Carbon monoxide free aminocarbonylation of aryl and alkenyl iodides using DMF as an amide source.
[reaction: see text] Palladium-catalyzed coupling reaction of N,N-dimethylformamide with aryl or alkenyl halides successfully proceeded in the presence of phosphoryl chloride to afford the corresponding tertiary amides in good yields.
Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan.
Kazushi
K
Hosoi
Kyoko
K
Nozaki
Tamejiro
T
Hiyama