Polymer-supported catalysts: enantioselective hydrogenation and hydrogen transfer reduction.
Different types of heterogenized catalysts were involved in asymmetric reactions. Hydrogen transfer reduction was performed with amino alcohols derived from poly((S)-(GMA-co-EGDMA or DVB)) and hydrogenation with BINAP grafted onto PEG or copolymerized with isocyanates as ligands. Attempts of catalysts recycling are reported.
Saluzzo
Christine
C
Laboratoire de Catalyse et Synthèse Organique, UMR 5622, Université Claude Bernard Lyon 1, CPE, 43 Bd. du 11 Novembre 1918, 69622 Villeurbanne Cedex, France.
Lamouille
Thierry
T
Hérault
Damien
D
Lemaire
Marc
M
D000090:Acetoacetates / Q000737:chemistry; D000098:Acetophenones / Q000737:chemistry; D000605:Amino Alcohols / Q000737:chemistry*; D002384:Catalysis; D006859:Hydrogen / Q000737:chemistry*; D006865:Hydrogenation; D009281:Naphthalenes / Q000737:chemistry*; D010084:Oxidation-Reduction; D011108:Polymers / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D013237:Stereoisomerism
D000090:Acetoacetates; D000098:Acetophenones; D000605:Amino Alcohols; C406943:BINAP, 2-naphthol; D009281:Naphthalenes; D011108:Polymers; C016635:acetoacetic acid; D012428:Ruthenium; D006859:Hydrogen; C038699:acetophenone