title: Amorphous solidification in polymer-platelet nanocomposites.
abstract: Computer simulations are used to understand the molecular basis of the rheology changes in polymer melts when loaded with platelet filler particles, specifically when the polymer and nanofiller interact attractively. With decreasing temperature, there is increasing aggregation between chains and filler and an increase in the polymer matrix structural relaxation time. These lifetimes are predicted to diverge at an extrapolated temperature, which we identify with the emergence of an amorphous solid state. Our findings suggest that filled polymers are phenomenologically similar to solutions of associating polymers and to supercooled liquids near their glass transition.
authors.affiliation: Department of Materials Science and Engineering, Pennsylvania State University, University Park, USA.
authors.forename: Sumeet
authors.initials: S
authors.lastname: Salaniwal
authors.forename: Sanat K
authors.initials: SK
authors.lastname: Kumar
authors.forename: Jack F
authors.initials: JF
authors.lastname: Douglas