in the epoxides and its use for the synthesis of oxygenated heterocycles by a ring expansion strategy.
abstract: The bicyclic epoxy alcohols when treated with DAST gave a new class of rearranged organofluorine compounds, by a ring expansion via C-C bond cleavage of the oxirane ring. The outcome of this reaction with respect to ring size and stereochemical relation between the functionalities is presented here.
authors.affiliation: ENSCR, Laboratoire de Synthèses et Activations de Biomolécules, CNRS UMR 6052, Avenue du Général Leclerc, 35700 Rennes, France.
authors.forename: Pandarinathan
authors.initials: P
authors.lastname: Lakshmipathi
authors.forename: Danielle
authors.initials: D
authors.lastname: Grée
authors.forename: René
authors.initials: R
authors.lastname: Grée