title: Synthesis and properties of fac-Re(dmbpy)(CO)3CHO (dmbpy = 4,4'-dimethyl-2,2'-bipyridine), a possible intermediate in reductions of CO2 catalyzed by fac-Re(dmbpy)(CO)3Cl.
abstract: Synthesis of fac-Re(dmbpy)(CO)3CHO 2 and its reactions with CO2 in DMF and DMSO have been conducted; 2 transfers hydride to CO2 to give Re(dmbpy)(CO)4+ OCHO- 5 which is rapidly transformed to fac-Re(dmbpy)(CO)3(OCHO) 3 in DMF, thus supporting the viability of 2 in photocatalytic reactions of fac-Re(dmbpy)(CO)3Cl with CO2.
authors.affiliation: Department of Chemistry and Center for Chemical Catalysis, University of Louisville, Louisville, KY 40292, USA. dorothy.gibson@louisville.edu
authors.forename: D H
authors.initials: DH
authors.lastname: Gibson
authors.forename: H
authors.initials: H
authors.lastname: He