Analysis of photodecomposition of gaseous chlorobenzene by KrF excimer laser.
Gaseous monochlorobenzene was irradiated with KrF excimer laser (248 nm) under reduced pressure. The photodecomposition was an apparent first order reaction. When the system contained no additive gas, the photolysis was found to give benzene (conversion yield: 49%) in the gas phase and many unidentified products in the solid phase. On the other hand, in the presence of oxygen, carbon dioxide (10%), carbon monoxide (16%), hydrogen chloride (52%) and acetylene (2%) are produced and the peaks shown on the gas chromatogram of the solid phase were effectively suppressed.
Nakayama
Kunihiko
K
Applied Laser Engineering Research Institute, 2085-16 Uenoyama, Fukasawamachi, Nagaoka 940-2135, Japan.
Fukatsu
Ken-ichi
K
Maruyama
Kazunori
K
Ogawa
Kouji
K
Hasegawa
Tadashi
T
Morohashi
Toshimasa
T
Fujii
Nobuyuki
N
D002722:Chlorobenzenes / Q000032:analysis*; D002849:Chromatography, Gas; D004785:Environmental Pollutants / Q000032:analysis*; D005740:Gases; D006843:Hydrocarbons, Chlorinated / Q000032:analysis; D007834:Lasers; D010313:Partial Pressure; D010782:Photolysis; D013055:Spectrophotometry, Infrared
D002722:Chlorobenzenes; D004785:Environmental Pollutants; D005740:Gases; D006843:Hydrocarbons, Chlorinated; C031294:chlorobenzene