title: Palladium/Me(3)SiOTf-catalyzed bis-silylation of alpha,beta-unsaturated carbonyl compounds without involving oxidative addition of disilane.
abstract: In the presence of a catalytic amount of Me(3)SiOTf and palladium(0), the addition of disilane to alpha,beta-unsaturated carbonyl compounds proceeds under very mild conditions via eta(3)-siloxyallylpalladium generated by the reaction of enone, enal, or aromatic aldehyde with palladium and Me(3)SiOTf.
authors.affiliation: Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan.
authors.forename: Sensuke
authors.initials: S
authors.lastname: Ogoshi
authors.forename: Sadayuki
authors.initials: S
authors.lastname: Tomiyasu
authors.forename: Masaki
authors.initials: M
authors.lastname: Morita
authors.forename: Hideo
authors.initials: H
authors.lastname: Kurosawa