Dimeric iron n-confused porphyrin complexes.
A dimeric iron N-confused porphyrin, [Fe(NCTPP)]2 was obtained from the anaerobic reaction of Fe(NCTPP)Br with NaSePh while under aerobic conditions a hydroxo bridged iron dimer with Na bridging the outer-N atoms was obtained and oxygenation occurred on the inner core pyrrolic carbon to form a novel ONCTPP porphyrinic ring.
Department of Chemistry, National Changhua University of Education, Changhua 50058, Taiwan. chhung@cc.ncue.edu.tw
Chen-Hsiung
CH
Hung
Wan-Chin
WC
Chen
Gene-Hsiang
GH
Lee
Shie-Ming
SM
Peng