Electron-donating properties of p-phenylene phosphine imides: an electrochemical and spectroscopic investigation.
[reaction: see text] Electronic properties of phosphine imide based organic electron donors have been investigated. N,N'-p-Phenylenebis(triphenyl)phosphine imide (Ph(3)P=NC(6)H(4)N=PPh(3), 1) has two reversible single-electron oxidations (0.04 and 0.53 V vs SCE). Spectroscopic investigations of poly(p-phenylene phosphine imide)s (2) are similar to those of polymer model compounds, suggesting formation of localized radical cations on the polymer chains and electronically insulating phosphorus atoms.
Escobar
Marcela
M
Department of Chemistry, University of Rhode Island, Kingston, Rhode Island 02881, USA.
Jin
Zhou
Z
Lucht
Brett L
BL