Stereoselective intermolecular carboazidation of chiral allylsilanes.
[reaction: see text] Easily available chiral allylsilanes were used as substrate for carboazidation reactions. For the first time, a substantial control of the stereochemistry of the azidation of acyclic nonconjugated radicals was achieved.
Chabaud
Laurent
L
Université de Bordeaux 1, Laboratoire de Chimie Organique et Organométallique, 351, Cours de la Libération, F-33405 Talence Cedex, France.
Landais
Yannick
Y
Renaud
Philippe
P