Sorption of lambda-cyhalothrin, cypermethrin, deltamethrin and fenvalerate to quartz, corundum, kaolinite and montmorillonite.
Sorption to mineral surfaces may be important for retention and degradation of hydrophobic pesticides in subsoils and aquifers poor in organic matter. In this work the title pyrethroids have been used to investigate selective interactions with the surfaces of four minerals. Sorption of the four pyrethroids was quantified in batch experiments with initial pyrethroid concentrations of 1-100 microg/l. Sorption to centrifuge tubes used in the batch experiments accounted for 25-60% of total sorption. Net sorption was obtained from total sorption after subtracting the amounts of pyrethroids sorbed to centrifuge tubes used. All isotherms could be fitted by the Freundlich equation with n ranging between 0.9 and 1.1. Bonding affinities per unit surface area decreased in the order: corundum > quartz > montmorillonite approximately equal kaolinite. A similar sequence as found for the total surface tension of the minerals. All minerals showed the same selectivity order with respect to sorption affinity of the four pyrethroids: lambda-cyhalothrin > deltamethrin > cypermethrin > fenvalerate, which shows that the most hydrophobic compound is sorbed most strongly. Stereochemical properties of the four pyrethroid formulations may also contribute to the selectivity pattern.
Oudou
H Chaaieri
HC
Department of Chemistry, Royal Veterinary and Agricultural University, Thorvaldsensvej 40, 1871-DK Frederiksberg C, Denmark. h_oudou@hotmail.com
Hansen
H C Bruun
HC
D000327:Adsorption; D000537:Aluminum Oxide / Q000737:chemistry; D001546:Bentonite / Q000737:chemistry; D002849:Chromatography, Gas; D007306:Insecticides / Q000737:chemistry*; D007616:Kaolin / Q000737:chemistry; D008968:Molecular Conformation; D011722:Pyrethrins / Q000737:chemistry*; D011791:Quartz / Q000737:chemistry
D007306:Insecticides; D011722:Pyrethrins; D001546:Bentonite; D011791:Quartz; D007616:Kaolin; D000537:Aluminum Oxide