Chlorobis(thiourea-kappa S)copper(I) bis(4,5-diazafluoren-9-one) monohydrate.
The title compound, [CuCl(CH(4)N(2)S)(2)] x 2C(11)H(6)N(2)O x H(2)O, consists of molecules of a Cu(I)-thiourea complex, free 4,5-diazafluoren-9-one (dafone) and crystalline water. The planar complex molecule has trigonal coordination geometry around the Cu(I) atom. The dafone and water molecules, which are hydrogen bonded to the Cu(I) complex, are approximately coplanar with this complex. The crystal displays a sheet structure and pi-pi stacking is observed between neighbouring sheets.
Wu
Zhiyong
Z
Department of Chemistry, Zhejiang University, Hangzhou Zhejiang, People's Republic of China.
Xu
Duanjun
D
Wu
Jingyun
J
Chiang
Michael Y
MY