Polyacetylene glycosides from Gymnaster koraiensis.
Two polyacetylene glycosides, gymnasterkoreasides A and B, were isolated from the roots of Gymnaster koraiensis. Their structures were elucidated to be (3R)-8-decene-4,6-diyne-1,3-diol 1-O-beta-D-glucopyraside and (3R)-8-decene-4,6-diyne-1,3-diol 1-O-beta-D-apiofuranosyl-(1-->6)-beta-D-glucopyraside on the basis of spectroscopic analysis including COSY, HMQC, and HMBC experiments, as well as chemical methods, which confirmed the determination of a chiral center by the modified Mosher's method.
Park
JinYoung
J
College of Pharmacy, Chungnam National University, Taejon, Korea.
Min
ByungSun
B
Jung
HyunJu
H
Kim
YoungHo
Y
Lee
HyeongKyu
H
Bae
KiHwan
K
D000114:Acetylene / Q000031:analogs & derivatives* / Q000737:chemistry* / Q000302:isolation & purification; D000480:Alkynes; D002241:Carbohydrates / Q000032:analysis; D002849:Chromatography, Gas; D004187:Disaccharides / Q000737:chemistry* / Q000302:isolation & purification; D053281:Enediynes; D006027:Glycosides / Q000737:chemistry*; D006868:Hydrolysis; D007723:Korea; D009682:Magnetic Resonance Spectroscopy; D009005:Monosaccharides / Q000737:chemistry* / Q000302:isolation & purification; D018517:Plant Roots / Q000737:chemistry; D010946:Plants, Medicinal / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D053279:Polyynes; D016339:Spectrometry, Mass, Fast Atom Bombardment; D013056:Spectrophotometry, Ultraviolet
D000480:Alkynes; D002241:Carbohydrates; D004187:Disaccharides; D053281:Enediynes; D006027:Glycosides; D009005:Monosaccharides; D011108:Polymers; C468048:gymnasterkoreaside A; C468047:gymnasterkoreaside B; D053279:Polyynes; D000114:Acetylene