Formation and reactivity of a cobalt (II) hydroperoxide intermediate.
Reaction of Tpt-Bu,MeCo-H with O2 proceeds via a spectroscopically observable hydroperoxide whose reactivity in solution and in the solid state differ dramatically.
Thyagarajan
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Department of Chemistry and Biochemistry, Center for Catalytic Science and Technology, University of Delaware, Newark, DE 19716, USA.
Incarvito
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Rheingold
A L
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Theopold
K H
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