Reaction of singlet oxygen with Ir(I) and Rh(I) thiolato complexes: oxidative addition vs. S-oxidation.
Singlet oxygen reacts with Ir(I) and Rh(I) thiolato complexes to form the corresponding Ir(III) and Rh(III) peroxo thiolato complexes which do not undergo intramolecular oxidation of the thiolate moiety.
Ho
David G
DG
Department of Chemistry and Biochemistry, California State University, Los Angeles, Los Angeles, CA 90032, USA.
Ismail
Rehana
R
Franco
Nestor
N
Gao
Ruomei
R
Leverich
Edward P
EP
Tsyba
Irina
I
Ho
Nam Nhat
NN
Bau
Robert
R
Selke
Matthias
M
D004583:Electrons; D007495:Iridium / Q000737:chemistry*; D008024:Ligands; D009942:Organometallic Compounds / Q000737:chemistry; D010100:Oxygen / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*; D013438:Sulfhydryl Compounds / Q000737:chemistry*; D013455:Sulfur / Q000737:chemistry
D008024:Ligands; D009942:Organometallic Compounds; D013438:Sulfhydryl Compounds; D007495:Iridium; D013455:Sulfur; D012238:Rhodium; D010100:Oxygen