A substrate-unspecified glycosylation reaction promoted by copper(II) trifluoromethanesulfonate in benzotrifluoride.
A glycosylation reaction induced by copper(II) trifluoromethanesulfonate is described. Using benzotrifluoride as the reaction solvent, five kinds of glycosyl donors, a glucosyl chloride, a fluoride, a trichloroacetimidate, a 1-O-acetyl compound, and a lactol were activated to give the corresponding glucosides.
Yamada
Hidetoshi
H
School of Science, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, Japan. hidetosh@kwansei.ac.jp
Hayashi
Tomomi
T
D005464:Fluorobenzenes / Q000737:chemistry*; D005960:Glucosides / Q000138:chemical synthesis* / Q000737:chemistry; D006031:Glycosylation; D009942:Organometallic Compounds / Q000737:chemistry*
D005464:Fluorobenzenes; D005960:Glucosides; D009942:Organometallic Compounds; C464593:copper(II) trifluoromethanesulfonate; C044697:benzotrifluoride