title: Attenuation of methyl tert-butyl ether in water using sunlight and a photocatalyst.
abstract: The use of methyl tert-butyl ether (MTBE) as a gasoline additive has resulted in increasing pollution of groundwater. Most of the conventional treatment technologies are inefficient or costly when the initial concentration of MTBE is low (< 200 microg/L). To find an ecology friendly and inexpensive method for MTBE remediation, we used solar radiation with titanium dioxide (TiO2) as a photocatalyst. For synthetic samples, almost complete degradation (99+%) of MTBE was observed at the end of 5-hour test run with 0.05 g/L of slurry TiO2. Intermediate products detected were tertiary butyl formate, tertiary butyl alcohol, and trace amounts of acetone. Studies conducted using contaminated groundwater samples with TiO2 and sunlight showed that aromatic organic species benzene, toluene, ethylbenzene, and xylenes (BTEX) were degraded up to a factor of 10 times faster than MTBE. However, dissolved metals (Fe2+) and chloride ions in contaminated waters decreased the photo-activity of TiO2 for the degradation of MTBE. Reducing the pH of the groundwater samples increased the MTBE degradation rate threefold. Photocatalysis accelerates the solar degradation of MTBE and reduces its half-life by more than 3 orders of magnitude. The study indicated that solar degradation is a low-cost and effective alternative to attenuate MTBE in drinking water supplies.
authors.affiliation: U.S. Environmental Protection Agency, National Risk Management Research Laboratory, Cincinnati, Ohio 45269, USA. Sahle-Demessie.Endalkachew@epa.gov
authors.forename: E
authors.initials: E
authors.lastname: Sahle-Demessie
authors.forename: J
authors.initials: J
authors.lastname: Enriquez
authors.forename: G
authors.initials: G
authors.lastname: Gupta
mesh_terms: D002273:Carcinogens / Q000737:chemistry*; D002384:Catalysis; D004396:Coloring Agents / Q000737:chemistry; D006207:Half-Life; D008738:Methyl Ethers / Q000737:chemistry*; D010777:Photochemistry; D013472:Sunlight; D014025:Titanium / Q000737:chemistry; D014876:Water Pollution / Q000517:prevention & control; D018508:Water Purification / Q000379:methods*
chemical_list: D002273:Carcinogens; D004396:Coloring Agents; D008738:Methyl Ethers; C009495:titanium dioxide; C043243:methyl tert-butyl ether; D014025:Titanium