title: The bridging bidentate perchlorato group in ReO3(ClO4), ReO3(ClO4Cl2O6 and Sb2Cl6(O)(OH)(ClO4), a vibrational analysis.
abstract: Raman and infrared analysis of the new compounds: ReO3(ClO4), an ivory-white solid, and (ClO2)xReO3(ClO4)1+x (x < or = 1), an orange-red chloryl salt, showed that bridging bidentate [ClO4] and terminal ReO3 groups are present in both complexes. Vibrational data on [ClO4] in ReO3(ClO4) were compared to those obtained experimentally and by DFT calculation on a bridging bidentate [ClO4] in Sb2Cl6(O)(OH)(ClO4).
authors.affiliation: Laboratoire des Agrégats Moléculaires et Matériaux Inorganiques, UMR CNRS 5072, Case Courrier 015, Université de Montpellier 2, Sciences et Techniques du Languedoc, 34095 Montpellier Cedex 5, France. fcunin@ucsd.edu
authors.forename: Frederique
authors.initials: F
authors.lastname: Cunin
authors.forename: Frédéric
authors.initials: F
authors.lastname: Favier
authors.forename: Jean Louis
authors.initials: JL
authors.lastname: Pascal
mesh_terms: D000965:Antimony / Q000737:chemistry*; D010472:Perchlorates / Q000138:chemical synthesis / Q000737:chemistry*; D012211:Rhenium / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D013059:Spectrum Analysis, Raman
chemical_list: D010472:Perchlorates; D012211:Rhenium; D000965:Antimony