title: Rhodium(I)-catalyzed silylation of aryl halides with triethoxysilane: practical synthetic route to aryltriethoxysilanes.
abstract: [reaction: see text] The specific silylation of aryl iodides and bromides with triethoxysilane (EtO)(3)SiH in the presence of NEt(3) and a catalytic amount of [Rh(cod)(MeCN)(2)]BF(4) provides the corresponding aryltriethoxysilanes in high yield.
authors.affiliation: Department of Materials Science, Kitami Institute of Technology, Kitami 090-8507, Japan. muratamk@mail.kitami-u.ac.jp
authors.forename: Miki
authors.initials: M
authors.lastname: Murata
authors.forename: Masanori
authors.initials: M
authors.lastname: Ishikura
authors.forename: Masayuki
authors.initials: M
authors.lastname: Nagata
authors.forename: Shinji
authors.initials: S
authors.lastname: Watanabe
authors.forename: Yuzuru
authors.initials: Y
authors.lastname: Masuda