Towards a molecular model for bismuth(III) subsalicylate. Synthesis and solid-state structure of [Bi(Hsal)3(bipy)(C7H8]2 and [Bi(Hsal)(sal)(1,10-phenanthroline)(C7H8]2.
The synthesis and characterization of the first bismuth salicylate complexes, stabilized by chelating amine ligands, offers the possibility for detailed investigation of molecular precursors of the biologically significant compound bismuth subsalicylate (BSS).
Thurston
John H
JH
Department of Chemistry, Rice University, 1600 Main St, MS-60, Houston, Texas 77005, USA.
Marlier
Elodie M
EM
Whitmire
Kenton H
KH
D000588:Amines / Q000737:chemistry; D001729:Bismuth / Q000737:chemistry; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010618:Phenanthrolines / Q000138:chemical synthesis*; D012459:Salicylates / Q000138:chemical synthesis* / Q000737:chemistry
D000588:Amines; D008024:Ligands; D009942:Organometallic Compounds; D010618:Phenanthrolines; D012459:Salicylates; C015715:bismuth subsalicylate; D001729:Bismuth