The spin population difference of hydrogen atoms dissociated from mercury hydride molecules.
The spin population difference between m(s) = 1/2 and - 1/2, (malpha - mbeta)(t) of the hydrogen atoms dissociated from the mercury hydride molecules is calculated as a function of time for the reaction of Hg* + H2 in a magnetic field. Starting from zero value, the population difference increases to a certain limit that is equal to the room temperature population difference. The H/D electron spin resonance (ESR) signal ratio obtained from the isotopic experiment, Hg* + H2/D2, is also explained by comparing the ratio of (malpha - mbeta)H(t) and (malpha - mbeta)D(t). The isotopic effect is interpreted to originate mostly from spin-rotation constant energies of mercury hydride molecules.
Yi
Whikun
W
FED Project, Samsung Advanced Institute of Technology, Suwon, South Korea. wkyi@sait.samsung.co.kr
Yu
SeGi
S
Bersohn
Richard
R
D004578:Electron Spin Resonance Spectroscopy / Q000379:methods*; D006859:Hydrogen / Q000737:chemistry*; D007554:Isotopes; D008280:Magnetics; D008628:Mercury / Q000737:chemistry*; D008956:Models, Chemical; D013696:Temperature; D013997:Time Factors
D007554:Isotopes; D006859:Hydrogen; D008628:Mercury