Hydrothermal synthesis of the first vanadomolybdenum polyoxocation with a "metal-bonded" spherical framework.
The heteropoly compound [(V(V)O(4))Mo(VI)(12)O(36)(V(IV)O)(6)][(OH)(9)].11H(2)O (1), synthesized by hydrothermal method under weak basic conditions, represents the first mixed Mo/V six-capped Keggin structural derivative with a spherical skeleton, and the first transition metal polyoxocation. The successful synthesis of 1 demonstrates that basic hydrothermal synthesis might be a power synthetic route to the isolation of more new polycationic metal-oxo clusters.
The State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, P.R. China.
Wenbin
W
Yang
Canzhong
C
Lu
Xiaoping
X
Zhan
Honghui
H
Zhuang