Total synthesis of (+/-)-momilactone A.
The first total synthesis of (+/-)-momilactone A was accomplished using a highly diastereoselective transannular Diels-Alder reaction on a trans-trans-cis macrocyclic triene.
Laboratoire de synthèse organique, Département de chimie, Institut de Pharmacologie, Université de Sherbrooke, 3001, 12e avenue nord, Sherbrooke, Québec, Canada J1H 5N4.
Julie
J
Germain
Pierre
P
Deslongchamps
D002384:Catalysis; D002625:Chemistry, Organic / Q000379:methods*; D018360:Crystallography, X-Ray; D003500:Cyclization; D004224:Diterpenes / Q000138:chemical synthesis*; D015394:Molecular Structure; D019906:Nuclear Magnetic Resonance, Biomolecular; D012275:Oryza / Q000737:chemistry; D012639:Seeds / Q000737:chemistry; D013237:Stereoisomerism
D004224:Diterpenes; C116023:momilactone A