title: Modeling of single-step and multistep adsorption isotherms of organic pesticides on soil.
abstract: The aim of this study was to investigate the sorption behavior and mechanisms of the organic pesticides on soil. To establish the sorption isotherms of six commonly used pesticides (acetochlor, atrazine, diazinon, carbendazim, imidacloprid, and isoproturon), laboratory equilibrium studies were performed at extended concentration ranges on brown forest soil using the batch equilibrium technique. The pesticide concentrations in the equilibrated liquid phase were quantified with high-performance liquid chromatograph by ultraviolet detection. The adsorption processes could be described by a single-step (Langmuir) isotherm for acetochlor and carbendazim, by a two-step curve for diazinon, isoproturon, and atrazine, and by a three-step curve for imidacloprid. A nonlinear mathematical model-derived from the Langmuir equation-has been developed that represents well the detected single-step and multistep shaped adsorption isotherms. The interpreted model was found to fit the experimental data well and allows the description of the adsorption profile with great precision. The altered adsorption activity, which was indicated by the step arising on the plot, may represent the existence/occurrence of a different specific type of adsorption mechanism. This binding force starts to operate simultaneously at a critical concentration of solute in the studied soil-pesticide system. The parameters calculated from the equation provide an opportunity to estimate the extent of absorption constant, adsorption capacity, and concentration limit characteristic to the measured stepwise isotherms.
authors.affiliation: Institute for Veterinary Medicinal Products, 8 Szállás Street, H-1107 Budapest, Hungary. livia@oai.hu
authors.forename: Lívia N
authors.initials: LN
authors.lastname: Konda
authors.forename: Imre
authors.initials: I
authors.lastname: Czinkota
authors.forename: György
authors.initials: G
authors.lastname: Füleky
authors.forename: György
authors.initials: G
authors.lastname: Morovján
mesh_terms: D000327:Adsorption; D001280:Atrazine / Q000032:analysis / Q000737:chemistry; D001562:Benzimidazoles / Q000032:analysis / Q000737:chemistry; D002219:Carbamates; D002851:Chromatography, High Pressure Liquid; D003976:Diazinon / Q000032:analysis / Q000737:chemistry; D007093:Imidazoles / Q000032:analysis / Q000737:chemistry; D008433:Mathematics; D008782:Methylurea Compounds / Q000737:chemistry; D008956:Models, Chemical; D000073943:Neonicotinoids; D009574:Nitro Compounds; D010575:Pesticides / Q000032:analysis / Q000737:chemistry*; D010671:Phenylurea Compounds; D012987:Soil / Q000032:analysis*; D013696:Temperature; D014052:Toluidines / Q000032:analysis / Q000737:chemistry; D014197:Trees
chemical_list: D001562:Benzimidazoles; D002219:Carbamates; D007093:Imidazoles; D008782:Methylurea Compounds; D000073943:Neonicotinoids; D009574:Nitro Compounds; D010575:Pesticides; D010671:Phenylurea Compounds; D012987:Soil; D014052:Toluidines; C082359:imidacloprid; C028904:isoproturon; C043377:acetochlor; C006698:carbendazim; D001280:Atrazine; D003976:Diazinon