Total synthesis of both enantiomers of dictyochromenol and their (Z)-isomers.
Total syntheses of both enantiomers of dictyochromenol (1) and its (Z)-stereoisomer (2) were achieved with high enantiomeric purity. The results of this study reveal the relationship between the optical rotation of the resolved 1 enantiomers.
Aoki
Kota
K
Faculty of Agriculture and Life Science, Hirosaki University, Japan.
Takahashi
Mihoko
M
Hashimoto
Masaru
M
Okuno
Toshikatsu
T
Kurata
Kazuya
K
Suzuki
Minoru
M
D001578:Benzopyrans / Q000138:chemical synthesis* / Q000737:chemistry*; D006574:Heterocyclic Compounds, 2-Ring / Q000138:chemical synthesis* / Q000737:chemistry*; D015394:Molecular Structure; D009904:Optical Rotation; D013237:Stereoisomerism
D001578:Benzopyrans; D006574:Heterocyclic Compounds, 2-Ring; C474815:dictyochromenol