Evidence that gold(III) porphyrins are not electrochemically inert: facile generation of gold(II) 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin.
Gold(III) porphyrin 1 is shown to undergo reduction at the central metal ion to give the first known gold(II) porphyrin overturning the long held assumption that reduction of such complexes only occurs at the macrocycle.
Department of Chemistry, University of Houston, Houston, Texas, TX 77204-5003, USA.
Karl M
KM
Kadish
E
E
Wenbo
Zhongping
Z
Ou
Jianguo
J
Shao
Paul J
PJ
Sintic
Kei
K
Ohkubo
Shunichi
S
Fukuzumi
Maxwell J
MJ
Crossley