Dissociative cycloelimination, a new selenium based pericyclic reaction.
The stereospecific oxidation of hydrazine into cis-diimide and the catalytic disproportionation of hydrogen peroxide effected by selenoxides are suggested to involve a dissociative cycloelimination from an intermediary selenurane.
Henriksen
L
L
Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen, Denmark. larsh@kiku.dk
Jakobsen
S
S