title: Hexaamminecobalt(III) aquabis(nitrilotriacetato-kappa4N,O,O',O")gadolinate(III) octahydrate.
abstract: Crystals of the title compound, [Co(NH(3))(6)][Gd(C(6)H(6)NO(6))(2)(H(2)O)].8H(2)O, were synthesized in and collected from aqueous solution. The hexaamminecobalt(III) cation has the expected octahedral geometry, while the Gd coordination sphere has the geometry of a tricapped trigonal prism, with the two nitrilotriacetate N atoms and one water molecule occupying the capping positions.
authors.affiliation: Department of Chemistry, Bucknell University, Lewisburg, PA 17837, USA.
authors.forename: Steven M
authors.initials: SM
authors.lastname: Baldwin
authors.forename: M E
authors.initials: ME
authors.lastname: Kastner
mesh_terms: D003460:Crystallization; D005682:Gadolinium / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*
chemical_list: D009942:Organometallic Compounds; C472317:hexaamminecobalt(III) aquabis(nitrilotriacetato-kappa4N,O,O',O'')gadolinate(III) octahydrat; D005682:Gadolinium