A novel intramolecular through-space interaction between F and CN: a strategy for the conformational control of an acyclic system.
X-Ray crystallographic analyses of fluorocyanides anti-1 and 2 revealed a novel intramolecular through-space interaction between F and CN in an acyclic system, which was applied to a stereoselective protonation of acyclic fluorocyanides 2 having flexible conformation.
Nishide
K
K
Department of Pharmaceutical Manufacturing Chemistry, Kyoto Pharmaceutical University, Misasagi, Yamashina, Kyoto 607-8414, Japan.
Hagimoto
Y
Y
Hasegawa
H
H
Shiro
M
M
Node
M
M
D018360:Crystallography, X-Ray; D005459:Fluorides / Q000737:chemistry*; D015394:Molecular Structure; D009570:Nitriles / Q000737:chemistry; D055672:Static Electricity
D009570:Nitriles; D005459:Fluorides