Efficient predetermination of chirality-at-zirconium.
Only one of eight possible diastereomers of the organometallic chiral-at-metal complex [ZrL2(CH2Ph)2] (L = a bidentate, chiral non-racemic pyrdine alcoholate) is observed by NMR spectroscopy in the slow exchange regime.
Munslow
Ian J
IJ
Department of Chemistry, University of Warwick, Coventry, UK CV4 7AL.
Clarke
Adam J
AJ
Deeth
Robert J
RJ
Westmoreland
Ian
I
Scott
Peter
P