title: Degradation of perchloroethylene in cosolvent solutions by zero-valent iron.
abstract: Remediation of sites contaminated by chlorinated organic compounds is a significant priority in the environmental field. Subsequently, the addition of cosolvent solutions for in situ flushing of contaminated source zones has been successfully field tested. However, the treatment of effluent fluids in such cleanup efforts is an often overlooked component of this technology implementation. The purpose of this research was to evaluate the effectiveness of zero-valent iron (Fe(0)) in treating perchloroethylene (PCE) in an aqueous solution, and how the presence of a cosolvent (ethanol) and modification of the iron surface altered dechlorination. The modified iron surfaces included in this study were nickel-plated iron, acid-treated iron, and untreated iron surfaces. PCE dechlorination in the presence of each of the iron surfaces displayed pseudo first-order kinetics. The highest degradation rate of PCE occurred on the nickel-plated iron surface, 5.83 x 10(-3)h(-1), followed by the acid-treated iron, 4.92 x 10(-3)h(-1), and the untreated iron, 3.34 x 10(-3)h(-1). Dechlorination on each of the surfaces decreased with increasing cosolvent fractions. It was shown that as cosolvent fractions increased, PCE adsorption decreased and resulted in a concomitant decrease in PCE degradation rates.
authors.affiliation: Inter-disciplinary Program in Hydrologic Sciences, Department of Civil Engineering, University of Florida, Gainesville, FL 32611, USA. clark@ce.ufl.edu
authors.forename: Clayton J
authors.initials: CJ
authors.lastname: Clark
authors.forename: P S C
authors.initials: PS
authors.lastname: Rao
authors.forename: Michael D
authors.initials: MD
authors.lastname: Annable
mesh_terms: D002851:Chromatography, High Pressure Liquid; D004785:Environmental Pollutants / Q000032:analysis*; D000431:Ethanol / Q000737:chemistry; D007501:Iron / Q000737:chemistry*; D007700:Kinetics; D012997:Solvents / Q000737:chemistry*; D013750:Tetrachloroethylene / Q000032:analysis* / Q000737:chemistry; D014873:Water Pollutants / Q000032:analysis*
chemical_list: D004785:Environmental Pollutants; D012997:Solvents; D014873:Water Pollutants; D000431:Ethanol; D007501:Iron; D013750:Tetrachloroethylene