title: Enantioselective total synthesis of callipeltoside A.
abstract: An asymmetric total synthesis of callipeltoside A has been accomplished highlighted by a catalytic enantioselective vinylogous aldol reaction and a boron-mediated anti-aldol reaction influenced by remote stereocontrol.
authors: Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, USA. evans@chemistry.harvard.edu
authors: David A
authors: DA
authors: Evans
authors: Essa
authors: E
authors: Hu
authors: Jason D
authors: JD
authors: Burch
authors: Georg
authors: G
authors: Jaeschke
mesh_terms: D000818:Animals; D000900:Anti-Bacterial Agents / Q000138:chemical synthesis*; D019380:Anti-HIV Agents / Q000138:chemical synthesis; D000970:Antineoplastic Agents / Q000138:chemical synthesis; D018942:Macrolides; D011161:Porifera / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D000900:Anti-Bacterial Agents; D019380:Anti-HIV Agents; D000970:Antineoplastic Agents; D018942:Macrolides; C410329:callipeltoside A