Local tilting angles tau for Fe+ in Cd2+ site and Fe3+ in Si4+ site of CdSiP2 semiconductor.
The EPR parameters (g factors, g(parallel), g(perdendicular) and zero-field splitting D) for Fe+ in Cd2+ site and Fe3+ in Si4+ site of CdSiP2 semiconductor are calculated from the distinct high-order perturbation formulas. From the calculations, the local tetragonal distortions and hence the local tilting angles tau (which are different from the corresponding host values) for both paramagnetic centers are estimated. The results are discussed.
Wen-Chen
Zheng
Z
Department of Material Science, Sichuan University, Chengdu, People's Republic of China. zhengwenchen@netease.com
Shao-Yi
Wu
W
D002104:Cadmium / Q000737:chemistry*; D019187:Cadmium Compounds / Q000737:chemistry*; D003460:Crystallization; D004578:Electron Spin Resonance Spectroscopy; D007501:Iron / Q000737:chemistry*; D012666:Semiconductors; D012825:Silicon / Q000737:chemistry*
D019187:Cadmium Compounds; D002104:Cadmium; D007501:Iron; D012825:Silicon