Quadrupolar transitions evidenced by resonant auger spectroscopy.
From absorption spectra, the only way to bring to the fore the occurrence of quadrupolar transitions is to study their angular dependence. Resonant spectroscopies offer a new opportunity to obtain more insight into excited electronic states by studying lineshape and intensity of decay processes. We show here that resonantly excited Ti KL(2,3)L(2,3) Auger spectra of TiO2(110) carry a clear signature of quadrupolar transitions to localized e(g) and t(2g) d-like states, giving access to a direct measurement of crystal field splitting.
Danger
J
J
Laboratoire pour l'Utilisation du Rayonnement Electromagnétique, Université Paris Sud, Bâtiment 209d, BP 34, 91898 Orsay Cedex, France.
Le Fèvre
P
P
Magnan
H
H
Chandesris
D
D
Bourgeois
S
S
Jupille
J
J
Eickhoff
T
T
Drube
W
W