Detection of hydrogen peroxide at mesoporous platinum microelectrodes.
Mesoporous (H(I)-ePt) platinum microelectrodes electrodeposited from the hexagonal (H(I)) lyotropic liquid crystalline phase are shown to be excellent amperometric sensors for the detection of hydrogen peroxide over a wide range of concentrations. Good reproducibility, high precision, and accuracy of measurements are demonstrated. Mesoporous microelectrodes retain the high rates of mass transport typical of conventional microelectrodes, and their high real surface area greatly enhances their catalytic activity. This unique combination of properties overcomes the limitations of previous amperometric hydrogen peroxide sensors and yields outstanding qualitative and quantitative results.
Evans
Stuart A G
SA
Department of Chemistry, The University of Southampton, UK.
Elliott
Joanne M
JM
Andrews
Lynn M
LM
Bartlett
Philip N
PN
Doyle
Peter J
PJ
Denuault
Guy
G