Peracetylated sugar derivatives show high solubility in liquid and supercritical carbon dioxide.
[structure: see text] Acetylated sugars derivatives exhibit high solubility in liquid and supercritical carbon dioxide (scCO(2)). Peracetylated sorbitol and beta-D-galactose are soluble under mild conditions in scCO(2), high pressures are required to dissolve peracetylated beta-cyclodextrin, and peracetoxyalkyl chains impart CO(2)-solubility to amides.
Potluri
Vijay K
VK
Department of Chemistry, Yale University, PO Box 208107, New Haven, Connecticut 06520-8107, USA.
Xu
Jianhang
J
Enick
Robert
R
Beckman
Eric
E
Hamilton
Andrew D
AD
D000107:Acetylation; D002240:Carbohydrate Sequence; D002241:Carbohydrates / Q000138:chemical synthesis / Q000737:chemistry*; D002245:Carbon Dioxide / Q000737:chemistry*; D003505:Cyclodextrins / Q000737:chemistry; D008969:Molecular Sequence Data; D012995:Solubility; D012997:Solvents; D047392:beta-Cyclodextrins
D002241:Carbohydrates; D003505:Cyclodextrins; D012997:Solvents; D047392:beta-Cyclodextrins; D002245:Carbon Dioxide; C031215:betadex