Total synthesis of (-)- and (+)-lentiginosine.
Total synthesis of (-)-lentiginosine was achieved from D-mannitol using highly stereoselective reactions. Similarly, (+)-lentiginosine was synthesized from L-tartaric acid.
Chandra
Kusum L
KL
Department of Chemistry, Indian Institute of Technology, Kanpur, India.
Chandrasekhar
M
M
Singh
Vinod K
VK
D000470:Alkaloids / Q000138:chemical synthesis* / Q000737:chemistry; D001685:Biological Factors / Q000138:chemical synthesis / Q000737:chemistry; D002384:Catalysis; D002851:Chromatography, High Pressure Liquid; D018360:Crystallography, X-Ray; D009682:Magnetic Resonance Spectroscopy; D008353:Mannitol / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D013237:Stereoisomerism; D013644:Tartrates / Q000737:chemistry
D000470:Alkaloids; D001685:Biological Factors; D013644:Tartrates; C063984:lentiginosine; D008353:Mannitol; C029768:tartaric acid