A new approach to heterofunctionalized dendrimers: a versatile triallyl chloride core.
A reactive triallyl chloride moiety was prepared as a suitable core for aliphatic polyether dendrons. In addition to allowing access to fourth generation dendrimers, this core contains three alkene functionalities that can be modified after dendrimer formation and used for further dendritic growth.
Grayson
Scott M
SM
Department of Chemistry, University of California, Berkeley 94720-1460, USA.
Fréchet
Jean M J
JM
D001665:Binding Sites; D002384:Catalysis; D003432:Cross-Linking Reagents / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D015394:Molecular Structure; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry*
D003432:Cross-Linking Reagents; D011108:Polymers