Oxidic nanotubes and nanorods--anisotropic modules for a future nanotechnology.
The discovery of carbon nanotubes in 1991 is a milestone in nanomaterials research. Since then, more and more anisotropic nanoparticles have been detected and characterized. The development of nanodevices might benefit from the distinct morphology and high aspect ratio of nanorods and nanotubes as these can be functionalized in unique ways such as incorporation of nanorods in nanotubes. Downscaling a broad range of materials to 1D nanoscopic structures is currently the focus of a rapidly growing scientific community. Developing general pathways to this goal would transfer a wide variety of properties to the nanoscale-a spectrum of phenomena so diverse that it would cover not only inorganic systems but all of materials science. Synthesis of real functional materials, however, always involves considerable synthetic ingenuity, interdisciplinary collaboration, as well as technological and economical realism. The major topic of this review is to provide a survey of recent progress in the synthesis of oxidic nanotubes and nanorods-with their non-oxidic counterparts briefly highlighted-and to outline the major synthetic routes leading to them. With the challenges of synthesizing bulk oxidic materials in mind, the establishment of trustworthy and uncomplicated ways of providing them as anisotropic nano-modules on an industrial scale appears to be more or less serendipity. Of the methods utilized in nanotube and nanorod synthesis solvothermal processes have emerged as powerful tools for generalizing and systematizing controlled syntheses of nano-morphologies. The flexibility and reliability of this synthetic approach is demonstrated here for the transformation of transition-metal oxides into high-quality anisotropic nanomaterials.
Laboratory of Inorganic Chemistry, ETH Hönggerberg-HCI, 8093 Zürich, Switzerland.
Greta R
GR
Patzke
Frank
F
Krumeich
Reinhard
R
Nesper