The effect of ionic strength on the complexation of copper (II) with salicylate ion.
The complexation of Cu2+ with the hydrogen salicylate, HL-, ion has been studied, at 25 degrees C, by potentiometric measurements with a glass electrode in NaClO4 media for an ionic strength range from 0.5 to 3 M. The complexes found were CuL, CuL2(2-) and CuHL+. Stability constants, extrapolated to zero ionic strength by using the Specific Interaction Theory were: [formula: see text]
Furia
Emilia
E
Dipartimento di Chimica, Università della Calabria, Via P. Bucci, Arcavacata di Rende, 87036 Rende, CS.
Porto
Raffaella
R
D006801:Humans; D017736:Ion-Selective Electrodes; D009942:Organometallic Compounds / Q000737:chemistry*; D009994:Osmolar Concentration; D012459:Salicylates / Q000737:chemistry*
D009942:Organometallic Compounds; D012459:Salicylates; C025564:copper salicylate complex