title: Facile synthesis of 1-thio-beta-lactoside clusters scaffolded onto p-methoxyphenyl, beta-D-galactopyranoside, beta-D-glucopyranoside, and lactoside.
abstract: The free-radical addition of 2,3,4,6-tetra-O-acetyl-beta-D-galactopyranosyl-(1-->4)-2,3,6-tri-O-acetyl-1-thio-beta-D-glucopyranose to the allyl ether functions of p-methoxyphenyl per-O-allyl-D-galactopyranoside, D-glucopyranoside, and lactoside provides a concise and effective route for synthesis of glycoside clusters, of use for exploring anti-metastatic activity.
authors.affiliation: Department of Chemical Biology, School of Pharmaceutical Science, National Research Laboratory of Natural and Biomimetic Drugs, Peking University, Beijing 100083, China.
authors.forename: Xiang-Bao
authors.initials: XB
authors.lastname: Meng
authors.forename: Lian-Dai
authors.initials: LD
authors.lastname: Yang
authors.forename: Hui
authors.initials: H
authors.lastname: Li
authors.forename: Qing
authors.initials: Q
authors.lastname: Li
authors.forename: Tie-Ming
authors.initials: TM
authors.lastname: Cheng
authors.forename: Meng-Shen
authors.initials: MS
authors.lastname: Cai
authors.forename: Zhong-Jun
authors.initials: ZJ
authors.lastname: Li
mesh_terms: D005690:Galactose / Q000737:chemistry; D006027:Glycosides / Q000138:chemical synthesis* / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy
chemical_list: D006027:Glycosides; C008245:lactosides; D005690:Galactose