Insertion of an electron-rich alkyne into a molybdenum amido bond.
A pseudo-octahedral molybdenum dimethylamido complex that readily inserts 3-hexyne forming a new C-N bond has been characterized.
Katayev
Evgeny
E
Department of Chemistry, East Lansing, MI, USA.
Li
Yahong
Y
Odom
Aaron L
AL
D000480:Alkynes / Q000737:chemistry*; D000577:Amides / Q000737:chemistry; D055598:Chemical Phenomena; D002621:Chemistry; D004583:Electrons; D008956:Models, Chemical; D015394:Molecular Structure; D008982:Molybdenum / Q000737:chemistry* / Q000378:metabolism
D000480:Alkynes; D000577:Amides; D008982:Molybdenum