Critical concentration fluctuations of the ionic binary mixture ethylammonium nitrate-n-octanol: an ultrasonic spectrometry study.
Between 200 kHz and 130 MHz, the ultrasonic attenuation spectrum of the ionic ethylammonium nitrate--n-octanol mixture of critical composition has been measured at various reduced temperatures (1.5 x 10(-4)<or= t <or=5.7 x 10(-2)). Using static and dynamic light scattering data as well as viscosity and heat capacity data from the literature, the experimental spectra have been evaluated to yield the scaling function, with the background contribution to the spectra as the only adjustable parameter. Agreement, within the limits of experimental error, of the measured scaling function with that of the nonionic binary system ethanol--dodecane and with the theoretical predictions of the Bhattacharjee-Ferrell dynamic scaling model is found. The amplitude of the fluctuation correlation length xi(o) (=0.47 nm) and the amount of the coupling constant /g/ (=1.3) are rather high as compared to nonionic binary critical mixtures. The amplitude of the relaxation rate of order parameter fluctuations Gamma(o)(=2.6 x 10(8) s(-1)) exhibits an unusual small value, likely to the most part a reflection of the high viscosity and thus small diffusion coefficient of the ionic liquid.
Mirzaev
S Z
SZ
Heat Physics Department, Uzbekistan Academy of Sciences, Katartal 28, Tashkent, 700135 Uzbekistan.
Kaatze
U
U