title: Pentaporphyrin with flexible, chiral nucleosidic linkers: unexpected duality of the physico-chemical properties of its core.
abstract: A new star-like pentaporphyrin, bearing nucleosidic linkers, has been synthesized, and the unexpected duality of the physico-chemical properties of its core is reported; beside the quenching of the fluorescence of the peripheral porphyrins by the central chromophore, this pentaporphyrin exhibits an unexpected shielding of the redox capabilities of its central core.
authors.affiliation: Laboratoire d'Electrochimie et de Chimie Physique du Corps Solide, Université Louis Pasteur et CNRS, 4 rue Blaise Pascal, 67000 Strasbourg, France. nsolladie@chimie.u-strasbg.fr
authors.forename: N
authors.initials: N
authors.lastname: Solladié
authors.forename: M
authors.initials: M
authors.lastname: Gross
authors.forename: J P
authors.initials: JP
authors.lastname: Gisselbrecht
authors.forename: C
authors.initials: C
authors.lastname: Sooambar