Estimation of the critical rate of temperature rise for thermal explosion of first-order autocatalytic decomposition reaction systems using non-isothermal DSC.
A method of estimating the critical rate of temperature rise for thermal explosion of first-order autocatalytic decomposition reaction systems using non-isothermal DSC is presented. Information is obtained on the increasing rate of temperature in highly nitrated nitrocellulose containing 14.14% of nitrogen when the first-order autocatalytic decomposition converts into thermal explosion.
Hai
Zhang
Z
Shaanxi Key Laboratory of Physico-Inorganic Chemistry and Department of Chemistry, Northwest University, Xi'an, China.
Zhiming
Xia
X
Pengjiang
Guo
G
Rongzu
Hu
H
Shengli
Gao
G
Binke
Ning
N
Yan
Fang
F
Qizhen
Shi
S
Rong
Liu
L
D002384:Catalysis; D005107:Explosions; D005544:Forecasting; D008962:Models, Theoretical; D013696:Temperature