[Infrared laser photochemistry of metal carbonyls in the presence of cyclopentadiene].
Mixtures of C5H6 and Fe(CO)5, Cr(CO)6, and Co2(CO)8 were irradiated in the gaseous phase with the P-20 line (944.21 cm-1) of a CW CO2 laser using SF6 as a sensitizer. The reaction products were metal particles and carbon monoxide, and in the C5H6/Fe(CO)5/SF6 mixture the iron dimer (C5H5)2Fe2(CO)4 was isolated.
Barriola
Antonio M
AM
Departamento de Química, Universidad Simón Bolívar, Apartado 89.000 Caracas 1080A, Venezuela.
Fernández
Alfredo
A
D002248:Carbon Monoxide; D002857:Chromium; D003035:Cobalt; D003517:Cyclopentanes / Q000737:chemistry*; D007259:Infrared Rays; D007501:Iron; D007834:Lasers; D009942:Organometallic Compounds / Q000737:chemistry*; D010777:Photochemistry
D003517:Cyclopentanes; D009942:Organometallic Compounds; D002857:Chromium; D003035:Cobalt; D002248:Carbon Monoxide; D007501:Iron