An unexpected Diels-Alder reaction on the fullerene core rather than an expected 1,3-dipolar cycloaddition.
Fullerene derivatives resulting from an unexpected Diels-Alder cycloaddition have been obtained by reaction of trans-2-stilbenecarboxaldehyde derivatives with N-methylglycine and C60.
Eckert
Jean-François
JF
Institut de Physique et Chimie des Matériaux de Strasbourg, Groupe des Matériaux Organiques, Université Louis Pasteur et CNRS, 23 rue du Loess, 67037 Strasbourg, France.
Bourgogne
Cyril
C
Nierengarten
Jean-François
JF
D037741:Fullerenes / Q000737:chemistry*; D015394:Molecular Structure; D012521:Sarcosine / Q000737:chemistry; D013267:Stilbenes / Q000737:chemistry
D037741:Fullerenes; D013267:Stilbenes; C069837:fullerene C60; D012521:Sarcosine