Hydrogen bonding and perhalometallate ions: a supramolecular synthetic strategy for new inorganic materials.
A synthetic strategy for constructing ionic hydrogen-bonded materials by combining perhalometallate anions with cations able to serve as hydrogen bond donors is presented. The approach is based on identification of well defined hydrogen bond acceptor sites on the anions by a combination of experimental and theoretical approaches. Selective population of these sites by hydrogen bond donors has the potential to afford organized crystalline arrays in one, two, or three dimensions. The approach is applicable to a wide range of metal centers.
Brammer
Lee
L
Department of Chemistry, University of Sheffield, Sheffield S3 7HF, United Kingdom. lee.bramer@sheffield.ac.uk
Swearingen
John K
JK
Bruton
Eric A
EA
Sherwood
Paul
P
D001665:Binding Sites; D003460:Crystallization; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D007477:Ions; D008024:Ligands; D046911:Macromolecular Substances; D008670:Metals / Q000737:chemistry; D008956:Models, Chemical; D008958:Models, Molecular
D007477:Ions; D008024:Ligands; D046911:Macromolecular Substances; D008670:Metals