A new drimane from the heartwood of the Japanese yew, Taxus cuspidata.
A new drimane sesquiterpenoid was isolated from the heartwood of the Japanese yew, Taxus cuspidata Sieb. et Zucc. Its structure was established as 1beta-acetoxyisodrimeninol (1beta-acetoxy-11,12-epoxy-7-drimen-11-ol, 1). This compound was gradually oxidized to give y-lactone (1beta-acetoxy-8-drimeno-11,12-lactone, 4).
Kiyota
Hiromasa
H
Division of Life Science, Graduate School of Agricultural Science, Tohoku University, Sendai, Japan. kiyota@biochem.tohoku.ac.jp
Shi
Qing-Wen
QW
Oritani
Takayuki
T
D002853:Chromatography, Liquid; D007564:Japan; D007783:Lactones / Q000737:chemistry / Q000302:isolation & purification; D008968:Molecular Conformation; D015394:Molecular Structure; D019906:Nuclear Magnetic Resonance, Biomolecular; D010946:Plants, Medicinal / Q000737:chemistry*; D012717:Sesquiterpenes / Q000737:chemistry / Q000302:isolation & purification*; D021241:Spectrometry, Mass, Electrospray Ionization; D013055:Spectrophotometry, Infrared; D020946:Taxus / Q000737:chemistry*
C456090:1beta-acetoxy-8-drimeno-11,12-lactone; C456089:1beta-acetoxyisodrimeninol; D007783:Lactones; D012717:Sesquiterpenes