title: Occupational exposure to metalworking fluid mist and sump fluid contaminants.
abstract: This paper summarizes the analytical and occupational hygiene findings from a recent survey of occupational exposure to metalworking fluids (MWFs) in the engineering industry. The aim of the survey was to link MWF mist exposure measurements with particular engineering processes and controls, and utilize the data obtained to develop exposure standards. At the same time the opportunity was taken to assess fluid management and control, including bacterial and fines contamination in the machine sumps. In general, occupational exposure to mineral oil MWF mist was controlled to <3 mg/m(3) (8 h time-weighted average) and to <1 mg/m(3) for water-mix MWF mist (in terms of the concentrate). These exposure values do not necessarily represent best practice, but are believed to be achievable and representative of industry as a whole. Gravimetric analysis of the total inhalable particulate was found to be a good predictor of mineral oil MWF mist but not for water-mix MWF mist. Grinding and drilling operations produced higher exposures than turning and milling for water-mix fluids. There were insufficient data to compare machining operations for mineral oil MWFs. On the whole, fluid management was found to be poor, with most sites failing to meet industry good practice or Health & Safety Executive (HSE) standards. Some of the operating procedures utilized were deficient or unsatisfactory. Poor standards of fluid management were found at all sizes of company. High levels of bacteria, endotoxin and fines were found in sumps, and control of other factors, such as water-mix fluid concentration, was often poor. Mineral oils had higher levels of fines than water-mix fluids (medians of 395 and 18 mg/l, respectively), and grinding produced high levels of fines in both types of MWF. Many water-mix sumps contained bacterial levels of >1 x 10(6) CFU/ml, and endotoxin levels of >100 000 EU/ml were not uncommon. The median values were 109 000 CFU/ml and 8039 EU/ml, respectively. Mists could potentially contain extensive contamination from bacteria and endotoxin. Analysis of the data suggests that sumps operating under typical conditions for machining (a temperature of 20 degrees C, a pH of 9 and a fluid strength below 10%), also appear to provide optimum conditions for the proliferation of bacteria. Low levels of benzo[a]pyrene (median 0.03 micro g/g) were found in the mineral oils, and low levels of N-nitrosodiethanolamine (median 0.4 micro g/ml) were found in the water-mix MWFs. The results of this work will contribute to guidance from the HSE, setting out accepted industry good practice, including guide values for MWF mist and sump fluid contaminants, with significant emphasis on sump fluid management (maintenance and monitoring), as well as control issues.
authors.affiliation: Health and Safety Laboratory, Broad Lane, Sheffield S3 7HQ, UK.
authors.forename: A T
authors.initials: AT
authors.lastname: Simpson
authors.forename: M
authors.initials: M
authors.lastname: Stear
authors.forename: J A
authors.initials: JA
authors.lastname: Groves
authors.forename: M
authors.initials: M
authors.lastname: Piney
authors.forename: S D
authors.initials: SD
authors.lastname: Bradley
authors.forename: S
authors.initials: S
authors.lastname: Stagg
authors.forename: B
authors.initials: B
authors.lastname: Crook
mesh_terms: D000336:Aerosols; D000391:Air Microbiology; D000395:Air Pollutants, Occupational / Q000032:analysis*; D004784:Environmental Monitoring / Q000379:methods; D006801:Humans; D007219:Industrial Oils / Q000032:analysis*; D019570:Inhalation Exposure / Q000032:analysis*; D008669:Metallurgy; D016273:Occupational Exposure / Q000032:analysis*
chemical_list: D000336:Aerosols; D000395:Air Pollutants, Occupational