Blennione, a green aminobenzoquinone derivative from Lactarius blennius.
A green pigment, blennione (1), was isolated from fruit bodies of the toadstool Lactarius blennius. Its structure was established by 2D NMR methods and confirmed by a biomimetic synthesis. Compound 1 represents a diphenylquinone derivative, which may be formed biosynthetically from two 3,6-dihydroxyanthranilic acid units.
Spiteller
Peter
P
Department Chemie der Ludwig-Maximilians-Universität, Butenandtstrasse 5-13, D-81377 München, Germany.
Steglich
Wolfgang
W
D000363:Agaricales / Q000737:chemistry*; D016227:Benzoquinones / Q000138:chemical synthesis / Q000737:chemistry / Q000302:isolation & purification*; D002384:Catalysis; D002851:Chromatography, High Pressure Liquid; D005858:Germany; D006865:Hydrogenation; D008968:Molecular Conformation; D015394:Molecular Structure; D019906:Nuclear Magnetic Resonance, Biomolecular; D010860:Pigments, Biological / Q000138:chemical synthesis / Q000737:chemistry / Q000302:isolation & purification*; D014641:Vanillic Acid / Q000031:analogs & derivatives / Q000737:chemistry
C461042:2-amino-6-hydroxy-3-methylbenzoic acid; D016227:Benzoquinones; D010860:Pigments, Biological; C458538:blennione; D014641:Vanillic Acid