One-, two-, and three-dimensional organization of colloidal particles using nonuniform alternating current electric fields.
We demonstrate here the use of nonuniform alternating current (AC) electric fields, generated by planar electrodes, for the organization of num-sized particles into one-, two-, and three-dimensional assemblies. The electrodes, with separations that vary from 35 to 300 num, are made of gold deposited on glass substrata. Latex, silica and graphite particles have been examined inside organic or aqueous media in order to illustrate the general applicability of the technique. Theoretical predictions of the particle response under the electric fields are experimentally confirmed for all the above particle/media combinations and can thus be used as a valuable design tool. The size and shape of the final structures are mainly dependent on the electrode shape and dimensions, but are also subject to the particle type and operating conditions. Particle organization in one dimension (strings) is achieved under conditions of positive or negative dielectrophoresis in the space between two energized electrodes. Two-dimensional particle organization (ordered, planar particles assemblies) was observed under conditions of negative dielectrophoresis, when quadrupole electrodes were employed. Moreover, when negative dielectrophoresis and stronger electric fields are applied (of the order of 50 kV(rms) m(-1)), three-dimensional, pyramid-like structures with a vertical dimension 1000-fold higher than that of the corresponding (planar) electrodes can be assembled. These 3-D structures can grow as free-standing assemblies, or inside templates etched in the substratum. The dielectrophoresis (DEP)-organized particle assemblies can subsequently be rendered permanent via the in situ fixing (cross-linking) of the individual particles.
Docoslis
Aristides
A
Department of Chemical Engineering, University at Buffalo, The State University of New York, Buffalo, NY 14260-4200, USA.
Alexandridis
Paschalis
P
D003102:Colloids / Q000737:chemistry*; D003460:Crystallization; D004586:Electrophoresis / Q000295:instrumentation / Q000379:methods*; D008832:Microchemistry / Q000295:instrumentation / Q000379:methods; D008839:Microelectrodes; D008956:Models, Chemical; D010316:Particle Size
D003102:Colloids