Density matrix renormalization group studies of the effect of constraint release on the viscosity of polymer melts.
The scaling of the viscosity of polymer melts is investigated with regard to the molecular weight. We present a generalization of the Rubinstein-Duke model, which takes constraint releases into account and calculates the effects on the viscosity by the use of the density matrix renormalization group algorithm. Using input from Rouse theory, the rates for the constraint releases are determined in a self-consistent way. We conclude that shape fluctuations of the tube caused by constraint release are not a likely candidate for improving Doi's crossover theory for the scaling of the polymer viscosity.
Paessens
Matthias
M
Institut für Festkörperforschung, Forschungszentrum Jülich-52425 Jülich, Germany. m.paessens@fz-juelich.de
Schütz
Gunter M
GM