The bridging bidentate perchlorato group in ReO3(ClO4), ReO3(ClO4Cl2O6 and Sb2Cl6(O)(OH)(ClO4), a vibrational analysis.
Raman and infrared analysis of the new compounds: ReO3(ClO4), an ivory-white solid, and (ClO2)xReO3(ClO4)1+x (x < or = 1), an orange-red chloryl salt, showed that bridging bidentate [ClO4] and terminal ReO3 groups are present in both complexes. Vibrational data on [ClO4] in ReO3(ClO4) were compared to those obtained experimentally and by DFT calculation on a bridging bidentate [ClO4] in Sb2Cl6(O)(OH)(ClO4).
Cunin
Frederique
F
Laboratoire des Agrégats Moléculaires et Matériaux Inorganiques, UMR CNRS 5072, Case Courrier 015, Université de Montpellier 2, Sciences et Techniques du Languedoc, 34095 Montpellier Cedex 5, France. fcunin@ucsd.edu
Favier
Frédéric
F
Pascal
Jean Louis
JL
D000965:Antimony / Q000737:chemistry*; D010472:Perchlorates / Q000138:chemical synthesis / Q000737:chemistry*; D012211:Rhenium / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D013059:Spectrum Analysis, Raman
D010472:Perchlorates; D012211:Rhenium; D000965:Antimony