Low-activation solid-state syntheses by reducing transport lengths to atomic scales as demonstrated by case studies on AgNO(3) and AgO.
We have studied solid-state reactions of educt mixtures of elements in an atomic dispersion. The reduced transport distances allow for extremely low activated reactions. This has been demonstrated by case studies on AgNO3 and AgO, which form and crystallize from the atoms below room temperature.
Fischer
Dieter
D
Max-Planck-Institut of Solid State Research, Heisenbergstrasse 1, 70569 Stuttgart, Germany.
Jansen
Martin
M