Isolation of a new mixed valence Pt molecular oxide using phosphine as protecting group.
A novel tetranuclear mixed valence cationic Pt molecular oxide [((Me3P)2Pt)3Pt(OH)6]4+ is obtained by reacting H2Pt(OH)6 and (Me3P)2Pt2+, whose NMR spectra suggest the existence of another species in solution that may serve as a starting point for further synthesis of Pt molecular oxides.
Department of Chemistry, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, Japan.
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K
Noro
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Y
Ozawa
M
M
Taguchi
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Yagasaki