Cross-coupling reactions of organosilicon compounds: new concepts and recent advances.
This review highlights the rapid evolution of the newly-developed class of palladium-catalyzed cross-coupling reactions of organosilicon compounds. A myriad of heteroatom-containing silicon moieties (silyl hydrides, siletanes, silanols, silyl ethers, orthosiliconates, di- and polysiloxanes and pyridylsilanes) undergo mild and stereospecific cross-coupling. The diversity of methods for introduction of silicon groups into organic molecules and the range of organic electrophiles that can be used are emphasized.
Denmark
Scott Eric
SE
Department of Chemistry, University of Illinois, Urbana, Illinois 61801, USA. denmark@scs.uiuc.edu
Sweis
Ramzi Farah
RF
D002384:Catalysis; D004988:Ethers, Cyclic / Q000737:chemistry; D017646:Organosilicon Compounds / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry; D010165:Palladium / Q000737:chemistry; D000644:Quaternary Ammonium Compounds / Q000737:chemistry; D018030:Silver Compounds / Q000737:chemistry; D013237:Stereoisomerism
D004988:Ethers, Cyclic; D017646:Organosilicon Compounds; D010087:Oxides; D000644:Quaternary Ammonium Compounds; D018030:Silver Compounds; D010165:Palladium; C040225:disilver oxide; C009405:tetrabutylammonium