Palladium-catalysed cross-coupling reactions in supercritical carbon dioxide.
Heck and Suzuki reactions proceed in good yield in supercritical carbon dioxide in the presence of palladium acetate and tri-tert-butylphosphine with both free and polymer-tethered substrates.
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Melville Laboratory for Polymer Synthesis, Department of Chemistry, University of Cambridge, Pembroke Street, Cambridge, UK CB2 3RA.
Gordon
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Carroll
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Holmes
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Shute
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McConvey
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