In situ generation of endohedral metallocenophanes of cobalt and rhodium with one cyclopentadienone unit.
[reaction: see text] Endohedral metallocenophanes of cobalt and rhodium were prepared using thermolysis of cyclopentadienylmetaldicarbonyl complexes bearing two alkyne units. In the case of the rhodium cyclopentadienonophanes, the structures of two isomeric complexes were confirmed by X-ray diffraction analysis.
Organisch-Chemisches Institut, Universität Heidelberg, INF 270, D-69120 Heidelberg, Germany.
Gerald
G
Scholz
Carsten
C
Schaefer
Frank
F
Rominger
Rolf
R
Gleiter