Intrazeolite photooxidations of electron-poor alkenes.
The inability of the intrazeolite environment to influence the regiochemistry of addition of singlet oxygen to electron-poor olefins is reported. This divergent behavior with respect to electron-rich alkenes is rationalized with a multicomplexation model that emphasizes the importance of intrazeolite substrate-cation binding.
Clennan
Edward L
EL
Department of Chemistry, University of Wyoming, Laramie, WY 82071, USA. clennane@uwyo.edu
Sram
Jakub P
JP
Pace
Andrea
A
Vincer
Katie
K
White
Sophia
S
D000475:Alkenes / Q000737:chemistry*; D008956:Models, Chemical; D010084:Oxidation-Reduction; D010777:Photochemistry; D012996:Solutions; D013379:Substrate Specificity; D017641:Zeolites / Q000737:chemistry*
D000475:Alkenes; D012996:Solutions; D017641:Zeolites