Continuous green biocatalytic processes using ionic liquids and supercritical carbon dioxide.
Soluble Candida antarctica lipase B dissolved in ionic liquids showed good synthetic activity, enantioselectivity and operational stability in supercritical carbon dioxide for both butyl butyrate synthesis and the kinetic resolution of 1-phenylethanol processes by transesterification.
Lozano
Pedro
P
Departamento de Bioquímica y Biología Molecular B e Inmunología, Facultad de Química, Universidad de Murcia, P.O. Box 4021, E-30100 Murcia, España.
de Diego
Teresa
T
Carrié
Daniel
D
Vaultier
Michel
M
Iborra
José L
JL
D000397:Air Pollution / Q000517:prevention & control; D002087:Butyrates / Q000138:chemical synthesis; D002245:Carbon Dioxide / Q000737:chemistry*; D002384:Catalysis; D004951:Esterification; D005656:Fungal Proteins; D007218:Industrial Microbiology / Q000379:methods*; D007477:Ions; D008049:Lipase / Q000378:metabolism*; D010626:Phenylethyl Alcohol / Q000302:isolation & purification
D002087:Butyrates; D005656:Fungal Proteins; D007477:Ions; D002245:Carbon Dioxide; D008049:Lipase; C431349:lipase B, Candida antarctica; D010626:Phenylethyl Alcohol