title: Chiral 2,2'-bipyridine-type N-monoxides as organocatalysts in the enantioselective allylation of aldehydes with allyltrichlorosilane.
abstract: [reaction: see text] The Sakurai-Hosomi-type allylation of aromatic and heteroaromatic aldehydes can be catalyzed by the new heterobidenate bipyridine monoxide PINDOX with high enantioselectivities. The sterochemical outcome is mainly controlled by the axial chirality in PINDOX, which in turn is determined by the annulated terpene units.
authors.affiliation: Department of Chemistry, University of Glasgow, Glasgow G12 8QQ, UK. amalkov@chem.gla.ac.uk
authors.forename: Andrei V
authors.initials: AV
authors.lastname: Malkov
authors.forename: Monica
authors.initials: M
authors.lastname: Orsini
authors.forename: Daniele
authors.initials: D
authors.lastname: Pernazza
authors.forename: Ken W
authors.initials: KW
authors.lastname: Muir
authors.forename: Vratislav
authors.initials: V
authors.lastname: Langer
authors.forename: Premji
authors.initials: P
authors.lastname: Meghani
authors.forename: Pavel
authors.initials: P
authors.lastname: Kocovský