Tetrapotassium nonastannide, K(4)Sn(9).
In K(4)Sn(9), which crystallizes with a new structure type, the Sn atoms form isolated Wade nido-[Sn(9)]4- clusters of approximate C(4v) symmetry (monocapped square antiprisms), with Sn-Sn distances ranging from 2.9264 (9) to 3.348 (1) A. The cluster anions are separated by K+ cations and are in a hexagonal close-packed arrangement.
Hoch
Constantin
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Institut für Anorganische und Analytische Chemie, Universität Freiburg, Albertstrasse 21, Germany.
Wendorff
Marco
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Röhr
Caroline
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