A facile synthesis of novel types of cyclodextrin derivatives by insertion of an aromatic dicarbonyl spacer into a permethylated alpha-cyclodextrin skeleton.
Novel types of cyclodextrin derivatives are easily synthesized by the insertion of an aromatic dicarbonyl spacer into the skeleton of permethylated alpha-cyclodextrin, and the isophthaloyl-inserted one shows almost the same complexing ability toward p-nitrophenol as permethylated beta-cyclodextrin.
Kida
Toshiyuki
T
Department of Molecular Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan. kida@chem.eng.osaka-u.ac.jp
Michinobu
Takao
T
Zhang
Wanbin
W
Nakatsuji
Yohji
Y
Ikeda
Isao
I
D018360:Crystallography, X-Ray; D003505:Cyclodextrins / Q000138:chemical synthesis* / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008745:Methylation; D019032:Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization; D013055:Spectrophotometry, Infrared; D047391:alpha-Cyclodextrins
D003505:Cyclodextrins; D047391:alpha-Cyclodextrins; C032613:alpha-cyclodextrin