title: Intramolecular allyl transfer reaction from allyl ether to aldehyde groups: experimental and theoretical studies.
abstract: The intramolecular transfer of the allyl group of functionalized allyl aryl ethers to an aldehyde group in the presence of Ni0 complexes was studied from chemical, electrochemical and theoretical points of view. The chemical reaction involves the addition of Ni0 to the allyl ether followed by stoichiometric allylation. The electrochemical process is catalytic in nickel and involves the reduction of intermediate eta3-allylnickel(II) complexes.
authors.affiliation: Laboratoire Arĵmes Synthèse Interactions, Faculté des Sciences, Université de Nice-Sophia Antipolis, France.
authors.forename: Delphine
authors.initials: D
authors.lastname: Franco
authors.forename: Karine
authors.initials: K
authors.lastname: Wenger
authors.forename: Serge
authors.initials: S
authors.lastname: Antonczak
authors.forename: Daniel
authors.initials: D
authors.lastname: Cabrol-Bass
authors.forename: Elisabet
authors.initials: E
authors.lastname: Duñach
authors.forename: Mercè
authors.initials: M
authors.lastname: Rocamora
authors.forename: Montserrat
authors.initials: M
authors.lastname: Gomez
authors.forename: Guillermo
authors.initials: G
authors.lastname: Muller