title: Poly[1-(trimethylsilyl)-1-propine] as chromatographic adsorbent and prospects of its application in packed and capillary columns.
abstract: The application of film-forming organic polymers, which are in common use in membrane technology, as chromatographic adsorbents for packed and capillary columns has been suggested. The chromatographic characteristics of poly[1-(trimethylsilyl)-1-propine] (PTMSP) as an adsorbent were studied. The film-forming properties of PTMSP simplify manufacturing of capillary and packed gas-solid columns. It was shown that separation of C1-C4 hydrocarbon gases on the columns with PTMSP is of practical interest. In the authors' opinion, PTMSP is also promising for the separation of inorganic gases.
authors.affiliation: AV Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow. berezkin@ips.ac.ru
authors.forename: Victor G
authors.initials: VG
authors.lastname: Berezkin
authors.forename: Alexander A
authors.initials: AA
authors.lastname: Korolev
authors.forename: Irina V
authors.initials: IV
authors.lastname: Malyukova
authors.forename: Tamara P
authors.initials: TP
authors.lastname: Popova
authors.forename: Valeriya E
authors.initials: VE
authors.lastname: Shiryaeva
authors.forename: Valerii S
authors.initials: VS
authors.lastname: Khotimskii
mesh_terms: D000327:Adsorption; D002849:Chromatography, Gas / Q000295:instrumentation*; D006838:Hydrocarbons / Q000302:isolation & purification; D014297:Trimethylsilyl Compounds / Q000737:chemistry*
chemical_list: D006838:Hydrocarbons; D014297:Trimethylsilyl Compounds