title: Structures of bromoalkanes' photodissociation in solution by means of ultrafast extended x-ray absorption fine-structure spectroscopy.
abstract: The structures of initial and final products of bromoalkanes' photodisociation reaction in cyclohexane solution have been measured with a bond length accuracy of 0.02 A by means of ultrafast time-resolved extended x-ray absorption fine structure spectroscopy. The photoredaction mechanism is also discussed.
authors.affiliation: Department of Chemistry, University of California, Irvine, CA 92697, USA.
authors.forename: D A
authors.initials: DA
authors.lastname: Oulianov
authors.forename: I V
authors.initials: IV
authors.lastname: Tomov
authors.forename: A S
authors.initials: AS
authors.lastname: Dvornikov
authors.forename: P M
authors.initials: PM
authors.lastname: Rentzepis
mesh_terms: D005583:Fourier Analysis; D006842:Hydrocarbons, Brominated / Q000737:chemistry*; D008027:Light; D008956:Models, Chemical; D012542:Scattering, Radiation; D013052:Spectrometry, X-Ray Emission / Q000379:methods*; D013997:Time Factors; D022882:Trihalomethanes / Q000737:chemistry*; D014466:Ultraviolet Rays
chemical_list: D006842:Hydrocarbons, Brominated; D022882:Trihalomethanes; C031387:carbon tetrabromide; C015044:bromoform; C027947:methylene bromide