title: Reversing the stereoselectivity of the intermolecular Pauson-Khand reaction: formation of endo-fused norbornadiene adducts.
abstract: [reaction: see text] An unprecedented endo-selective and regioselective intermolecular Pauson-Khand reaction takes place when heterobimetallic (Mo-Co) complexes derived from N-(2-alkynoyl)oxazolidinones or sultams are heated in the presence of norbornadiene.
authors.affiliation: Unitat de Recerca en Síntesi Asimètrica, Departament de Química Orgànica, Facultat de Química, Universitat de Barcelona, Martí i Franquès, 1-11, 08028 Barcelona, Spain.
authors.forename: Ramon
authors.initials: R
authors.lastname: Rios
authors.forename: Miquel A
authors.initials: MA
authors.lastname: Pericàs
authors.forename: Albert
authors.initials: A
authors.lastname: Moyano
authors.forename: Miguel A
authors.initials: MA
authors.lastname: Maestro
authors.forename: José
authors.initials: J
authors.lastname: Mahía