Ligand trans-effect: using an old concept as a novel approach to bis(dipolar) NLO-phores.
In plane parallel arrangement and enhancement of NLO-activity are observed upon coordination of heteroditopic dipoles containing a phosphole ring on square-planar d8-palladium centre.
Fave
Claire
C
UMR 6509 CNRS-Université de Rennes 1, Institut de Chimie, Campus de Beaulieu, 35042 Rennes, France.
Hissler
Muriel
M
Sénéchal
Katell
K
Ledoux
Isabelle
I
Zyss
Joseph
J
Réau
Régis
R