Synthesis of planar chiral (1,3-disubstituted arene) Mn(CO)3+ cations via addition of nucleophiles to (oxocyclohexadienyl)Mn(CO)3 in the presence of chiral ligands.
The first example of the synthesis of planar chiral (1,3-disubstituted arene)Mn(CO)3+ cations (3) has been demonstrated by a reaction of (p-cresol)Mn(CO)3+ with KOBut followed by addition of nucleophiles and subsequent quenching with electrophiles in the presence of (S)-binaphthol in CH2Cl2.
School of Chemistry, Center for Molecular Catalysis, Seoul National University, Seoul 151-747, Korea.
Seung Uk
SU
Son
Kang Hyun
KH
Park
Seung Jung
SJ
Lee
Hwimin
H
Seo
Young Keun
YK
Chung