Electrochemical platinum coatings for improving performance of implantable microelectrode arrays.
The formation and properties of electrochemical platinum films grown on platinum contacts contained in implantable flexible microelectrodes were investigated. The resulting platinum deposits were obtained by applying cyclic voltammetry to baths containing concentrations around 70 mM of chloroplatinic acid. A pre-activation step was necessary before the platinum-electroplating step in order to achieve good adhesive properties. The benefits of this process were ascribed to higher corrosion resistance, lower impedance and improved adhesion to the sputtered platinum. These improvements can make the application of this electrochemical technique highly useful for increasing the lifetime of implantable microelectrode arrays, such as cuff structures (IEEE Trans. Biomed. Eng. 40 (1993) 640). These medical devices, obtained by semiconductor technology could be used for selective stimulation of nerve fascicles, although, poor long-term performance has been achieved with them. The dissolution rate for platinum thin-film microelectrodes under fixed corrosion test conditions was 38.8 ng/C. Lower rates were observed for electroplated microelectrodes, obtaining a dissolution rate of 7.8 ng/C under analogous experimental ageing conditions. The corrosion behaviour of the electroplated platinum during stimulation experimental conditions was estimated by electrochemical impedance spectroscopy.
D001672:Biocompatible Materials; D017097:Electric Impedance; D004563:Electrochemistry / Q000379:methods; D004566:Electrodes; D008839:Microelectrodes; D018625:Microscopy, Atomic Force; D008855:Microscopy, Electron, Scanning; D010984:Platinum / Q000494:pharmacology*; D017671:Platinum Compounds / Q000494:pharmacology; D013696:Temperature; D013997:Time Factors
D001672:Biocompatible Materials; D017671:Platinum Compounds; C002999:chloroplatinic acid; D010984:Platinum