Novel catalysis of dendrimer-bound Pd(0) complexes: sterically steered allylic amination and the first application for a thermomorphic system.
Phosphinated dendrimer-bound Pd(0) complex catalysts show high stereoselectivity for allylic amination due to the surface congestion of dendrimers and can be easily recycled without loss of activity under thermomorphic conditions.
Mizugaki
Tomoo
T
Department of Chemical Science and Engineering, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan.
Murata
Makoto
M
Ooe
Masahiko
M
Ebitani
Kohki
K
Kaneda
Kiyotomi
K