title: Catalytic hydrophosphination of styrenes.
abstract: [reaction: see text] The first example of intermolecular hydrophosphination of styrenes catalyzed by Ni and Pd complexes is described. The reaction of Ph2PH with styrene, 4-vinylpyridine, 2-vinylpyridine, 4-methoxystyrene, 2-methoxystyrene, and 5-vinyl-2-methylpyridine in benzene under Ni[P(OEt)3]4 catalysis proceeds with high yield and selectivity to give only anti-Markovnikov product.
authors.affiliation: Department of Chemistry, Moscow State University, Leninskie Gory, GSP-3 Moscow, Russian Federation.
authors.forename: Mstislav O
authors.initials: MO
authors.lastname: Shulyupin
authors.forename: Marina A
authors.initials: MA
authors.lastname: Kazankova
authors.forename: Irina P
authors.initials: IP
authors.lastname: Beletskaya