Polymer-supported chiral catalysts with positive support effects.
In this paper, we discuss the rational design of polymeric catalysts and the positive effect of polymer supports on the catalytic asymmetric reactions. The attachment of chiral catalysts to soluble polymers, particularly dendritic polymers, offered a potential combination of the advantages of homogeneous and heterogeneous asymmetric catalysis.
Fan
Qing-Hua
QH
Center for Molecular Science, Institute of Chemistry, The Chinese Academy of Sciences, Beijing 100080, PR China.
Wang
Rui
R
Chan
Albert S C
AS
D000179:Acrylates / Q000737:chemistry; D000447:Aldehydes / Q000737:chemistry; D001555:Benzene Derivatives / Q000737:chemistry; D002384:Catalysis; D002625:Chemistry, Organic / Q000379:methods*; D006865:Hydrogenation; D007700:Kinetics; D008024:Ligands; D009281:Naphthalenes / Q000737:chemistry*; D009284:Naphthols / Q000138:chemical synthesis; D009942:Organometallic Compounds / Q000737:chemistry; D011108:Polymers / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry; D012995:Solubility; D013237:Stereoisomerism; D013329:Structure-Activity Relationship; D014025:Titanium / Q000737:chemistry
D000179:Acrylates; D000447:Aldehydes; C406943:BINAP, 2-naphthol; D001555:Benzene Derivatives; D008024:Ligands; D009281:Naphthalenes; D009284:Naphthols; D009942:Organometallic Compounds; D011108:Polymers; C412332:1,1'-bi-2-naphthol; D012428:Ruthenium; D014025:Titanium; C036658:acrylic acid; C454811:diethylzinc