Self-assembly luminescent heteroheptanuclear complexes with metal diphosphine and metal thiolate as components.
Self-assembly between the building blocks [M2(mu-dppm)2(MeCN)2]2+ (M = Cu or Ag; dppm = bis(diphenylphosphino)methane) and M'(aet)2 (aet = 2-aminoethanethiolate) afforded luminescent heterohepta-nuclear complexes [Cu4M'3(mu-dppm)3(mu 3-aet)4(mu-aet)2]4+ (M' = Ni 1; Pd 2) or heterotrinuclear complexes [Ag2M'(mu-dppm)2(mu-aet)2]2+ (M' = Ni 3, Pd 4).
Xu
Hong-Wu
HW
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 35002, China.
Chen
Zhong-Ning
ZN
Ishizaka
Shoji
S
Kitamura
Noboru
N
Wu
Ji-Gui
JG