Long-term water-aging of whisker-reinforced polymer-matrix composites.
Long-term water exposure may degrade polymer-matrix composites. This study investigated the water-aging of whisker composites. It was hypothesized that whiskers would provide stable and substantial reinforcement, and that whisker type would affect water-aging resistance. Silica-fused Si(3)N(4) and SiC whiskers were incorporated into a resin. The specimens were tested by three-point flexure and nano-indentation vs. water-aging for 1 to 730 days. After 730 days, SiC composite had a strength (mean +/- SD; n = 6) of 185 +/- 33 MPa, similar to 146 +/- 44 MPa for Si(3)N(4) composite (p = 0.064); both were significantly higher than 67 +/- 23 MPa for an inlay/onlay control (p < 0.001). Compared with 1 day, the strength of the SiC composite showed no decrease, while that of the Si(3)N(4) composite decreased. The decrease was due to whisker weakening rather than to resin degradation or interface breakdown. Whisker composites also had higher moduli than the controls. In conclusion, silica-fused whiskers bonded to polymer matrix and resisted long-term water attack, resulting in much stronger composites than the controls after water-aging.
Xu
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Paffenbarger Research Center, 100 Bureau Dr. Stop 8546, American Dental Association Health Foundation, Building 224, Room A-153, National Institute of Standards and Technology, Gaithersburg, MD 20899-8546, USA. hockin.xu@nist.gov
D000704:Analysis of Variance; D017438:Bisphenol A-Glycidyl Methacrylate / Q000737:chemistry; D017554:Carbon Compounds, Inorganic / Q000737:chemistry; D002516:Ceramics / Q000737:chemistry; D003188:Composite Resins / Q000737:chemistry*; D003764:Dental Materials / Q000737:chemistry*; D003776:Dental Porcelain / Q000737:chemistry; D004548:Elasticity; D005899:Glass Ionomer Cements / Q000737:chemistry; D006244:Hardness; D006801:Humans; D008422:Materials Testing; D008689:Methacrylates / Q000737:chemistry; D008855:Microscopy, Electron, Scanning; D018583:Pliability; D011092:Polyethylene Glycols / Q000737:chemistry; D011108:Polymers / Q000737:chemistry*; D011109:Polymethacrylic Acids / Q000737:chemistry; D011140:Polyurethanes / Q000737:chemistry; D012823:Silicate Cement / Q000737:chemistry; D017655:Silicon Compounds / Q000737:chemistry*; D012822:Silicon Dioxide / Q000737:chemistry; D013223:Statistics as Topic; D013314:Stress, Mechanical; D013499:Surface Properties; D013997:Time Factors; D014867:Water / Q000737:chemistry*
D017554:Carbon Compounds, Inorganic; D003188:Composite Resins; C069352:Concept resin; D003764:Dental Materials; D005899:Glass Ionomer Cements; D008689:Methacrylates; D011108:Polymers; D011109:Polymethacrylic Acids; D011140:Polyurethanes; D017655:Silicon Compounds; C111282:dental polyglass; D014867:Water; D003776:Dental Porcelain; C029824:urethane dimethacrylate luting resin; D012823:Silicate Cement; C020946:triethylene glycol dimethacrylate; D011092:Polyethylene Glycols; D017438:Bisphenol A-Glycidyl Methacrylate; D012822:Silicon Dioxide; C032734:silicon nitride; C022088:silicon carbide