Non-centrosymmetric packing of 1-D coordination networks based on chirality.
Using CoCl2 and a chiral tecton possessing C2 chirality and based on two coordination poles composed of a pyridine unit connected at the 4-position to a pyridine bearing at the 2 and 6 positions two optically active oxazoline moieties, a polar solid is obtained. The latter results from the acentric packing of directional 1-D coordination networks.
Jouaiti
Abdelaziz
A
Université Louis Pasteur, Laboratoire de Chimie de Coordination Organique, Institut Le Bel, 4, rue Blaise Pascal, F-67000 Strasbourg, France.
Hosseini
Mir Wais
MW
Kyritsakas
Nathalie
N