A highly selective arene hydrogenation catalyst that operates in ionic liquid.
The synthesis and structural characterization of [Ru(eta(6)-p-cymene)(eta(2)-TRIPHOS)Cl][PF(6)] is described. The complex is a highly active, homogeneous arene hydrogenation catalyst that is selective toward the hydrogenation of aromatic rings in preference to alkenes, as demonstrated by the hydrogenation of allylbenzene to allylcyclohexane. The catalyst operates in both dichloromethane and ionic liquids and undergoes no decomposition in the latter solvent.
Boxwell
Clive J
CJ
Department of Chemistry, The University of York, Heslington, UK.
Dyson
Paul J
PJ
Ellis
David J
DJ
Welton
Thomas
T