Application of tin and nanometer tin in allylation of carbonyl compounds in tap water.
[reaction: see text] Nanometer tin-mediated allylation of aldehydes or ketones in distilled or tap water gave rise to corresponding homoallyl alcohol in high yield without any other assistance such as heat or supersonic or acidic media.
Wang
Zhiyong
Z
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China. zwang3@ustc.edu.cn
Zha
Zhenggen
Z
Zhou
Cunliu
C
D000447:Aldehydes / Q000737:chemistry; D000498:Allyl Compounds / Q000737:chemistry*; D002384:Catalysis; D007202:Indicators and Reagents; D007659:Ketones / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D014001:Tin / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000032:analysis*; D014881:Water Supply / Q000032:analysis*
D000447:Aldehydes; D000498:Allyl Compounds; D007202:Indicators and Reagents; D007659:Ketones; D014874:Water Pollutants, Chemical; D014001:Tin