Design and post-functionalisation of ordered mesoporous zirconia thin films.
Bidimensional hexagonal or centred-rectangular mesoporous zirconia thin films have been reproducibly prepared by evaporation-induced self-assembly (EISA), which are stable up to 300 degrees C, with pore size around 35 A; the films can be post-functionalised with organic ligands presenting different functions, opening a land of opportunities for the design of new hybrid mesostructured materials, based on the synergy of a transition metal oxide network and organic groups.
Crepaldi
E L
EL
Laboratoire Chimie de la Matière Condensée, Université Pierre et Marie Curie, 4 Place Jussieu, 75252 Paris, France. clems@ccr.jussieu.fr
de A A Soler-Illia
G J
GJ
Grosso
D
D
Albouy
P A
PA
Sanchez
C
C