title: Intramolecular addition of acyl radicals to alpha-substituted vinylogous carbonates: demonstrating the effect of ring size on acyclic stereocontrol.
abstract: The level of stereocontrol obtained in the reduction of the free radical derived from the intramolecular addition of an acyl radical to an alpha-branched vinylogous carbonate is dependent upon the ring-size of the cyclic ether.
authors.affiliation: Department of Chemistry, Indiana University, Bloomington, IN 47405, USA. paevans@indiana.edu
authors.forename: P A
authors.initials: PA
authors.lastname: Evans
authors.forename: S
authors.initials: S
authors.lastname: Raina
authors.forename: K
authors.initials: K
authors.lastname: Ahsan
mesh_terms: D002254:Carbonates / Q000737:chemistry*; D004988:Ethers, Cyclic / Q000737:chemistry*; D013237:Stereoisomerism; D013696:Temperature; D014753:Vinyl Compounds / Q000737:chemistry*
chemical_list: D002254:Carbonates; D004988:Ethers, Cyclic; D014753:Vinyl Compounds