[Zn8(SiO4)(C8H4O4)6]n: the firstborn of a metallosilicate-organic hybrid material family (C8H4O4 = isophthalate).
[Zn8(SiO4)(C8H4O4)6]n (C8H4O4 = isophthalate), synthesized by hydrothermal reaction, possesses a diamondoid framework structure constructed from hexahedron-like Zn8(SiO4) cores and C8H4O4 linkers and remains stable up to 500 degrees C in air, representing the first member of a new class of metallosilicate-organic hybrid materials.
State Key Laboratory for Physical Chemistry of Solid Surface, Department of Chemistry, Xiamen University, Xiamen 361005, China.
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Yang
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Long
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Huang
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Zheng