[Development of highly selective reactions based on metal carbonyls and its application to synthesis of bioactive compounds].
Alkynes react with commercially available Co2 (CO)8 to give the corresponding alkyne-Co2 (CO)6 complexes. Similarly, treatment of arenes with Cr(CO)6 produces arene-Cr (CO)3 complexes. By taking advantage of the intriguing properties of these metal carbonyl complexes, we developed some selective reactions. In this review, the following topics are discussed: (i) development of selective reactions based on alkyne-Co2 (CO)6 complexes; (ii) development of selective reactions based on arene-Cr (CO)3 complexes; and (iii) their application to syntheses of bioactive compounds.
Mukai
Chisato
C
Faculty of Pharmaceutical Sciences, Kanazawa University, 13-1 Takara-machi, Kanazawa 920-0934, Japan.
D000480:Alkynes; D001643:Bridged Bicyclo Compounds / Q000138:chemical synthesis*; D017554:Carbon Compounds, Inorganic / Q000737:chemistry*; D002625:Chemistry, Organic; D055601:Organic Chemistry Phenomena; D013237:Stereoisomerism
D000480:Alkynes; D001643:Bridged Bicyclo Compounds; D017554:Carbon Compounds, Inorganic