Liquid anion exchanger study of gold (III) from aqueous halide media with N-n-octylaniline.
N-n-octylaniline in xylene is used for the extractive separation of gold(III) from halide media. Gold(III) was extracted quantitatively with 10 ml of 2% reagent in xylene from 0.5-10 M and 0.5-8 M hydrochloric acid and hydrobromic acid, respectively. It was stripped from the organic phase with ammonia buffer solution (pH 10.1) and estimated spectrophotometrically with stannous chloride. The effect of metal ion, acids, reagent concentration and of various foreign ions has been investigated. Method is applicable to the analysis of synthetic mixtures containing platinum metals and alloy samples. The method is fast, accurate and precise.
Analytical Chemistry Laboratory, Department of Chemistry, Shivaji University, Kolhapur-416004, India.
Tukaram N
TN
Lokhande
Shashikant H
SH
Gaikwad
Mansing A
MA
Anuse
Manohar B
MB
Chavan
D000814:Aniline Compounds / Q000737:chemistry*; D002412:Cations / Q000737:chemistry; D006046:Gold / Q000737:chemistry*; D006801:Humans; D007474:Ion Exchange; D012997:Solvents / Q000737:chemistry*
D000814:Aniline Compounds; D002412:Cations; C470114:N-n-octylaniline; D012997:Solvents; D006046:Gold