Vibrational spectroscopic study on pyrimidine metal(II) tetracyanometalate complexes.
The results of an infrared and Raman spectroscopic study are reported for seven new metal(II) pyrimidine tetracyanonickelate complexes, M(pyr)2Ni(CN)4 [where (pyr) = pyrimidine; M = Mn, Fe, Co, Zn, Ni, Cu or Cd] and an IR spectroscopic study is presented for new cadmium pyrimidine tetracyanometalate complex, Cd(pyr)2Cd(CN)4. The spectral data suggest that the first seven compounds belong to the Hofmann-type and the last compound belongs to the Hofmann-Td-type of complexes.
Bahat
Mehmet
M
Fen-Edebiyat Fakultesi, Gazi Universitesi, Fizik Bölümü, Ankara, Turkey.
Yurdakul
Senay
S
D055592:Biophysical Phenomena; D001703:Biophysics; D002621:Chemistry / Q000379:methods; D003486:Cyanides / Q000737:chemistry*; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D011743:Pyrimidines / Q000737:chemistry*; D013053:Spectrophotometry / Q000379:methods*
D003486:Cyanides; D009942:Organometallic Compounds; D011743:Pyrimidines; C030986:pyrimidine