The thermodynamic water retention capacity of solutions and gels.
The thermodynamic water retention capacity (WRC) has been defined and applied to different heterogeneous phase equilibria. This definition includes others known from the literature for testing heterogeneous systems. For the type of a real solution it is shown that at constant values of temperature and pressure the WRC is related to the difference of the chemical potential of water between the original state and the state after having applied a constraint. The dependence of WRC on concentration of a solute is predicted to be described by an e-function which has been experimentally confirmed in the literature.
Borchard
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W
Institut für Chemie der Gerhard-Mercator-Universität, Duisburg, Lotharstr. u Fakultät 4, 47048 Duisburg, Germany. borchard@uni-duisburg.de
Jablonski
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P
D008962:Models, Theoretical; D012987:Soil; D013816:Thermodynamics; D014867:Water / Q000737:chemistry*
D012987:Soil; D014867:Water