title: CsMoO2(HO3P-CH2-PO3): a new metallodiphosphonate with a hybrid framework.
abstract: Crystals of caesium molybdenomethylenediphosphonate, [CsMoO(2)(CH(3)O(6)P(2))], were hydrothermally synthesized at 473 K. The monoclinic structure, as determined from single-crystal X-ray diffraction, is two-dimensional and consists of stacked mixed layers of corner-sharing tetrahedral diphosphonate groups and MoO(6) octahedra, between which Cs+ cations are intercalated.
authors.affiliation: Institut Lavoisier, UMR CNRS C 8637, Université de Versailles, Saint-Quentin-en-Yvelines, 45 Avenue des Etats Unis, 78035 Versailles Cedex, France.
authors.forename: Karin
authors.initials: K
authors.lastname: Barthelet
authors.forename: Didier
authors.initials: D
authors.lastname: Riou
authors.forename: Gerard
authors.initials: G
authors.lastname: Férey