"ortho-Wurster's crowns": synthesis and properties of a novel phenylenediamine-based redox-active macrocyclic ligand.
A hybrid, macrocyclic structure based on o-phenylenediamine and a crown ether promotes an intimate mutual interaction with a bound potassium ion in the form of chelation by the redox-active moiety. A general synthetic method and properties are described for the first member of a new class of redox-active, lariat-type macrocycles called the "o-Wurster's crowns".
Sibert
John W
JW
Department of Chemistry, The University of Texas at Dallas, P.O. Box 830688, Richardson, Texas 75083-0688, USA. sibertj@utdallas.edu.
Forshee
Philip B
PB