title: Reaction of N,N-dimethylselenocarbamoyl chloride with nucleophiles. Preparation of diselenocarbamates, selenothiocarbamates, and selenoureas.
abstract: Reactions of N,N-dimethylselenocarbamoyl chloride prepared by using LiAlHSeH with nucleophiles such as lithium alkylselenolate, lithium alkylthiolate, and amines afford the corresponding diselenocarbamates, selenothiocarbamates, and selenoureas. The crystal structure of the Se-phenyl N,N-dimethyldiselenocarbamate was also determined by X-ray diffraction.
authors.affiliation: Department of Chemistry, Faculty of Engineering, Gifu University, Yanagido 1-1, Gifu 501-1193, Japan. koketsu@cc.gifu-u.ac.jp
authors.forename: Mamoru
authors.initials: M
authors.lastname: Koketsu
authors.forename: Yoshihisa
authors.initials: Y
authors.lastname: Fukuta
authors.forename: Hideharu
authors.initials: H
authors.lastname: Ishihara