1,5-Bis(benzothiazolyl)-3-thiapentane and its asymmetric dinuclear Ag(I) complex with three distinct intermolecular-stacking interactions.
Synthesis of a dibenzothiazole thioether ligand that coordinates Ag(I) yielding an asymmetric dinuclear complex with three unique intermolecular pi-stacking interactions, which influence the first coordination spheres of the silver centers, is reported.
Department of Chemistry, University of Louisville, Louisville, KY 40292, USA. grapperhaus@louisville.edu
Craig A
CA
Grapperhaus
Ming
M
Li
Mark S
MS
Mashuta
D052160:Benzothiazoles; D003500:Cyclization; D008024:Ligands; D015394:Molecular Structure; D012834:Silver / Q000737:chemistry*; D013440:Sulfides / Q000138:chemical synthesis* / Q000737:chemistry*; D013844:Thiazoles / Q000138:chemical synthesis* / Q000737:chemistry*
C476126:1,5-bis(benzothiazolyl)-3-thiapentane; D052160:Benzothiazoles; D008024:Ligands; D013440:Sulfides; D013844:Thiazoles; D012834:Silver