Highly saddle shaped (porphyrinato)iron(III) iodide with a pure intermediate spin state.
Combined analyses using NMR, EPR and Mössbauer spectroscopy as well as SQUID magnetometry have revealed that highly saddle shaped Fe(OETPP)I adopts an essentially pure intermediate spin state in spite of the coordination of an iodide ligand.
Department of Chemistry, Toho University School of Medicine, Ota-ku, Tokyo 143-8540, Japan. mnakamu@med.toho-u.ac.jp
Mikio
M
Nakamura
Takahisa
T
Ikeue
Yoshiki
Y
Ohgo
Masashi
M
Takahashi
Masuo
M
Takeda