A novel modified baylis-hillman reaction of propiolate.
A new reaction of propiolates and aldehydes mediated by DABCO analogous to the Baylis-Hillman reaction is described. This reaction provided novel beta-functionalized Baylis-Hillman products and a new methodology for the generation of alkylidene carbene species.
Matsuya
Yuji
Y
Faculty of Pharmaceutical Sciences, Toyama Medical and Pharmaceutical University, Sugitani 2630, Japan.
Hayashi
Kousuke
K
Nemoto
Hideo
H