title: [Gas chromatography-infrared spectroscopy(GC-IR) analysis of the oxidation products of cyclohexene].
abstract: Gas chromatography-infrared spectroscopy technique integrates the excellent resolution ability of GC with the structural information of IR. Based on the GC and IR spectra, the complicated products of a reaction can be analyzed quantitatively and qualitatively. From the analysis of the products, the reaction process and its mechanism can be elucidated. In this work, analysis by GC-IR of the oxidation products of cyclohexene catalyzed by zeolite TS-1 in H2O2 was performed. The products are 2-cyclohexenone, 2-cyclohexen-1-ol and 2,3-epoxy-1-cyclohexanone. 2,3-Epoxy-1-cyclohexanone is an unexpected product. It must be a further oxidation product of 2-cyclohexenone. From the analysis, the reaction mechanisms were presumed.
authors.affiliation: State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000.
authors.forename: B
authors.initials: B
authors.lastname: Xie
authors.forename: Y
authors.initials: Y
authors.lastname: Kou
authors.forename: C
authors.initials: C
authors.lastname: Xia
authors.forename: Z
authors.initials: Z
authors.lastname: Zhang
authors.forename: Y
authors.initials: Y
authors.lastname: Yin
mesh_terms: D000473:Alkanes / Q000032:analysis; D000475:Alkenes / Q000032:analysis; D002849:Chromatography, Gas / Q000379:methods; D003510:Cyclohexanes / Q000032:analysis*; D003512:Cyclohexanones / Q000032:analysis; D053138:Cyclohexenes; D007462:Iodobenzenes / Q000032:analysis; D010084:Oxidation-Reduction; D013055:Spectrophotometry, Infrared / Q000379:methods
chemical_list: D000473:Alkanes; D000475:Alkenes; D003510:Cyclohexanes; D003512:Cyclohexanones; D053138:Cyclohexenes; D007462:Iodobenzenes; C052568:cyclohexene; C028215:2-cyclohexen-1-one; C031905:iodobenzene; C117224:1-hexene; C012867:decane