sigma-donor, pi-donor, and anion competition in pi-complexation of alkali metal cations.
Removal of or replacement of one of two phenylethyl sidearms on azalariats leads to clear evidence for cation-pi interactions with the remaining sidearm.
Hu
Jiaxin
J
Division of Bioorganic Chemistry, Bioorganic Chemistry Program, Department of Molecular Biology & Pharmacology, Washington University School of Medicine, 660 South Euclid Ave., Campus Box 8103, St. Louis, MO 63110, USA.
Barbour
Leonard J
LJ
Gokel
George W
GW
D000838:Anions / Q000737:chemistry*; D002414:Cations, Monovalent / Q000737:chemistry*; D006860:Hydrogen Bonding; D008672:Metals, Alkali / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure
D000838:Anions; D002414:Cations, Monovalent; D008672:Metals, Alkali