Synthesis of dicobalt hexacarbonyl 5-p-tolylethynyl-2'-deoxyuridine.
Reactions of 5-p-tolylethynyl-2'-deoxyuridine and 3',5'-di-O-acetyl-5-p-tolylethynyl-2'-deoxyuridine with Co2(CO)8 in THF gave 5-p-tolC2[CO2(CO)6]-2'-deoxyuridine and 3',5'-di-O-acetyl-5-p-tolC2[CO2(CO)6]-2'-deoxyuridine (92 and 66%).
Esho
Noor
N
Department of Chemistry and Center for Biomedical Research, Oakland University, 2200 N. Squirrel Road, Rochester, MI 48309-4477, USA.
Davies
Brian
B
Lee
Janet
J
Dembinski
Roman
R
D003500:Cyclization; D015342:DNA Probes / Q000138:chemical synthesis* / Q000737:chemistry; D003857:Deoxyuridine / Q000031:analogs & derivatives / Q000737:chemistry / Q000145:classification*; D006860:Hydrogen Bonding; D009682:Magnetic Resonance Spectroscopy; D008670:Metals / Q000737:chemistry
D015342:DNA Probes; D008670:Metals; C461920:dicobalt hexacarbonyl 5-p-tolylethynyl-2'-deoxyuridine; D003857:Deoxyuridine