Hydrogen-bonded extended structure of the 1:3 adduct of a C3 symmetric cobalt(III) complex with a tripod-ligand involving three imidazolate groups and hydroquinone or resorcinol.
The assembly reaction arising from hydrogen bonding between a chiral C3 symmetric cobalt(III) complex and a tripod-ligand involving three imidazolate groups [tris[2-(((2-methylimidazolato-4-yl)methylidene)amino)ethyl]amine]cobalt(III) and either hydroquinone or resorcinol gave the 1:3 adducts, with 3D extended structures showing the template effect of the complex.
Nagasato
Shigeyuki
S
Department of Chemistry, Faculty of Science, Kumamoto University, Kurokami 2-39-1, Kumamoto 860-8555, Japan.
Sunatsuki
Yukinari
Y
Ohsato
Susumu
S
Kido
Takafumi
T
Matsumoto
Naohide
N
Kojima
Masaaki
M