Organometallic chemistry of carbaporphyrinoids: synthesis and characterization of nickel(II) and palladium(II) azuliporphyrins.
Brief treatment of azuliporphyrins 5 with nickel(II) or palladium(II) acetate in refluxing DMF afforded excellent yields of the related chelates; these novel organometallic compounds retain cross-conjugated borderline aromatic structures as judged by UV-Vis and NMR spectroscopy, and X-ray crystallography.
Department of Chemistry, Illinois State University, Normal, Illinois 61790-4160, USA.
Shelley R
SR
Graham
Gregory M
GM
Ferrence
Timothy D
TD
Lash
D018360:Crystallography, X-Ray; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D011166:Porphyrins / Q000138:chemical synthesis* / Q000737:chemistry* / Q000378:metabolism; D013055:Spectrophotometry, Infrared; D013056:Spectrophotometry, Ultraviolet
D009942:Organometallic Compounds; D011166:Porphyrins; D009532:Nickel