Calcium cation complexation by lariat ether receptors having arene-terminated sidearms.
The first reported calcium azalariat complex has an arene terminated sidearm that behaves differently from an otherwise identical indole-sidearmed complex; twin phenolic sidearms on a diaza-18-crown-6 lead to an infinite, H-bonded network.
Hu
Jiaxin
J
Division of Bioorganic Chemistry, Bioorganic Chemistry Program, Department of Molecular Biology & Pharmacology, Washington University School of Medicine, 660 South Euclid Ave., Campus Box 8103, St. Louis, MO 63110, USA.
Barbour
Leonard J
LJ
Ferdani
Riccardo
R
Gokel
George W
GW
D002118:Calcium / Q000737:chemistry*; D002413:Cations, Divalent / Q000737:chemistry*; D004987:Ethers / Q000737:chemistry*; D006860:Hydrogen Bonding; D008958:Models, Molecular; D008968:Molecular Conformation; D015394:Molecular Structure; D010636:Phenols / Q000737:chemistry
D002413:Cations, Divalent; D004987:Ethers; D010636:Phenols; D002118:Calcium