title: A novel organic intercalation system with layered polymer crystals as the host compounds derived from 1,3-diene carboxylic acids.
abstract: A new type of organic intercalation system using poly(muconic acid) and poly(sorbic acid) crystals as the host compounds is described. The layered polymer crystals as the host are derived from benzyl-, dodecyl-, or naphthylmethylammonium salts of (Z,Z)-muconic or (E,E)-sorbic acids by topochemical polymerization. The subsequent solid-state hydrolysis of the resulting ammonium polymer crystals provides the corresponding carboxylic acid polymer crystals. When alkylamines are reacted with poly(muconic acid) or poly(sorbic acid) crystals dispersed in methanol at room temperature for a few hours, the intercalation proceeds to give layered ammonium polymer crystals via solid-state reactions, in which the polymers maintain a layered structure throughout. The interplanar spacing value of the polymer crystals changes according to the size of the guest molecules; that is, it exactly depends on the carbon number of the alkylamines used for each reaction of poly(muconic acid) or poly(sorbic acid) crystals. The stacking structure of alkyl chains with a tilt in the intercalated alkylammonium layers exists irrespective of the chemical and crystal structures of the host polymers. The intercalation of higher alkylamines into poly(muconic acid) crystals proceeds fast and quantitatively, while the conversion is dependent on the reaction conditions such as the structure and amount of the amine and the reaction time during the intercalation with poly(sorbic acid) crystals, due to the difference in the repeating layered structures of these polymer crystals. Some functional amines are also used as the guest molecules for this organic intercalation system.
authors.affiliation: Department of Applied Chemistry, Graduate School of Engineering, Osaka City University, and PRESTO, Japan Science and Technology Corporation (JST), Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan. matsumoto@a-chem.eng.osaka-cu.ac.jp
authors.forename: Akikazu
authors.initials: A
authors.lastname: Matsumoto
authors.forename: Shinya
authors.initials: S
authors.lastname: Oshita
authors.forename: Daisuke
authors.initials: D
authors.lastname: Fujioka