title: Cross-coupling reactions of organosilicon compounds: new concepts and recent advances.
abstract: This review highlights the rapid evolution of the newly-developed class of palladium-catalyzed cross-coupling reactions of organosilicon compounds. A myriad of heteroatom-containing silicon moieties (silyl hydrides, siletanes, silanols, silyl ethers, orthosiliconates, di- and polysiloxanes and pyridylsilanes) undergo mild and stereospecific cross-coupling. The diversity of methods for introduction of silicon groups into organic molecules and the range of organic electrophiles that can be used are emphasized.
authors.affiliation: Department of Chemistry, University of Illinois, Urbana, Illinois 61801, USA. denmark@scs.uiuc.edu
authors.forename: Scott Eric
authors.initials: SE
authors.lastname: Denmark
authors.forename: Ramzi Farah
authors.initials: RF
authors.lastname: Sweis
mesh_terms: D002384:Catalysis; D004988:Ethers, Cyclic / Q000737:chemistry; D017646:Organosilicon Compounds / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry; D010165:Palladium / Q000737:chemistry; D000644:Quaternary Ammonium Compounds / Q000737:chemistry; D018030:Silver Compounds / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D004988:Ethers, Cyclic; D017646:Organosilicon Compounds; D010087:Oxides; D000644:Quaternary Ammonium Compounds; D018030:Silver Compounds; D010165:Palladium; C040225:disilver oxide; C009405:tetrabutylammonium