The first structurally characterised homoleptic sigma-organotitanium(III) compound.
The paramagnetic [EPR, S = 1/2, d1; gav = 1.959(2)] organotitanate(III) anion [TiIII(C6Cl5)4] has been found to be a mononuclear species with nearly tetrahedral geometry (X-ray).
Alonso
Pablo J
PJ
Instituto de Ciencia de Materiales de Aragón, Facultad de Ciencias, Universidad de Zaragoza-C.S.I.C, Pza. S. Francisco s/n, E-50009, Zaragoza, Spain.
Forniés
Juan
J
García-Monforte
M Angeles
MA
Martín
Antonio
A
Menjón
Babil
B