Controlling the variation of axial water exchange rates in macrocyclic lanthanide(III) complexes.
The rate of axial water exchange in well-defined series of lanthanide complexes depends on the extent of second sphere hydration which is determined by complex hydrophobicity and the nature of the lanthanide ion and its counter-ion.
Aime
Silvio
S
Dipartimento di Chimica IFM, Università di Torino, Via P. Giuria I-10125, Torino, Italy.
Barge
Alessandro
A
Batsanov
Andrei S
AS
Botta
Mauro
M
Castelli
Daniela Delli
DD
Fedeli
Franco
F
Mortillaro
Armando
A
Parker
David
D
Puschmann
Horst
H