Bis(3,5-dimethylpyrazole-kappaN2)silver(I) nitrate.
The two independent bis(3,5-dimethylpyrazole)silver(I) cations in crystalline [Ag(C(5)H(7)N(2))(2)]NO(3) display N-Ag-N angles of 175.51 (14) and 174.44 (13) degrees, and an average Ag-N distance of 2.124 (5) A. The nitrate anion is situated between [Ag(C(5)H(7)N(2))(2)]+ units and interacts via hydrogen bonds with the NH groups. The two 3,5-dimethylpyrazole ligands are trans about the silver center. Only a small deviation from linearity is observed in the coordination around silver.
Mohamed
Ahmed A
AA
Laboratory for Molecular Structure and Bonding, Department of Chemistry, Texas A&M University, PO Box 30012, College Station 77842-3012, USA.
Fackler
John P
JP