A dynamic (reversible) covalent polymer: radical crossover behaviour of TEMPO-containing poly(alkoxyamine ester)s.
A dynamic covalent polymer incorporating thermally alkoxyamine units in the main chain was synthesized. Due to a radical crossover reaction between the alkoxyamine units, an interchange of the main chains in poly(alkoxyamine ester) was observed on heating.
Otsuka
Hideyuki
H
Institute for Fundamental Research of Organic Chemistry, Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-858, Japan. otsuka@ms.ifoc.kyushu-u.ac.jp
Aotani
Koichiro
K
Higaki
Yuji
Y
Takahara
Atsushi
A