title: Evaluation of the RAMS continuous monitor for determination of PM2.5 mass including semi-volatile material in Philadelphia, PA.
abstract: The real-time ambient mass sampler (RAMS) is a continuous monitor based on particle concentrator, denuder, drier, and tapered element oscillating microbalance (TEOM) monitor technology. It is designed to measure PM2.5 mass, including the semi-volatile species NH4NO3 and semi-volatile organic material, but not to measure PM2.5 water content. The performance of the RAMS in an urban environment with high humidity was evaluated during the July 1999 NARSTO-Northeast Oxidant and Particles Study (NEOPS) intensive study at the Baxter water treatment plant in Philadelphia, PA. The results obtained with the RAMS were compared to mass measurements made with a TEOM monitor and to constructed mass obtained with a Particle Concentrator-Brigham Young University Organic Sampling System (PC-BOSS) sampler designed to determine the chemical composition of fine particles, including the semi-volatile species. An average of 28% of the fine particulate material present during the study was semi-volatile organic material lost from a filter during particle collection, and 1% was NH4NO3 that was also lost from the particles during sampling. The remaining mass was dominantly nonvolatile (NH4)2SO4 (31%) and organic material (37%), with minor amounts of soot, crustal material, and nonvolatile NH4NO3. Comparison of the RAMS and PC-BOSS results indicated that the RAMS correctly monitored for fine particulate mass, including the semivolatile material. In contrast, the heated filter of the TEOM monitor did not measure the semi-volatile material. The comparison of the RAMS and PC-BOSS data had a precision of +/-4.1 microg/m3 (+/-9.6%). The precision of the RAMS data was limited by the uncertainty in the blank correction for the reversible adsorption of water by the charcoal-impregnated cellulose sorbent filter of the RAMS monitor. The precision of the measurement of fine particulate components by the PC-BOSS was +/-6-8%.
authors.affiliation: Department of Chemistry and Biochemistry, Brigham Young University, Provo, Utah 84602-5700, USA.
authors.forename: Yanbo
authors.initials: Y
authors.lastname: Pang
authors.forename: Norman L
authors.initials: NL
authors.lastname: Eatough
authors.forename: William K
authors.initials: WK
authors.lastname: Modey
authors.forename: Delbert J
authors.initials: DJ
authors.lastname: Eatough
mesh_terms: D000393:Air Pollutants / Q000032:analysis*; D002947:Cities; D004784:Environmental Monitoring / Q000295:instrumentation* / Q000379:methods; D005374:Filtration; D010316:Particle Size; D015203:Reproducibility of Results; D012680:Sensitivity and Specificity; D014835:Volatilization
chemical_list: D000393:Air Pollutants