title: Molecular design of DABNTf as a highly efficient resolving reagent for racemic Pd complex with Tropos biphenylphosphine (BIPHEP) ligand: circular dichroism (CD) spectra of enantiopure BIPHEP-Pd complex.
abstract: The racemic Pd complexes with chirally flexible (tropos) biphenylphosphine (BIPHEP) ligands can be resolved but transformed into the enantio- and diastereo-pure complex. The enantiopure metal complex of BIPHEP ligand is thus obtained through enantiomer-selective complexation of a racemic BIPHEP-Pd complex with enantiopure 1,1'-binaphthyl-2,2'-di(triflyl)amide, DABNTf. The differential CD spectra of the enantiopure BIPHEP-Pd complex is also reported.
authors.affiliation: Department of Applied Chemistry, Tokyo Institute of Technology, Tokyo, Japan. kmikami@o.cc.titech.ac.jp
authors.forename: Koichi
authors.initials: K
authors.lastname: Mikami
authors.forename: Yukinori
authors.initials: Y
authors.lastname: Yusa
authors.forename: Kohsuke
authors.initials: K
authors.lastname: Aikawa
authors.forename: Manabu
authors.initials: M
authors.lastname: Hatano