One-pot synthesis of 1-exo-alkylidene-2,3-anhydro furanoses: convenient precursors for exo-glycals and functionalized C-glycals.
1-exo-Methylene-2,3-anhydro furanoses, obtained from C-glycals in a one-pot, three step operation can be readily transformed into functionalized C-glycals by palladium-catalyzed nucleophilic addition.
D002241:Carbohydrates / Q000138:chemical synthesis*; D005663:Furans / Q000138:chemical synthesis*; D006027:Glycosides / Q000138:chemical synthesis
D002241:Carbohydrates; D005663:Furans; D006027:Glycosides