Directly linked dehydropurpurin-porphyrin dyads from Ag(I)-promoted oxidation of meso-phenylethynyl substituted zinc(II) porphyrins.
Ag(I)-promoted oxidation of (5,15-diaryl-10-phenylethynyl-porphyrinato)zinc(II) complexes in CHCl3 gave directly linked 12,13-dehydropurpurin-porphyrin dyads, the structures of which were revealed by X-ray analysis.
Nakano
A
A
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan.
Aratani
N
N
Furuta
H
H
Osuka
A
A