title: One-pot enantioselective formation of eight-membered rings from alkenyl Fischer carbene complexes and ketone enolates.
abstract: Eight-membered carbocycles with up to five new stereogenic centers are enantioselectively obtained following a one-pot procedure that involves the coupling of three components: an alkenyl Fischer carbene complex, a ketone enolate, and allyl lithium.
authors.affiliation: Instituto Universitario de Química Organometálica Enrique Moles, Unidad Asociada al C.S.I.C., Universidad de Oviedo, Julián Clavería, 8, E-33071 Oviedo, Spain. barluenga@sauron.quimica.uniovi.es
authors.forename: José
authors.initials: J
authors.lastname: Barluenga
authors.forename: Alejandro
authors.initials: A
authors.lastname: Diéguez
authors.forename: Félix
authors.initials: F
authors.lastname: Rodríguez
authors.forename: Josefa
authors.initials: J
authors.lastname: Flórez
authors.forename: Francisco J
authors.initials: FJ
authors.lastname: Fañanás