Pentaporphyrin with flexible, chiral nucleosidic linkers: unexpected duality of the physico-chemical properties of its core.
A new star-like pentaporphyrin, bearing nucleosidic linkers, has been synthesized, and the unexpected duality of the physico-chemical properties of its core is reported; beside the quenching of the fluorescence of the peripheral porphyrins by the central chromophore, this pentaporphyrin exhibits an unexpected shielding of the redox capabilities of its central core.
Solladié
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Laboratoire d'Electrochimie et de Chimie Physique du Corps Solide, Université Louis Pasteur et CNRS, 4 rue Blaise Pascal, 67000 Strasbourg, France. nsolladie@chimie.u-strasbg.fr
Gross
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Gisselbrecht
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JP
Sooambar
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