The first 1,3-digermyla-2-nickela-carboranylene and the Ni-catalyzed double germylation of unsaturated organic substrates.
The reaction of o-bis(dimethylgermyl)carborane with Ni(PEt3)4 in pentane affords the reactive intermediate, [o-(GeMe2)2C2B10H10]Ni(PEt3)2 2: the facile double germylation of unsaturated organic substrates catalyzed by 2 is reported.
Lee
J
J
Department of Chemistry, Korea University, Chochiwon, Chungnam 339-700, Korea.
Lee
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Lee
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Kang
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Ko
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