Visible light induced biohydrogen production from sucrose using the photosensitization of Mg chlorophyll-a.
A photoinduced hydrogen production system, coupling sucrose degradation with invertase and glucose dehydrogenase (GDH) and hydrogen production with colloidal platinum as a catalyst using the visible light-induced photosensitization of Mg chlorophyll-a (Mg Chl-a), has been developed. Continuous hydrogen gas production was observed when the reaction mixture containing sucrose, invertase, GDH, nicotinamide adenine dinucleotide (NAD(+)), Mg Chl-a, methyl viologen (MV(2+), an electron relay reagent), and colloidal platinum was irradiated by visible light.
Saiki
Yoshinobu
Y
Department of Applied Chemistry, Oita University, Dannoharu 700, Oita 870-1192, Japan.
Amao
Yutaka
Y
D002734:Chlorophyll / Q000737:chemistry* / Q000528:radiation effects; D000077194:Chlorophyll A; D042843:Glucose 1-Dehydrogenase; D005948:Glucose Dehydrogenases / Q000378:metabolism; D006026:Glycoside Hydrolases / Q000378:metabolism; D006859:Hydrogen / Q000737:chemistry*; D007700:Kinetics; D008027:Light; D008274:Magnesium; D009243:NAD / Q000737:chemistry; D010084:Oxidation-Reduction; D010269:Paraquat / Q000737:chemistry; D010777:Photochemistry; D017319:Photosensitizing Agents / Q000737:chemistry / Q000528:radiation effects; D010984:Platinum / Q000737:chemistry / Q000528:radiation effects; D013395:Sucrose / Q000737:chemistry* / Q000528:radiation effects; D043324:beta-Fructofuranosidase
D017319:Photosensitizing Agents; D009243:NAD; D002734:Chlorophyll; D010984:Platinum; D013395:Sucrose; D006859:Hydrogen; D005948:Glucose Dehydrogenases; D042843:Glucose 1-Dehydrogenase; D006026:Glycoside Hydrolases; D043324:beta-Fructofuranosidase; D008274:Magnesium; D010269:Paraquat; D000077194:Chlorophyll A