Intramolecular dealkylation of chelating diamines with Ru(II) complexes.
N,N, N',N'-Tetraethylethylenediamine undergoes simple or double intramolecular dealkylation reactions in the presence of the complexes [RuCl2(diene)]n (diene = cod, nbd) or trans-[RuCl2(diene)(morfoline)2 at 80 degrees C to afford chelating amine ligands which contains one or two N-H functionalities.
Morilla
M Esther
ME
Departamento de Química y Ciencia de los Materiales, Universidad de Huelva, Carretera de Palos de la Frontera s/n, E-21819 Huelva, Spain.
Morfes
Galanda
G
Nicasio
M Carmen
MC
Belderrain
Tomás R
TR
Mar Díaz-Requejo
M
M
Graiff
Claudia
C
Tiripicchio
Antonio
A
Sánchez-Delgado
Roberto
R
Pérez
Pedro J
PJ