[Biomimetic oxidation of benzene by a polynuclear manganese complex [Mn12O12(CH3CO2)16(H2O)4] under mild conditions].
The possibility of monooxygenase enzymes biomimetic construction models with the use of polynuclear manganese complexes was shown. It was demonstration that benzene is oxidized by polynuclear manganese complex [Mn12O12(CH3CO2)16(H2O)4] in acetonitrile solution at room temperature and atmospheric pressure yielding phenol with the selectivity more than 80%. It was determined that the addition of air oxygen as the reoxidizer to the reaction mixture didn't transfer the reaction into the catalytic mode.
Pavlishchuk
V V
VV
Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Kyiv.
Gavrilenko
K S
KS
Pavlenko
N V
NV
D001554:Benzene / Q000737:chemistry*; D002384:Catalysis; D017895:Manganese Compounds / Q000737:chemistry*; D018716:Molecular Mimicry; D010084:Oxidation-Reduction; D013696:Temperature
D017895:Manganese Compounds; D001554:Benzene