title: Analysis of aromatic sulfur compounds in gas oils using GC with sulfur chemiluminescence detection and high-resolution MS.
abstract: The analysis of alkylbenzothiophenes (alkyl-BT) and alkyl-dibenzothiophenes (alkyl-DBT) in light cycle oil (LCO) and straight run (SR) gas oils is described. A detailed identification and quantitative analysis of alkyl-BT and alkyl-DBT present in LCO gas oils was carried out using GC-SCD. For the SR gas oils, the simultaneous presence of thiophenic and nonthiophenic compounds does not allow for a selective analysis of thiophenic compounds by GC-SCD. A new method using gas chromatography coupled with high-resolution mass spectrometry (GC-HRMS) is proposed to selectively detect and quantify the alkyl-BT and alkyl-DBT in SR gas oils. The development of the method and comparison of results between GC-SCD and GC-HRMS are presented.
authors.affiliation: Institut Français du Pétrole, CEDI René Navarre,Vernaison, France.
authors.forename: C López
authors.initials: CL
authors.lastname: García
authors.forename: M
authors.initials: M
authors.lastname: Becchi
authors.forename: M F
authors.initials: MF
authors.lastname: Grenier-Loustalot
authors.forename: O
authors.initials: O
authors.lastname: Païsse
authors.forename: R
authors.initials: R
authors.lastname: Szymanskit
mesh_terms: D008401:Gas Chromatography-Mass Spectrometry / Q000592:standards*; D008163:Luminescent Measurements; D010578:Petroleum / Q000032:analysis* / Q000592:standards; D011084:Polycyclic Aromatic Hydrocarbons / Q000032:analysis* / Q000592:standards; D012680:Sensitivity and Specificity; D013457:Sulfur Compounds / Q000032:analysis* / Q000592:standards; D013876:Thiophenes / Q000032:analysis / Q000592:standards
chemical_list: D010578:Petroleum; D011084:Polycyclic Aromatic Hydrocarbons; D013457:Sulfur Compounds; D013876:Thiophenes; C088015:benzothiophene; C016366:dibenzothiophene