Cu(2+)-induced formation of cage-like compounds containing pyrazole macrocycles.
The crystal structure of the complex [Cu4(H-2L)2(H2O)2(ClO4)2](ClO4)(2).2H2O where L is a new pyrazole ligand containing 1,5-diaminopentane spacers represents a new form of obtaining metal ion-induced inorganic-organic cages.
Departamento de Quimica Inorganica, Universidad de Valencia, c/Dr. Moliner, 50, 46100-Burjassot Valencia, Spain.
Francisco
F
Escartí
Carlos
C
Miranda
Laurent
L
Lamarque
Julio
J
Latorre
Enrique
E
García-España
M
M
Kumar
Vicente J
VJ
Arán
Pilar
P
Navarro