Spontaneous disproportionation of rhodium(I) bisoxazolinates to rhodium(II).
[RhI(t-Bu2-boxate)(C2H4)2] spontaneously disproportionates to the mononuclear [RhII(t-Bu2-boxate)2], whereas [RhI(Ph2-boxate)(C2H4)2] is stable against disproportionation.
Department of Inorganic Chemistry, University of Nijmegen, Toernooiveld 1, 6525 ED, Nijmegen, The Netherlands.
Sander T H
ST
Willems
Jaap C
JC
Russcher
Peter H M
PH
Budzelaar
Bas
B
de Bruin
René
R
de Gelder
Jan M M
JM
Smits
Anton W
AW
Gal