Unique crown thioether complexes of f elements: the crystal structure of U(III) and La(III) complexes of 1,4,7-trithiacyclononane.
The crystal structures of the first U(III) complex of a crown thioether and of its La(III) analog have been determined; a stronger M-S interaction is observed for U(III) with respect to La(III) and Ce(III) in solution and in the solid state.
Karmazin
Lydia
L
Laboratoire de Reconnaissance Ionique, Département de Recherche Fondamentale sur la Matière Condensée, CEA-Grenoble, 17 rue des Martyrs, 38054 Grenoble, France.
Mazzanti
Marinella
M
Pécaut
Jacques
J
D000473:Alkanes / Q000737:chemistry; D018360:Crystallography, X-Ray; D004988:Ethers, Cyclic / Q000737:chemistry*; D007811:Lanthanum / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry; D011850:Radioactive Waste; D013457:Sulfur Compounds / Q000737:chemistry; D014501:Uranium / Q000737:chemistry*
D000473:Alkanes; D004988:Ethers, Cyclic; D009942:Organometallic Compounds; D011850:Radioactive Waste; D013457:Sulfur Compounds; C421311:trithiacyclononane; D014501:Uranium; D007811:Lanthanum