Epoxidation of allylic alcohols in aqueous solutions of non surfactant amphiphilic sugars.
A variety of cyclic and acyclic allylic alcohols undergo efficient chemo-, regio- and/or stereoselective epoxidations in neutral aqueous solutions of amphiphilic carbohydrates (sucrose, L-arabinose, methyl or ethyl beta-D-fructopyranoside) by using dilute hydrogen peroxide in the presence of molybdic or tungstic salts.
Denis
C
C
Ecole Nationale Supérieure de Chimie de Rennes, Synthèses et Activations de Biomolécules, CNRS UMR 6052, Institut de Chimie de Rennes, Avenue du Général Leclerc F-35700, Rennes, France.
Misbahi
K
K
Kerbal
A
A
Ferrières
V
V
Plusquellec
D
D