Raman scattering determination of the depth of cure of light-activated composites: influence of different clinically relevant parameters.
The purpose of this research was to determine the depth of cure of light-activated composites in relation with different clinically relevant parameters. A Raman spectroscopic method has been used. The measurement of cure is made on a relative basis by comparing the vibration band of the residual unpolymerized methacrylate C=C bond at 1640 cm-1 against the aromatic C=C stretching band at 1610 cm-1 used as an internal standard. The information gained draw attention to the importance of light transmission during the exposure. The influence of sample's thickness on the depth of cure is illustrated by a second order polynomial regression. The shade and translucency of the resin composite also modify the light transmission and thus have a significant influence on the degree of conversion. Moreover the light-source intensity and the distance from the curing tip are important parameters of influence. A significant reduction of the depth of cure is observed for all sample thickness of resin composite tested when using a light device with an intensity of 300 mW cm-2 as well as using a distance from the curing tip higher than 20 mm.
Leloup
G
G
Department of Operative Dentistry, Université catholique de Louvain, Bruxelles, Belgium. leloup@patd.ucl.ac.be
Holvoet
P E
PE
Bebelman
S
S
Devaux
J
J
D017438:Bisphenol A-Glycidyl Methacrylate / Q000737:chemistry / Q000528:radiation effects; D002244:Carbon / Q000737:chemistry; D003188:Composite Resins / Q000737:chemistry* / Q000528:radiation effects*; D008027:Light; D015394:Molecular Structure; D011108:Polymers / Q000737:chemistry; D012542:Scattering, Radiation; D012822:Silicon Dioxide / Q000737:chemistry / Q000528:radiation effects; D013059:Spectrum Analysis, Raman; D015040:Zirconium / Q000737:chemistry / Q000528:radiation effects
D003188:Composite Resins; C079764:Pertac hybrid; D011108:Polymers; C099128:Prodigy; C403464:SureFil packable composite; C083568:Z100 composite resin; D017438:Bisphenol A-Glycidyl Methacrylate; D002244:Carbon; D012822:Silicon Dioxide; D015040:Zirconium