Discriminating between lanthanide ions: self-assembly of heterodimetallic triple-stranded helicates.
A bis-terdentate segmental ligand has been designed which self-assembles with lanthanide ions of different size to yield heterodimetallic triple-stranded helicates.
Institute of Molecular and Biological Chemistry, BCH, Swiss Federal Institute of Technology, CH-1015-Lausanne, Switzerland.
Nicolas
N
André
Rosario
R
Scopelliti
Gérard
G
Hopfgartner
Claude
C
Piguet
Jean-Claude G
JC
Bünzli
D004247:DNA / Q000737:chemistry*; D028581:Lanthanoid Series Elements / Q000737:chemistry*; D008670:Metals / Q000737:chemistry*; D008958:Models, Molecular; D013816:Thermodynamics
D028581:Lanthanoid Series Elements; D008670:Metals; C051802:triplex DNA; D004247:DNA