Molybdenum alkynyls as alkynyl transfer reagents.
Molybdenum alkynyl complexes [Mo(C identical to CR)(eta 3-allyl)(CO)2(phen)] feature long Mo-Calkynyl bond distances and propensity to undergo the cleavage of these bonds, a property that allowed their use as acetylide transfer reagents.
Departamento de Química Orgánica e Inorgánica/I.U.Q.O.E.M, Facultad de Quínica, Universidad de Oviedo-C.S.I.C 33071, Oviedo, Spain.
Julio
J
Pérez
Lucía
L
Riera
Víctor
V
Riera
Santiago
S
García-Granda
Esther
E
García-Rodríguez
Daniel
D
Miguel