Stereoselective one-pot preparation of 1,2,4,5-tetraalkylidene- and 1,4-dialkylidenecyclohexanes.
1,2,4,5-Tetraalkylidene- and 1,4-dialkylidenecyclohexanes were prepared by the regio- and stereoselective homocoupling of skip-type diynes and enynes, and their Diels-Alder reaction to form a polycyclic compound was demonstrated.
Delas
Christophe
C
Department of Biomolecular Engineering, Graduate School of Bioscience and Biotechnology, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama, Kanagawa 226-8501, Japan.
Urabe
Hirokazu
H
Sato
Fumie
F
D003510:Cyclohexanes / Q000138:chemical synthesis*; D011083:Polycyclic Compounds / Q000138:chemical synthesis*; D013237:Stereoisomerism; D014297:Trimethylsilyl Compounds / Q000138:chemical synthesis*
D003510:Cyclohexanes; D011083:Polycyclic Compounds; D014297:Trimethylsilyl Compounds