(1S,3R,8S,9S,10R)-2,2-Dichloro-9,10-epoxy-3,7,7,10-tetramethyltricyclo[6.4.0.0(1,3)]dodecane and (1S,3R,8S,10R)-2,2-dichloro-3,7,7,10-tetramethyltricyclo[6.4.0.0(1,3)]dodecan-9-one.
The stereochemistries of the title compounds, both C(16)H(24)Cl(2)O, have been established by X-ray diffraction. In both structures, the seven-membered ring adopts the same conformation, whereas the six-membered ring shows an envelope conformation in the epoxydodecane structure and a boat conformation in the dodecan-9-one structure.
Sbai
F
F
Laboratoire de Chimie Organique Hétérocyclique, Faculté des Sciences, Université Mohamed V, Rabat, Morocco.
Dakir
M
M
Auhmani
A
A
El Jamili
H
H
Akssira
M
M
Benharref
A
A
Kenz
A
A
Pierrot
M
M
D001952:Bridged-Ring Compounds / Q000737:chemistry*; D018360:Crystallography, X-Ray; D004852:Epoxy Compounds / Q000737:chemistry*; D006860:Hydrogen Bonding; D008958:Models, Molecular; D009018:Morocco; D009822:Oils, Volatile / Q000737:chemistry*; D010938:Plant Oils / Q000737:chemistry*
C467523:(1,3,8,10)-2,2-dichloro-3,7,7,10-tetramethyltricyclo(6.4.0.0(1,3))dodecan-9-one; C467522:(1,3,8,9,10)-2,2-dichloro-9,10-epoxy-3,7,7,10-tetramethyltricyclo(6.4.0.0(1,3))dodecane; D001952:Bridged-Ring Compounds; D004852:Epoxy Compounds; D009822:Oils, Volatile; D010938:Plant Oils