Acetylation of methyl 5-amino-1H-[1,2,4]triazole-3-carboxylate.
Acetylation with acetic anhydride of methyl 5-amino-1H-[1,2,4]triazole-3-carboxylate, one of the hetareneamino acids, was studied using HPLC, H NMR, FTIR and GC-MS. The compound has a significantly decreased susceptibility to acetylation compared to 5-amino-1H-[1,2,4]triazole itself. Two isomeric diacetylated products were found.
Dzygiel
A
A
Institute of Chemistry, University of Opole, Poland.
Masiukiewicz
E
E
Rzeszotarska
B
B
D000107:Acetylation; D001965:Bromides / Q000737:chemistry; D002264:Carboxylic Acids / Q000737:chemistry* / Q000378:metabolism*; D002851:Chromatography, High Pressure Liquid; D004121:Dimethyl Sulfoxide / Q000737:chemistry; D008401:Gas Chromatography-Mass Spectrometry; D007700:Kinetics; D009682:Magnetic Resonance Spectroscopy; D008956:Models, Chemical; D009584:Nitrogen / Q000737:chemistry; D017680:Potassium Compounds / Q000737:chemistry; D017550:Spectroscopy, Fourier Transform Infrared; D013696:Temperature; D014230:Triazoles / Q000737:chemistry* / Q000378:metabolism
C457540:5-amino-1H-(1,2,4)triazole-3-carboxylate; D001965:Bromides; D002264:Carboxylic Acids; D017680:Potassium Compounds; D014230:Triazoles; D009584:Nitrogen; C039004:potassium bromide; D004121:Dimethyl Sulfoxide