A general method for convergent synthesis of functionalized exo-glycals based on halogenation and Suzuki cross-coupling of 1-exo-methylene sugars.
Functionalized exo-glycals can be readily obtained by palladium catalyzed Suzuki cross-coupling of halo-exo-glycals with boronic acids.
D002241:Carbohydrates / Q000138:chemical synthesis*; D006027:Glycosides / Q000737:chemistry; D006842:Hydrocarbons, Brominated / Q000138:chemical synthesis*; D013237:Stereoisomerism
D002241:Carbohydrates; D006027:Glycosides; D006842:Hydrocarbons, Brominated