title: Sulfinyl-mediated chirality transfer in diastereoselective Claisen rearrangements.
abstract: [reaction: see text] The highly selective Claisen rearrangements of substrates bearing a sulfinyl moiety at C-5 allow for creation of up to two asymmetric centers and preserve a useful vinyl sulfoxide.
authors.affiliation: Instituto de Química Orgánica, CSIC, Juan de la Cierva, 3, 28006 Madrid, Spain. iqofp19@iqog.csic.es
authors.forename: Roberto
authors.initials: R
authors.lastname: Fernández de la Pradilla
authors.forename: Carlos
authors.initials: C
authors.lastname: Montero
authors.forename: Mariola
authors.initials: M
authors.lastname: Tortosa