Lipase-catalyzed kinetic resolution of (+/-)-cis-flavan-4-ol and its acetate: synthesis of chiral 3-hydroxyflavanones.
Lipase-catalyzed kinetic resolution of (+/-)-cis-flavan-4-ol and its acetate led to enantiomerically enriched flavan-4-ol and its acetate. These chiral compounds were converted to (2R, 3R)- and (25, 3S)-3-hydroxyflavanones.
D000085:Acetates / Q000138:chemical synthesis / Q000302:isolation & purification; D000438:Alcohols / Q000737:chemistry; D002384:Catalysis; D004951:Esterification; D005419:Flavonoids / Q000138:chemical synthesis* / Q000302:isolation & purification; D006868:Hydrolysis; D007700:Kinetics; D008049:Lipase / Q000737:chemistry*; D013237:Stereoisomerism
D000085:Acetates; D000438:Alcohols; D005419:Flavonoids; D008049:Lipase