The structures of Cu(I) and Ag(I) coordination polymers using the tricyanofluoroborate anion.
The anion BF(CN)3-forms isomorphous network polymers with Cu(I) and Ag(I) that exhibit one-dimensional channels along the b axis and demonstrate stability to air and light respectively.
Department of Chemistry, University of Akron, Akron, OH 44325-3601, USA.
Barton H
BH
Hamilton
Christopher J
CJ
Ziegler
D000838:Anions / Q000737:chemistry; D001881:Borates / Q000737:chemistry*; D055598:Chemical Phenomena; D002627:Chemistry, Physical; D003300:Copper / Q000737:chemistry*; D003486:Cyanides / Q000737:chemistry; D015394:Molecular Structure; D011108:Polymers; D012834:Silver / Q000737:chemistry*
D000838:Anions; D001881:Borates; D003486:Cyanides; D011108:Polymers; D012834:Silver; D003300:Copper; C098759:fluoroboric acid