Biocatalysis in ionic liquids: batchwise and continuous flow processes using supercritical carbon dioxide as the mobile phase.
A new and environmentally benign protocol for enzymatic reactions in ionic liquids is described using supercritical CO2 as the mobile phase; the products are obtained in solvent-free form and the enzyme/ionic liquid mixture can be recycled in batchwise or continuous flow operations.
Reetz
Manfred T
MT
Max-Planck-Institut für Kohlenforschung, D-45470 Mülheim/Ruhr, Germany. reetz@mpi-muelheim.mpg.de
Wiesenhöfer
Wolfgang
W
Franciò
Giancarlo
G
Leitner
Walter
W
D002175:Candida / Q000201:enzymology; D002245:Carbon Dioxide; D002384:Catalysis; D005656:Fungal Proteins; D007477:Ions; D008049:Lipase / Q000378:metabolism*; D012996:Solutions
D005656:Fungal Proteins; D007477:Ions; D012996:Solutions; D002245:Carbon Dioxide; D008049:Lipase; C431349:lipase B, Candida antarctica