title: The first general method for Z-selective olefination of acylsilanes via ynolate anions providing multisubstituted alkenes.
abstract: We have developed the first general method for a stereoselective olefination of acylsilanes via ynolate anions to produce (Z)-beta-silyl-alpha,beta-unsaturated ester, which leads to tri- and tetrasubstituted alkenes.
authors.affiliation: Institute for Medicinal Resources, University of Tokushima, Sho-machi 1, Tokushima 770-8505, Japan. shindo@ph2.tokushima-u.ac.jp
authors.forename: Mitsuru
authors.initials: M
authors.lastname: Shindo
authors.forename: Kenji
authors.initials: K
authors.lastname: Matsumoto
authors.forename: Seiji
authors.initials: S
authors.lastname: Mori
authors.forename: Kozo
authors.initials: K
authors.lastname: Shishido