Hybrid coordination polymer constructed from beta-octamolybdates linked by quinoxaline and its oxidized product benzimidazole coordinated to binuclear copper(I) fragments.
The one-dimensional polymer, [Cu(2)(C(8)H(6)N(2))(2)(C(7)H(6)N(2))](2)[Mo(8)O(26)] (1), which consists of beta-[Mo(8)O(26)](4)(-) anions linked by quinoxaline and its oxidized product benzimidazole ligands coordinated to binuclear copper(I) fragments, provides the first demonstration that the isolated copper(I) complex under hydrothermal conditions "captures" the reduction product of original starting organonitrogen ligand to form a copper(I)-beta-octamolybdate complex.
Wu
Chuan-De
CD
The State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian 350002, P.R. China.
Lu
Can-Zhong
CZ
Zhuang
Hong-Hui
HH
Huang
Jin-Shun
JS