A comparison between the sonochemical and thermal reaction of 5H,5Cl-dibenz[a,d]cycloheptatriene with nitrobenzene.
The reaction of 5H,5Cl-dibenzo[a,d]cycloheptatriene with nitrobenzene was investigated under both thermal (210 degrees C) and ultrasonic (50 degrees C, 40 kHz) activation. The reaction products of both procedures are similar, but their amounts depend on the activation source. To account for the products a common electron transfer reaction is postulated through the dibenzotropylium cation. The differences between the thermal and ultrasonic process is thought to arise from the role of nitrobenzene as oxidant. Under thermal conditions this occurs throughout the reaction mixture but under sonication it occurs only in the cavitation bubble and in its immediate vicinity.
Stavarache
Carmen
C
C.D. Nenitzescu, Institute of Organic Chemistry, Romanian Academy, C.P. 254, P.O. Box 15-254, 71141 Bucharest, Romania.
Pocsan
Ana Maria
AM
Vinatoru
Mircea
M
Mason
Timothy J
TJ