title: Inhibition and acceleration of deuterium exchange in amide-functionalized monolayer-protected gold clusters.
abstract: Hydrogen/deuterium exchange rates in amide-functionalized monolayer protected gold clusters (MPCs) are controlled by the radial nature of the surface, with inhibition and catalysis observed at different chain lengths.
authors.affiliation: Department of Chemistry, University of Massachusetts, Amherst, MA 01003, USA.
authors.forename: Cheryl
authors.initials: C
authors.lastname: Briggs
authors.forename: Tyler B
authors.initials: TB
authors.lastname: Norsten
authors.forename: Vincent M
authors.initials: VM
authors.lastname: Rotello
mesh_terms: D000577:Amides / Q000737:chemistry*; D002384:Catalysis; D003102:Colloids / Q000737:chemistry; D003903:Deuterium / Q000737:chemistry*; D006046:Gold / Q000737:chemistry*; D006860:Hydrogen Bonding; D007700:Kinetics; D011522:Protons
chemical_list: D000577:Amides; D003102:Colloids; D011522:Protons; D006046:Gold; D003903:Deuterium