Novel catalysis of dendrimer-bound Pd(0) complexes: sterically steered allylic amination and the first application for a thermomorphic system.
Phosphinated dendrimer-bound Pd(0) complex catalysts show high stereoselectivity for allylic amination due to the surface congestion of dendrimers and can be easily recycled without loss of activity under thermomorphic conditions.
Department of Chemical Science and Engineering, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan.
Tomoo
T
Mizugaki
Makoto
M
Murata
Masahiko
M
Ooe
Kohki
K
Ebitani
Kiyotomi
K
Kaneda