Photoinduced electron transfer in hydrogen-bonded oligo(p-phenylene vinylene)-perylene bisimide chiral assemblies.
Well-defined chiral fibers incorporating hydrogen-bonded oligo(p-phenylene vinylene) donor and perylene bisimide acceptor chromophores have been realized by self-assembly. Upon photoillumination of these fibers electron-transfer takes place, leading to charge separation within the aggregated dyes.
Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands.
Albertus P H J
AP
Schenning
Jeroen
J
V  Herrikhuyzen
Pascal
P
Jonkheijm
Zhijian
Z
Chen
Frank
F
Würthner
E W
EW
Meijer
D005456:Fluorescent Dyes / Q000737:chemistry*; D006860:Hydrogen Bonding; D008958:Models, Molecular; D010569:Perylene / Q000031:analogs & derivatives* / Q000737:chemistry; D010777:Photochemistry; D014227:Triazines / Q000737:chemistry*
D005456:Fluorescent Dyes; D014227:Triazines; D010569:Perylene