The Cologne Carbon Cluster experiment: ro-vibrational spectroscopy on C8 and other small carbon clusters.
We report on our ongoing efforts in obtaining the IR-spectra of the linear carbon cluster molecules Cn with n=8-13. So far C8, C9, C10, and C13 have been recorded at Cologne. With the exception of C8 all assignments have been secured. For C8 a tentative assignment could be derived with the bandcenter of the sigmau antisymmetric stretching mode located at nu0=2067.9779 cm(-1) and a preliminary rotational constant in the vibrational ground state of B"=0.02068 cm(-1). The measured signal to noise ratio of the ro-vibrational band is fairly weak and thus the lower J ro-vibrational transitions can not be assigned with certainty. As a consequence the band center remains uncertain by 4 J or 0.17 cm(-1). For a more reliable assignment the sensitivity of the system has to be increased by at least one order of magnitude. The envisaged sensitivity increase of our experiment will be discussed along with the intention to perform terahertz observations of the low energetic bending ro-vibrational spectra. These sub-mm wave measurements will be carried out simultaneously with the IR measurements.
Neubauer-Guenther
P
P
I. Physikalisches Institut, Universität zu Köln, Zülpicher Str. 77, D-50937 Koln, Germany. neubauer@phl.uni-koeln.de
Giesen
T F
TF
Berndt
U
U
Fuchs
G
G
Winnewisser
G
G
D002244:Carbon / Q000737:chemistry*; D005858:Germany; D007834:Lasers; D012680:Sensitivity and Specificity; D013055:Spectrophotometry, Infrared / Q000295:instrumentation / Q000379:methods / Q000706:statistics & numerical data
D002244:Carbon