Molecular batteries: synthesis and characterization of a dendritic 19-electron FeI complex that reduces C60 to its mono-anion.
Both redox forms of the dendrimer [dendr-64-NHCOCpFeII(eta 6-C6Me6)]64+/0, 6/7, are synthesized and characterized, and the 19-electron form reduces C60 to [dendr-64-NHCOCpFeII(eta 6-C6Me6)]64+(C60-.)64, 8.
Ruiz
Jamie
J
Groupe de Chimie Supramoléculaire des Métaux de Transition, LCOO, UMR CNRS No 5802, Université Bordeaux I, 33405 Talence Cedex, France.
Pradet
Charlotte
C
Varret
François
F
Astruc
Didier
D