Structures of bromoalkanes' photodissociation in solution by means of ultrafast extended x-ray absorption fine-structure spectroscopy.
The structures of initial and final products of bromoalkanes' photodisociation reaction in cyclohexane solution have been measured with a bond length accuracy of 0.02 A by means of ultrafast time-resolved extended x-ray absorption fine structure spectroscopy. The photoredaction mechanism is also discussed.
Oulianov
D A
DA
Department of Chemistry, University of California, Irvine, CA 92697, USA.
Tomov
I V
IV
Dvornikov
A S
AS
Rentzepis
P M
PM
D005583:Fourier Analysis; D006842:Hydrocarbons, Brominated / Q000737:chemistry*; D008027:Light; D008956:Models, Chemical; D012542:Scattering, Radiation; D013052:Spectrometry, X-Ray Emission / Q000379:methods*; D013997:Time Factors; D022882:Trihalomethanes / Q000737:chemistry*; D014466:Ultraviolet Rays
D006842:Hydrocarbons, Brominated; D022882:Trihalomethanes; C031387:carbon tetrabromide; C015044:bromoform; C027947:methylene bromide