Carbon monoxide free aminocarbonylation of aryl and alkenyl iodides using DMF as an amide source.
[reaction: see text] Palladium-catalyzed coupling reaction of N,N-dimethylformamide with aryl or alkenyl halides successfully proceeded in the presence of phosphoryl chloride to afford the corresponding tertiary amides in good yields.
Hosoi
Kazushi
K
Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan.
Nozaki
Kyoko
K
Hiyama
Tamejiro
T