title: Access to aldehydo acetals of sugars via palladium-catalyzed oxidation of alpha,beta-unsaturated cyclic acetals.
abstract: The palladium(II)-catalyzed oxidation of alpha,beta-unsaturated cyclic acetals derived from mono- and disaccharides leads in appreciable yields to new aldehydo acetals which, overall, results in an anti-Markovnikov addition.
authors.affiliation: Laboratoire de Chimie des Hétérocycles et Glucides, EA 987, Ecole Nationale Supérieure de Chimie de Clermont-Ferrand, Ensemble Scientifique des Cézeaux, BP 187, F-63174 Aubière Cedex, France. cfayet@ensccf.univ-bpclermont.fr
authors.forename: Catherine
authors.initials: C
authors.lastname: Fayet
authors.forename: Jacques
authors.initials: J
authors.lastname: Gelas
authors.forename: Katerina
authors.initials: K
authors.lastname: Danková
authors.forename: Alexandre
authors.initials: A
authors.lastname: Yokaris
mesh_terms: D000080:Acetals / Q000737:chemistry*; D002241:Carbohydrates / Q000737:chemistry*; D002384:Catalysis; D004187:Disaccharides / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D009005:Monosaccharides / Q000737:chemistry; D010084:Oxidation-Reduction; D010165:Palladium
chemical_list: D000080:Acetals; D002241:Carbohydrates; D004187:Disaccharides; D009005:Monosaccharides; D010165:Palladium