A new catalytic hetero-Heck type reaction.
Unsaturated N-chloroamines have been found to cyclise under palladium-catalysis in good yield, the proposed mechanism includes an oxidative addition of the chloroamine to Pd(0), thus opening a new entry to the amides of the late transition metals.
Helaja
Juho
J
Organisch-Chemisches Institut der Westfälischen, Wilhelms-Universität Münster, Corrensstr. 40, D-48149 Münster, Germany.
Göttlich
Richard
R