NMR characterisation of unstable solvent and dihydride complexes generated at low temperature by in-situ UV irradiation.
Low temperature in-situ UV irradiation of toluene solutions containing bis(alkene)rhodium complexes and parahydrogen in conjunction with NMR monitoring enables the characterisation of unstable eta 2-solvent complexes and dihydrogen activation products.
Godard
Cyril
C
Department of Chemistry, University of York, Heslington, York, UK YO10 5DD.
Callaghan
Philip
P
Cunningham
Jenny L
JL
Duckett
Simon B
SB
Lohman
Joost A B
JA
Perutz
Robin N
RN