Ferrimagnetic-like ordering in a unique three-dimensional coordination polymer featuring mixed azide/carboxylate-bridged trinuclear manganese (II) clusters as subunits.
The crystal structure of the coordination polymer [Mn3(N3)2(nta)4(H2O)2]n (nta = nicotinate) consists of trinuclear subunits bridged by mixed mu-1,1-azide and mu-carboxylate-O,O groups, which are linked by mu 3-nta-N,O,O ligands into a three-dimensional network exhibiting ferrimagnetic-like ordering.
Chen
H J
HJ
School of Chemistry & Chemical Engineering, Zhongshan University, Guangzhou 510275, China.
Mao
Z W
ZW
Gao
S
S
Chen
X M
XM