Synthesis of (chlorovinyl)cobaloxime complexes, model complexes of proposed intermediates in the B12-catalyzed dehalogenation of chlorinated ethylenes.
(Chlorovinyl)cobaloxime complexes, (dmgH)2(py)CoR (R = cis-dichlorovinyl, trans-2-chlorovinyl or 1-chlorovinyl, dmgH = dimethylglyoximate) were synthesized from the reaction of chlorinated ethylenes with in situ generated (dmgH)2Co(I) in the presence of pyridine.
Rich
Autumn E
AE
Department of Chemistry, University of Minnesota, 207 Pleasant St. SE, Minneapolis, MN, USA.
DeGreeff
Angela D
AD
McNeill
Kristopher
K