Decarboxylation and alkaline colour fading reactions in presence of humic substances.
Humic substances (HSs) can substantially influence velocity of reactions in the environment as shown on example of decarboxylation and alkaline colour (e.g., malachite green and crystal violet) fading reactions. In colour fading and decarboxylation reactions of 6-nitrobenzisoxazole-3-carboxylic acid HS act as inhibitors, but additions of surfactants change the pattern of reaction. The inhibitory activity of HSs much depends on their origin. The velocity of studied reactions depends also on pH, temperature and concentration of HS used. Possible micellar catalysis mechanism has been suggested.
Klavins
Maris
M
Department of Environmental Science, University of Latvia, Riga. mklavins@lanet.lv
Babre
Kristine
K
D002264:Carboxylic Acids / Q000737:chemistry; D002384:Catalysis; D003116:Color; D003653:Decarboxylation; D005840:Gentian Violet / Q000737:chemistry; D006812:Humic Substances / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D006878:Hydroxides / Q000737:chemistry; D007700:Kinetics; D008823:Micelles; D008958:Models, Molecular; D012394:Rosaniline Dyes / Q000737:chemistry; D013501:Surface-Active Agents / Q000737:chemistry; D013696:Temperature
D002264:Carboxylic Acids; D006812:Humic Substances; D006878:Hydroxides; D008823:Micelles; D012394:Rosaniline Dyes; D013501:Surface-Active Agents; C005095:malachite green; C031356:hydroxide ion; D005840:Gentian Violet