The first organically templated thorium compounds, [C4N2H12]0.5[ThF5] and [C5N2H14][ThF6].0.5H2O.
Organically templated thorium compounds were synthesized for the first time under hydrothermal conditions; the piperazine containing compound consists of 2-D layers, while the 2-methylpiperazine phase contains unprecedented 1-D chains of face-sharing ThF9 polyhedra.
Kim
Jong-Young
JY
Inorganic Chemistry Laboratory, South Parks Road, University of Oxford, Oxford, UK 0X1 3QR.
Norquist
Alexander J
AJ
O'Hare
Dermot
D