Layered (ethylenediamine-kappa2N,N')cobalt(II) molybdate(VI).
The structure of poly[[(ethylenediamine-kappa2N,N')cobalt(II)]-mu-tetraoxomolybdato(VI)], [Co(C(2)H(8)N(2))MoO(4)](n) or [CoMoO(4)(C(2)H(8)N(2))](n), is composed of puckered layers constructed from MoO(4) tetrahedra and CoN(2)O(4) octahedra, with the ethylenediamine ligand coordinated to the Co atom in a cis fashion. Each pair of cobalt sites forms a binuclear edge-sharing unit through a (Co(2)O(2)) interaction. The binuclear octahedral units are interconnected through the bridging MoO(4) tetrahedra into a layer structure.
Lin
Bi-Zhou
BZ
Institute of Material Physical Chemistry, Huaqiao University, Quanzhou 362011, People's Republic of China. bzlin@hqu.edu.cn