Oxidative cleavage of the C-C bond of 3,6-dialkylcyclohexane-1,2-diones by cell suspension cultures of Marchantia polymorpha.
Biotransformation of 3,6-dialkylcyclohexane-1,2-diones by cell suspension cultures of Marchantia polymorpha involves regioselective oxidative cleavage of the C-C bond to give the corresponding oxocarboxylic acids shortened by one carbon unit. In the case of cyclohexane-1,2-dione, adipic acid was obtained.
Matsuura
Yoshitomo
Y
Department of Chemistry, Rikkyo (St. Paul's) University, Nishi-Ikebukuro, Toshima-Ku, Tokyo 171-8501, Japan.
Chai
Wen
W
Endoh
Etsuko
E
Suhara
Jyumpei
J
Hamada
Hiroki
H
Horiuchi
C Akira
CA
D002478:Cells, Cultured; D003510:Cyclohexanes / Q000737:chemistry / Q000378:metabolism*; D035926:Hepatophyta / Q000166:cytology / Q000378:metabolism*; D009682:Magnetic Resonance Spectroscopy; D010084:Oxidation-Reduction; D021241:Spectrometry, Mass, Electrospray Ionization; D017550:Spectroscopy, Fourier Transform Infrared
D003510:Cyclohexanes