Long-range self-assembly of a polyunsaturated linear organosilane at the n-tetradecane/Au(111) interface studied by STM.
We report on the formation of self-assembled monolayers of 13-(trimethylsilyl)-1-tridecene-6,12-diyne [C13H17-Si(CH3)3], an organosilane derivative with a linear polyunsaturated chain, on Au(111) substrates. Molecular resolution STM images recorded at the liquid-solid interface between gold and tetradecane reveal a long-range and densely packed hexagonal lattice with a ( radical3 x radical3)R30 degrees -like structure commensurate against gold adlattice.
Marchenko
Alexandr
A
CEA-Saclay, Service de Physique et Chimie des Surfaces et Interfaces, DRECAM/DSM, 91191 Gif-sur-Yvette, France.
Katsonis
Nathalie
N
Fichou
Denis
D
Aubert
Corinne
C
Malacria
Max
M