title: Free radical-mediated vinyl amination: access to N,N-dialkyl enamines and their beta-stannyl and beta-thio derivatives.
abstract: [reaction: see text] The first examples of free radical-mediated vinyl amination are described by nonconventional vinyl radical addition to azomethine nitrogen. This new vinyl amination protocol is mild and provides convenient synthetic access to nonstabilized N,N-dialkyl enamines and tandem bond-forming processes.
authors.affiliation: Department of Chemistry, Indiana University, Bloomington, Indiana 47405-7102, USA.
authors.forename: Erode N
authors.initials: EN
authors.lastname: Prabhakaran
authors.forename: Benjamin M
authors.initials: BM
authors.lastname: Nugent
authors.forename: Amie L
authors.initials: AL
authors.lastname: Williams
authors.forename: Kristen E
authors.initials: KE
authors.lastname: Nailor
authors.forename: Jeffrey N
authors.initials: JN
authors.lastname: Johnston
mesh_terms: D000586:Amination; D005609:Free Radicals / Q000737:chemistry*; D006571:Heterocyclic Compounds / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure
chemical_list: D005609:Free Radicals; D006571:Heterocyclic Compounds