title: Sensitivity analysis for validating expert opinion as to ideal data set criteria for transport modeling.
abstract: Environmental fate modeling results are often used in risk assessment without adequately considering uncertainty in exposure predictions. Sensitivity analysis is fundamental to model validation and error prediction since sensitive model input parameters account for the largest variance in model prediction. Once identified, sensitive model input parameters can be used to propagate parametric uncertainty in numerical predictions. Output sensitivity to variation in input code sequences was investigated for the pesticide root zone model (PRZM 3) using Plackett-Burman analysis for six runoff and leaching data sets. The analysis utilized an incomplete block factorial design with even parameter weighting and uniform proportional input perturbation. Timing and duration of key period rainfall were assumed a priori to be dominant sensitive inputs. Thus, meteorological data were fixed, allowing identification of additional input components contributing to model sensitivity. Results validated expert modeler assumptions concerning parameters most critical for model validation. For leaching data sets, the application rate, soil bulk density (an indicator of available water-holding capacity), chemical partition coefficient, and pesticide degradation rates were commonly the most sensitive inputs. For runoff data sets, the in-crop runoff curve number was the most significant input governing pesticide loss in runoff and erosion flux. The chemical partition coefficient, soil and foliar decay rates, and soil bulk density were also common sensitive components for runoff predictions. These commonly observed sensitive components for runoff and leaching prediction need to be carefully considered in the design and conduct of relevant field studies, modeling assessment of such studies, and future improvements in algorithms for environmental transport modeling.
authors.affiliation: Dow AgroSciences, Indianapolis, Indiana 46268, USA. jdwolt@dow.com
authors.forename: Jeff
authors.initials: J
authors.lastname: Wolt
authors.forename: Piyush
authors.initials: P
authors.lastname: Singh
authors.forename: Steven
authors.initials: S
authors.lastname: Cryer
authors.forename: Jim
authors.initials: J
authors.lastname: Lin
mesh_terms: D008685:Meteorological Concepts; D008962:Models, Theoretical; D010575:Pesticides / Q000009:adverse effects* / Q000032:analysis; D018517:Plant Roots; D018570:Risk Assessment; D012680:Sensitivity and Specificity; D012989:Soil Pollutants / Q000032:analysis*; D012995:Solubility; D014873:Water Pollutants / Q000032:analysis*
chemical_list: D010575:Pesticides; D012989:Soil Pollutants; D014873:Water Pollutants