title: Structural characterisation of the H-bonded [MnII(OH2)2...(OCH3)2MnIII] motif: a model for resting state hydroxylic solvent coordination in M(II)-M(III) enzymes.
abstract: A mixed-valence dimanganese complex with two water ligands bound to the Mn(II) ion and two methoxide ligands bound to the Mn(III) ion in a H-bonded arrangement has been structurally characterised and models possible resting state water/hydroxide coordination in purple acid phosphatases.
authors.affiliation: Department of Chemistry, University of Southern Denmark, Campus, 5230 Odense M, Denmark.
authors.forename: A
authors.initials: A
authors.lastname: Boisen
authors.forename: A
authors.initials: A
authors.lastname: Hazell
authors.forename: C J
authors.initials: CJ
authors.lastname: McKenzie