Optimization of hydrogen peroxide in totally chlorine free bleaching of cellulose pulp from olive tree residues.
The influence of the operating conditions used in the bleaching of olive wood trimmings pulp (viz. hydrogen peroxide concentration and time) on the yield, kappa index and viscosity of the resulting pulp and on strength-related properties of paper sheets was studied to determine the optimal bleaching conditions of this pulp. Hydrogen peroxide bleached pulps at different sequences (oxygen, ozone, chlorine dioxide and alkaline extractions) were compared. Hydrogen peroxide bleaching proved to be suitable for this pulp. Considerable improvements in viscosity were obtained with respect to other bleaching sequences such as oxygen, ozone and chlorine dioxide. Hydrogen peroxide bleaching decreased the kappa index 51.3% less than ozone bleaching, 25.0% less than chlorine dioxide (D) and 6.3% less combined chlorine dioxide-alkaline extraction (DE). To obtain kappa indices 50.9% and 37.9% lower than the index achieved by hydrogen peroxide, oxygen (LaO(p)) and ozone (LaO(LaZ)R) sequences respectively were needed. Lower-medium levels of hydrogen peroxide concentrations (1-3%) and high reaction times (210 min) proved to be suitable for bleaching of pulp olive trimming residues. This approach could be used on this residue to produce adequately bleached pulp.
López
F
F
Departamento de Ingenieri;a Qui;mica, Escuela Politécnica Superior, Universidad de Huelva, Ctra. Huelva-Palos de la Frontera s/n, 21819 La Rábida, Palos de la Frontera, Huelva, Spain. baldovin@uhu.es
Díaz
M J
MJ
Eugenio
M E
ME
Ariza
J
J
Rodríguez
A
A
Jiménez
L
L
D002482:Cellulose / Q000737:chemistry*; D006861:Hydrogen Peroxide / Q000737:chemistry*; D007220:Industrial Waste; D031658:Olea; D016877:Oxidants / Q000737:chemistry*; D010209:Paper; D012037:Refuse Disposal / Q000379:methods*
D007220:Industrial Waste; D016877:Oxidants; D002482:Cellulose; D006861:Hydrogen Peroxide