title: Sorption of copper, zinc and cobalt by oat and oat products.
abstract: We determined copper, zinc and cobalt sorption by oat and its products under variable pH conditions as well as the content of neutral dietary fiber (NDF) and its fractional composition. Adsorbents in a model sorption system were: oat, dehulled oat, oats bran and oats flakes. Three various buffers (pH 1.8, 6.6 and 8.7) were used as dispersing solutions. Results collected during this study indicate that copper, zinc and cobalt sorption is significantly affected by the type of cereal raw material. Zinc and copper ions are subjected to higher sorption than cobalt ions. Examined metal ions were subjected to high sorption under conditions corresponding to the duodenum environment (pH 8.7), regardless of the kind of adsorbent. A little lower sorption capacity is observed under conditions close to the neutral environment, while the lowest one is found in environment reflecting conditions of stomach juice (pH 1.8). Zinc ions are bound intensively by dehulled oat, while oats flakes bound mostly copper and cobalt, independently on environmental conditions. Contents of dietary fiber in oat, dehulled oat, oat bran and oat flakes were: 40.1, 19.3, 20.3 and 14.3%, respectively. The dominating fraction in all oat products was the fraction of hemicelluloses. The content of remaining fractions varies in dependence on the product.
authors.affiliation: A. Cieszkowski Agricultural University, Department of Human Nutrition and Food Technology, Wojska Polskiego Str. 31, PL-60-637 Poznań, Poland.
authors.forename: Danuta
authors.initials: D
authors.lastname: Górecka
authors.forename: Jadwiga
authors.initials: J
authors.lastname: Stachowiak
mesh_terms: D000327:Adsorption; D018554:Avena / Q000737:chemistry* / Q000378:metabolism; D001682:Biological Availability; D003035:Cobalt / Q000493:pharmacokinetics*; D003300:Copper / Q000493:pharmacokinetics*; D003902:Detergents; D004043:Dietary Fiber / Q000032:analysis / Q000494:pharmacology; D006801:Humans; D006863:Hydrogen-Ion Concentration; D009753:Nutritive Value; D015032:Zinc / Q000493:pharmacokinetics*
chemical_list: D003902:Detergents; D004043:Dietary Fiber; D003035:Cobalt; D003300:Copper; D015032:Zinc