A sigma 4, lambda 5-phosphinine palladium complex: a new type of phosphorus ligand and catalyst. Application to the Pd-catalyzed formation of arylboronic esters.
A palladium(II) complex of a S-P-S pincer ligand featuring a metallated ylidic P-atom efficiently catalyzes the coupling between pinacolborane and various iodoaryls to yield the corresponding arylboronic esters (TON between 5100 and 76,500).
Doux
Marjolaine
M
Laboratoire Hétéroéléments et Coordination, UMR CNRS 7653, Ecole Polytechnique, 91128 Palaiseau, France.
Mézailles
Nicolas
N
Melaimi
Mohand
M
Ricard
Louis
L
Le Floch
Pascal
P