A trigonal-bipyramidal ferric aqua complex with a sterically hindered salen ligand as a model for the active site of protocatechuate 3,4-dioxygenase.
Fujii
Hiroshi
H
Institute for Molecular Science and Center for Integrative Bioscience Okazaki National Research Institutes Myodaiji, Okazaki 444-8585, Japan. hiro@ims.ac.jp
Funahashi
Yasuhiro
Y
D001665:Binding Sites; D049308:Dioxygenases; D006571:Heterocyclic Compounds / Q000737:chemistry*; D007501:Iron / Q000378:metabolism; D008024:Ligands; D008956:Models, Chemical; D008958:Models, Molecular; D015394:Molecular Structure; D010105:Oxygenases / Q000737:chemistry* / Q000378:metabolism; D013054:Spectrophotometry, Atomic
D006571:Heterocyclic Compounds; D008024:Ligands; D007501:Iron; D010105:Oxygenases; D049308:Dioxygenases; C067216:protocatechuate 2,3-dioxygenase