title: Total synthesis of sphingofungin F.
abstract: [reaction: see text] A concise, stereocontrolled synthesis of sphingofungin F was achieved. Key features involve diastereoselective oxazoline formation catalyzed by palladium(0), MgBr(2)-promoted gamma-alkoxy allylic stannane addition, and palladium(0)-catalyzed coupling of a vinyl iodide with an organozinc reagent.
authors.affiliation: College of Pharmacy, SungKyunKwan University, Suwon 440-746, Korea.
authors.forename: Kee-Young
authors.initials: KY
authors.lastname: Lee
authors.forename: Chang-Young
authors.initials: CY
authors.lastname: Oh
authors.forename: Won-Hun
authors.initials: WH
authors.lastname: Ham
mesh_terms: D000596:Amino Acids / Q000138:chemical synthesis* / Q000737:chemistry*; D000935:Antifungal Agents / Q000138:chemical synthesis* / Q000737:chemistry*; D002384:Catalysis; D005231:Fatty Acids, Unsaturated / Q000138:chemical synthesis* / Q000737:chemistry*; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D000596:Amino Acids; D000935:Antifungal Agents; D005231:Fatty Acids, Unsaturated; C078944:sphingofungin F; D010165:Palladium