title: Turn formation initiated by a bissulfoximine motif: synthesis and structural investigation.
abstract: [reaction: see text] Bissulfoximines containing heterochiral SulfCO-SulfCO units may be used as molecular templates, which induce U-shaped conformations in peptidelike structures. The synthesis of such molecules has been investigated, and the structural requirements of this new turn motif have been identified.
authors.affiliation: Institut für Organische Chemie der RWTH Aachen, Professor-Pirlet-Str.1, D-52056 Aachen, Germany. carsten.bolm@oc.rwth-aachen.de
authors.forename: Carsten
authors.initials: C
authors.lastname: Bolm
authors.forename: Dirk
authors.initials: D
authors.lastname: Müller
authors.forename: Christian P R
authors.initials: CP
authors.lastname: Hackenberger
mesh_terms: D007097:Imines / Q000138:chemical synthesis* / Q000737:chemistry; D008968:Molecular Conformation
chemical_list: D007097:Imines