Enantioselective stereoinversion in the kinetic resolution of rac-sec-alkyl sulfate esters by hydrolysis with an alkylsulfatase from Rhodococcus ruber DSM 44541 furnishes homochiral products.
Pogorevc
Mateja
M
Department of Organic and Bioorganic Chemistry, University of Graz, Heinrichstrasse 28, 8010 Graz, Austria.
Kroutil
Wolfgang
W
Wallner
Sabine R
SR
Faber
Kurt
K
D004952:Esters / Q000737:chemistry* / Q000378:metabolism*; D006868:Hydrolysis; D007700:Kinetics; D008968:Molecular Conformation; D012240:Rhodococcus / Q000201:enzymology*; D013237:Stereoisomerism; D013429:Sulfatases / Q000378:metabolism*; D013431:Sulfates / Q000737:chemistry* / Q000378:metabolism*
D004952:Esters; D013431:Sulfates; D013429:Sulfatases; C019244:alkylsulfatase