title: Nature of the divergence in low shear viscosity of colloidal hard-sphere dispersions.
abstract: Measurements of the low-shear viscosity eta(o) with a Zimm-Crothers viscometer for dispersions of colloidal hard spheres are reported as a function of volume fraction phi up to 0.56. Nonequilibrium theories based on solutions to the two-particle Smoluchoski equation or ideal mode coupling approximations do not capture the divergence. However, the nonhydrodynamic contribution to the relative viscosity Deltaeta(o) is correlated over a wide range of volume fractions by the Doolittle and Adam-Gibbs equations, indicating an exponential divergence at phi(m)=0.625+/-0.015. The data extend the previously proposed master curve, providing a test for improved theories for the many-body thermodynamic and hydrodynamic interactions that determine the viscosity of hard-sphere dispersions.
authors: Department of Physics, Princeton University, Princeton, New Jersey 08544, USA.
authors: Zhengdong
authors: Z
authors: Cheng
authors: Jixiang
authors: J
authors: Zhu
authors: Paul M
authors: PM
authors: Chaikin
authors: See-Eng
authors: SE
authors: Phan
authors: William B
authors: WB
authors: Russel