Electronic state and three-dimensional structure of Mn(III) active sites in manganese-containing aluminophosphate molecular sieve catalysts for the oxyfunctionalisation of alkanes.
Combined in situ X-ray absorption spectroscopy measurements and quantum mechanical calculations yield a quantitative three-dimensional structure of the tetrahedrally coordinated Mn(III) active sites in MnAlPO catalysts.
Corà
Furio
F
Davy Faraday Research Laboratory, The Royal Institution of GB, 21 Albemarle Street, London, UK W1S 4BS.
Sankar
Gopinathan
G
Catlow
C Richard A
CR
Thomas
John Meurig
JM