Palladium dimethylsilanedithiolato complex: a precursor for Ti-Pd and Ti-Pd2 heterometallic complexes.
The silanedithiolato complex Pd(S2SiMe2)(PEt3)2 1 reacted with (C5H5)TiCl3 and TiCl4(thf)2 to produce the heterometallic clusters (C5H5)TiCl(mu-S)2Pd(PEt3)2 2 and TiCl2(S)(mu-S)2Pd2(PEt3)4 3 along with silicon-sulfur bond cleavage, respectively.
Research Center for Materials Science, Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan.
Takashi
T
Komuro
Tsukasa
T
Matsuo
Hiroyuki
H
Kawaguchi
Kazuyuki
K
Tatsumi