title: Quantitative trace element analysis of individual fly ash particles by means of X-ray microfluorescence.
abstract: A new quantification procedure was developed for the evaluation of X-ray microfluorescence (XRF) data sets obtained from individual particles, based on iterative Monte Carlo (MC) simulation. Combined with the high sensitivity of synchrotron radiation-induced XRF spectroscopy, the method was used to obtain quantitative information down to trace-level concentrations from micrometer-sized particulate matter. The detailed XRF simulation model was validated by comparison of calculated and experimental XRF spectra obtained for glass microsphere standards, resulting in uncertainties in the range of 3-10% for the calculated elemental sensitivities. The simulation model was applied for the quantitative analysis of X-ray tube and synchrotron radiation-induced scanning micro-XRF spectra of individual coal and wood fly ash particles originating from different Hungarian power plants. By measuring the same particles by both methods the major, minor, and trace element compositions of the particles were determined. The uncertainty of the MC based quantitative analysis scheme is estimated to be in the range of 5-30%.
authors.affiliation: Department of Chemistry, University of Antwerp (UIA), Belgium.
authors.forename: L
authors.initials: L
authors.lastname: Vincze
authors.forename: A
authors.initials: A
authors.lastname: Somogyi
authors.forename: J
authors.initials: J
authors.lastname: Osan
authors.forename: B
authors.initials: B
authors.lastname: Vekemans
authors.forename: S
authors.initials: S
authors.lastname: Torok
authors.forename: K
authors.initials: K
authors.lastname: Janssens
authors.forename: F
authors.initials: F
authors.lastname: Adams
mesh_terms: D000395:Air Pollutants, Occupational / Q000032:analysis*; D000465:Algorithms; D002244:Carbon / Q000032:analysis*; D060729:Coal Ash; D009010:Monte Carlo Method; D052638:Particulate Matter; D015203:Reproducibility of Results; D013052:Spectrometry, X-Ray Emission
chemical_list: D000395:Air Pollutants, Occupational; D060729:Coal Ash; D052638:Particulate Matter; D002244:Carbon