catena-Poly[[bis(thiocyanato-kappa N)cadmium(II)]-di-mu-thiourea-kappa(4)S:S].
The Cd(II) ion in the title complex, [Cd(SCN)(2)[SC(NH(2))(2)](2)](infinity), is situated at a centre of symmetry, and is bound to two N atoms belonging to thiocyanate groups and to four S atoms of bridging thiourea ligands. The structure consists of infinite chains of slightly distorted edge-shared Cd-centred octahedra. The bridging S atoms of two thiourea ligands comprise the common edge. Some thermal properties are described.
Wang
Xin Qiang
XQ
State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University, Jinan 250100, People's Republic of China. xqwang@icm.sdu.edu.cn
Yu
Wen Tao
WT
Xu
Dong
D
Lu
Meng Kai
MK
Yuan
Duo Rong
DR