title: Hydrogen-bond dynamics near a micellar surface: origin of the universal slow relaxation at complex aqueous interfaces.
abstract: The dynamics of hydrogen bonds among water molecules themselves and with the polar head groups (PHG) at a micellar surface have been investigated by long molecular dynamics simulations. The lifetime of the hydrogen bond between a PHG and a water molecule is found to be much longer than that between any two water molecules, and is likely to be a general feature of hydrophilic surfaces of organized assemblies. Analyses of individual water trajectories suggest that water molecules can remain bound to the micellar surface for more than 100 ps. The activation energy for such a transition from the bound to a free state for the water molecules is estimated to be about 3.5 kcal/mol.
authors.affiliation: Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Bangalore 560064, India.
authors.forename: Sundaram
authors.initials: S
authors.lastname: Balasubramanian
authors.forename: Subrata
authors.initials: S
authors.lastname: Pal
authors.forename: Biman
authors.initials: B
authors.lastname: Bagchi
mesh_terms: D006845:Hydrocarbons, Fluorinated / Q000737:chemistry; D006860:Hydrogen Bonding; D007700:Kinetics; D008823:Micelles; D008956:Models, Chemical; D013501:Surface-Active Agents / Q000737:chemistry; D014867:Water / Q000737:chemistry*
chemical_list: D006845:Hydrocarbons, Fluorinated; D008823:Micelles; D013501:Surface-Active Agents; D014867:Water