Synthesis and structure of poly(binaphthyl salen manganese complex) and its application to asymmetric epoxidation.
Poly(binaphthyl salen manganese complex)es 3-Mn were synthesized from a 3,3'-diformylbinaphthol derivative, alpha,omega-diamines, and Mn(OAc)2. Their helical structures were well-supported by their IR, UV, and CD spectra. The catalysis of 3-Mn in an asymmetric epoxidation was investigated.
Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, Sakai, Osaka, Japan.
Takeshi
T
Maeda
Yoshio
Y
Furusho
Toshikazu
T
Takata
D000438:Alcohols / Q000737:chemistry; D002851:Chromatography, High Pressure Liquid; D005029:Ethylenediamines / Q000737:chemistry*; D005663:Furans / Q000737:chemistry; D008956:Models, Chemical; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D012997:Solvents; D013237:Stereoisomerism; D013696:Temperature; D020122:tert-Butylhydroperoxide / Q000737:chemistry
D000438:Alcohols; D005029:Ethylenediamines; D005663:Furans; D009942:Organometallic Compounds; D012997:Solvents; C463419:poly(binaphthyl salen manganese complex); C018674:tetrahydrofuran; C090577:N,N'-bis(salicylideneamino)ethane-manganese(II); D020122:tert-Butylhydroperoxide