Analyses of the wood preservative component N-cyclohexyl-diazeniumdioxide in impregnated pine sapwood by direct thermal desorption-gas chromatography-mass spectrometry.
Investigations concerning the qualitative and quantitative determination of the organic wood preservative component N-cyclohexyl-diazeniumdioxide (HDO) in treated timber were carried out by means of direct thermal desorption-gas chromatography-mass spectrometry (DTD-GC-MS). It could be shown that the identification of HDO in treated pine sapwood (Pinus sylyestris L.) is relatively simple using this analytical technique. Quantification of this active ingredient can be carried out using the peak area of the specific mass fragment m/z 114. A calibration curve with a high correlation coefficient was obtained in the range from 40 to 550 mg HDO per kg timber. Furthermore it can be deduced that the results obtained are characterised by an excellent reproducibility with standard deviations ranging from 5 to 10% in general. For the chosen experimental set up a detection limit of 4 mg HDO per kg treated pine sapwood was calculated, although merely 20% of the active ingredient was desorbed.
Jüngel
Peter
P
Federal Research Centre for Forestry and Forest Products, Institute for Wood Biology and Wood Protection, Hamburg, Germany. juengel@holz.uni-hamburg.de
de Koning
Sjaak
S
Brinkman
Udo A Th
UA
Melcher
Eckhard
E
D003510:Cyclohexanes / Q000737:chemistry*; D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods*; D007094:Imides / Q000737:chemistry*; D028223:Pinus; D015203:Reproducibility of Results; D012680:Sensitivity and Specificity; D014934:Wood
D003510:Cyclohexanes; D007094:Imides; C469872:N-cyclohexyl-diazeniumdioxide