Alkyl isomerisation in three-coordinate iron(II) complexes.
The tertiary to iso-butyl isomerisation of three-coordinate iron(II) diketiminate complexes is reported and a hydride intermediate is proposed on the basis of exchange experiments.
Vela
Javier
J
Department of Chemistry, University of Rochester, Rochester, NY 14627, USA.
Smith
Jeremy M
JM
Lachicotte
Rene J
RJ
Holland
Patrick L
PL