Vanadium nitride functionalization and denitrogenation by carbon disulfide and dioxide.
A dramatic difference in behavior is observed for the dithiocarbamate and carbamate complexes [Ar(But)N]3V(NCE2)Na(THF)2(E = S or O, respectively), prepared from the corresponding nitride species ([Ar(But)N]3V identical to NNa)2 by way of a nucleophilic addition reaction involving carbon disulfide or dioxide, and is rationalized with the aid of DFT calculations.
Department of Chemistry, Room 2-227, Massachusetts Institute of Technology, Cambridge, MA 02139-4307, USA.
Justin K
JK
Brask
Víctor
V
Durà-Vilà
Paula L
PL
Diaconescu
Christopher C
CC
Cummins
D002245:Carbon Dioxide / Q000494:pharmacology*; D002246:Carbon Disulfide / Q000494:pharmacology*; D008433:Mathematics; D008956:Models, Chemical; D009584:Nitrogen / Q000737:chemistry*; D013859:Thiocarbamates / Q000737:chemistry*; D017968:Vanadium Compounds / Q000378:metabolism*
D013859:Thiocarbamates; D017968:Vanadium Compounds; D002245:Carbon Dioxide; D009584:Nitrogen; D002246:Carbon Disulfide