Revealing the photophysics of fac-[(dppz-12-NO2)Re(CO)3(4-Me2Npy)]+: a picosecond time-resolved IR study.
The photophysics of fac-[(dppz-12-NO2)Re(CO)3(4-Me2Npy)]+ in CH3CN have been investigated using picosecond time-resolved IR (ps-TRIR) spectroscopy, to reveal the first example of a Re(I)-dppz complex with a charge separated lowest-lying excited state.
Dyer
Joanne
J
School of Chemistry, University of Nottingham, University Park, Nottingham, UK NG7 2RD.
Grills
David C
DC
Matousek
Pavel
P
Parker
Anthony W
AW
Towrie
Michael
M
Weinstein
Julia A
JA
George
Michael W
MW
D007700:Kinetics; D008968:Molecular Conformation; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010777:Photochemistry; D055585:Physical Phenomena; D010825:Physics; D012211:Rhenium / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared; D013997:Time Factors
D009942:Organometallic Compounds; D012211:Rhenium