A three-dimensional zeolite-like organic-inorganic hybrid material constructed from (CuMo2O8N)n double helical chains linked via [Cu(4,4'-bpy)]n fragments.
The three-dimensional microporous [Cu2Mo2O8(4,4'-bpy)]n.3nH2O 1 contains (CuMo2O8N) double helical chains, which are built up from (CuIIO4N) square pyramids linked by (MoVIO4) tetrahedra and further connected to each other by 4,4'-bpy coordinated (CuIIO5N); the study of the physical properties of 1 demonstrates it is a paramagnetic semiconductor and a zeolite material; the specific channeling cavities in 1 have potential adsorption activities, indicating that 1 might be an attractive functional microporous solid material.
Lu
Can-Zhong
CZ
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. czlu@ms.fjirsm.ac.cn
Wu
Chuan-De
CD
Lu
Shao-Fang
SF
Liu
Jia-Cheng
JC
Wu
Qiang-Jin
QJ
Zhuang
Hong-Hui
HH
Huang
Jin-Shun
JS