title: Pressure-induced structural change of liquid silicon.
abstract: High-pressure and high-temperature x-ray diffraction measurements indicate that liquid silicon contracts with increasing pressure without significant changes in the local structure up to 8 GPa and then transforms to a denser structure between 8 and 14 GPa. In spite of volume contraction, the nearest-neighbor interatomic distance expands by about 1.6% within this pressure interval, accompanied by an anomalous increase in the coordination number. These findings reveal that the drastic pressure-induced structural change can take place in three-dimensional-network liquids with rather isotropic bonding.
authors.affiliation: Department of Earth and Planetary Science, University of Tokyo, Tokyo 113-0033, Japan.
authors.forename: Nobumasa
authors.initials: N
authors.lastname: Funamori
authors.forename: Kazuhiko
authors.initials: K
authors.lastname: Tsuji