Frustrated soft modes and negative thermal expansion in ZrW2O8.
Negative thermal expansion (NTE) in cubic ZrW2O8 has generated much interest due to its large, isotropic, and temperature independent behavior. Here, x-ray absorption fine structure data are presented for various atom pairs, providing evidence that the low-energy modes causing NTE correspond to the correlated vibrations of a WO4 tetrahedron and its three nearest ZrO6 octahedra. This involves translations of the WO4 as a rigid unit along each of the four <111> axes. The interconnectivity of these modes prevents an anisotropic soft mode from developing, a new geometrical phenomenon that we call the "frustrated soft mode."
Cao
D
D
Physics Department, University of California, Santa Cruz, California 95064, USA.
Bridges
F
F
Kowach
G R
GR
Ramirez
A P
AP