A novel ribbon-candy-like supramolecular architecture of cadmium(II)-terephthalate polymer with giant rhombic channels: twofold interpenetration of the 3D 8(2)10-a net.
The hydrothermal reaction of H2tp (tp = terephthalate), [Ph3PCH2Ph]Cl and water with Cd(O2CCH3)(2).2H2O gives rise to a novel ribbon-candy-like supramolecular architecture with twofold interpenetration of an unprecedented 3D 8(2)10-a net formed by polymer ([Ph3PCH2Ph][Cd(tp).Cl].2H2O]n containing giant rhombic channels, which displays strong fluorescent emission in the solid state.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
Jing-Cao
JC
Dai
Xin-Tao
XT
Wu
Zhi-Yong
ZY
Fu
Sheng-Min
SM
Hu
Wen-Xing
WX
Du
Chuan-Peng
CP
Cui
Li-Ming
LM
Wu
Han-Hui
HH
Zhang
Rui-Qing
RQ
Sun