title: Assembling the biosynthetic puzzle of crucifer metabolites: indole-3-acetaldoxime is incorporated efficiently into phytoalexins but glucobrassicin is not.
abstract: First biosynthetic studies utilizing tetradeuterated precursors indicate that the indole glucosinolate glucobrassicin is not a precursor of the phytoalexin brassinin, and that indole-3-acetaldoxime is an efficient precursor.
authors.affiliation: Department of Chemistry, University of Saskatchewan, 110 Science Place, Saskatoon SK S7N 5C9, Canada. soledade.pedras@usask.ca
authors.forename: M S
authors.initials: MS
authors.lastname: Pedras
authors.forename: S
authors.initials: S
authors.lastname: Montaut
authors.forename: Y
authors.initials: Y
authors.lastname: Xu
authors.forename: A Q
authors.initials: AQ
authors.lastname: Khan
authors.forename: A
authors.initials: A
authors.lastname: Loukaci
mesh_terms: D001937:Brassica / Q000737:chemistry* / Q000378:metabolism*; D005961:Glucosinolates / Q000378:metabolism*; D007211:Indoles / Q000737:chemistry / Q000378:metabolism*; D015394:Molecular Structure; D010091:Oximes / Q000737:chemistry / Q000378:metabolism*; D010936:Plant Extracts / Q000096:biosynthesis* / Q000378:metabolism*; D018515:Plant Leaves / Q000737:chemistry / Q000378:metabolism; D018517:Plant Roots / Q000737:chemistry / Q000378:metabolism; D012717:Sesquiterpenes; D013729:Terpenes; D000094162:Phytoalexins
chemical_list: D005961:Glucosinolates; D007211:Indoles; D010091:Oximes; D010936:Plant Extracts; D012717:Sesquiterpenes; D013729:Terpenes; C467098:indole-3-acetaldoxime; C048308:glucobrassicin; D000094162:Phytoalexins