Cascade reaction of imines with phenylsulfinylallene. X-ray structure of the product and its formation mechanism.
The structure of the product derived from the reaction of a dihydropyridine derivative with phenylsulfinylallene has been clarified by a single crystal X-ray analysis and the formation mechanism is discussed on the basis of the reaction-path calculations by semiempirical and ab initio molecular orbital methods.
Oiso
Shigeru
S
Faculty of Pharmaceutical Sciences, Kumamoto University, Japan.
Yoshitake
Yasuyuki
Y
Eto
Masashi
M
Harano
Kazunobu
K
D018360:Crystallography, X-Ray / Q000379:methods; D007097:Imines / Q000737:chemistry* / Q000378:metabolism; D015394:Molecular Structure; D013463:Sulfuric Acid Esters / Q000737:chemistry* / Q000378:metabolism
D007097:Imines; D013463:Sulfuric Acid Esters; C025208:phenylsulfate