Model for the cofactor formation reaction of E. coli ribonucleotide reductase. From a diiron(II) precursor to an FeIIIFeIV species via a peroxo intermediate.
MacMurdo
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VL
Department of Chemistry, Center for Metals in Biocatalysis, University of Minnesota, Minneapolis, Minnesota 55455, USA.
Zheng
H
H
Que
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L
D001665:Binding Sites; D002384:Catalysis; D004578:Electron Spin Resonance Spectroscopy; D004926:Escherichia coli / Q000201:enzymology*; D007501:Iron / Q000737:chemistry* / Q000378:metabolism; D007700:Kinetics; D008956:Models, Chemical; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry* / Q000378:metabolism; D010084:Oxidation-Reduction; D012264:Ribonucleotide Reductases / Q000737:chemistry* / Q000378:metabolism; D013056:Spectrophotometry, Ultraviolet
D009942:Organometallic Compounds; D007501:Iron; D012264:Ribonucleotide Reductases