Morphological changes during the order-disorder transition in the two- and three-dimensional systems of scalar nonconserved order parameters.
The order-disorder transition is studied in a system of a scalar nonconserved order parameter. We use this well studied system to show that the application of the methods of topology and geometry reveals that our knowledge of the kinetic pathways by which the order-disorder transition proceeds is far from being complete. We show that in two-dimensional (2D) and 3D systems there are three dynamical regimes in the evolution of the system: early, intermediate, and late. In the intermediate regime two length scales govern the behavior of the system, whereas in the early and intermediate regime there is only one length scale. The size distribution of the domain area indicates the pathway by which the domains change their size. There are only two types of domains in a 2D system: circular and elongated with well defined characteristics (scaling of the area with the contour length) which in the late regime do not depend on time after rescaling by the average area and contour in the system. The elongated domains continuously change into circular domains reducing in this way the overall dissipation in the system. In order to reach a Lifshitz-Cahn-Allen (LCA) late stage regime the number of elongated domains must be strongly reduced. In the intermediate regime the number of elongated domains is large and simple LCA scaling does not hold. In a 3D symmetric system we always have a bicontinuous structure that evolves by cutting small connections. The late stage regime seems to be associated with the appearance of the preferred nonzero mean curvature. The early-intermediate regime crossover is associated with the saturation of the order parameter inside the domains, while the intermediate-late stage regime crossover is related to the global breaking of the +/- order parameter symmetry (marked by the appearance of the nonzero mean curvature but still zero average magnetization). The times for the occurrence of these crossovers do not depend on the size of the system.
Fiałkowski
Marcin
M
Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland.
Hołyst
Robert
R