Triaqua(2,2'-bipyridine-kappa2N,N')(nitrato-kappaO)manganese(II) nitrate.
The crystal structure of the title compound, [Mn(NO(3))(C(10)H(8)N(2))(H(2)O)(3)]NO(3), contains a monomeric [Mn(NO(3))(bpy)(H(2)O)(3)]+ cation (bpy is 2,2'-bipyridine) and a nitrate anion. The Mn(II) ion is coordinated by one chelating bpy [Mn-N 2.241 (3) and 2.259 (3) A], three water molecules [Mn-O 2.120 (3)-2.188 (3) A] and a nitrate ligand [Mn-O 2.228 (2) A] in a distorted octahedral geometry. There are O.H-O hydrogen-bonding interactions between the ligated water molecules and the ligated and unligated nitrate anions, resulting in double columns of stacked cations and anions.
Zhang
Xiaofeng
X
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou, Fujian 350002, People's Republic of China.
Huang
Deguang
D
Wang
Wenguo
W
Chen
Changneng
C
Liu
Qiutian
Q
D018360:Crystallography, X-Ray; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D045322:Photosynthetic Reaction Center Complex Proteins / Q000378:metabolism; D010944:Plants / Q000378:metabolism*
D009942:Organometallic Compounds; D045322:Photosynthetic Reaction Center Complex Proteins; C459719:triaqua(2,2'-bipyridine-N,N')(nitrato-O)manganese(II) nitrate