title: A dynamic mass budget for toxaphene in North America.
abstract: A continental-scale dynamic mass budget for toxaphene in North America is presented, based on available information on physicochemical properties, usage patterns, and reported environmental concentrations and using the Berkeley-Trent North American mass balance contaminant fate model (BETR North America). The model describes contaminant fate in 24 ecological regions of North America, including advective transport between regions in the atmosphere, freshwater, and near-shore coastal water. The dynamic mass budget accounts for environmental partitioning, transport, and degradation of the estimated 534 million kg of toxaphene that were used in North America as an insecticide and piscicide between 1945 and 2000. Satisfactory agreement exists between model results and current and historically reported concentrations of toxaphene in air, water, soil, and sediments throughout North America. An estimated 15 million kg of toxaphene are believed to remain in active circulation in the North American environment in the year 2000, with the majority in soils in the southern United States and Mexico, where historic usage was highest. Approximately 70% of total toxaphene deposition from the atmosphere to the Great Lakes is attributed to sources outside the Great Lakes Basin, and an estimated total of 3.9 million kg of toxaphene have been transported to this region from other parts of the continent. The toxaphene mass budget presented here is believed to be the first reported continental-scale multimedia mass budget for any contaminant.
authors.affiliation: Canadian Environmental Modelling Centre, Trent University, Peterborough, Ontario. mmacleod@trentu.ca
authors.forename: Matthew
authors.initials: M
authors.lastname: MacLeod
authors.forename: David
authors.initials: D
authors.lastname: Woodfine
authors.forename: Jenn
authors.initials: J
authors.lastname: Brimacombe
authors.forename: Liisa
authors.initials: L
authors.lastname: Toose
authors.forename: Don
authors.initials: D
authors.lastname: Mackay
mesh_terms: D000383:Agriculture; D000392:Air Movements; D004784:Environmental Monitoring; D004785:Environmental Pollutants / Q000032:analysis* / Q000378:metabolism; D006114:Great Lakes Region; D007306:Insecticides / Q000032:analysis* / Q000378:metabolism; D008962:Models, Theoretical; D009656:North America; D014112:Toxaphene / Q000032:analysis* / Q000378:metabolism; D014872:Water Movements
chemical_list: D004785:Environmental Pollutants; D007306:Insecticides; D014112:Toxaphene