title: Living polymers in a size-asymmetric electrolyte.
abstract: A living polymers transition is found in molecular dynamics simulations of a charge-symmetric size-asymmetric electrolyte with no anisotropic interactions. The fluid has strong polymeric character at low temperatures, where it consists of large, alternating-charge linear chains and rings in chemical equilibrium. A mean-field theory of chain association is consistent with the existence of such a transition. In the polymeric phase, the system is very weakly conducting or electrically insulating.
authors.affiliation: Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94550, USA. bastea2@llnl.gov
authors.forename: Sorin
authors.initials: S
authors.lastname: Bastea