C-Cl/Si-H exchange catalysed by P,N-chelated Pt(II) complexes.
Alkyl chlorides R-Cl are dehalogenated by HSiMe2Ph in the presence of catalytic amounts of the complex [(kappa 2-P,N)-Ph2PCH2CH2NMe2]PtMeCl to give R-H and ClSiMe2Ph.
Stöhr
Frank
F
Institute of Materials Chemistry, Vienna University of Technology, Getreidemarkt 9/165, A-1060, Wien, Austria.
Sturmayr
Dietmar
D
Schubert
Ulrich
U