Enantioselective formation of (R)-9-HPODE and (R)-9-HPOTrE in marine green alga Ulva conglobata.
When linoleic and linolenic acid were incubated with a crude enzyme of marine green alga Ulva conglobata, the corresponding (R)-9-hydroperoxy-(10E, 12Z)-10, 12-octadecadienoic acid [(R)-9-HPODE] and (R)-9-hydroperoxy-(10E, 12Z, 15Z)-10, 12, 15-octadecatrienoic acid [(R)-9-HPOTrE] were formed with a high enantiomeric excess (>99%), respectively.
Akakabe
Yoshihiko
Y
Department of Biological Chemistry, Faculty of Agriculture, Yamaguchi University, 1677-1 Yoshida, Yamaguchi, Japan.
Matsui
Kenji
K
Kajiwara
Tadahiko
T
D000460:Chlorophyta / Q000201:enzymology / Q000378:metabolism*; D002851:Chromatography, High Pressure Liquid; D019787:Linoleic Acid / Q000378:metabolism; D008041:Linoleic Acids / Q000096:biosynthesis* / Q000737:chemistry; D008054:Lipid Peroxides / Q000096:biosynthesis* / Q000737:chemistry; D013237:Stereoisomerism; D017962:alpha-Linolenic Acid / Q000378:metabolism
D008041:Linoleic Acids; D008054:Lipid Peroxides; D017962:alpha-Linolenic Acid; C060746:9-hydroperoxy-10,12,15-octadecatrienoic acid; C049606:9-hydroperoxy-11,12-octadecadienoic acid; D019787:Linoleic Acid