First determination of the absolute stereochemistry of a naturally occurring 1,1'-biphenanthrene, (--)-blestriarene C, and its unexpected photoracemization.
A naturally occurring 1,1'-biphenanthrene, blestriarene C, was prepared and its absolute stereochemistry was determined to be Sa-(-) by an empirical method, during which the compound was found to undergo rapid photoracemization even under ambient light exposure.
Hattori
Tetsutaro
T
Department of Biomolecular Engineering, Graduate School of Engineering, Tohoku University, Aramaki-Aoba 07, Aoba-ku, Sendai 980-8579, Japan. hattori@orgsynth.che.tohoku.ac.jp
Shimazumi
Yuhi
Y
Yamabe
Osamu
O
Koshiishi
Eiji
E
Miyano
Sotaro
S
D002851:Chromatography, High Pressure Liquid; D010616:Phenanthrenes / Q000737:chemistry*; D010777:Photochemistry; D013056:Spectrophotometry, Ultraviolet; D013237:Stereoisomerism; D013267:Stilbenes
C468327:1,1'-biphenanthrene; D010616:Phenanthrenes; D013267:Stilbenes; C468328:blestriarene C