Brillouin-scattering study of propylene carbonate: an evaluation of phenomenological and mode coupling analyses.
Brillouin-scattering spectra of the molecular glass-forming material propylene carbonate (PC) in the temperature range 140 K to 350 K were analyzed using both the phenomenological Cole-Davidson memory function and a hybrid memory function consisting of the Cole-Davidson function plus a power-law term representing the critical decay part of the fast beta relaxation. The spectra were also analyzed using the extended two-correlator schematic mode-coupling theory (MCT) model recently employed by Götze and Voigtmann to analyze depolarized light backscattering, dielectric, and neutron-scattering spectra of PC [Phys. Rev. E 61, 4133 (2000)]. We assess the ability of the phenomenological and MCT fits, each with three free fitting parameters, to simultaneously describe the spectra and give reasonable values for the alpha-relaxation time tau(alpha).
Brodin
Alexander
A
Physics Department, City College of the City University of New York, New York, New York 10031, USA.
Frank
Martin
M
Wiebel
Sabine
S
Shen
Guoqing
G
Wuttke
Joachim
J
Cummins
H Z
HZ