Synthesis, structure determination and properties of MIL-53as and MIL-53ht: the first CrIII hybrid inorganic-organic microporous solids: CrIII(OH).(O2C-C6H4-CO2).(HO2C-C6H4-CO2H)x.
The first three-dimensional chromium(III) dicarboxylate compounds have been isolated and their structures solved from powder X-ray diffraction data; the flexible framework of these materials delimits large pores.
Institut Lavoisier, UMR CNRS 8637, Université de Versailles Saint-Quentin-en-Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles, France.
Franck
F
Millange
Christian
C
Serre
Gérard
G
Férey
D002857:Chromium / Q000737:chemistry*; D017608:Chromium Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D003998:Dicarboxylic Acids / Q000737:chemistry*; D006358:Hot Temperature; D008968:Molecular Conformation; D014961:X-Ray Diffraction
D017608:Chromium Compounds; D003998:Dicarboxylic Acids; D002857:Chromium