Sulfenamide catalyzed oxidation of alcohols to the corresponding carbonyl compounds with anhydrous chloramine-T.
N-tert-Butylbenzenesulfenamide (1) catalyzed oxidation of various alcohols with stoichiometric amount of anhydrous chloramines-T (2) proceeded smoothly at room temperature to afford the corresponding carbonyl compounds in good yields.
Kitagawa
Hideo
H
The Kitasato Institute, Center for Basic Research, Tokyo, Japan.
Mukaiyama
Teruaki
T
D000438:Alcohols / Q000737:chemistry; D001547:Benzaldehydes / Q000737:chemistry; D002384:Catalysis; D002700:Chloramines / Q000737:chemistry*; D007202:Indicators and Reagents; D009682:Magnetic Resonance Spectroscopy; D009828:Oleanolic Acid / Q000031:analogs & derivatives / Q000737:chemistry*; D010084:Oxidation-Reduction; D013055:Spectrophotometry, Infrared; D014105:Tosyl Compounds / Q000737:chemistry*; D014315:Triterpenes / Q000737:chemistry*
C471389:4-hydroxyfilican-3-one; D000438:Alcohols; D001547:Benzaldehydes; D002700:Chloramines; D007202:Indicators and Reagents; D014105:Tosyl Compounds; D014315:Triterpenes; C016300:chloramine-T; C471390:fern-9(11)-en-12-ol; C471391:olean-18-en-3-one; D009828:Oleanolic Acid