Reactivity of stable trifluoroacetaldehyde hemiaminals. 2. Generation and synthetic potentialities of fluorinated iminiums.
Under Lewis acid activation, hemiaminals of trifluoroacetaldehyde and related (fluoroalkyl)aldehydes generate iminium species that can react with various nucleophiles to provide fluorinated amines.
Billard
Thierry
T
Laboratoire SERCOF (UMR CNRS 5622), Université Claude Bernard-Lyon 1, Bât. Chevreul, 43, Bd du 11 novembre 1918, 69622 Villeurbanne, France. billard@univ-lyon1.fr
Langlois
Bernard R
BR