Structural characterization of U(VI) in apatite by X-ray absorption spectroscopy.
X-ray absorption spectroscopy was used to determine the local structure of U(VI) within synthetic fluorapatite at a concentration of 2.3 wt %. Extended X-ray absorption fine structure indicates that U(VI) substitutes into the Ca1 site. To accommodate this substitution the apatite structure significantly distorts such that the Ca1 site approximates octahedral coordination, with six uniform U-0 distances of 2.06A. An X-ray adsorption edge structure, with two inflection points, and optical emission spectra are consistent with 6d orbital crystal field splitting. These results indicate that significant amounts of U(VI) can be accommodated in the apatite structure but with an unexpected coordination, which may bear on the ultimate development of apatite-hosted nuclear-waste forms.
Department of Geology, Miami University, Oxford, Ohio 45056, USA. Rakovajf@muohio.edu
John
J
Rakovan
Richard J
RJ
Reeder
Evert J
EJ
Elzinga
Daniele J
DJ
Cherniak
C Drew
CD
Tait
David E
DE
Morriss
D001031:Apatites / Q000737:chemistry*; D004784:Environmental Monitoring; D015394:Molecular Structure; D011850:Radioactive Waste; D013057:Spectrum Analysis / Q000379:methods; D014501:Uranium / Q000737:chemistry*
D001031:Apatites; D011850:Radioactive Waste; D014501:Uranium