Structure and reactivity of a novel parallel thiosulfito (SSO2-S:S') rhodium dinuclear complex.
The parallel thiosulfite ligand (SSO2) in a rhodium complex, which is formed by oxygenation of a bridging disulfide, is converted to a bridging hydrocarbyl thiolate ligand and sulfur dioxide gas by the reaction with hydrocarbyl halides.
Shiomi
Kimie
K
Department of Material Science, Graduate School of Science, Osaka City University, Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan.
Breedlove
Brian K
BK
Kitayama
Hiroaki
H
Nishioka
Takanori
T
Kinoshita
Isamu
I
Koga
Nobuaki
N
Isobe
Kiyoshi
K