An unprecedented example of a cis-phosphonodithioato nickel(II) complex built by an extensive hydrogen bonding supramolecular network.
The P-N bond hydrolysis of the 4-methoxyphenyl-ammonium ethylamido-phosphonodithioato ligand during its complexation to NiII leads to the first example of phosphonodithioato nickel(II) complex having a cis configuration; this complex is stabilised in the solid state by an extensive and intricate network of hydrogen bondings involving the released ethylenediamine and a water molecule.
Dipartimento di Chimica G. Ciamician, Via Selmi 2, I-40126 Bologna, Italy.
Vincenzo G
VG
Albano
M Carla
MC
Aragoni
Massimiliano
M
Arca
Carlo
C
Castellari
Francesco
F
Demartin
Francesco A
FA
Devillanova
Francesco
F
Isaia
Vito
V
Lippolis
Laura
L
Loddo
Gaetano
G
Verani