Functionalisation of carbon dioxide by an iron(II) complex.
Addition of carbon dioxide to trans-Fe(dmpe)2(SCHNEt)H 2 affords the iminium carboxylate trans-Fe(dmpe)2(SCHN+(Et)CO2-)H 4, which rearranges to the ferracyle cis-Fe(dmpe)2(SCH2N(Et)C(O)O-kappa S,O) 5.
School of Chemistry, University of Sydney, New South Wales, 2006, Australia.
Leslie D
LD
Field
Warren J
WJ
Shaw
Peter
P
Turner