The first 3-D ferrimagnetic nickel fumarate with an open framework: [Ni3(OH)2(O2C-C2H2-CO2)(H2O)4].2H2O.
A three-dimensional nickel fumarate has been isolated by hydrothermal reaction and its structure solved from powder X-ray diffraction; its organisation reveals an unusual topology not previously seen in nickel chemistry and provided a scarce ferrimagnetic behaviour below 20 K.
Guillou
Nathalie
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Institut Lavoisier, UMR CNRS 8637, Université de Versailles Saint-Quentin-en-Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles, France.
Pastre
Sybille
S
Livage
Carine
C
Férey
Gérard
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