title: A new approach toward the stereoselective synthesis of novel benzo[b][1,5]oxazepines using MCM-41(H) zeolite.
abstract: Facile procedures have been developed for the stereoselective synthesis of novel benzo[b][1,5]oxazepines 4a-f by the condensation reaction between 2-amino phenol 2 and tert-butyl(4R)-2,2-dimethyl-4-(3-oxo-3-phenyl-1-propynyl)-1,3-oxazolane-3-carboxylate 3a-f with MCM-41(H) zeolite in acetonitrile.
authors.affiliation: Division of Organic Chemistry-II, Indian Institute of Chemical Technology, Hyderabad.
authors.forename: L
authors.initials: L
authors.lastname: Nagarapu
authors.forename: N
authors.initials: N
authors.lastname: Ravirala
authors.forename: N
authors.initials: N
authors.lastname: Venkateswara Rao
mesh_terms: D008401:Gas Chromatography-Mass Spectrometry; D006801:Humans; D009682:Magnetic Resonance Spectroscopy; D010077:Oxazepines / Q000138:chemical synthesis*; D013055:Spectrophotometry, Infrared; D017641:Zeolites / Q000737:chemistry*
chemical_list: D010077:Oxazepines; D017641:Zeolites