Quantification of composition and domain sizes of industrial poly(phthalamide)/poly(dimethylsiloxane) block copolymers using different 1H solid state NMR methods.
We have applied several 1H solid state NMR techniques to obtain structural information on industrial silicone copolymers as thermoplastic elastomers that proved difficult to be analysed by conventional techniques. Static measurements were applied to achieve the separation between mobile and rigid parts. To get structural information fast magic angle spinning at 25 kHz in combination with a high field of 700 MHz was used. 1H spin diffusion was applied to determine the domain sizes of the micro phase-separated polymer components.
Kretschmer
Axel
A
Dow Corning SA, Parc Industriel Zone C, B-7180 Seneffe, Belgium. a.kretschmer@dowcorning.com
Drake
Robert
R
Neidhoefer
Michael
M
Wilhelm
Manfred
M
D004129:Dimethylpolysiloxanes / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D010797:Phthalimides / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry; D011522:Protons; D015203:Reproducibility of Results; D012680:Sensitivity and Specificity; D012828:Silicones / Q000737:chemistry*
D004129:Dimethylpolysiloxanes; D010797:Phthalimides; D011108:Polymers; D011522:Protons; D012828:Silicones; C013830:baysilon