Facile synthesis of ketones from 1,1-disilylethenes via oxidation of gem-disilylalkanes.
The oxidation of gem-disilylalkanes, which can be derived from 1,1-disilylethene, alkyllithiums and alkyl halides, affords the corresponding ketones.
Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 606-8501, Japan.
Atsushi
A
Inoue
Junichi
J
Kondo
Hiroshi
H
Shinokubo
Koichiro
K
Oshima