Supramolecular self-assembly of a fluorinated Zn porphyrin. Molecular structure of a two-dimensional network of amine-functionalized, hexacoordinated Zn porphyrins.
[5,10,15,20-Tetrakis(4-n-propylamino-2,3,5,6- tetrafluorophenyl)porphyrinato]zinc(II) self-assembles into a two-dimensional supramolecular array in which each porphyrin is linked to four orthogonally-oriented chromophores.
Barkigia
Kathleen M
KM
Materials Science Department, Brookhaven National Laboratory, Upton, New York 11973-5000, USA. barkigia@bnl.gov
Battioni
Pierrette
P
Riou
Vanessa
V
Mansuy
Daniel
D
Fajer
Jack
J
D000588:Amines / Q000737:chemistry; D005461:Fluorine; D008665:Metalloporphyrins / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation
D000588:Amines; D008665:Metalloporphyrins; C017802:zinc hematoporphyrin; D005461:Fluorine