Confirmation of the structure of tetra-O-(tert-butyldimethylsilyl)-D-glucono-1,4-lactone formed by silylation of D-glucono-1,5-lactone.
The structure of tetra-O-(tert-butyldimethylsilyl)-D-glucono-1,4-lactone made by the silylation of D-glucono-1,5-lactone has been confirmed by single-crystal X-ray analysis.
Singh
Janak
J
Process Research and Development, Bristol-Myers Squibb Pharmaceutical Research Institute, Princeton, NJ 08543, USA. janak.singh@bms.com
DiMarco
John
J
Kissick
Thomas P
TP
Deshpande
Prashant
P
Gougoutas
Jack Z
JZ
D002236:Carbohydrate Conformation; D018360:Crystallography, X-Ray / Q000379:methods; D005942:Gluconates / Q000737:chemistry*; D007783:Lactones; D008958:Models, Molecular; D012828:Silicones / Q000737:chemistry*; D014961:X-Ray Diffraction / Q000379:methods
D005942:Gluconates; D007783:Lactones; D012828:Silicones; C010730:beta-glucono-1,5-lactone