Electronic structure of Ni complexes by X-ray resonance Raman spectroscopy (resonant inelastic X-ray scattering).
The potential of 1s2p resonant inelastic (Raman) X-ray scattering (RIXS) is demonstrated for a series of Ni coordination complexes. In this technique, incident and scattered photon energies lie in the hard X-ray range (>5 keV). The 1s2p RIXS contour plots provide information that is complementary to K-edge and L-edge spectroscopy. RIXS spectroscopy promises to be a valuable probe of electronic structure
Glatzel
Pieter
P
Department of Applied Science, University of California, Davis, California 95616, USA. PGlatzel@lbl.gov
Bergmann
Uwe
U
Gu
Weiwei
W
Wang
Hongxin
H
Stepanov
Sergey
S
Mandimutsira
Beaven S
BS
Riordan
Charles G
CG
Horwitz
Colin P
CP
Collins
Terry
T
Cramer
Stephen P
SP
D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D012542:Scattering, Radiation; D013059:Spectrum Analysis, Raman / Q000379:methods*; D014965:X-Rays
D009942:Organometallic Compounds; D009532:Nickel