Reaction of singlet oxygen with Ir(I) and Rh(I) thiolato complexes: oxidative addition vs. S-oxidation.
Singlet oxygen reacts with Ir(I) and Rh(I) thiolato complexes to form the corresponding Ir(III) and Rh(III) peroxo thiolato complexes which do not undergo intramolecular oxidation of the thiolate moiety.
Department of Chemistry and Biochemistry, California State University, Los Angeles, Los Angeles, CA 90032, USA.
David G
DG
Ho
Rehana
R
Ismail
Nestor
N
Franco
Ruomei
R
Gao
Edward P
EP
Leverich
Irina
I
Tsyba
Nam Nhat
NN
Ho
Robert
R
Bau
Matthias
M
Selke
D004583:Electrons; D007495:Iridium / Q000737:chemistry*; D008024:Ligands; D009942:Organometallic Compounds / Q000737:chemistry; D010100:Oxygen / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*; D013438:Sulfhydryl Compounds / Q000737:chemistry*; D013455:Sulfur / Q000737:chemistry
D008024:Ligands; D009942:Organometallic Compounds; D013438:Sulfhydryl Compounds; D007495:Iridium; D013455:Sulfur; D012238:Rhodium; D010100:Oxygen