The first successful investigation into a cyclodextrin-based enzyme model as an efficient catalyst for luminol chemiluminescent reaction.
The chemiluminescence of the luminol-H2O2 system is found for the first time to be remarkably enhanced by the Ce(IV) complexes of cyclodextrin dimers.
Faculty of Pharmaceutical Sciences, Nagasaki University, 1-14 Bunkyo-machi, Nagasaki 852-8521, Japan. deqiyuan@net.nagasaki-u.ac.jp
De-Qi
DQ
Yuan
Jianzhong
J
Lu
Masato
M
Atsumi
Ayako
A
Izuka
Masaaki
M
Kai
Kahee
K
Fujita
D002384:Catalysis; D003505:Cyclodextrins / Q000737:chemistry*; D019281:Dimerization; D004798:Enzymes / Q000737:chemistry*; D007202:Indicators and Reagents; D008163:Luminescent Measurements; D008165:Luminol / Q000737:chemistry*; D008958:Models, Molecular; D018716:Molecular Mimicry
D003505:Cyclodextrins; D004798:Enzymes; D007202:Indicators and Reagents; D008165:Luminol