title: Synthesis of trifluoromethyl ketones using polymer-supported reagents.
abstract: A two step synthesis of trifluoromethyl ketones from aldehydes is reported. A combination of polymer-supported reagents and sequestering agents were employed to effect the transformation without the need for chromatographic purification.
authors.affiliation: Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, UK.
authors.forename: I R
authors.initials: IR
authors.lastname: Baxendale
authors.forename: S V
authors.initials: SV
authors.lastname: Ley
authors.forename: W
authors.initials: W
authors.lastname: Lumeras
authors.forename: M
authors.initials: M
authors.lastname: Nesi
mesh_terms: D000447:Aldehydes / Q000737:chemistry; D020650:Combinatorial Chemistry Techniques; D006845:Hydrocarbons, Fluorinated / Q000737:chemistry; D007202:Indicators and Reagents; D007475:Ion Exchange Resins; D007659:Ketones / Q000737:chemistry; D010084:Oxidation-Reduction; D011108:Polymers / Q000737:chemistry*
chemical_list: D000447:Aldehydes; D006845:Hydrocarbons, Fluorinated; D007202:Indicators and Reagents; D007475:Ion Exchange Resins; D007659:Ketones; D011108:Polymers