Base promoted isomerization of aziridinyl ethers: a new access to alpha- and beta-amino acids.
Aziridinyl ethers are selectively and easily converted to either amino vinyl ethers or alkoxy allylamines by treatment with mixed metal bases (superbases).
Mordini
Alessandro
A
Istituto di Chimica dei Composti Organometallici (ICCOM), Dipartimento di Chimica Organica U. Schiff, Via della Lastruccia 13, 50019 Sesto Fiorentino, Firenze, Italy. alessandro.mordini@unifi.it
Sbaragli
Laura
L
Valacchi
Michela
M
Russo
Francesco
F
Reginato
Gianna
G
D000596:Amino Acids / Q000138:chemical synthesis*; D001388:Aziridines / Q000737:chemistry; D004987:Ethers / Q000737:chemistry*; D006898:Hydroxylamines / Q000138:chemical synthesis; D007536:Isomerism
D000596:Amino Acids; D001388:Aziridines; D004987:Ethers; D006898:Hydroxylamines