title: Radical-molecule complexes: changing our perspective on the molecular mechanisms of radical-molecule reactions and their impact on atmospheric chemistry.
abstract: The strong binding energies for radical-molecule complexes allow these unique systems to influence both the photochemical and reaction pathways for both chemical and atmospherically important reactions. This Minireview summarizes the work that has been presented in the literature and also introduces new radical-molecule complexes that may play important roles in new chemistry.
authors.affiliation: Departments of Chemistry and Earth and Atmospheric Sciences, Purdue University, West Lafayette, IN 47907-1393, USA.
authors.forename: Jaron C
authors.initials: JC
authors.lastname: Hansen
authors.forename: Joseph S
authors.initials: JS
authors.lastname: Francisco
mesh_terms: D001272:Atmosphere; D055598:Chemical Phenomena; D002627:Chemistry, Physical; D005609:Free Radicals; D008958:Models, Molecular; D013997:Time Factors; D014867:Water / Q000737:chemistry*
chemical_list: D005609:Free Radicals; D014867:Water