title: Chiral phosphinooxathiane ligands for catalytic asymmetric Diels-Alder reaction.
abstract: Chiral cationic palladium[bond]phosphinooxathiane complexes have been found to be effective catalysts for enantioselective Diels-Alder (DA) reaction of cyclopentadiene with acyl-1,3-oxazolidin-2-ones to give the corresponding DA adducts in good yield and high enantioselectivity up to 93% ee.
authors.affiliation: Tohoku Pharmaceutical University, 4-4-1 Komatsushima, Aoba-ku, Sendai 981-8558, Japan. hnakano@tohoku-pharm.ac.jp
authors.forename: Hiroto
authors.initials: H
authors.lastname: Nakano
authors.forename: Yuichiro
authors.initials: Y
authors.lastname: Suzuki
authors.forename: Chizuko
authors.initials: C
authors.lastname: Kabuto
authors.forename: Reiko
authors.initials: R
authors.lastname: Fujita
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Hongo