title: TpPt(IV)Me(H)(2) forms a sigma-CH(4) complex that is kinetically resistant to methane liberation.
abstract: Complex 1 undergoes H/D scrambling in methanol without concomitant liberation of either methane or dihydrogen (k(H)/k(D) = 0.76, 55 degrees C). The measured isotope effect was proposed to directly relate to the initial reductive coupling step in reductive elimination reactions.
authors.affiliation: Department of Molecular Biology, Skaggs Institute for Chemical Biology, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, CA 92037, USA.
authors.forename: H Christine
authors.initials: HC
authors.lastname: Lo
authors.forename: Ariel
authors.initials: A
authors.lastname: Haskel
authors.forename: Moshe
authors.initials: M
authors.lastname: Kapon
authors.forename: Ehud
authors.initials: E
authors.lastname: Keinan