title: Extremely high activity catalysts for the Suzuki coupling of aryl chlorides: the importance of catalyst longevity.
abstract: The incorporation of a new pi-acidic, orthometallated phosphite ligand into a palladium pre-catalyst gives considerably enhanced catalyst longevity and thus extremely high activity in the Suzuki coupling of deactivated, activated and sterically hindered aryl chloride substrates.
authors.affiliation: School of Chemistry, University of Exeter, Exeter, UK EX4 4QD. r.bedford@ex.ac.uk
authors.forename: Robin B
authors.initials: RB
authors.lastname: Bedford
authors.forename: Samantha L
authors.initials: SL
authors.lastname: Hazelwood
authors.forename: Michael E
authors.initials: ME
authors.lastname: Limmert