A mixed-valence copper coordination polymer generated by hydrothermal metal/ligand redox reactions.
A novel coordination polymer of mixed-valence copper(I,II) with 4,4'-bipyridine and in situ oxidized isophthalate, [Cu2(ipO)(4,4'-bpy)] (ipOH = 2-hydroxyisophthalate), was hydrothermally synthesized and crystallographically characterized to be a laminated structure via weak copper(II)--oxygen interactions.
Tao
Jun
J
School of Chemistry and Chemical Engineering, Zhongshan University, Guangzhou 510275, China.
Zhang
Yong
Y
Tong
Ming-Liang
ML
Chen
Xiao-Ming
XM
Yuen
Tan
T
Lin
C L
CL
Huang
Xiaoying
X
Li
Jing
J
D015082:2,2'-Dipyridyl / Q000737:chemistry; D003300:Copper / Q000737:chemistry / Q000378:metabolism*; D018360:Crystallography, X-Ray; D006358:Hot Temperature; D008024:Ligands; D008280:Magnetics; D008956:Models, Chemical; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010100:Oxygen / Q000378:metabolism*; D010795:Phthalic Acids / Q000737:chemistry; D011108:Polymers / Q000737:chemistry*
D008024:Ligands; D010795:Phthalic Acids; D011108:Polymers; C059768:isophthalate; D015082:2,2'-Dipyridyl; D003300:Copper; D010100:Oxygen