title: Intramolecular cycloadditions of alpha-allyloxycarbonylnitrones: stereoselective synthesis of 3-amino-2(5H)furanones.
abstract: Treatment of furoisoxazolidines with NaH leads to functionalized 3-amino-2(5H)-furanones through a new rearrangement pattern of the isoxazolidine nucleus. This process has been usefully exploited for the synthesis of enantiomerically pure (5R)-3-alkylamino-5-methyl-2(5H)-furanones.
authors.affiliation: Dipartimento di Scienze Chimiche, Università di Catania, Viale Andrea Doria 6, 95125, Italy. uchiacchio@dipchi.unict.it
authors.forename: Ugo
authors.initials: U
authors.lastname: Chiacchio
authors.forename: Antonino
authors.initials: A
authors.lastname: Corsaro
authors.forename: Daniela
authors.initials: D
authors.lastname: Iannazzo
authors.forename: Anna
authors.initials: A
authors.lastname: Piperno
authors.forename: Antonio
authors.initials: A
authors.lastname: Procopio
authors.forename: Antonio
authors.initials: A
authors.lastname: Rescifina
authors.forename: Giovanni
authors.initials: G
authors.lastname: Romeo
authors.forename: Roberto
authors.initials: R
authors.lastname: Romeo