Sustainable photochemistry: solvent-free singlet oxygen-photooxygenation of organic substrates embedded in porphyrin-loaded polystyrene beads.
A solvent-free photooxygenation process that uses organic substrates embedded in porphyrin-loaded polystyrene beads as solid support is described and applied for ene- and [4 + 2]-cycloaddition reactions involving singlet oxygen (1 delta g).
Griesbeck
Axel G
AG
Institute of Organic Chemistry, University of Cologne, Greinstr. 4, D-50939 Köln, Germany. griesbeck@uni-koeln.de
Bartoschek
Anna
A