Unique crown thioether complexes of f elements: the crystal structure of U(III) and La(III) complexes of 1,4,7-trithiacyclononane.
The crystal structures of the first U(III) complex of a crown thioether and of its La(III) analog have been determined; a stronger M-S interaction is observed for U(III) with respect to La(III) and Ce(III) in solution and in the solid state.
Laboratoire de Reconnaissance Ionique, Département de Recherche Fondamentale sur la Matière Condensée, CEA-Grenoble, 17 rue des Martyrs, 38054 Grenoble, France.
Lydia
L
Karmazin
Marinella
M
Mazzanti
Jacques
J
Pécaut
D000473:Alkanes / Q000737:chemistry; D018360:Crystallography, X-Ray; D004988:Ethers, Cyclic / Q000737:chemistry*; D007811:Lanthanum / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry; D011850:Radioactive Waste; D013457:Sulfur Compounds / Q000737:chemistry; D014501:Uranium / Q000737:chemistry*
D000473:Alkanes; D004988:Ethers, Cyclic; D009942:Organometallic Compounds; D011850:Radioactive Waste; D013457:Sulfur Compounds; C421311:trithiacyclononane; D014501:Uranium; D007811:Lanthanum