Multianvil high-pressure synthesis of Dy(4)B(6)O(15): the first oxoborate with edge-sharing BO(4) tetrahedra.
In all known oxoborates the linkage of BO(3) and BO(4) groups is performed via common corners. Here we present the high-pressure/high-temperature synthesis of Dy(4)B(6)O(15), which is the first oxoborate exhibiting edge-sharing BO(4) tetrahedra.
Huppertz
Hubert
H
Department of Chemistry, Ludwig-Maximilians-University of Munich, Butenandtstrasse 5-13, Germany. huh@cup.uni-muenchen.de
von der Eltz
Benjamin
B