Mechanistic molecular model of liquid-solid chromatography retention-eluent composition relationships.
The development of a simple molecular model of liquid-solid chromatography leading to linear logarithmic relationships between retention factor and eluent composition is discussed. Further evolution of the model and its practical applications in method development are reviewed.
Soczewiński
Edward
E
Department of Inorganic and Analytical Chemistry, Medical University, Lublin, Poland.
D002845:Chromatography / Q000379:methods*; D008958:Models, Molecular