Polyethylene glycol as a non-ionic liquid solvent for polyoxometalate catalyzed aerobic oxidation.
The H5PV2Mo10O40 polyoxometalate in a polyethylene glycol solvent was effective for a series of aerobic oxidation reactions including oxydehydrogenation of alcohols and cyclic dienes, oxidation of sulfides and the Wacker reaction; the solvent-catalyst phase can be recovered and recycled.
Department of Organic Chemistry, Weizmann Institute of Science, Rehovot, Israel, 76100.
Adina
A
Haimov
Ronny
R
Neumann
D004355:Drug Stability; D006863:Hydrogen-Ion Concentration; D010084:Oxidation-Reduction; D011092:Polyethylene Glycols / Q000737:chemistry*; D012997:Solvents; D013501:Surface-Active Agents / Q000737:chemistry*; D013696:Temperature; D017973:Tungsten Compounds / Q000737:chemistry*; D000099294:Polyoxometalates
D011092:Polyethylene Glycols; D012997:Solvents; D013501:Surface-Active Agents; D017973:Tungsten Compounds; C102296:polyoxometalate I; D000099294:Polyoxometalates