Heterodyne-detected fifth-order nonresonant Raman scattering from room temperature CS2.
Actively phase-locked heterodyne-detected fifth-order nonresonant Raman scattering from room temperature CS2 has been measured. The experimental signals have similar magnitudes, shapes, and sign changes as calculated responses obtained via molecular dynamics simulations [S. Saito and I. Ohmine, Phys. Rev. Lett. 88, 207401 (2002)]. The measured signals contain sign changes that appear to be associated with the coupling of rotational motions both to each other and to translational motions.
Kaufman
Laura J
LJ
Department of Chemistry, University of California, Berkeley, California 94720, USA.
Heo
Jiyoung
J
Ziegler
Larry D
LD
Fleming
Graham R
GR