title: Vibrational spectra of melamine diborate, C3N6H62H3BO3.
abstract: IR and Raman spectra of melamine diborate have been recorded and analysed. Band assignments are given based on the vibrations of melamine and boric acid molecules. Three sets of frequencies observed for the N-H stretching mode region is ascribed to different types of hydrogen bonds in the amino groups of the triazine ring. Due to the lower symmetry of the melamine and boric acid molecules in the crystal, activation of inactive modes and lifting of the degeneracy of certain vibrational modes are observed. Lower symmetry of the melamine molecule in the crystal has resulted in the decrease of intensity of the Raman active melamine band around 1490 cm(-1). All the internal modes of boric acid molecule were identified. All the ring breathing modes of melamine molecule show frequency shift towards the high wavenumber side. In other words, hydrogen bonding affects the ring breathing modes of melamine.
authors.affiliation: Department of Physics, T.K.M. Arts and Science College, Kollam, India.
authors.forename: C Yohannan
authors.initials: CY
authors.lastname: Panicker
authors.forename: Hema Tresa
authors.initials: HT
authors.lastname: Varghese
authors.forename: Annamma
authors.initials: A
authors.lastname: John
authors.forename: Daizy
authors.initials: D
authors.lastname: Philip
authors.forename: Helena I S
authors.initials: HI
authors.lastname: Nogueira
mesh_terms: D001888:Boric Acids / Q000737:chemistry; D006860:Hydrogen Bonding; D017550:Spectroscopy, Fourier Transform Infrared; D013059:Spectrum Analysis, Raman; D014227:Triazines / Q000737:chemistry*
chemical_list: D001888:Boric Acids; D014227:Triazines; C011907:melamine; C032688:boric acid