Exceptional kinetic propensity of hydroxymethyl phosphanes toward Rh(III) stabilization in water.
The reactions of (HOCH2)2P(C6H4)P(CH2OH)2 (HMPB) and P(CH2OH)3 (THP) with RhCl3.xH2O in aqueous media gave water-soluble complexes cis-[RhCl2{eta2-(HOCH2)2P(C6H4)P(CH2OH)2}2]Cl (3) and fac-[RhCl3(P(CH2OH)3)3] (4) respectively in good yields, X-ray crystal structures of 3 and 4 confirmed their molecular constitution. These reactions provide the first examples demonstrating the kinetic propensity of hydroxymethyl phosphanes to stabilize Rh in +3 oxidation state in water.
Raghuraman
Kannan
K
Radiopharmaceutical Sciences Institute, Department of Radiology, 301, Business Loop 70W, Alton Building Laboratories, University of Missouri-Columbia, Columbia, Missouri 65211,USA.
Pillarsetty
Nagavarakishore
N
Volkert
Wynn A
WA
Barnes
Charles
C
Jurisson
Silvia
S
Katti
Kattesh V
KV
D018360:Crystallography, X-Ray; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D012996:Solutions; D014867:Water / Q000737:chemistry
D009942:Organometallic Compounds; D010720:Phosphines; D012996:Solutions; D014867:Water; D012428:Ruthenium; C044646:phosphine