title: Triangular and tetrahedral array of silver(I) ions by a novel disk-shaped tridentate ligand: dynamic control of coordination equilibrium of the silver(I) complexes.
abstract: A disk-shaped tridentate ligand 1 arranges silver(I) ions in a two-dimensional triangular and a three-dimensional tetrahedral fashion in the metal-ligand ratios, 3:2 and 1:1, respectively. The resulting sandwich-type (Ag312) and tetrahedral (Ag414) architectures are in a dynamic equilibrium in solution.
authors.affiliation: Department of Chemistry, Graduate School of Science, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
authors.forename: Shuichi
authors.initials: S
authors.lastname: Hiraoka
authors.forename: Tao
authors.initials: T
authors.lastname: Yi
authors.forename: Motoo
authors.initials: M
authors.lastname: Shiro
authors.forename: Mitsuhiko
authors.initials: M
authors.lastname: Shionoya