The rational design of novel chiral oxovanadium(IV) complexes for highly enantioselective oxidative coupling of 2-naphthols.
Several novel chiral oxovanadium(IV) complexes have been designed and prepared for the asymmetric catalytic oxidative coupling of 2-naphthols with high enantioselectivities of 83-98% ee.
Luo
Zhibin
Z
Union Laboratory of Asymmetric Synthesis, Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, China.
Liu
Quanzhong
Q
Gong
Liuzhu
L
Cui
Xin
X
Mi
Aiqiao
A
Jiang
Yaozhong
Y
D002384:Catalysis; D002625:Chemistry, Organic; D006863:Hydrogen-Ion Concentration; D015394:Molecular Structure; D009284:Naphthols / Q000138:chemical synthesis* / Q000737:chemistry* / Q000378:metabolism; D055601:Organic Chemistry Phenomena; D010084:Oxidation-Reduction; D013237:Stereoisomerism; D014638:Vanadates / Q000138:chemical synthesis* / Q000737:chemistry*
D009284:Naphthols; C075743:oxovanadium IV; D014638:Vanadates; C028405:2-naphthol