Optically detected magnetic resonance in the photoexcited triplet states of Ti(IV) and Zr(IV) cylopentadienyl complexes.
The class of compounds (RCp)2MX2, where M is a group IV metal, Cp is cyclopentadienyl, R is an alkyl, and X is a halide, has been of continuing interest as precursors for olefin coordination polymerization catalysts. In this communication, we demonstrate that the technique of optically detected magnetic resonance (ODMR) reveals subtle differences in the composition of the frontier molecular orbitals associated with the nature of the alkyl substituents on the Cp rings.
Endeward
Burkhard
B
ExxonMobil Research and Engineering Company, 1545 Route 22 East, Annandale, New Jersey 08801, USA.
Bernardo
Marcelino
M
Brant
Pat
P
Thomann
Hans
H