title: Stereospecific synthesis of highly substituted skipped dienes through multifunctional palladium catalysis.
abstract: [reaction: see text] Multifunctional palladium catalysis is utilized in the one-pot stereocontrolled synthesis of tetrasubstituted alkenes. The homogeneous palladium dihalide catalyst utilized for bromo-/chloroallylation of alkynes is then reused in situ for a subsequent Suzuki cross-coupling reaction.
authors.affiliation: Department of Chemistry, The University of Chicago, 5735 South Ellis Avenue, Chicago, Illinois 60637, USA.
authors.forename: Avinash N
authors.initials: AN
authors.lastname: Thadani
authors.forename: Viresh H
authors.initials: VH
authors.lastname: Rawal
mesh_terms: D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry*; D017605:Bromine Compounds / Q000737:chemistry; D002384:Catalysis; D017606:Chlorine Compounds / Q000737:chemistry; D008968:Molecular Conformation; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000475:Alkenes; D017605:Bromine Compounds; D017606:Chlorine Compounds; D010165:Palladium