Polymer-assisted Horner-Emmons olefination using PASSflow reactors: pure products without purification.
A PASSflow protocol for the Horner-Emmons olefination of aldehydes using polymer-bound hydroxide ions in flowthrough reactors is presented which allows preparation of alkenes in very high yield with minimal purification.
Solodenko
Wladimir
W
Institut für Organische Chemie der Universität Hannover, Schneiderberg 1B, Germany.
Kunz
Ulrich
U
Jas
Gerhard
G
Kirschning
Andreas
A
D000447:Aldehydes / Q000737:chemistry; D000475:Alkenes / Q000737:chemistry*; D002625:Chemistry, Organic / Q000295:instrumentation / Q000379:methods*; D020650:Combinatorial Chemistry Techniques; D005898:Glass / Q000737:chemistry; D006878:Hydroxides / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008855:Microscopy, Electron, Scanning; D063065:Organophosphonates / Q000737:chemistry; D011137:Polystyrenes / Q000737:chemistry*; D013237:Stereoisomerism
D000447:Aldehydes; D000475:Alkenes; D006878:Hydroxides; D063065:Organophosphonates; D011137:Polystyrenes; C031356:hydroxide ion