Selective oxidation of glycerol to glyceric acid using a gold catalyst in aqueous sodium hydroxide.
Glycerol is oxidised to glyceric acid with 100% selectivity using either 1% Au/charcoal or 1% Au/graphite catalyst under mild reaction conditions (60 degrees C, 3 h, water as solvent).
Department of Chemistry, Cardiff University, P.O. Box 912, Cardiff, UK CF10 3TB.
Silvio
S
Carrettin
Paul
P
McMorn
Peter
P
Johnston
Ken
K
Griffin
Graham J
GJ
Hutchings