title: Model for the cofactor formation reaction of E. coli ribonucleotide reductase. From a diiron(II) precursor to an FeIIIFeIV species via a peroxo intermediate.
authors.affiliation: Department of Chemistry, Center for Metals in Biocatalysis, University of Minnesota, Minneapolis, Minnesota 55455, USA.
authors.forename: V L
authors.initials: VL
authors.lastname: MacMurdo
authors.forename: H
authors.initials: H
authors.lastname: Zheng
authors.forename: L
authors.initials: L
authors.lastname: Que
mesh_terms: D001665:Binding Sites; D002384:Catalysis; D004578:Electron Spin Resonance Spectroscopy; D004926:Escherichia coli / Q000201:enzymology*; D007501:Iron / Q000737:chemistry* / Q000378:metabolism; D007700:Kinetics; D008956:Models, Chemical; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry* / Q000378:metabolism; D010084:Oxidation-Reduction; D012264:Ribonucleotide Reductases / Q000737:chemistry* / Q000378:metabolism; D013056:Spectrophotometry, Ultraviolet
chemical_list: D009942:Organometallic Compounds; D007501:Iron; D012264:Ribonucleotide Reductases