Reaction chemistry of metallotexaphyrins: the synthesis and characterization of the first meso-oxotexaphlorin.
Ring-oxygenation of metallotexaphyrins, promoted by strong bases, produces oxotexaphlorin, the first example of a meso-oxo functionalized texaphyrin derivative.
Wang
Zhong
Z
Pharmacyclics, Inc, 995 East Arques Avenue, Sunnyvale, California 94085, USA.
Fu
Lei
L
Mody
Tarak D
TD
D005682:Gadolinium / Q000737:chemistry; D028581:Lanthanoid Series Elements / Q000737:chemistry*; D007811:Lanthanum / Q000737:chemistry; D008024:Ligands; D008665:Metalloporphyrins / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D010100:Oxygen / Q000737:chemistry; D011166:Porphyrins / Q000138:chemical synthesis* / Q000737:chemistry
D028581:Lanthanoid Series Elements; D008024:Ligands; D008665:Metalloporphyrins; D011166:Porphyrins; C442892:texaphyrin; D007811:Lanthanum; D005682:Gadolinium; D010100:Oxygen