Heterogeneous nucleation of supercooled water, and the effect of an added catalyst.
The statistics of liquid-to-crystal nucleation are measured rigorously by using a recently developed automated lag-time apparatus (ALTA). A single sample, in this case a sample of pure water both with and without an (insoluble) AgI crystal, is repeatedly cooled, nucleated, and thawed. Analysis of the data, coupled with a second kind of experiment, shows that the statistics of nucleation are consistent with a first-order kinetic mechanism over a wide range of supercooling temperatures. The limitations of classical nucleation theory are exhibited. Our analysis unifies many related experiments in biology, physics, chemistry, and chemical engineering.
Heneghan
A F
AF
Department of Chemistry, University of Houston, Houston, TX 77204-5003, USA.
Wilson
P W
PW
Haymet
A D J
AD
D002384:Catalysis; D003460:Crystallization; D007700:Kinetics; D013816:Thermodynamics; D014867:Water / Q000737:chemistry*
D014867:Water