Efficient radical addition of tertiary amines to electron-deficient alkenes using semiconductors as photochemical sensitisers.
Tertiary amines can be added to electron-deficient alkenes with yields up to 98% in a radical chain reaction initiated by a photochemical electron transfer using inorganic semiconductors like TiO2 as sensitiser.
Marinković
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Laboratoire des Réactions Sélectives et Applications, UMR CNRS et Université de Reims Champagne-Ardenne, UFR Sciences, B.P. 1039, F-51687 Reims, France.
Hoffmann
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