title: Asymmetric deactivation of racemic BINAP-Ru(II) catalysts through complete enantiomer discrimination by dimethylbinaphthylamine: highly enantioselective hydrogenation of olefin and beta-keto ester.
abstract: [reaction: see text] 3,3'-Dimethyl-2,2'-diamino-1,1'-binaphthyl (DM-DABN) is designed as a "chiral poison" (deactivator) for complete enantiomer resolution of racemic BINAP-Ru(II) catalysts in a highly enantioselective hydrogenation of beta-keto ester and kinetic resolution of racemic 2-cyclohexen-1-ol.
authors: Department of Applied Chemistry, Tokyo Institute of Technology, 152-8552, Japan. kmikami@o.cc.titech.ac.jp
authors: Koichi
authors: K
authors: Mikami
authors: Yukinori
authors: Y
authors: Yusa
authors: Toshinobu
authors: T
authors: Korenaga