Controlling the variation of axial water exchange rates in macrocyclic lanthanide(III) complexes.
The rate of axial water exchange in well-defined series of lanthanide complexes depends on the extent of second sphere hydration which is determined by complex hydrophobicity and the nature of the lanthanide ion and its counter-ion.
Dipartimento di Chimica IFM, Università di Torino, Via P. Giuria I-10125, Torino, Italy.
Silvio
S
Aime
Alessandro
A
Barge
Andrei S
AS
Batsanov
Mauro
M
Botta
Daniela Delli
DD
Castelli
Franco
F
Fedeli
Armando
A
Mortillaro
David
D
Parker
Horst
H
Puschmann