Two-dimensional materials based on trans-[FeII(CN)4(CO)2]2- building blocks; first structural evidence for a hydrated metal carbonyl ligation.
Analogues to the Hofmann-type clathrates have been characterized using trans-[FeII(CN)4(CO)2]2- as the building blocks.
Jiang
Jianfeng
J
Department of Chemistry, State University of New York at Stony Brook, Stony Brook, NY 11794-3400, USA.
Koch
Stephen A
SA
D001665:Binding Sites; D003460:Crystallization; D003486:Cyanides / Q000737:chemistry; D004583:Electrons; D005296:Ferrous Compounds / Q000737:chemistry*; D006860:Hydrogen Bonding; D058085:Iron Compounds / Q000138:chemical synthesis*; D008024:Ligands; D015394:Molecular Structure; D014867:Water / Q000737:chemistry
D003486:Cyanides; D005296:Ferrous Compounds; D058085:Iron Compounds; D008024:Ligands; C476125:dicarbonyltetracyanoiron(II); D014867:Water