Layered droplet microstructures in sheared emulsions: finite-size effects.
We investigate the influence of confinement on the steady state microstructure of emulsions sheared between parallel plates, in a regime where the average droplet dimension is comparable to the gap width between the confining walls. Utilizing droplet velocimetry, we find that the droplets can organize into discrete layers under the influence of shear. The number of layers decreases from two (at relatively higher shear rates) to one (at lower shear rates), as the drops grow slightly larger due to coalescence. We argue that the layering and overall composition profile may be controlled by the interplay of droplet collisions (which can cause separation of droplet centers in the velocity gradient direction), droplet migration toward the centerline (due to wall effects), and droplet packing constraints. We also study the effects of mixture composition on droplet microstructure, and summarize these results in the form of a morphology diagram in the parameter space of mass fraction and shear rate. We find that formation of strings of the suspended phase (reported earlier by our group in flow-visualization studies on confined emulsions) is observed over a broad composition window. We also find a stable (nontransient) morphology wherein the droplets are arranged in highly ordered pearl-necklace chain structures.
Pathak
Jai A
JA
Polymers Division, National Institute of Standards and Technology, 100 Bureau Drive, Gaithersburg, MD 20899-8544, USA. Jai.Pathak@nist.gov
Davis
Melissa C
MC
Hudson
Steven D
SD
Migler
Kalman B
KB
D004655:Emulsions / Q000737:chemistry*; D008853:Microscopy; D008962:Models, Theoretical; D012212:Rheology; D013314:Stress, Mechanical; D013329:Structure-Activity Relationship; D014867:Water
D004655:Emulsions; D014867:Water