Novel photo-induced coupling reaction of 9-fluorenylidenemalononitrile with 10-methyl-9,10-dihydroacridine.
9-Fluorenylidenemalononitrile reacts with 10-methyl-9,10-dihydroacridine in deaerated acetonitrile under irradiation with lambda > 320 nm to give a coupling product 9-dicyanomethyl-9-(10'-methyl-9'-acridinyl)fluorene, characterized by X-ray crystallographic, MS and NMR analyses.
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China.
Hong
H
Jiang
You-Cheng
YC
Liu
Jing
J
Li
Guan-Wu
GW
Wang
Yun-Dong
YD
Wu
Quan-Ming
QM
Wang
Thomas C W
TC
Mak
D000097:Acetonitriles / Q000737:chemistry; D000166:Acridines / Q000737:chemistry* / Q000378:metabolism; D018360:Crystallography, X-Ray; D005449:Fluorenes / Q000737:chemistry*; D008027:Light; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry; D015394:Molecular Structure; D009570:Nitriles / Q000737:chemistry* / Q000378:metabolism; D010777:Photochemistry
D000097:Acetonitriles; D000166:Acridines; D005449:Fluorenes; D009570:Nitriles; C000945:dicyanmethane; C032159:acetonitrile