Polymorphism in Cs[AgZn(NCS)4].
The title compound, caesium silver zinc tetrathiocyanate, crystallizes in two polymorphic forms, in space groups P2(1)/n and C2/c. Both structures form a continuous three-dimensional network. The structure in C2/c contains a delocalized Ag atom in a binuclear-like anion, where two [Ag(NCS)(4)] units (delocalized Ag as an average) share two common NCS(-) ligands.
Güneş
Minna
M
Department of Chemistry, University of Jyväskylä, PO Box 35, FIN-40014 University of Jyväskylä, Finland. mmlaurik@cc.jyu.fi
Valkonen
Jussi
J