An extended chain structure formed by covalently linking polyoxovanadate cages with tetrahedral six rings.
The compound Cs10.5[(V16O40)(Si4.5V1.5O10)].3.5H2O is the first example of an extended structure in which a polyoxometallate anion is linked by an extended tetrahedral unit.
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Department of Chemistry, Materials Research Science and Engineering Center, University of Houston, Houston, TX 77204-5641, USA.
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Zhang
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Jacobson
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