Intramolecular allyl transfer reaction from allyl ether to aldehyde groups: experimental and theoretical studies.
The intramolecular transfer of the allyl group of functionalized allyl aryl ethers to an aldehyde group in the presence of Ni0 complexes was studied from chemical, electrochemical and theoretical points of view. The chemical reaction involves the addition of Ni0 to the allyl ether followed by stoichiometric allylation. The electrochemical process is catalytic in nickel and involves the reduction of intermediate eta3-allylnickel(II) complexes.
Franco
Delphine
D
Laboratoire Arĵmes Synthèse Interactions, Faculté des Sciences, Université de Nice-Sophia Antipolis, France.
Wenger
Karine
K
Antonczak
Serge
S
Cabrol-Bass
Daniel
D
Duñach
Elisabet
E
Rocamora
Mercè
M
Gomez
Montserrat
M
Muller
Guillermo
G