Self-similar renormalization approach to barrier crossing processes.
An algebraic self-similar renormalization method developed recently for summation of divergent field-theoretical series is applied to the thermally activated escape of a Brownian particle over an arbitrarily shaped barrier. Based on the Mel'nikov-Meshkov result for the underdamped Brownian motion and the inverse friction expansion of the underlying Fokker-Planck equation for strong friction, an overall rate formula is constructed. This formula agrees in the weak friction regime with the rate obtained from a diffusion equation in energy variables and, in the limiting case of strong friction with the rate following from a Smoluchowski equation. Its validity is tested for Brownian motion in bistable potentials with parabolic, cusped, and quartic barriers of different heights. The proposed formula is found to give a reasonable description of activated rate processes even though the barrier is quite low. Our comparison also includes results from various different crossover theories. In most of the cases considered the present formula is in considerably better agreement with exact numerical rates than the other interpolation formulas.
Drozdov
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Department of Applied Physics and Chemistry, University of Electro-Communications, Chofu, Tokyo 182-8585.
Hayashi
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