Tetrakis(micro-benzothiazole-2-thiolato)-1:2kappa4N:S2;1:2kappa4S2:N-dichloro-1kappaCl,2kappaCl-dirhenium(III)(Re-Re) dichloromethane solvate: a bridged complex with a long Re-Re quadruple bond.
The title compound, [Re(2)(C(7)H(4)NS(2))(4)Cl(2)].CH(2)Cl(2), consists of dirhenium molecules with bridging N,S-benzothiazole-2-thiolate ligands, axial Cl(-) ligands and intramolecular hydrogen bonding. These molecules adopt somewhat staggered conformations, with a long Re-Re quadruple bond distance of 2.2716 (3) A.
Horne
Keri T
KT
Department of Chemistry, Abilene Christian University, ACU Box 28132, Abilene, TX 79699-8132, USA.
Powell
Gregory L
GL
Daniels
Lee M
LM