The d2/d3 alkyne redox pair [WF2(PhC identical to CPh)Tp']z (z = +1 or 0): missing links in a 'redox family tree'.
The d2/d3 redox pair [WF2(PhC identical to CPh)Tp']z [z = +1 or 0, Tp' = hydrotris(3,5-dimethylpyrazolyl)borate] is the missing link in a 'redox family tree' relating the d6 tricarbonyls [M(CO)3L]- to the d2 trihalides [MX3L] (M = Mo or W, L = Cp or Tp') by a series of stepwise reactions involving sequential one-electron oxidation followed by ligand substitution.
Adams
Christopher J
CJ
School of Chemistry, University of Bristol, Bristol, UK BS8 1TS.
Anderson
Kirsty M
KM
Connelly
Neil G
NG
Harding
David J
DJ
Orpen
A Guy
AG
Patron
Elena
E
Rieger
Philip H
PH