Highly saddle shaped (porphyrinato)iron(III) iodide with a pure intermediate spin state.
Combined analyses using NMR, EPR and Mössbauer spectroscopy as well as SQUID magnetometry have revealed that highly saddle shaped Fe(OETPP)I adopts an essentially pure intermediate spin state in spite of the coordination of an iodide ligand.
Nakamura
Mikio
M
Department of Chemistry, Toho University School of Medicine, Ota-ku, Tokyo 143-8540, Japan. mnakamu@med.toho-u.ac.jp
Ikeue
Takahisa
T
Ohgo
Yoshiki
Y
Takahashi
Masashi
M
Takeda
Masuo
M