Stability and structure in alpha- and beta-Keggin Heteropolytungstates, [X(n)(+)W12O40)](8-n)(-), X = p-block cation.
beta-[SiW(12)O(40)](4)(-) (C(3)(v) symmetry) is sufficiently higher in energy than its alpha-isomer analogue that effectively complete conversion to alpha-[SiW(12)O(40)](4)(-) (T(d)) is observed. By contrast, beta- and alpha-[AlW(12)O(40)](5)(-) (beta- and alpha-1; C(3)(v) and T(d), respectively) are sufficiently close in energy that both isomers are readily seen in (27)Al NMR spectra of equilibrated (alpha-beta) mixtures. Recently published DFT calculations ascribe the stability of beta-1 to an electronic effect of the large, electron-donating [AlO(4)](5)(-) (T(d)) moiety encapsulated within the polarizable, fixed-diameter beta-W(12)O(36) (C(3)(v)) shell. Hence, no unique structural distortion of beta-1 is needed or invoked to explain its unprecedented stability. The results of these DFT calculations are confirmed by detailed comparison of the X-ray crystal structure of beta-1 (beta-Cs(4.5)K(0.5)[Al(III)W(12)O(40)].7.5H(2)O; orthorhombic, space group Pmc2(1), a = 16.0441(10) A, b = 13.2270(8) A, c = 20.5919(13) A, Z = 4 (T = 100(2) K)) with previously reported structures of alpha-1, alpha- and beta-[SiW(12)O(40)](4)(-), and beta(1)-[SiMoW(11)O(40)](4)(-).
Neiwert
Wade A
WA
Department of Chemistry, Emory University, Atlanta, Georgia 30322, USA.
Cowan
Jennifer J
JJ
Hardcastle
Kenneth I
KI
Hill
Craig L
CL
Weinstock
Ira A
IA