title: A novel intramolecular through-space interaction between F and CN: a strategy for the conformational control of an acyclic system.
abstract: X-Ray crystallographic analyses of fluorocyanides anti-1 and 2 revealed a novel intramolecular through-space interaction between F and CN in an acyclic system, which was applied to a stereoselective protonation of acyclic fluorocyanides 2 having flexible conformation.
authors.affiliation: Department of Pharmaceutical Manufacturing Chemistry, Kyoto Pharmaceutical University, Misasagi, Yamashina, Kyoto 607-8414, Japan.
authors.forename: K
authors.initials: K
authors.lastname: Nishide
authors.forename: Y
authors.initials: Y
authors.lastname: Hagimoto
authors.forename: H
authors.initials: H
authors.lastname: Hasegawa
authors.forename: M
authors.initials: M
authors.lastname: Shiro
authors.forename: M
authors.initials: M
authors.lastname: Node
mesh_terms: D018360:Crystallography, X-Ray; D005459:Fluorides / Q000737:chemistry*; D015394:Molecular Structure; D009570:Nitriles / Q000737:chemistry; D055672:Static Electricity
chemical_list: D009570:Nitriles; D005459:Fluorides