title: Catalytic asymmetric synthesis of optically active atropisomeric anilides through enantioselective N-allylation with chiral Pd-tol-BINAP catalyst.
abstract: Catalytic asymmetric N-allylation reaction of ortho-tert-butylanilide derivatives with diallyl carbonate proceeds in the presence of tol-BINAP-Pd catalyst to give chiral N-allyl ortho-tert-butylanilides of 32-44%ee in excellent chemical yields (> or = 90%).
authors.affiliation: Tokyo University of Pharmacy and Life Science, 1432-1 Horinouchi, Hachioji, Tokyo 192-0392, Japan.
authors.forename: Osamu
authors.initials: O
authors.lastname: Kitagawa
authors.forename: Mitsuteru
authors.initials: M
authors.lastname: Kohriyama
authors.forename: Takeo
authors.initials: T
authors.lastname: Taguchi