Organic compounds in meteorites.
Recent studies of carbonaceous chondrites provide evidence that certain organic compounds are indigenous and the result of an abiotic, chemical synthesis. The results of several investigators have established the presence of amino acids and precursors, mono- and dicarboxylic acids, N-heterocycles, and hydrocarbons as well as other compounds. For example, studies of the Murchison and Murray meteorites have revealed the presence of at least 40 amino acids with nearly equal abundances of D and L isomers. The population consists of both protein and non-protein amino acids including a wide variety of linear, cyclic, and polyfunctional types. Results show a trend of decreasing concentration with increasing carbon number, with the most abundant being glycine (41 n Moles/g). The monocarboxylic acids are more abundant (1.83 micro Moles propanoic acid/g Murchison), with hydrocarbons present in even greater abundance. In addition, quantification of the monocarboxylic acids shows a nearly equal distribution of straight and branched chain isomers. These and other results to be reviewed provide persuasive support for the theory of chemical evolution and provide the only natural evidence for the protobiological subset of molecules from which life on earth may have arisen.
Lawless
J G
JG
Ames Research Center, NASA, Moffett Field, California, USA.
D000596:Amino Acids / Q000032:analysis* / Q000138:chemical synthesis / Q000737:chemistry; D002244:Carbon / Q000737:chemistry; D002264:Carboxylic Acids / Q000737:chemistry; D019418:Evolution, Chemical; D006880:Hydroxy Acids / Q000737:chemistry; D019110:Meteoroids
D000596:Amino Acids; D002264:Carboxylic Acids; D006880:Hydroxy Acids; D002244:Carbon