Dewetting of thin-film polymers.
In this paper we present a theoretical model for the dewetting of ultrathin polymer films. Assuming that the shear-thinning properties of these films can be described by a Cross-type constitutive equation, we analyze the front morphology of the dewetting film, and characterize the time evolution of the dry region radius, and of the rim height. Different regimes of growth are expected, depending on the initial film thickness, and on the power-law index involved in the constitutive equation. In the thin-films regime, the dry radius and the rim height obey power-law time dependences. We then compare our predictions with the experimental results obtained by Debrégeas et al. [Phys. Rev. Lett. 75, 3886 (1995)] and by Reiter [Phys. Rev. Lett. 87, 186101 (2001)].
Saulnier
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Laboratoire de Physique de la Matière Condensée, CNRS UMR 7125, Collège de France, 11 place Marcelin Berthelot, 75231 Paris Cedex 05, France. florent.saulnier@college-de-france.fr
Raphaël
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De Gennes
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