Chemical studies of the radical scavenging mechanism of bisorbicillinol using the 1,1-diphenyl-2-picrylhydrazyl radical.
A potent antioxidant, bisorbicillinol, which is a member of the bisorbicillinoid family isolated from the culture broth of Trichoderma sp. USF-2690, produces a stable radical-terminated symmetric dimer by donating two hydrogen atoms to the 1,1-diphenyl-2-picrylhydrazyl (DPPH) radical.
Abe
Naoki
N
School of Food and Nutritional Sciences, University of Shizuoka, 52-1 Yada, Shizuoka 422-8526, Japan. abe@fns1.u-shizuoka-ken.ac.jp
Hirota
Akira
A
D000975:Antioxidants / Q000737:chemistry; D001713:Biphenyl Compounds; D001952:Bridged-Ring Compounds / Q000737:chemistry*; D003512:Cyclohexanones / Q000737:chemistry*; D019281:Dimerization; D016166:Free Radical Scavengers / Q000737:chemistry*; D010851:Picrates / Q000737:chemistry; D014242:Trichoderma / Q000737:chemistry
D000975:Antioxidants; D001713:Biphenyl Compounds; D001952:Bridged-Ring Compounds; D003512:Cyclohexanones; D016166:Free Radical Scavengers; D010851:Picrates; C473617:bisorbicillinol; C453419:sorbicillinol; C004931:1,1-diphenyl-2-picrylhydrazyl