title: On-column complexation of metal ions using 2,6-pyridinedicarboxylic acid and separation of their anionic complexes by capillary electrophoresis with direct UV detection.
abstract: On-column complexation of metal ions with 2,6-pyridinedicarboxylate (2,6-PDC) to form anionic complexes enabled their separation by capillary zone electrophoresis with direct UV detection at 214 nm. Nine metal ions, Cu2+, Zn2+, Ni2+, Cd2+ Mn2+, Pb2+, Fe3+, Al3+ and Ca2+, were determined in less than 7 min using 10 mM 2.6-PDC solution containing 0.75 mM tetradecyltrimethylammonium bromide at pH 4.0. Satisfactory working ranges (20-300 microM), detection limits (3-10 microM) and good repeatability of the peak areas (RSD 2.1-4.2%, n=5) were obtained using hydrodynamic injection (30 s). The proposed method was used successfully for the determination of Mn2+, Fe3+, Al3+ and Ca2+ in groundwaters.
authors.affiliation: CSIRO Land and Water, Adelaide Laboratory, Glen Osmond, SA, Australia. zuliang.chen@csiro.au
authors.forename: Zuliang
authors.initials: Z
authors.lastname: Chen
authors.forename: Ravendra
authors.initials: R
authors.lastname: Naidu
mesh_terms: D019075:Electrophoresis, Capillary / Q000379:methods*; D008670:Metals / Q000737:chemistry*; D010848:Picolinic Acids / Q000737:chemistry*; D015203:Reproducibility of Results; D012680:Sensitivity and Specificity; D013056:Spectrophotometry, Ultraviolet / Q000379:methods*
chemical_list: D008670:Metals; D010848:Picolinic Acids; C004860:dipicolinic acid