Selectivity in an encapsulated cycloaddition reaction.
A 1,3-dipolar cycloaddition takes place within a reversibly formed, self-assembled capsule. The reaction proceeds through an unsymmetrically loaded encapsulation complex with absolute regioselectivity.
Chen
Jian
J
The Skaggs Institute for Chemical Biology, Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, CA 92037, USA.
Rebek
Julius
J
D055598:Chemical Phenomena; D015392:Chemistry, Inorganic; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure