Wet deposition of polychlorinated biphenyls in urban and background areas of the Mid-Atlantic States.
Spatial and temporal trends of polychlorinated biphenyl (PCB) concentrations in precipitation were measured at urban and background sites as part of the New Jersey Atmospheric Deposition Network (NJADN). The volume weighted mean concentration (VWM) of sigmaPCBs (sum of PCBs) based on precipitation measurements at three background sites was in the range of 0.30-0.50 ng/L. Concentrations in precipitation at two urban-industrial sites were on average 7-43 times higher than background concentrations. Wet deposition fluxes of sigmaPCBs at the two urbanized sites were 16 +/- 3.4 and 3.9 +/- 0.72 microg/m2-yr, while the background flux was approximately 0.30 microg/m2-yr. On average, 97% of the total atmospheric washout (WT) of PCBs resulted from particle scavenging. The fraction of atmospheric PCBs on particles was the best predictor of atmospheric washout in both urban (log WT = 0.71 (+/- 0.049) log psi + 4.9 (+/- 0.11); r2 = 0.81) and nonurban areas (log W(T) = 0.77 (+/- 0.083) log psi + 5.6 (+/- 0.16); r2 = 0.64). Wet deposition fluxes of sigmaPCBs are of the same order of magnitude as dry-particle deposition fluxes in all land-use regimes.
Department of Environmental Sciences, Rutgers University, New Brunswick, New Jersey 08901, USA.
Daryl A
DA
Van Ry
Cari L
CL
Gigliotti
Thomas R
TR
Glenn
Eric D
ED
Nelson
Lisa A
LA
Totten
Steven J
SJ
Eisenreich
D002947:Cities; D004784:Environmental Monitoring; D004785:Environmental Pollutants / Q000032:analysis*; D005544:Forecasting; D007221:Industry; D008962:Models, Theoretical; D011078:Polychlorinated Biphenyls / Q000032:analysis*; D011891:Rain; D013997:Time Factors; D014481:United States
D004785:Environmental Pollutants; D011078:Polychlorinated Biphenyls