title: Double catholyte electrochemical approach for preparing ferrate-aluminum: a compound oxidant-coagulant for water purification.
abstract: Ferrate is an excellent water treatment agent for its multi-functions in oxidation, disinfection, coagulation and adsorption, but its coagulation ability depends on its dosage and is after its oxidation. This paper focuses on preparing a new kind of ferrate combined with alum to enhance its coagulation function for water purification. An effective electrolysis reactor was designed and employed in the test. Some key parameters in the process of electrolysis concerning the preparation efficiency, such as the current density, temperature and alkalinity were also investigated. The proper conditions for ferrate-alum preparation were determined. Under the condition of 5 V given voltage, 6 h electrolyzing interval, below 2% alum concentration (in weight), a combined liquid ferrate-alum products was successfully prepared, which contained 0.0294 mol/L FeO4(2-) and 0.0302 mol/L total soluble ferron with 2% Al2O3. There was no insoluble ferron produced by controlling an optimum electrochemical condition.
authors.affiliation: State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China. jhqu@mail.rcees.ac.cn
authors.forename: Jiu-hui
authors.initials: JH
authors.lastname: Qu
authors.forename: Peng-ju
authors.initials: PJ
authors.lastname: Lei
authors.forename: Hui-juan
authors.initials: HJ
authors.lastname: Liu
mesh_terms: D000534:Alum Compounds / Q000737:chemistry; D004563:Electrochemistry; D007501:Iron / Q000737:chemistry*; D010084:Oxidation-Reduction; D018508:Water Purification / Q000379:methods*
chemical_list: D000534:Alum Compounds; C017311:ferrate ion; C041524:aluminum sulfate; D007501:Iron