title: Polymer-assisted Horner-Emmons olefination using PASSflow reactors: pure products without purification.
abstract: A PASSflow protocol for the Horner-Emmons olefination of aldehydes using polymer-bound hydroxide ions in flowthrough reactors is presented which allows preparation of alkenes in very high yield with minimal purification.
authors.affiliation: Institut für Organische Chemie der Universität Hannover, Schneiderberg 1B, Germany.
authors.forename: Wladimir
authors.initials: W
authors.lastname: Solodenko
authors.forename: Ulrich
authors.initials: U
authors.lastname: Kunz
authors.forename: Gerhard
authors.initials: G
authors.lastname: Jas
authors.forename: Andreas
authors.initials: A
authors.lastname: Kirschning
mesh_terms: D000447:Aldehydes / Q000737:chemistry; D000475:Alkenes / Q000737:chemistry*; D002625:Chemistry, Organic / Q000295:instrumentation / Q000379:methods*; D020650:Combinatorial Chemistry Techniques; D005898:Glass / Q000737:chemistry; D006878:Hydroxides / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008855:Microscopy, Electron, Scanning; D063065:Organophosphonates / Q000737:chemistry; D011137:Polystyrenes / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000447:Aldehydes; D000475:Alkenes; D006878:Hydroxides; D063065:Organophosphonates; D011137:Polystyrenes; C031356:hydroxide ion