The first example of a diazaarsolyl anion: structure and coordination polymerisation of the aromatic metallacycle benzo[1,3,2]diazaarsolyl lithium.2THF.
The first example of an aromatic diazaarsolyl anion 1 has been synthesised and structurally characterised; the X-ray crystal structure of 1 exhibits planar metallacyclic fragments which link together to generate a coordination polymer via bridging lithium cations.
Paver
M A
MA
Department of Chemistry, University of Southampton, Highfield, Southampton, UK SO17 1BJ. M.A.Paver@soton.ac.uk
Joy
J S
JS
Hursthouse
M B
MB