title: Effect of solvation on hole motion in DNA.
abstract: An excess charge on a DNA chain in solution interacts with polar solvent molecules and mobile counterions. We give the first theoretical estimate of the resulting hole self-localization energy and calculate the corresponding contribution to hole mobility on a DNA stack consisting of a single base pair repeated.
authors.affiliation: Department of Chemistry, University of Rochester, Rochester, NY 14627, USA. basko@chem.rochester.edu
authors.forename: D M
authors.initials: DM
authors.lastname: Basko
authors.forename: E M
authors.initials: EM
authors.lastname: Conwell
mesh_terms: D004247:DNA / Q000737:chemistry*; D008956:Models, Chemical; D016012:Poisson Distribution; D012996:Solutions / Q000737:chemistry; D055672:Static Electricity
chemical_list: D012996:Solutions; D004247:DNA