Synthesis and crystal structure of the first scandium-containing open framework solid.
A novel open framework scandium sulfate phosphate is prepared hydrothermally in the presence of the azamacrocycle cyclen (1,4,7,10-tetraazacyclododecane) in which secondary building units of formula Sc7(S,P)12O48 are linked to give a structure with supercages.
School of Chemistry, University of St Andrews, St Andrews, Fife, UK KY16 9ST.
Ivor
I
Bull
Paul S
PS
Wheatley
Philip
P
Lightfoot
Russell E
RE
Morris
Enrique
E
Sastre
Paul A
PA
Wright