New polyfluorinated organotin reagents. Stereoselective synthesis of (Z)-alpha-fluoro-beta-trifluoromethylvinylstannanes.
[reaction: see text] A new methodology for the synthesis of (Z)-alpha-fluoro-beta-trifluoromethylvinylstannanes, which are useful polyfluorinated organotin reagents for the synthesis of fluorine-containing biologically active compounds, is described.
Shen
Yanchang
Y
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Academia Sinica, Shanghai 200032, China. shenyc@pub.socio.ac.cn
Wang
Guoping
G