Reaction of N,N-dimethylselenocarbamoyl chloride with nucleophiles. Preparation of diselenocarbamates, selenothiocarbamates, and selenoureas.
Reactions of N,N-dimethylselenocarbamoyl chloride prepared by using LiAlHSeH with nucleophiles such as lithium alkylselenolate, lithium alkylthiolate, and amines afford the corresponding diselenocarbamates, selenothiocarbamates, and selenoureas. The crystal structure of the Se-phenyl N,N-dimethyldiselenocarbamate was also determined by X-ray diffraction.
Koketsu
Mamoru
M
Department of Chemistry, Faculty of Engineering, Gifu University, Yanagido 1-1, Gifu 501-1193, Japan. koketsu@cc.gifu-u.ac.jp
Fukuta
Yoshihisa
Y
Ishihara
Hideharu
H