New suppressor technology improves trace level anion analysis with carbonate-hydrogencarbonate mobile phases.
Sodium carbonate-hydrogencarbonate mobile phases are preferred over sodium hydroxide for anion analysis by suppressor-based ion chromatography (IC). Unlike hydroxide, carbonate-hydrogencarbonate has strong eluting power and its buffering capacity can be used as a selectivity tool for controlling separations. However, carbonate-hydrogencarbonate mobile phases fell out of favor for trace level analysis because the carbonic acid suppressor effluent has some background conductivity, which reduces sensitivity compared to sodium hydroxide. This paper describes a new suppressor technology that improved anion analysis with carbonate-hydrogencarbonate mobile phases. In addition to converting the carbonate-hydrogencarbonate buffer to carbonic acid like other traditional IC suppressors, the new DS-Plus suppressor also removed carbonic acid from the suppressor effluent. Anions are now detected in water background, just like when using sodium hydroxide as the mobile phase. The lower background conductivity improves sensitivity and reduces detection limits. The water-dip often seen with conventional suppressors is greatly reduced, improving fluoride quantification.
Douglas
Derick R
DR
Alltech Associates, Inc, Deerfield, IL 60015, USA. ddouglas@alltechemail.com
Saari-Nordhaus
Raaidah
R
Despres
Philippe
P
Anderson
James M
JM
D000838:Anions / Q000032:analysis*; D001639:Bicarbonates / Q000737:chemistry*; D002254:Carbonates / Q000737:chemistry*; D012680:Sensitivity and Specificity
D000838:Anions; D001639:Bicarbonates; D002254:Carbonates