Catalytic and highly regiospecific carbon-carbon bond formation at alpha-position of Michael acceptor by palladium complex.
Activated olefins react with allyl acetates and Bu3SnH in the presence of a catalytic amount of a palladium catalyst to afford the corresponding products which construct a new C-C bond selectively at the alpha-position of Michael acceptors.
Environment-Chemistry Group, Korea Electric Power Research Institute (KEPRI), Daejeon 305-380, Korea.
Jae-Goo
JG
Shim
Jong Chul
JC
Park
Chan Sik
CS
Cho
Sang Chul
SC
Shim
Yoshinori
Y
Yamamoto
D000475:Alkenes / Q000737:chemistry*; D000498:Allyl Compounds / Q000737:chemistry / Q000378:metabolism; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D055598:Chemical Phenomena; D002621:Chemistry; D007700:Kinetics; D010165:Palladium / Q000737:chemistry*
D000475:Alkenes; D000498:Allyl Compounds; D010165:Palladium; D002244:Carbon