Linear viscoelasticity of hard sphere colloidal crystals from resonance detected with dynamic light scattering.
We present measurements of the high-frequency shear modulus and dynamic viscosity for nonaqueous hard sphere colloidal crystals both in normal and microgravity environments. All experiments were performed on a multipurpose PHaSE instrument. For the rheological measurements, we detect the resonant response to oscillatory forcing with a dynamic light scattering scheme. The resonant response for colloidal crystals formed in normal and microgravity environments was similar, indicating that the bulk rheological properties are unaffected by differing crystal structure and crystallite size within the experimental error. Our high-frequency shear modulus seems reasonable, lying close to Frenkel and Ladd's predictions [Phys. Rev. Lett. 59, 1169 (1987)] for the static modulus of hard sphere crystals. Our high-frequency dynamic viscosity, on the other hand, seems high, exceeding Shikata and Pearson [J. Rheol. 38, 601 (1994)] and van der Werff et al.'s measurements [Phys. Rev. A 39, 795 (1989)] on the high-frequency dynamic viscosity for metastable fluids. The measurements are in the linear regime for the shear modulus but may not be for the dynamic viscosity as Frith et al. [Powder Technol. 51, 27 (1987)] report that the dynamic viscosity passes through a maximum with strain amplitude.
Phan
S E
SE
Department of Chemical Engineering, Princeton University, Princeton, New Jersey 08544, USA.
Li
M
M
Russel
W B
WB
Zhu
J
J
Chaikin
P M
PM
Lant
C T
CT
D003102:Colloids / Q000737:chemistry*; D003461:Crystallography / Q000295:instrumentation* / Q000379:methods*; D008027:Light; D008956:Models, Chemical; D004364:Pharmaceutical Preparations / Q000737:chemistry; D012212:Rheology / Q000295:instrumentation / Q000379:methods; D012542:Scattering, Radiation; D013314:Stress, Mechanical; D014732:Vibration; D014783:Viscosity
D003102:Colloids; D004364:Pharmaceutical Preparations