title: Synthesis of the core structure of salicylihalamide A by intramolecular Suzuki reaction.
abstract: [reaction: see text] An intramolecular Suzuki coupling was used to establish the core structure of the benzolactone enamide salicylihalamide A. This strategy combines a diastereoselective hydroboration with a subsequent cross-coupling.
authors.affiliation: Institut für Organische Chemie, Universität Tübingen, Auf der Morgenstelle 18, D-72076 Tübingen, Germany.
authors.forename: Matthias
authors.initials: M
authors.lastname: Bauer
authors.forename: Martin E
authors.initials: ME
authors.lastname: Maier
mesh_terms: D000818:Animals; D001685:Biological Factors / Q000138:chemical synthesis; D019086:Bridged Bicyclo Compounds, Heterocyclic / Q000138:chemical synthesis*; D003500:Cyclization; D004791:Enzyme Inhibitors / Q000138:chemical synthesis; D008958:Models, Molecular; D025262:Vacuolar Proton-Translocating ATPases / Q000037:antagonists & inhibitors
chemical_list: D001685:Biological Factors; D019086:Bridged Bicyclo Compounds, Heterocyclic; D004791:Enzyme Inhibitors; C410986:salicylihalamide A; D025262:Vacuolar Proton-Translocating ATPases