Determination of hyperfine tensor components from nuclear frequencies at canonical orientations of the g-tensor.
The analytical procedure for the determination of all components of the symmetric hyperfine tensor of the I=1/2 nucleus in the g-tensor coordinate system is described, assuming that nuclear frequencies corresponding to the principal directions of the g-tensor and exact values of the external magnetic field (or nuclear Zeeman frequencies) are experimentally available.
Shubin
Alexander A
AA
Boreskov Institute of Catalysis, Russian Academy of Sciences, Novosibirsk 630090, Russia.
Dikanov
Sergei A
SA
D016880:Anisotropy; D055598:Chemical Phenomena; D002627:Chemistry, Physical; D004578:Electron Spin Resonance Spectroscopy / Q000379:methods*; D008433:Mathematics