The acylation of an acyl complex resulting in a labile OCO tridentate ligand.
The reaction of propionic anhydride with [fac-Ru(C(O)Et)-(CO)2(H2O)3][CF3SO3] produces a new propylidin dipropionato group, which behaves as a tridentate ligand giving the neutral complex Ru(CEt(OC(O)Et)2)(CO)2(CF3SO3).
Funaioli
Tiziana
T
Dipartimento di Chimica e Chimica Industriale, Università di Pisa, Via Risorgimento 35, I-56126 Pisa, Italy.
Falchi
Giulia
G
Marchetti
Fabio
F
Fachinetti
Giuseppe
G