Photo-and-thiol-driven trans insertion of phenylacetylene into H-Pt bonds.
The photo-and-thiol-driven trans insertion of phenylacetylene into H-Pt bonds of Pt(X)(H)(PPh3)2 (X = SAr, Cl, Br, and I) took place to afford Pt[(Z)-C(H)=CH(Ph)](X)(PPh3)2 in good yields.
Ohtaka
Atsushi
A
Department of Molecular Chemistry and Frontier Research Center, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan.
Kuniyasu
Hitoshi
H
Kinomoto
Masanori
M
Kurosawa
Hideo
H