title: Highly effective epoxidation of alkenes with Ti-containing soluble polymers.
abstract: Ti-containing polysiloxane epoxidation catalysts have been prepared by controlled hydrolysis of titanium- and alkylsilane precursors. These polysilkoxanes exhibit very high yields to epoxides in the epoxidation reaction of primary alkenes with organic hydroproxides.
authors.affiliation: Instituto de Catálisis y Petroleoquímicaa, CSIC, Campus Cantoblanco, 28049 Madrid, Spain.
authors.forename: G
authors.initials: G
authors.lastname: Blanco-Brieva
authors.forename: J M
authors.initials: JM
authors.lastname: Campos-Martín
authors.forename: M P
authors.initials: MP
authors.lastname: de Frutos
authors.forename: J L
authors.initials: JL
authors.lastname: Fierro