title: [Infrared laser photochemistry of metal carbonyls in the presence of cyclopentadiene].
abstract: Mixtures of C5H6 and Fe(CO)5, Cr(CO)6, and Co2(CO)8 were irradiated in the gaseous phase with the P-20 line (944.21 cm-1) of a CW CO2 laser using SF6 as a sensitizer. The reaction products were metal particles and carbon monoxide, and in the C5H6/Fe(CO)5/SF6 mixture the iron dimer (C5H5)2Fe2(CO)4 was isolated.
authors.affiliation: Departamento de Química, Universidad Simón Bolívar, Apartado 89.000 Caracas 1080A, Venezuela.
authors.forename: Antonio M
authors.initials: AM
authors.lastname: Barriola
authors.forename: Alfredo
authors.initials: A
authors.lastname: Fernández
mesh_terms: D002248:Carbon Monoxide; D002857:Chromium; D003035:Cobalt; D003517:Cyclopentanes / Q000737:chemistry*; D007259:Infrared Rays; D007501:Iron; D007834:Lasers; D009942:Organometallic Compounds / Q000737:chemistry*; D010777:Photochemistry
chemical_list: D003517:Cyclopentanes; D009942:Organometallic Compounds; D002857:Chromium; D003035:Cobalt; D002248:Carbon Monoxide; D007501:Iron