Intramolecular addition of acyl radicals to alpha-substituted vinylogous carbonates: demonstrating the effect of ring size on acyclic stereocontrol.
The level of stereocontrol obtained in the reduction of the free radical derived from the intramolecular addition of an acyl radical to an alpha-branched vinylogous carbonate is dependent upon the ring-size of the cyclic ether.
Evans
P A
PA
Department of Chemistry, Indiana University, Bloomington, IN 47405, USA. paevans@indiana.edu
Raina
S
S
Ahsan
K
K
D002254:Carbonates / Q000737:chemistry*; D004988:Ethers, Cyclic / Q000737:chemistry*; D013237:Stereoisomerism; D013696:Temperature; D014753:Vinyl Compounds / Q000737:chemistry*
D002254:Carbonates; D004988:Ethers, Cyclic; D014753:Vinyl Compounds