Diverse pathways for the palladium(II)-mediated oxidation of olefins by tert-butylhydroperoxide.
[reaction: see text] New procedures are described for the palladium-catalyzed oxidation of olefins by tert-butylhydroperoxide under slightly basic conditions in CH(2)Cl(2) solution at 0-25 degrees C.
Yu
Jin-Quan
JQ
Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, USA.
Corey
E J
EJ