[Cleavage of a dithioacetalmonosulfoxide].
The aldehyde 5, the cyclic acylal 6 and the acetal 8 are obtained from the cleavage of the dithioacetal 3B with perchloric acid in acetonitrile. Acetone as solvent yields the acetonide 7, the structure of which is confirmed by X-ray structure determination.
Görlitzer
K
K
Institut für Pharmazeutische Chemie, Technischen Universität Braunschweig, Germany. k.goerlitzer@tu-bs.de
Fabian
J
J
Jones
P G
PG
D000080:Acetals / Q000737:chemistry; D000447:Aldehydes / Q000737:chemistry; D018360:Crystallography, X-Ray; D007202:Indicators and Reagents; D008958:Models, Molecular; D009578:Nitrobenzenes / Q000737:chemistry*; D010472:Perchlorates / Q000737:chemistry; D012997:Solvents; D013457:Sulfur Compounds / Q000737:chemistry*
D000080:Acetals; D000447:Aldehydes; D007202:Indicators and Reagents; D009578:Nitrobenzenes; D010472:Perchlorates; D012997:Solvents; D013457:Sulfur Compounds