Structure of intercalated Cs in zeolite ITQ-4: an array of metal ions and correlated electrons confined in a pseudo-1D nanoporous host.
The presence of Cs+ ions in the pseudo-1D nanopores of zeolite ITQ-4, Si32O64, is confirmed by x-ray diffraction and atomic pair distribution function analysis. Inside the nanopores the Cs+ ions are found to assemble in zigzag chains and thus form an extended, positively charged sublattice providing charge balance for a low-density electron gas also confined to the nanopores.
Petkov
V
V
Department of Physics and Astronomy and Center for Fundamental Materials Research, Michigan State University, East Lansing 48824, USA.
Billinge
S J L
SJ
Vogt
T
T
Ichimura
A S
AS
Dye
J L
JL