title: Functionalized heteropolyanions: high-valent metal nitrido fragments incorporated into a Keggin polyoxometalate structure.
abstract: Three examples of nitrido-functionalized polyoxometalate species are reported, namely (n-Bu4N)4[PW11O39(OsN)] (1), (n-Bu4N)4[PW11O39(ReN)] (2), and (n-Bu4N)3[PW11O39(ReN)] (3), which feature the incorporation of [OsVI identical to N]3+, [ReVI identical to N]3+ and [ReVII identical to N]4+ fragments, respectively, into the framework of a Keggin-type heteropolyanion.
authors.affiliation: Department of Chemistry, Kansas State University, Manhattan, Kansas 66506-3701, USA.
authors.forename: Haidoo
authors.initials: H
authors.lastname: Kwen
authors.forename: Sean
authors.initials: S
authors.lastname: Tomlinson
authors.forename: Eric A
authors.initials: EA
authors.lastname: Maatta
authors.forename: Céline
authors.initials: C
authors.lastname: Dablemont
authors.forename: René
authors.initials: R
authors.lastname: Thouvenot
authors.forename: Anna
authors.initials: A
authors.lastname: Proust
authors.forename: Pierre
authors.initials: P
authors.lastname: Gouzerh