Ferrocene-modified bis(spiropyridopyran)s as synthetic signaling receptors for guanine-guanine dinucleoside derivatives.
A ferrocene-linked bis(spiropyridopyran) was designed and synthesized, that recognized guanine-guanine dinucleoside derivatives via complementary hydrogen bonds in CH2Cl2, resulting in the isomerization of the colorless spiropyridopyran as self-indicating receptors.
Takase
M
M
Department of Chemistry, Graduate School of Science, Kyoto University, Kyoto 606-8502, Japan.
Inouye
M
M
D003124:Colorimetry; D005296:Ferrous Compounds / Q000737:chemistry*; D006147:Guanine / Q000031:analogs & derivatives* / Q000737:chemistry*; D006860:Hydrogen Bonding; D009682:Magnetic Resonance Spectroscopy; D000075163:Metallocenes; D009705:Nucleosides / Q000737:chemistry*; D011714:Pyrans / Q000737:chemistry*; D013141:Spiro Compounds / Q000737:chemistry*
D005296:Ferrous Compounds; D000075163:Metallocenes; D009705:Nucleosides; D011714:Pyrans; D013141:Spiro Compounds; D006147:Guanine; C004998:ferrocene