Long-range electrostatic interactions between like-charged colloids: steric and confinement effects.
Within the framework of a modified Poisson-Boltzmann theory accounting for steric effects of microions, we prove analytically that the effective pair interactions between like-charge colloids immersed in a confined electrolyte are repulsive. Our approach encompasses and extends previously known results to the case of complete confinement, and further incorporates the finite size of the microions which is absent in the standard Poisson-Boltzmann theory.
Trizac
E
E
Laboratoire de Physique Théorique, Unité Mixte de Recherche UMR 8627 du CNRS, Bâtiment 210, Université de Paris-Sud, 91405 Orsay Cedex, France. Emmanuel.Trizac@th.u-psud.fr
Raimbault
J L
JL