Discrete variable approaches to tetratomic molecules: part I: DVR(6) and DVR(3) + DGB methods.
We present two discrete variable representation (DVR) based methods for the determination of the vibrational energy levels of tetratomic molecules. Both methods are designed for orthogonal internal coordinates in a body-fixed reference frame and make use of the DVR of three angular variables. The angular DVRs allow the construction of a fixed-angle three-mode Hamiltonian for the stretching vibrations. For each of the angular triples, the stretching eigenvalue problems are solved by employing 3D radial DVRs in the DVR(6) approach and real three-dimensional distributed Gaussian functions in the DVR(3) + DGB method. The angular degrees of freedom are taken sequentially into account in conjunction with a contraction scheme resulting from several diagonalization/truncation steps. Vibrationally averaged geometries, expectation values of rotational constants, and several adiabatic projection schemes developed in this work for tetratomic molecules are used to characterize the vibrational levels calculated by the DVR(6) and DVR(3) + DGB.
Mladenović
Mirjana
M
Institut für Physikalische Chemie, Universität Göttingen, Germany. mmladen@gwdg.de
D000465:Algorithms; D002248:Carbon Monoxide / Q000737:chemistry; D005557:Formaldehyde / Q000737:chemistry; D006861:Hydrogen Peroxide / Q000737:chemistry; D017665:Hydroxyl Radical / Q000737:chemistry; D007700:Kinetics; D015233:Models, Statistical; D008962:Models, Theoretical; D016011:Normal Distribution; D013055:Spectrophotometry, Infrared / Q000379:methods*; D014732:Vibration
D005557:Formaldehyde; D017665:Hydroxyl Radical; D002248:Carbon Monoxide; D006861:Hydrogen Peroxide