C-phosphanyl-C-chloroiminium salts as electrophilic carbene synthetic equivalents.
C-Phosphanyl-C-chloroiminium salts formally react as phosphonio(amino)carbenes with tert-butyl isocyanide and trimethylphosphine, and as R2NC+ with vinyl ether and diisopropylamine.
Merceron
Nathalie
N
Laboratoire Hétérochimie Fondamentale et Appliquée du CNRS (UMR 5069), Université Paul Sabatier, 118, route de Narbonne, 31062 Toulouse, France.
Baceiredo
Antoine
A
Gornitzka
Heinz
H
Bertrand
Guy
G