Homochiral 3D lanthanide coordination networks with an unprecedented 4(9)6(6) topology.
Homochiral 3D metal-organic open frameworks based on enantiopure atropisomeric dicarboxylic acid bridging ligands and dilanthanide secondary building units exhibit an unprecedented 4(9)6(6) topology, and possess ethoxy-protected BINOL functionalities that are pointing toward the open channels.
Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, NC 27599, USA.
Yong
Y
Cui
Helen L
HL
Ngo
Peter S
PS
White
Wenbin
W
Lin