title: Synthesis, resolution, and reactivity of benzylmesitylphenylphosphine: a new p-chiral bulky ligand.
abstract: The synthesis of P,P'-dimesityl-P,P'-diphenyldiphosphine and benzylmesitylphenylphosphine is described as well as the resolution of the latter ligand by means of homochiral organometallic complexes. The absolute configuration of the phosphine is assigned by NMR spectra, using the homochiral palladacycle as a reference point. The configuration has been confirmed by single crystal X-ray diffraction. Molecular mechanics calculations were performed in [PdCl-(R)-(+)-C10H6CH(Me)NH2(PBnMesPh)], and showed that the rotation around the Pd-P bond is restricted in this complex. [Pd(eta3-2-MeC3H4)Cl(PBnMesPh)] was obtained and used as a precursor in the catalytic hydrovinylation of styrene. Benzylmesitylphenylphosphine has a strong tendency to form phosphapalladacycles by activation of one of the ortho-methyl groups. The formation of this metallacycle from cyclopalladated N-donor derivatives by a ligand-exchange reaction is also described.
authors.affiliation: Departament de Química Inorgànica, Universitat de Barcelona, Diagonal 647, 08028 Barcelona, Spain.
authors.forename: Joan
authors.initials: J
authors.lastname: Albert
authors.forename: Ramon
authors.initials: R
authors.lastname: Bosque
authors.forename: J Magali
authors.initials: JM
authors.lastname: Cadena
authors.forename: Sergio
authors.initials: S
authors.lastname: Delgado
authors.forename: Jaume
authors.initials: J
authors.lastname: Granell
authors.forename: Guillermo
authors.initials: G
authors.lastname: Muller
authors.forename: Juan I
authors.initials: JI
authors.lastname: Ordinas
authors.forename: Mercé
authors.initials: M
authors.lastname: Font Bardia
authors.forename: Xavier
authors.initials: X
authors.lastname: Solans