Bis(isoquinoline-1-carboxylato-kappa2O,N)(1,10-phenanthroline-kappa2N,N')zinc(II) dimethylformamide sesquisolvate.
The asymmetric unit of the title compound, [Zn(C(10)H(6)NO(2))(2)(C(12)H(8)N(2))] x 1.5C(3)H(7)NO, contains one monomeric zinc complex and 1.5 disordered dimethylformamide solvate molecules. The Zn atom is coordinated to one 1,10-phenanthroline ligand and to two isoquinolinecarboxylate anions (IQC-) via their N and O atoms. The complex exhibits a distorted octahedral geometry around the Zn(II) atom, with the apical positions occupied by the O atoms of the IQC- ligands. The Zn atom lies 0.049 (1) A out of the basal plane. The crystal packing is characterized by several hydrogen bonds.
Daran
Jean Claude
JC
Laboratoire de Chimie de Coordination, UPR 8241 CNRS, 205 route de Narbonne, 31077 Toulouse CEDEX 04, France.
Lemoine
Pascale
P
Viossat
Bernard
B