Tandem cobalt mediated rearrangement and Pauson-Khand reaction for the synthesis of functionalized polycyclic systems.
The cobalt mediated rearrangement of enol ether complex 2 furnishes cyclic ketone 6, which undergoes an intramolecular Pauson-Khand reaction allowing access to functionalized polycyclic systems.
Carbery
David R
DR
Department of Chemistry, Dainton Building, University of Sheffield, Brook Hill, Sheffield, UK S3 7HF.
Miller
Neil D
ND
Harrity
Joseph P A
JP