Different sites of insertion in the reaction of isocyanates with [Re(N(R)Ar)(CO)3(bipy)] (R = H or Me): N-H vs. Re-N.
The reactions of isocyanates with [Re(N(R)Ar)(CO)3(bipy)] complexes lead to R'NCO insertion into the Re-N bond (for R = Me) or the N-H bond (R = H).
Hevia
Eva
E
Departamento de Química Orgánica e Inorgánica/I. U. Q. O. E. M, Facultad de Química, Universidad de Oviedo/C. S. I. C, 33071 Oviedo, Spain.
Pérez
Julio
J
Riera
Víctor
V
Miguel
Daniel
D