Direct carbamoylation of aryl halides.
[reaction: see text] A carbamoylsilane is shown to carry out the direct carbamoylation of aryl chlorides, bromides, and iodides under catalysis by phosphinepalladium(0) complexes.
Cunico
Robert F
RF
Department of Chemistry and Biochemistry, Northern Illinois University, DeKalb, Illinois 60115, USA. rfc@marilyn.chem.niu.edu
Maity
Bikash C
BC