A novel ribbon-candy-like supramolecular architecture of cadmium(II)-terephthalate polymer with giant rhombic channels: twofold interpenetration of the 3D 8(2)10-a net.
The hydrothermal reaction of H2tp (tp = terephthalate), [Ph3PCH2Ph]Cl and water with Cd(O2CCH3)(2).2H2O gives rise to a novel ribbon-candy-like supramolecular architecture with twofold interpenetration of an unprecedented 3D 8(2)10-a net formed by polymer ([Ph3PCH2Ph][Cd(tp).Cl].2H2O]n containing giant rhombic channels, which displays strong fluorescent emission in the solid state.
Dai
Jing-Cao
JC
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
Wu
Xin-Tao
XT
Fu
Zhi-Yong
ZY
Hu
Sheng-Min
SM
Du
Wen-Xing
WX
Cui
Chuan-Peng
CP
Wu
Li-Ming
LM
Zhang
Han-Hui
HH
Sun
Rui-Qing
RQ