Expression of the prohelicity of bis-cyclomanganated 2,3-diphenylquinoxaline through reactions with diaryldiazomethanes.
The reactions of bis-cyclomanganated 2,3-diphenylquinoxaline with diazodiphenylmethane and 9-diazofluorene allowed the formation of a new oligomeric and dinuclear manganospiralene and the ready preparation of a pentacyclic helix comprising two (eta 5-fluorenyl)Mn(CO)3 fragments, whose helicity can be locked upon one-dimensional linear coordination to silver cation.
de Cian
André
A
UMR 7513 CNRS, Université Louis Pasteur, 67070 Strasbourg, France.
Djukic
Jean-Pierre
JP
Fischer
Jean
J
Pfeffer
Michel
M
Dötz
Karl Heinz
KH