NMR studies of molybdate complexes of D-erythro-L-manno-octose and D-erythro-L-gluco-octose and their alditols.
Different amounts and various types of bis-dinuclear tetradentate molybdate complexes of D-erythro-L-manno-octose, D-erythro-L-gluco-octose, D-erythro-L-manno-octitol and D-erythro-L-gluco-octitol were characterized by 1H and 13C NMR spectroscopy in aqueous solutions. Detailed analysis of 1H-(1)H coupling constants and NOEs, together with chemical shifts, allowed characterization of the different isomers of these complexes.
Matulová
Mária
M
Institute of Chemistry, Slovak Academy of Sciences, SK-842 38, Bratislava, Slovakia. matulova@chisgl.univ-bpclermont.fr
Hricovíniová
Zuzana
Z
D005947:Glucose / Q000031:analogs & derivatives*; D009682:Magnetic Resonance Spectroscopy; D008358:Mannose / Q000031:analogs & derivatives*; D008958:Models, Molecular; D008982:Molybdenum / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D013237:Stereoisomerism; D013402:Sugar Alcohols / Q000737:chemistry*
D009942:Organometallic Compounds; D013402:Sugar Alcohols; C044659:molybdate; D008982:Molybdenum; D005947:Glucose; D008358:Mannose