Novel hetero-bimetallic metalla-macrocycles based on the bis-1-pyridyl ferrocene [Fe(eta 5-C5H(4)-1-C5H4N)2] ligand. Design, synthesis and structural characterization of the complexes [Fe(eta 5-C5H(4)-1-C5H4N)2](AgI)2(2+)/(CuII)2(4+)/(ZnII)2(4+).
The bidentate sandwich ligand [Fe(eta 5-C5H(4)-1-C5H4N)2] has been prepared, structurally characterized and employed in the preparation of the novel supramolecular heterobimetallic metalla-macrocycles [Fe(eta 5-C5H(4)-1-C5H4N)2]Ag2(NO3)(2).1.5H2O, [Fe(eta 5-C5H(4)-1-C5H4N)2]Cu2(CH3COO)(4).3H2O and [Fe(eta 5-C5H(4)-1-C5H4N)2]Zn2Cl4.
Dipartimento di Chimica G. Ciamician, Università di Bologna, Via Selmi 2, 40126 Bologna, Italy. dbraga@ciam.unibo.it
Dario
D
Braga
Marco
M
Polito
Marco
M
Bracaccini
Daniela
D
D'Addario
Emilio
E
Tagliavini
Davide M
DM
Proserpio
Fabrizia
F
Grepioni