High conversion of olefins to cis-diols by non-heme iron catalysts and H2O2.
Efficient and highly stereoselective oxidation of olefins to cis-diols as the major product is obtained by using biomimetic non-heme FeII catalysts in combination with H2O2.
Department of Chemistry, Center for Metals in Biocatalysis, University of Minnesota, Minneapolis, MN 55455, USA.
Ju Yeon
JY
Ryu
Jinheung
J
Kim
Miquel
M
Costas
Kui
K
Chen
Wonwoo
W
Nam
Lawrence
L
Que
D000438:Alcohols / Q000138:chemical synthesis*; D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D005296:Ferrous Compounds / Q000737:chemistry*; D006861:Hydrogen Peroxide / Q000737:chemistry*; D018716:Molecular Mimicry; D019159:Nonheme Iron Proteins / Q000737:chemistry*; D016877:Oxidants / Q000737:chemistry; D010084:Oxidation-Reduction; D013237:Stereoisomerism
C461259:(Fe(II)(5-Me(3)-TPA)(CH3CN)2)(ClO4)2; D000438:Alcohols; D000475:Alkenes; D005296:Ferrous Compounds; D019159:Nonheme Iron Proteins; D016877:Oxidants; D006861:Hydrogen Peroxide