title: Formation and reactivity of a cobalt (II) hydroperoxide intermediate.
abstract: Reaction of Tpt-Bu,MeCo-H with O2 proceeds via a spectroscopically observable hydroperoxide whose reactivity in solution and in the solid state differ dramatically.
authors.affiliation: Department of Chemistry and Biochemistry, Center for Catalytic Science and Technology, University of Delaware, Newark, DE 19716, USA.
authors.forename: S
authors.initials: S
authors.lastname: Thyagarajan
authors.forename: C D
authors.initials: CD
authors.lastname: Incarvito
authors.forename: A L
authors.initials: AL
authors.lastname: Rheingold
authors.forename: K H
authors.initials: KH
authors.lastname: Theopold