Synthesis and crystal structure of a novel decanuclear silver cluster complex [Ag(SC6H2Pri(3)-2,4,6)](10).2CHCI3.C2H5OH.
The cluster [Ag(SC6H2Pri(3)-2,4,6)]10 (1) contains a 20-membered ring of alternating silver and sulfur atoms, which is compactly folded; the sulfur atoms are doubly bridging and each silver atom exhibits linear two-coordination in the primary Ag-S interactions.
Jin
Xianglin
X
Institute of Physical Chemistry, Peking University, Beijing 100871, P. R. China.
Xie
Xiangjin
X
Qian
Hua
H
Tang
Kaluo
K
Liu
Chunling
C
Wang
Xin
X
Gong
Qihuang
Q