title: Stereoselective C-glycosidation of unprotected D-glycals with trimethylsilyl cyanide.
abstract: Unprotected glycals reacted with trimethylsilyl cyanide in the presence of a catalytic amount of a palladium compound to yield the 2,3-unsaturated glycosyl cyanides in high yield and in alpha-selectivity.
authors.affiliation: Department of Chemistry, Faculty of Science, Kobe University, Nada, Kobe, Japan. mhayashi@kobe-u.ac.jp
authors.forename: Masahiko
authors.initials: M
authors.lastname: Hayashi
authors.forename: Hirotoshi
authors.initials: H
authors.lastname: Kawabata
authors.forename: Shu-Zo
authors.initials: SZ
authors.lastname: Nakayama
mesh_terms: D003486:Cyanides / Q000737:chemistry*; D006027:Glycosides / Q000138:chemical synthesis* / Q000737:chemistry; D006031:Glycosylation; D007202:Indicators and Reagents; D015394:Molecular Structure; D013237:Stereoisomerism; D014297:Trimethylsilyl Compounds / Q000737:chemistry*
chemical_list: D003486:Cyanides; D006027:Glycosides; D007202:Indicators and Reagents; D014297:Trimethylsilyl Compounds; C058010:trimethylsilyl cyanide