title: Regiospecific synthesis of a benanomicinone/pradimicinone analogue.
abstract: [reaction: see text] Condensation of a phenylsulfinyl naphthoate with an ortho-quinone monoketal has been used to accomplish a total synthesis of a benanomicinone/pradimicinone analogue.
authors.affiliation: Department of Chemistry, State University of New York at Albany, Albany, New York 12222, USA. FH473@mail.albany.edu
authors.forename: Frank M
authors.initials: FM
authors.lastname: Hauser
authors.forename: Hongbiao
authors.initials: H
authors.lastname: Liao
authors.forename: Yuanqiang
authors.initials: Y
authors.lastname: Sun
mesh_terms: D018943:Anthracyclines; D000903:Antibiotics, Antineoplastic / Q000138:chemical synthesis*; D000935:Antifungal Agents / Q000138:chemical synthesis*; D006900:Hydroxylation; D009279:Naphthacenes / Q000138:chemical synthesis; D011809:Quinones / Q000138:chemical synthesis; D000095643:Pradimicins and Benanomicins
chemical_list: D018943:Anthracyclines; D000903:Antibiotics, Antineoplastic; D000935:Antifungal Agents; D009279:Naphthacenes; D011809:Quinones; C108554:5,6-dihydrobenzo(a)naphthacenequinone; C466026:benanomicinone; C466025:pradimicinone; C056805:benanomicin A; D000095643:Pradimicins and Benanomicins; C058036:pradimicin A