Stable (amino)(phosphino)carbenes: difunctional molecules.
(Amino)(phosphino)carbenes are stable due to the donation of the nitrogen lone pair, the phosphino group remains strongly pyramidalized. Reactions can be performed selectively at the carbene center, but also at the phosphorus center leading to new stable carbenes. These difunctional molecules can be considered as hybrid ligands.
Merceron
Nathalie
N
Laboratoire d'Hétérochimie Fondamentale et Appliquée, UMR 5069, Université Paul Sabatier, 118 route de Narbonne, F-31062 Toulouse Cédex 04, France.
Miqueu
Karinne
K
Baceiredo
Antoine
A
Bertrand
Guy
G