Formation of a 1-azaallenylidene ligand by reaction of an amido complex with tetracyanoethylene.
Amido complexes of Mo(II) allyl carbonyl fragments containing monodentate amido ligands, prepared by reaction of suitable chloro precursors with potassium amides, react (for the N(H)(p-tolyl) derivative) with tetracyanoethylene to give a 1-azaallenylidene complex.
Morales
Dolores
D
Departamento de Química Orgánica e Inorgánica/IUQOEM Facultad de Química, Universidad de Oviedo-CSIC, 33071, Oviedo, Spain.
Pérez
Julio
J
Riera
Lucía
L
Riera
Víctor
V
Miguel
Daniel
D