Synthesis, spectroscopy and metallation of mixed carbaporphyrinoid systems.
Modified tripyrranes incorporating furan and thiophene rings were found to condense with benzene, pyridine and indene dialdehydes to give a series of novel porphyrin analogues, including thia- and oxa-carbaporphyrins; the latter readily forms nickel(II) and palladium(II) organometallic complexes.
Liu
Dachun
D
Department of Chemistry, Illinois State University, Normal, Illinois 61790-4160, USA.
Lash
Timothy D
TD