A novel catalyst containing a platinum complex in polyethylene glycol medium supported on silica gel for vapor-phase hydrosilylation of acetylene with trichlorosilane or trimethoxysilane.
Hydrosilylation of acetylene with trichlorosilane or trimethoxysilane was carried out using a vapor-phase flow reactor with use of tetraammineplatinum(II) chloride in polyethylene glycol medium supported on silica gel as a catalyst, which is an active and thermally stable supported liquid-phase catalyst prepared readily from easily available materials, tetraammineplatinum(II) chloride, polyethylene glycol and silica gel.
Okamoto
Masaki
M
Department of Applied Chemistry, Tokyo Institute of Technology, Ookayama, Meguro-ku, Tokyo 152-8552, Japan.
Kiya
Hironari
H
Yamashita
Hiromi
H
Suzuki
Eiichi
E