Peculiar magnetic behavior in ion-pair complex [1-(4'-fluorobenzyl)pyridinium][Ni(mnt)2] (mnt2- = maleonitriledithiolate).
An ion-pair complex [FBzPy][Ni(mnt)2], where [FBzPy]+ = 1-(4'-fluorobenzyl)pyridinium and mnt2- = maleonitriledithiolate, forms a discrete stacking column and shows a peculiar magnetic transition from paramagnetic to diamagnetic around 90 K.
Xie
Jingli
J
State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, 210093, Nanjing, P.R. China. njujlxie@yahoo.com
Ren
Xiaoming
X
Song
You
Y
Zhang
Wenwei
W
Liu
Wenlong
W
He
Cheng
C
Meng
Qingjin
Q