Controlled monomer insertion into polymer main chain: synthesis of sequence ordered polystyrene containing thiourethane and trithiocarbonate units by the RAFT process.
A polymer having a trithiocarbonate moiety in the main chain was applied as a polymeric precursor to the synthesis of a sequence ordered polymer by insertion polymerization of styrene into the main chain by a RAFT mechanism.
Motokucho
Suguru
S
Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8503, Japan.
Sudo
Atsushi
A
Sanda
Fumio
F
Endo
Takeshi
T