title: Wet oxidative regeneration of activated carbon loaded with reactive dye.
abstract: Wet Oxidative Regeneration (WOR) of powdered activated carbon (PAC) and granular activated carbon (GAC) loaded with the reactive dyes, namely chemictive brilliant blue R and cibacron turquoise blue G, was studied. Attempts were made to regenerate the loaded carbons designated now as spent carbon. A slurry (10% w/v) of spent carbon in distilled water was oxidized by wet oxidation in the temperature range of 150-250 degrees C using oxygen partial pressures between 0.69-1.38 MPa in an 1 1 SS 316 autoclave. The percent regeneration was determined from a ratio, X(RC)/X(VC), corresponding to an equilibrium adsorption capacity of regenerated carbon/equilibrium adsorption capacity of virgin carbon from an initial adsorption period of 3 h. It was observed that the regeneration mainly occurred due to the oxidation of the adsorbates taking place on the surface of carbon. It was possible to regenerate the spent GAC and PAC to the extent of more than 98% (approximately X(RC)/X(VC) > 0.98) by wet oxidation. After four consecutive cycles of adsorption and regeneration using the same stocks of GAC, carbon weight loss observed at 200 degrees C was about 40%. SEM studies of the regenerated carbon showed widening of the pores and loss of structure between the adjacent pores as compared with the virgin carbon. PAC was found to be more suitable as compared with GAC for the adsorption and wet oxidative regeneration processes to treat the aqueous solution containing lower concentration of unhydrolyzed reactive dye. The suitability of wet oxidative regeneration is demonstrated at a bench scale to treat the synthetic reactive dye solution.
authors.affiliation: Chemical Engineering Division, Department of Chemical Technology, University of Mumbai, Matunga, India.
authors.forename: R V
authors.initials: RV
authors.lastname: Shende
authors.forename: V V
authors.initials: VV
authors.lastname: Mahajani
mesh_terms: D000327:Adsorption; D002244:Carbon / Q000737:chemistry*; D004396:Coloring Agents / Q000737:chemistry*; D010084:Oxidation-Reduction; D013783:Textile Industry; D018505:Waste Management
chemical_list: D004396:Coloring Agents; D002244:Carbon