Formation and crystal structure of an unexpected inclusion complex of a metal-free phthalocyanine and oxalic acid.
Treatment of 3-(2,4-dimethyl-3-pentyloxy)phthalonitrile (2) with CeCl3 in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) in n-pentanol gives the corresponding metal-free phthalocyanine 3, which unexpectedly traps the oxalic acid in the crystal lattice forming a 1:1 inclusion complex.
Liu
Wei
W
Department of Chemistry, Chinese University of Hong Kong, Shatin, N.T., Hong Kong, China.
Lee
Chi-Hang
CH
Li
Hung-Wing
HW
Lam
Chi-Keung
CK
Wang
Jinzhi
J
Mak
Thomas C W
TC
Ng
Dennis K P
DK
D002563:Cerium / Q000737:chemistry; D018360:Crystallography, X-Ray; D007211:Indoles / Q000737:chemistry*; D054833:Isoindoles; D015394:Molecular Structure; D019815:Oxalic Acid / Q000737:chemistry*; D010778:Photochemotherapy
D007211:Indoles; D054833:Isoindoles; D002563:Cerium; D019815:Oxalic Acid; C013647:phthalocyanine