title: Bis(1,10-phenanthroline)(thiosulfato)manganese(II) methanol solvate and catena-poly[[diaqua(2,9-dimethyl-1,10-phenanthroline)manganese(II)]-mu-thiosulfato].
abstract: The structure of bis(1,10-phenanthroline-kappa(2)N,N')(thiosulfato-kappa(2)O:S)manganese(II) methanol solvate, [Mn(S(2)O(3))(C(12)H(8)N(2))(2)].CH(3)OH, is made up of Mn(2+) centers coordinated to two bidentate phenanthroline (phen) groups and an S,O-chelating thiosulfate anion, forming monomeric entities. The structure of catena-poly[[diaqua(2,9-dimethyl-1,10-phenanthroline-kappa(2)N,N')manganese(II)]-mu-thiosulfato-kappa(2)O:S], [Mn(S(2)O(3))(C(14)H(12)N(2))(H(2)O)(2)](n), is polymeric, consisting of Mn(dmph)(H(2)O)(2) units (dmph is 2,9-dimethyl-1,10-phenanthroline) linked by thiosulfate anions acting in an S,O-chelating manner.
authors.affiliation: Universidad Nacional de la Patagonia, Sede Puerto Madryn, and CenPat, CONICET, 9120 Puerto Madryn, Chubut, Argentina.
authors.forename: Eleonora
authors.initials: E
authors.lastname: Freire
authors.forename: Sergio
authors.initials: S
authors.lastname: Baggio
authors.forename: Juan Carlos
authors.initials: JC
authors.lastname: Muñoz
authors.forename: Ricardo
authors.initials: R
authors.lastname: Baggio