A simple and fast screening test to detect soils polluted by lead.
Lead pollution is an environmental priority. The evaluation of contaminated soils was often based on the results of the toxicity characteristic leaching procedure (TCLP) or the synthetic precipitation leaching procedure (SPLP). This paper presents a simple and fast screening test to detect soil contaminated by lead. The test is based on the chemistry of the stomach (Cl- concentration, pH 2, T = 37 degrees C) and simulates the incidental oral ingestion of soil by young children. The gastric juice simulation test (GJST) and the TCLP were applied to six size fractions from five soils. The GJST solubilized more Pb (up to 169 mg/l) than the TCLP especially for the smallest size fraction. Particle size had less effect on the TCLP. The percentage of lead released with the GJST, was most significant for the <63 microm size fraction and varied from 18 to 74% of the total lead content. Lead leached during the TCLP as a function of the total lead content showed poor linear regression coefficient (R) values for soils <250 microm. R values were significant for all size fractions with the GJST. The pH of approximately 5 in the TCLP limits the solubilization of lead in the small size fractions. The five soils exceeded the toxicity threshold of 10 microgPb/dl of blood for a significant fraction of children between 0 and 36 months using the EPA's IEUBK model (Integrated Exposure Uptake Biokinetic). But the TCLP did not detect lead contamination in two of these five soils. The GJST proved to be a better estimator of lead bioaccessibility in the gastrointestinal tract.
Mercier
Guy
G
INRS-Eau, Sainte-Foy, Québec, Canada. guy_mercier@inrs-eau.uquebec.ca
Duchesne
Josée
J
Carles-Gibergues
André
A
D001681:Biological Assay; D001682:Biological Availability; D002623:Chemistry Techniques, Analytical / Q000379:methods; D002675:Child, Preschool; D004064:Digestive System; D004784:Environmental Monitoring / Q000379:methods*; D005750:Gastric Juice / Q000737:chemistry*; D006801:Humans; D006863:Hydrogen-Ion Concentration; D007223:Infant; D007231:Infant, Newborn; D007408:Intestinal Absorption; D007854:Lead / Q000032:analysis*; D012680:Sensitivity and Specificity; D012989:Soil Pollutants / Q000032:analysis*
D012989:Soil Pollutants; D007854:Lead