A neutral complex of an azino[bond]DTDAF compound with TCNQ.
In the crystal structure of the title 1:1 complex, ethyl 2-[[5-(ethoxycarbonyl)-2,3-dihydro-3,4-dimethyl-1,3-thiazol-2-ylidene]hydrazono]-2,3-dihydro-3,4-dimethyl-1,3-thiazole-5-carboxylate-7,7,8,8-tetracyano-p-quinodimethane (1/1), C(16)H(22)N(4)O(4)S(2) x C(12)H(4)N(4), the planar donor and tetracyano-p-quinodimethane (TCNQ) molecules are each located on inversion centres and are stacked alternately. The bond lengths indicate that, in this complex, the donor and acceptor are neutral, as confirmed by IR investigation.
Toplak
Renata
R
Synthèse et Electrosynthèse Organiques, UMR CNRS 6510, Université de Rennes 1, 35042 Rennes Cedex, France.
Lorcy
Dominique
D