Uranium complexes supported by an aryloxide functionalised triazacyclononane macrocycle: synthesis and characterisation of a six-coordinate U(III) species and insights into its reactivity.
A reactive low-valent uranium(III) complex supported by an aryloxide functionalised triazacyclononane has been synthesised and provides a platform for enhanced uranium reactivity.
Castro-Rodriguez
Ingrid
I
University of California, San Diego, Department of Chemistry and Biochemistry, La Jolla, CA 92093, USA.
Olsen
Kristian
K
Gantzel
Peter
P
Meyer
Karsten
K
D001372:Aza Compounds / Q000737:chemistry; D004583:Electrons; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D017974:Uranium Compounds / Q000138:chemical synthesis* / Q000737:chemistry
D001372:Aza Compounds; D008024:Ligands; D017974:Uranium Compounds