The first tridentate phosphine ligand combining planar, phosphorus and carbon chirality.
Two new diastereomerically pure tridentate phosphine ligands combining planar, phosphorus and carbon chirality have been conveniently synthesized via resolution of their phosphineoxide-diborane adducts and structurally characterized by X-ray analyses.
Barbaro
Pierluigi
P
Instituto di Chimica dei Composti Organo Metallici-CNR, Via Jacopo Nardi 39, 50132 Firenze, Italy. pigi@fi.cnr.it
Bianchini
Claudio
C
Giambastiani
Giuliano
G
Togni
Antonio
A