A bis-bidentate dioxolene ligand induces thermal hysteresis in valence tautomerism interconversion processes.
The use of a bis-bidentate ligand in a solid cobalt dioxolene complex affords the necessary cooperative properties that lead to thermal hysteresis in a valence tautomeric interconversion equilibrium.
Bodnar
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Department of Chemistry, North Carolina State University, Raleigh, North Carolina, USA.
Caneschi
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Dei
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Shultz
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DA
Sorace
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