Analysis of chlorinated paraffins in cutting fluids and sealing materials by carbon skeleton reaction gas chromatography.
Chlorinated paraffins (CPs) pose a major risk in the environment, due to their wide application, to their persistence, to their carcinogenic potential, and in view of the fact, that they cannot be easily identified. Various commercial cutting fluids and sealing materials were analysed for CPs with carbon skeleton reaction gas chromatography (GC) and flame ionization detection. CPs are simultaneously dechlorinated and hydrogenated to the corresponding alkanes with Pd catalyst material in the GC injector. With this method, the carbon chain length of commercial technical CPs was determined. In six of sixteen sealing materials we found five short and one medium chain length polychlorinated paraffins in percentages of 9-16% (w/w). In five cutting fluids we found predominantly medium to long chain length chloroparaffins with percentages of 2.5-31% (w/w), only one fluid contained short chain CPs.
Koh
In-Ock
IO
Department of Physical and Environmental Chemistry, University of Bremen, Germany. koh@uni-bremen.de
Rotard
Wolfgang
W
Thiemann
Wolfram H P
WH
D002384:Catalysis; D017606:Chlorine Compounds / Q000032:analysis / Q000737:chemistry*; D002849:Chromatography, Gas; D004785:Environmental Pollutants / Q000032:analysis*; D008420:Manufactured Materials; D010165:Palladium / Q000737:chemistry; D010232:Paraffin / Q000032:analysis / Q000737:chemistry*
D017606:Chlorine Compounds; D004785:Environmental Pollutants; D010165:Palladium; D010232:Paraffin