title: Solvent effects and photophysical studies of a new class of acridine(1,8)dione dyes.
abstract: Spectroscopic properties of a new family of acridinedione dyes are reported. The absorption and fluorescence spectra of the different substituted acridinediones have been recorded in different solvents and the difference in the dipole moment between ground and excited state has been obtained by solvatochromic shift method. The value of the Onsager cavity radius was calculated from the total surface area using software PCMODEL. Fluorescence quantum yield and fluorescence lifetime were determined. Radiative and non-radiative constants have been calculated. The triplet-triplet absorption maxima and triplet lifetime show variation depending on the substitution.
authors.affiliation: National Centre for Ultrafast Processes, University of Madras, Chennai, India.
authors.forename: V
authors.initials: V
authors.lastname: Karunakaran
authors.forename: P
authors.initials: P
authors.lastname: Ramamurthy
authors.forename: T
authors.initials: T
authors.lastname: Josephrajan
authors.forename: V T
authors.initials: VT
authors.lastname: Ramakrishnan
mesh_terms: D000097:Acetonitriles / Q000737:chemistry; D000166:Acridines / Q000737:chemistry*; D004396:Coloring Agents / Q000737:chemistry*; D007834:Lasers; D008027:Light; D008956:Models, Chemical; D012984:Software; D012997:Solvents / Q000737:chemistry*; D013050:Spectrometry, Fluorescence
chemical_list: D000097:Acetonitriles; D000166:Acridines; D004396:Coloring Agents; D012997:Solvents; C032159:acetonitrile