Novel silver(I)-organic coordination polymers: conversion of extended structures in the solid state as driven by argentophilic interactions.
Structurally distinct coordination polymers [Ag(bpp)]ClO4 1 and [Ag(bpp)]PF6 2 [bpp = 1,3-bis(4-pyridyl)propane] have been assembled; the conversion of 1 into 2 on treatment with NaPF6 is driven by argentophilic interactions and is the first such transformation reported for silver(I)-organic coordination polymers.
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Department of Chemistry, Campus Box 194, University of Colorado at Denver, P.O. Box 173364, Denver, Colorado 80217-3364, USA.
Woodlock
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Wang
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Lam
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Rheingold
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