Preparation, properties, and synthetic potentials of novel boronates in a fluorous version (fluorous boronates).
[reaction: see text] A series of boronic acids were attached to a fluorous tag by esterification. Functional transformations of these boronates together with the fluorous Suzuki coupling reaction illustrated their usefulness in fluorous-phase techniques.
Chen
Dajun
D
Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China.
Qing
Feng-ling
FL
Huang
Yangen
Y