title: Vibrational spectroscopic study on pyrimidine metal(II) tetracyanometalate complexes.
abstract: The results of an infrared and Raman spectroscopic study are reported for seven new metal(II) pyrimidine tetracyanonickelate complexes, M(pyr)2Ni(CN)4 [where (pyr) = pyrimidine; M = Mn, Fe, Co, Zn, Ni, Cu or Cd] and an IR spectroscopic study is presented for new cadmium pyrimidine tetracyanometalate complex, Cd(pyr)2Cd(CN)4. The spectral data suggest that the first seven compounds belong to the Hofmann-type and the last compound belongs to the Hofmann-Td-type of complexes.
authors.affiliation: Fen-Edebiyat Fakultesi, Gazi Universitesi, Fizik Bölümü, Ankara, Turkey.
authors.forename: Mehmet
authors.initials: M
authors.lastname: Bahat
authors.forename: Senay
authors.initials: S
authors.lastname: Yurdakul
mesh_terms: D055592:Biophysical Phenomena; D001703:Biophysics; D002621:Chemistry / Q000379:methods; D003486:Cyanides / Q000737:chemistry*; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D011743:Pyrimidines / Q000737:chemistry*; D013053:Spectrophotometry / Q000379:methods*
chemical_list: D003486:Cyanides; D009942:Organometallic Compounds; D011743:Pyrimidines; C030986:pyrimidine