3,3-Disubstituted allyl alcohols from palladium-catalyzed coupling of hydroaluminated propargyl alcohols with aryl iodides.
3,3-Disubstituted prop-2-en-1-ols 4 were synthesized with a high degree of stereoselectivity from 3-substituted prop-2-yn-1-ols 1 via hydroalumination and subsequent Pd-catalyzed coupling with aryl iodides 3.
Havránek
Miroslav
M
Department of Organic Chemistry, Prague Institute of Chemical Technology, Technická 5, 166 28 Prague 6, Czech Republic.
Dvorák
Dalimil
D