title: Palladium-iminophosphine-catalysed carbostannylation of arynes: synthesis of ortho-substituted arylstannanes.
abstract: Arynes were found to insert into a carbon-tin bond of alkynyl- and vinylstannanes in the presence of a catalytic amount of a palladium-iminophosphine complex to afford ortho-substituted arylstannanes, which were convertible into a wide variety of 1,2-disubstituted arenes via carbon-carbon bond forming reactions.
authors.affiliation: Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto 606-8501, Japan.
authors.forename: H
authors.initials: H
authors.lastname: Yoshida
authors.forename: Y
authors.initials: Y
authors.lastname: Honda
authors.forename: E
authors.initials: E
authors.lastname: Shirakawa
authors.forename: T
authors.initials: T
authors.lastname: Hiyama