Absorption spectra of nitroanilines in micellar solution--II.
The absorption spectra of nitroanilines (o-, m- and p-) in aqueous and nonaqueous solution of neutral surfactant-Triton X-100 (TX-100) reveal many interesting phenomena. Nitroanilines and TX-100 behave as electron acceptor and donor, respectively, in both media during charge-transfer (CT) complex formation though water plays an important role in aqueous media. The thermodynamic and spectrophotometric parameters of nitroanilines-TX-100 interactions in two media have been determined and the electron accepting capability among the nitroanilines have been also established. In addition to this, role of surface in CT interaction, the site of CT interaction, intensity and stability of CT interaction between nitroanilines and TX-100 have been pointed out.
Jana
Asok K
AK
Department of Chemistry, Kanchi Mamunivar Centre for Post-Graduate Studies, Lawspet, Pondicherry, India.
Mukhopadhyay
Sushil K
SK
Bhowmik
Benoy B
BB
D000814:Aniline Compounds / Q000737:chemistry*; D008823:Micelles; D017830:Octoxynol; D012996:Solutions; D013053:Spectrophotometry; D013056:Spectrophotometry, Ultraviolet; D013501:Surface-Active Agents; D013816:Thermodynamics
D000814:Aniline Compounds; D008823:Micelles; D012996:Solutions; D013501:Surface-Active Agents; C008625:nitroaniline; D017830:Octoxynol