Potential energy landscape equation of state.
Depth, number, and shape of the basins of the potential energy landscape are the key ingredients of the inherent structure thermodynamic formalism introduced by Stillinger and Weber [F. H. Stillinger and T. A. Weber, Phys. Rev. A 25, 978 (1982)]. Within this formalism, an equation of state based only on the volume dependence of these landscape properties is derived. Vibrational and configurational contributions to pressure are sorted out in a transparent way. Predictions are successfully compared with data from extensive molecular dynamics simulations of a simple model for the fragile liquid orthoterphenyl.
La Nave
Emilia
E
Dipartimento di Fisica, INFM UdR and INFM, Center for Statistical Mechanics and Complexity, Università di Roma "La Sapienza," Piazzale Aldo Moro 2, I-00185, Roma, Italy.
Mossa
Stefano
S
Sciortino
Francesco
F