The first humulene type sesquiterpene from Lactarius hirtipes.
A new sesquiterpene of humulene type, named 2beta, alpha-epoxy-6Z, 9Z-humuladien-8alpha-ol (1) together with a known compound lactarinic acid was isolated from the fruiting bodies of Lactarius hirtipes. Their structures were established on the basis of spectral evidence (MS, IR, NMR, HMBC, HMQC, 1H-1H COSY, ROSEY experiments). Compound 1 was found as the first humulene-type sesquiterpene in higher fungi.
Lin
Hu
H
Kunming Institute of Botany, The Chinese Academy of Sciences, PR China.
Ji-Kai
Liu
L
D000363:Agaricales / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D008968:Molecular Conformation; D000081222:Monocyclic Sesquiterpenes; D012717:Sesquiterpenes / Q000737:chemistry* / Q000302:isolation & purification; D021241:Spectrometry, Mass, Electrospray Ionization
D000081222:Monocyclic Sesquiterpenes; D012717:Sesquiterpenes; C042686:humulene