Synthesis and crystal structure of a novel decanuclear silver cluster complex [Ag(SC6H2Pri(3)-2,4,6)](10).2CHCI3.C2H5OH.
The cluster [Ag(SC6H2Pri(3)-2,4,6)]10 (1) contains a 20-membered ring of alternating silver and sulfur atoms, which is compactly folded; the sulfur atoms are doubly bridging and each silver atom exhibits linear two-coordination in the primary Ag-S interactions.
Institute of Physical Chemistry, Peking University, Beijing 100871, P. R. China.
Xianglin
X
Jin
Xiangjin
X
Xie
Hua
H
Qian
Kaluo
K
Tang
Chunling
C
Liu
Xin
X
Wang
Qihuang
Q
Gong