title: Geochemical evidence for atmospheric pollution derived from prehistoric copper mining at Copa Hill, Cwmystwyth, mid-Wales, UK.
abstract: This paper presents geochemical data from a blanket peat located close to a Bronze Age copper mine on the northern slopes of the Ystwyth valley, Ceredigion, mid-Wales, UK. The research objective was to explore the possibility that the peat contained a geochemical record of the pollution generateD by mining activity. Four peat monoliths were extracted from the blanket peat to reconstruct the pollution history of the prehistoric mine. Three different geochemical measurement techniques were employed and four copper profiles have been reconstructed, two of which are radiocarbon-dated. The radiocarbon dates at one profile located close to the mine confirm that copper enrichment occurs in the peat during the known period of prehistoric mining. Similar enrichment of copper concentrations is shown in one adjacent profile and a profile within 30 m away. In contrast, copper was not enriched in the other radiocarbon-dated monolith, collected approximately 1.35 km to the north of the mine. Whilst other possible explanations to explain the copper concentrations are discussed, it is argued that the high copper concentrations represent evidence of localised atmospheric pollution caused by Bronze Age copper mining in the British Isles. The results of this study suggest that copper may be immobile in blanket peat and such deposits can usefully be used to reconstruct atmospheric pollution histories in former copper mining areas.
authors.affiliation: Centre for Quaternary Science, Geography, School of Science and the Environment, Coventry University, UK. gex043@cov.ac.uk
authors.forename: T M
authors.initials: TM
authors.lastname: Mighall
authors.forename: P W
authors.initials: PW
authors.lastname: Abrahams
authors.forename: J P
authors.initials: JP
authors.lastname: Grattan
authors.forename: D
authors.initials: D
authors.lastname: Hayes
authors.forename: S
authors.initials: S
authors.lastname: Timberlake
authors.forename: S
authors.initials: S
authors.lastname: Forsyth
mesh_terms: D000393:Air Pollutants / Q000032:analysis* / Q000266:history; D002250:Carbon Radioisotopes; D003300:Copper / Q000032:analysis*; D004784:Environmental Monitoring / Q000379:methods*; D005844:Geology / Q000379:methods; D049690:History, Ancient; D008906:Mining; D012987:Soil / Q000032:analysis; D014852:Wales
chemical_list: D000393:Air Pollutants; D002250:Carbon Radioisotopes; D012987:Soil; D003300:Copper