title: A sigma 4, lambda 5-phosphinine palladium complex: a new type of phosphorus ligand and catalyst. Application to the Pd-catalyzed formation of arylboronic esters.
abstract: A palladium(II) complex of a S-P-S pincer ligand featuring a metallated ylidic P-atom efficiently catalyzes the coupling between pinacolborane and various iodoaryls to yield the corresponding arylboronic esters (TON between 5100 and 76,500).
authors.affiliation: Laboratoire Hétéroéléments et Coordination, UMR CNRS 7653, Ecole Polytechnique, 91128 Palaiseau, France.
authors.forename: Marjolaine
authors.initials: M
authors.lastname: Doux
authors.forename: Nicolas
authors.initials: N
authors.lastname: Mézailles
authors.forename: Mohand
authors.initials: M
authors.lastname: Melaimi
authors.forename: Louis
authors.initials: L
authors.lastname: Ricard
authors.forename: Pascal
authors.initials: P
authors.lastname: Le Floch