(-)-alpha-Isosparteine copper(II) diazide.
In the title complex, [Cu(N(3))(2)(C(15)H(26)N(2))], the Cu atom is surrounded by the two N atoms of the chelating (-)-alpha-isosparteine ligand and another two N atoms from the two azide anions, forming a distorted CuN(4) tetrahedron. The two azide anions are terminally bound to the Cu(II) atom, and the dihedral angle between the N(sparteine)[bond]Cu[bond]N(sparteine) and N(azide)[bond]Cu[bond]N(azide) planes is 50.0 (2) degrees.
Kim
Bun-Joo
BJ
Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University, Pusan 609-735, South Korea.
Lee
Yong-Min
YM
Kim
Eun Hee
EH
Kang
Sung Kwon
SK
Choi
Sung-Nak
SN