Thioepoxide formation by ring closure of allylthiyl radicals--a novel rearrangement of allylic thionitrites.
Tertiary allylic thionitrites undergo thermal rearrangement to alpha,beta-episulfide nitroso dimers via ring closure of allylthiyl radicals.
Cavero
Marta
M
University College London, Christopher Ingold Laboratories, 20 Gordon Street, London, UK WC1H 0AJ.
Motherwell
William B
WB
Potier
Pierre
P
Weibel
Jean-Marc
JM