Dichlorobis(DL-proline-kappaO)zinc(II).
The title compound, [ZnCl(2)(C(5)H(9)NO(2))(2)], crystallizes in the centrosymmetric space group C2/c with the Zn atom on a twofold axis. The two proline residues in any one complex thus have the same absolute configuration. Hydrogen bonding links the molecules into linear chains, which run in the crystallographic b direction. The proline residues within any one chain also have an identical absolute configuration.
Lutz
Martin
M
Department of Crystal and Structural Chemistry, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands. m.lutz@chem.uu.nl
Bakker
Ruud
R
D000596:Amino Acids / Q000737:chemistry; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D011392:Proline / Q000031:analogs & derivatives / Q000737:chemistry*; D013237:Stereoisomerism; D015032:Zinc / Q000737:chemistry*
D000596:Amino Acids; D009942:Organometallic Compounds; C475485:dichlorobis(DL-proline-kappaO)zinc(II); D011392:Proline; D015032:Zinc