title: Possible impact of a primordial oil slick on atmospheric and chemical evolution.
abstract: Low molecular weight liquid hydrocarbons from various sources, could have formed an oil layer covering the primeval ocean (present already 4.0-4.4 x 10(9) yr ago), preventing water from evaporating into the atmosphere. Water from other sources, precipitated by cold traps at higher altitude in the atmosphere, becomes trapped in the ocean. In a thereby more dry and presumably reducing atmosphere (before 3.9 x 10(9) yr ago) even more hydrocarbons, as well as reactive molecules will form. An oil layer can possibly act as a dry solvent for reactions, where the reactive molecules can produce monomers and condensing agents. Monomers and eventual polymers formed could become strongly concentrated at the oil-water interface, favouring molecular interactions at high mobility and low dilution, without exposure to the destructive action of UV-light. Increased water leakiness of the oil layer due to accumulation of polar molecules within, would lead to photooxidation of liquid hydrocarbons, and subsequent emulsification at the oil-water interface, forming cellular structures. The atmosphere would then have lost its reducing character.
authors.affiliation: Department of Biotechnology, Center for Chemistry and Chemical Engineering, Lund University, Sweden. frans_peder.nilson@biotek.lu.se
authors.forename: Frans Peder R
authors.initials: FP
authors.lastname: Nilson
mesh_terms: D001272:Atmosphere; D005075:Biological Evolution; D006838:Hydrocarbons / Q000737:chemistry; D000069497:Origin of Life; D012997:Solvents / Q000737:chemistry
chemical_list: D006838:Hydrocarbons; D012997:Solvents