Synthesis and crystal structure of a novel pentaconta-nuclear silver anionic cluster complex [HNEt3]4[Ag50S7(SC6H4But-4)40].2CS(2).6C3H6O.
A silver 4-tert-butylthiophenolate complex generated in situ reacted with CS2 in acetone to give an anionic cluster [Ag50S7(SC6H4But-4)40]4-, the core of which consists of fifty silver atoms and forty-seven sulfur atoms, shaped like a discus with a diameter of ca. 2.0 nm.
Institute of Physical Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P R China.
Kaluo
K
Tang
Xiangjin
X
Xie
Yaohua
Y
Zhang
Xia
X
Zhao
Xianglin
X
Jin