title: Intermolecular rhodium(II)-catalyzed reactions with silicon-substituted carbonyl ylides.
abstract: [reaction: see text] The Rh(II)-catalyzed reaction of benzyl 2-trialkylsilyl-2-diazoacetates with various acyclic and cyclic ketones affords novel dioxolanones via silicon-substituted carbonyl ylides in up to 98% yield.
authors.affiliation: Institute of Organic Chemistry, RWTH Aachen, Professor-Pirlet-Strasse 1, D-52056 Aachen, Germany. carsten.bolm@oc.rwth-aachen.de
authors.forename: Carsten
authors.initials: C
authors.lastname: Bolm
authors.forename: Sandra
authors.initials: S
authors.lastname: Saladin
authors.forename: Andrey
authors.initials: A
authors.lastname: Kasyan