Fast and unprecedented chemoselective hydroformylation of acrylates with a fluoropolymer ligand in supercritical CO2.
A fluorous polymeric phosphine, when combined with supercritical CO2 (scCO2) and rhodium, effects fast and highly chemoselective hydroformylation of acrylates, one of the least reactive olefins in hydroformylation reactions.
Hu
Yulai
Y
Leverhulme Centre for Innovative Catalysis, Department of Chemistry, University of Liverpool, Liverpool, UK L69 7ZD.
Chen
Weiping
W
Osuna
Anna M Banet
AM
Iggo
Jon A
JA
Xiao
Jianliang
J