Free radical-mediated vinyl amination: access to N,N-dialkyl enamines and their beta-stannyl and beta-thio derivatives.
[reaction: see text] The first examples of free radical-mediated vinyl amination are described by nonconventional vinyl radical addition to azomethine nitrogen. This new vinyl amination protocol is mild and provides convenient synthetic access to nonstabilized N,N-dialkyl enamines and tandem bond-forming processes.
Prabhakaran
Erode N
EN
Department of Chemistry, Indiana University, Bloomington, Indiana 47405-7102, USA.
Nugent
Benjamin M
BM
Williams
Amie L
AL
Nailor
Kristen E
KE
Johnston
Jeffrey N
JN
D000586:Amination; D005609:Free Radicals / Q000737:chemistry*; D006571:Heterocyclic Compounds / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure
D005609:Free Radicals; D006571:Heterocyclic Compounds