Catalytic enantioselective allylation of ketones with novel chiral bis-titanium(IV) catalyst.
Our recently designed chiral bis-titanium(IV) catalyst can be successfully utilized for the catalytic enantioselective allylation of ketones with tetraallyltin. The high asymmetric induction is achievable in the case of aromatic ketones.
Kii
Satoshi
S
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto, Japan.
Maruoka
Keiji
K