Determination of the structure of the organized phase of the block copolymer PEO-PPO-PEO in aqueous solutions under flow by small-angle neutron scattering.
The organization of Tetronic 908 (T908), a star copolymer of poly(ethylene oxide) (PEO) and poly(propylene oxide) (PPO) blocks, has been examined. Above critical conditions of temperature and concentration, the micelles formed by the aggregation of PPO units self-organize into particular structures. While small-angle neutron scattering (SANS) characterizations performed with static conditions demonstrate the organization of the medium, the experimental results do not allow us to make a distinction between simple cubic and body-centered-cubic structures. However, SANS measurements realized under shear produce characteristic diffraction diagrams. In this paper, an accurate methodology is proposed to identify, without ambiguity, the exact nature of the organized phase. Applied to our system, indexing of the diffraction pattern spots reveals that the organization of T908 is of bcc type oriented with the [111] direction parallel to the direction of flow, but the crystals can present any orientation about this direction. The lattice size has been estimated and compared to previous published results.
Perreur
Christelle
C
Laboratoire de Physico-Chimie des Polymères UMR 5067, Université de Pau et des Pays de l'Adour Avenue de l'Université, 64000 PAU, France.
Habas
Jean-Pierre
JP
François
Jeanne
J
Peyrelasse
Jean
J
Lapp
Alain
A
D015394:Molecular Structure; D009502:Neutrons; D011092:Polyethylene Glycols / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D011409:Propylene Glycols / Q000737:chemistry*; D012542:Scattering, Radiation; D012996:Solutions / Q000737:chemistry; D014961:X-Ray Diffraction / Q000379:methods
C116176:PEO-PPO-PEO; D011108:Polymers; D011409:Propylene Glycols; D012996:Solutions; D011092:Polyethylene Glycols