CsMoO2(HO3P-CH2-PO3): a new metallodiphosphonate with a hybrid framework.
Crystals of caesium molybdenomethylenediphosphonate, [CsMoO(2)(CH(3)O(6)P(2))], were hydrothermally synthesized at 473 K. The monoclinic structure, as determined from single-crystal X-ray diffraction, is two-dimensional and consists of stacked mixed layers of corner-sharing tetrahedral diphosphonate groups and MoO(6) octahedra, between which Cs+ cations are intercalated.
Barthelet
Karin
K
Institut Lavoisier, UMR CNRS C 8637, Université de Versailles, Saint-Quentin-en-Yvelines, 45 Avenue des Etats Unis, 78035 Versailles Cedex, France.
Riou
Didier
D
Férey
Gerard
G