Chirality induction in supramolecular aggregate: chiral recognition between armed cyclen-Na+ complexes having quadruplicated helical geometry.
A water-soluble self-aggregate of octadentate Na+ complex with chiral cholesterol-armed cyclen provides unique microenvironments for chirality induction of guest cyclen-Na+ complex via supramolecular interaction.
Department of Chemistry, Graduate School of Science, Osaka City University, Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan.
Tomoko
T
Nishimura
Satoshi
S
Shinoda
Hiroshi
H
Tsukube
D002942:Circular Dichroism; D008956:Models, Chemical; D012964:Sodium / Q000737:chemistry*; D013237:Stereoisomerism; D014867:Water / Q000737:chemistry
D014867:Water; D012964:Sodium