Chiral discrimination of 2,3-butanediols by laser spectroscopy.
The resonance enhanced two-photon ionization time-of-flight (R2PI-TOF) excitation spectra of supersonically expanded complexes of isomeric 2,3-butanediols with a suitable chromophore, i.e. R-(+)-1-phenyl-1-propanol, represent powerful means for structurally discriminating the diol moiety and for investigating the nature of the intra- and intermolecular interactions involved in the complexes.
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Dipartimento di Studi di Chimica e Tecnologia delle Sostanze Biologicamente Attive, Università di Roma La Sapienza, pl. A. Moro 5, I-00185 Roma, Italy.
Paladini
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Piccirillo
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Satta
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Catone
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Giardini
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Filippi
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Speranza
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