Flexible inner and outer coordination of Zn(II) N-confused porphyrin complex.
Tetra- and dinuclear Zn(II) N-confused porphyrin dimers (1, 2) and pyridine-coordinating Zn(II) monomer complex (3) were synthesized, and the ditopic, inner and outer coordination of Zn metal in the dimer complex (1) was demonstrated by X-ray analyses.
Furuta
Hiroyuki
H
Department of Chemistry, Graduate School of Science, Kyoto University, Kyoto 606-8502, Japan.
Ishizuka
Tomoya
T
Osuka
Atsuhiro
A