title: Intrazeolite photooxidations of electron-poor alkenes.
abstract: The inability of the intrazeolite environment to influence the regiochemistry of addition of singlet oxygen to electron-poor olefins is reported. This divergent behavior with respect to electron-rich alkenes is rationalized with a multicomplexation model that emphasizes the importance of intrazeolite substrate-cation binding.
authors.affiliation: Department of Chemistry, University of Wyoming, Laramie, WY 82071, USA. clennane@uwyo.edu
authors.forename: Edward L
authors.initials: EL
authors.lastname: Clennan
authors.forename: Jakub P
authors.initials: JP
authors.lastname: Sram
authors.forename: Andrea
authors.initials: A
authors.lastname: Pace
authors.forename: Katie
authors.initials: K
authors.lastname: Vincer
authors.forename: Sophia
authors.initials: S
authors.lastname: White
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D008956:Models, Chemical; D010084:Oxidation-Reduction; D010777:Photochemistry; D012996:Solutions; D013379:Substrate Specificity; D017641:Zeolites / Q000737:chemistry*
chemical_list: D000475:Alkenes; D012996:Solutions; D017641:Zeolites