Novel 1,4-palladium migration in organopalladium intermediates derived from o-iodobiaryls.
A novel 1,4-palladium migration in organopalladium intermediates derived from o-iodobiaryls has been observed under modified Heck reaction conditions. This migration process can be switched "on" or "off" by simply choosing the appropriate reaction conditions.
Campo
Marino A
MA
Department of Chemistry, Iowa State University, Ames, Iowa 50011, USA.
Larock
Richard C
RC