Synthesis of (chlorovinyl)cobaloxime complexes, model complexes of proposed intermediates in the B12-catalyzed dehalogenation of chlorinated ethylenes.
(Chlorovinyl)cobaloxime complexes, (dmgH)2(py)CoR (R = cis-dichlorovinyl, trans-2-chlorovinyl or 1-chlorovinyl, dmgH = dimethylglyoximate) were synthesized from the reaction of chlorinated ethylenes with in situ generated (dmgH)2Co(I) in the presence of pyridine.
Department of Chemistry, University of Minnesota, 207 Pleasant St. SE, Minneapolis, MN, USA.
Autumn E
AE
Rich
Angela D
AD
DeGreeff
Kristopher
K
McNeill