title: Cyclic tetraselenadiynes: rigid cycles with long-range van der Waals forces between chalcogen centers.
abstract: The synthesis of cyclic tetraselenadiynes could be achieved by a stepwise approach. Key steps were the reaction of the lithium salt of trimethylsilylacetylene (1) with alpha,omega-diselenocyanatoalkanes 2(m) (m = 2-5). By treating the bis-lithium salt of the resulting alpha,omega-diselenaalkadiynes 4(m) (m = 2-5) again with 2(n) (n = 2-5) the cyclic tetraselenadiynes 5(m.n) resulted, with methylene chains of length m and n between the SeC triple bond CSe units. The structures of seven ring systems could be investigated in the solid state. These investigations reveal that the molecular structures are determined by the rigid SeC triple bond CSe units, which try to adopt torsion angles of the CH(2)-Se sigma-bonds between 60 degrees and 90 degrees. In the solid state, the systems 5(3.3) and 5(5.5) show columnar structures that can be traced back to close contacts between Se atoms of neighboring rings.
authors.affiliation: Organisch-Chemisches Institut der Universität Heidelberg, Im Neuenheimer Feld 270, Germany.
authors.forename: Daniel B
authors.initials: DB
authors.lastname: Werz
authors.forename: Rolf
authors.initials: R
authors.lastname: Gleiter
authors.forename: Frank
authors.initials: F
authors.lastname: Rominger