title: Adsorption of p-chlorophenol from aqueous solutions on bentonite and perlite.
abstract: The adsorption of p-chlorophenol (p-CP) from aqueous solutions on bentonite and perlite was studied. These materials are available in large quantities in Bulgaria. Model solutions of various concentrations (1-50 mgdm(-3)) were shaken with certain amounts of adsorbent to determine the adsorption capacity of p-CP on bentonite and perlite as well. The influence of several individual variables (initial adsorbate concentration, adsorbent mass) on the rate of uptake of the studied compound on the adsorbent was determined by carrying out experiments at different contact times using the batch adsorber vessel designed according to the standard tank configuration. Rapid adsorption was observed 20-30 min after the beginning for every experiment. After that, the concentration of p-CP in the liquid phase remained constant. The adsorption equilibrium of p-CP on bentonite and perlite was described by the Langmuir and the Freundlich models. A higher adsorption capacity was observed for bentonite (10.63 mgg(-1)) compared to that for perlite (5.84 mgg(-1)).
authors.affiliation: Department of Chemical Engineering, University of Chemical Technology and Metallurgy, 8 Kliment Ohridski Blvd., Sofia 1756, Bulgaria. bogdana@uctm.edu
authors.forename: Bogdana
authors.initials: B
authors.lastname: Koumanova
authors.forename: P
authors.initials: P
authors.lastname: Peeva-Antova
mesh_terms: D000327:Adsorption; D000537:Aluminum Oxide; D001546:Bentonite; D002733:Chlorophenols / Q000302:isolation & purification*; D012822:Silicon Dioxide
chemical_list: D002733:Chlorophenols; C003076:Perlite; D001546:Bentonite; D012822:Silicon Dioxide; D000537:Aluminum Oxide