Bis(tetra-n-butylammonium) bis(mu-1,2-dicyanoethene-1,2-dithiolato-kappa3S,S':S')bis[(1,2-dicyanoethene-1,2-dithiolato-kappa2S,S')cobalt(III)].
In the title compound, (C(16)H(36)N)(2)[Co(C(4)N(2)S(2))(2)](2), pairs of [Co(C(4)N(2)S(2))(2)](-) anions combine to form discrete crystallographically centrosymmetric dimers, which stack along the c axis, surrounded by the counter-cations. The metal atom in the anion has a five-coordinate distorted square-pyramidal geometry.
Mochida
Tomoyuki
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Department of Chemistry, Faculty of Science, Toho University, Miyama, Funabashi, Chiba 274-8510, Japan. mochida@chem.sci.toho-u.ac.jp
Takazawa
Kousuke
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Matsushita
Michio M
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Sugawara
Tadashi
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