epi-Cubebanes from Solidago canadensis.
GC-MS of the essential oil prepared by hydrodistillation of the green parts of a specimen of Solidago canadensis collected near Katowice, Poland, revealed two new sesquiterpene hydrocarbons. Their EI mass spectra resembled the mass spectrum of beta-ylangene (1) but the retention indices of the new compounds differed markedly from this known compound. After isolation of the new compounds by preparative GC their investigation by one- and two-dimensional NMR techniques resulted in the identification of 6-epi-alpha-cubebene (2) (minor constituent, 1.5%) and 6-epi-beta-cubebene (3) (major constituent, 20.5%).
Kasali
Adeleke A
AA
Institut für Organische Chemie, Universität Hamburg, Martin-Luther-King-Platz 6, D-20146, Hamburg, Germany.
Ekundayo
Olusegun
O
Paul
Claudia
C
König
Wilfried A
WA
D019659:Asteraceae / Q000737:chemistry*; D008401:Gas Chromatography-Mass Spectrometry; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D009822:Oils, Volatile / Q000737:chemistry; D012717:Sesquiterpenes / Q000032:analysis / Q000737:chemistry* / Q000302:isolation & purification
C465314:6-cubebene; D009822:Oils, Volatile; D012717:Sesquiterpenes