Molecular batteries: synthesis and characterization of a dendritic 19-electron FeI complex that reduces C60 to its mono-anion.
Both redox forms of the dendrimer [dendr-64-NHCOCpFeII(eta 6-C6Me6)]64+/0, 6/7, are synthesized and characterized, and the 19-electron form reduces C60 to [dendr-64-NHCOCpFeII(eta 6-C6Me6)]64+(C60-.)64, 8.
Groupe de Chimie Supramoléculaire des Métaux de Transition, LCOO, UMR CNRS No 5802, Université Bordeaux I, 33405 Talence Cedex, France.
Jamie
J
Ruiz
Charlotte
C
Pradet
François
F
Varret
Didier
D
Astruc