title: (5,10,15,20-Tetraphenylporphyrinato-kappa4N)bis(L-valine-kappaN methyl ester)iron(III) trifluoromethylsulfonate dichloromethane solvate.
abstract: The title compound, [Fe(C(44)H(28)N(4))(C(6)H(13)NO(2))(2)](CF(3)O(3)S).CH(2)Cl(2), is the first amino ester complex of iron porphyrins to be investigated using X-ray diffraction and it can be considered as a model complex of cytochrome f. The Fe atom is six-coordinate to four N atoms of the porphyrin ring and to two N atoms of the axial amino ester ligands.
authors.affiliation: Laboratoire de Chimie Organométallique et Biologique, UMR CNRS 6509, Université de Rennes I, Campus de Beaulieu, 35042 Rennes Cedex, France.
authors.forename: Marwan
authors.initials: M
authors.lastname: Kobeissi
authors.forename: Loic
authors.initials: L
authors.lastname: Toupet
authors.forename: Gerard
authors.initials: G
authors.lastname: Simonneaux
mesh_terms: D018360:Crystallography, X-Ray; D003580:Cytochromes / Q000737:chemistry*; D045348:Cytochromes f; D005290:Ferric Compounds / Q000737:chemistry*; D006860:Hydrogen Bonding; D008958:Models, Molecular; D010788:Photosynthesis
chemical_list: C467378:(5,10,15,20-tetraphenylporphyrinato-4N)bis(valine-N methyl ester)iron(III) trifluoromethylsulfonate; D003580:Cytochromes; D005290:Ferric Compounds; D045348:Cytochromes f