Aqueous enantioselective hydrogenation of methyl 2-acetamidoacrylate with Rh-MeDuPHOS occluded in PDMS.
A new chiral heterogeneous catalytic system obtained by occlusion of the Rh-MeDuPHOS complex in a polydimethylsiloxane film was tested in the asymmetric hydrogenation of methyl 2-acetamidoacrylate in aqueous medium.
Department of Chemical Engineering, Ben-Gurion University of the Negev, Beer-Sheva, 84105, Israel.
Adi
A
Wolfson
Sofie
S
Janssens
Ivo
I
Vankelecom
Shimona
S
Geresh
Moshe
M
Gottlieb
Moti
M
Herskowitz