[Preparation of gas chromatographic capillary columns with beta-cyclodextrin polymer stationary phase modified with methyl phenyl silicone(OV-17)].
An insoluble beta-cyclodextrin polymer cross-linked with epichlorohydrin was prepared. beta-Cyclodextrin polymer (0.26 g) was treated for 0.5 h by a ultrasonator in the mixed solvent (10 mL) of isopropyl ether, methylene dichloride and benzene with a volume ratio 2:1:2, and a 26 g/L colloidal stationary liquid was prepared. It was coated on a fused silica capillary by superdynamic coating method. The capillary column was of high column efficiency of above 3,000/m with good thermal stability and moderate polarity. Enantiomers of xylene, dichlorobenzene, alpha-pinene, beta-pinene, ethyl lactate, alpha-phenyl ethanol, 1, 2-propanediol, alpha-lonone, methyl alpha-chloropropionate and gamma-valerolactone were separated on the capillary column. The experimental results showed that beta-cyclodextrin polymer treated by a ultrasonator is a capillary chromatographic stationary phase with good performance and high selectivity.
Chen
G B
GB
Department of Chemical Engineering, Yueyang Normal University, Yueyang 414000, China.
Tang
K W
KW
D002849:Chromatography, Gas / Q000295:instrumentation*; D003505:Cyclodextrins; D011108:Polymers; D019946:Propylene Glycol / Q000302:isolation & purification; D012833:Siloxanes; D013237:Stereoisomerism; D014465:Ultrasonics; D014992:Xylenes / Q000737:chemistry / Q000302:isolation & purification; D047392:beta-Cyclodextrins
D003505:Cyclodextrins; D011108:Polymers; D012833:Siloxanes; D014992:Xylenes; D047392:beta-Cyclodextrins; C014763:polymethylphenylsiloxane; D019946:Propylene Glycol; C031215:betadex