Synthetic applications of electrophilic fluorodesilylation.
Recently, with the appearance of electrophilic sources of fluorine including the commercially available N-F reagents, the concept of electrophilic fluorodesilylation has emerged as a new strategy to prepare a variety of fluorine containing compounds. This paper highlights how this concept has been applied to the preparation of a series of fluorinated molecules including fluoroaromatic compounds, fluoroalkenes, difluoroamides, difluoroalcohols, difluoroethers and alpha-fluorinated carbonyl derivatives.
Gouverneur
Véronique
V
University of Oxford, The Dyson Perrins Laboratory South Parks Road, OX1 3QY Oxford, UK. veronique.gouverneur@chem.ox.ac.uk
Greedy
Benjamin
B