Dimeric and monomeric forms of manganese N-confused porphyrin.
The synthesis and structural characterization of a manganese adduct of N-confused tetraphenylporphyrin (NCTPP) is presented; in the absence of coordinating ligands this complex forms a novel dimer structure and demonstrates a potential manganese agostic interaction with the interior pyrrolic CH as seen in other first row transition metal NCTPP compounds.
Harvey
John D
JD
Department of Chemistry, University of Akron, Akron, OH 44325-3601, USA.
Ziegler
Christopher J
CJ
D019281:Dimerization; D008665:Metalloporphyrins / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D015394:Molecular Structure; D013057:Spectrum Analysis
D008665:Metalloporphyrins; C041471:manganese tetraphenylporphyrin