title: Regioselective synthesis of substituted o-alkoxyphenol derivatives through thermal benzannulation of Fischer (alkenylcyclobutenyl)carbene complexes.
abstract: A convenient, regioselective, and general synthetic method for producing highly substituted o-phenol-containing polycycles from Fischer (alkenylcyclobutenyl)carbene complexes has been described. The starting complexes have been synthesized by means of the [2 + 2] cycloaddition reaction of (alkenylethynyl)carbene complexes and a range of enol ethers, and in most cases, they have proven to be stable at room temperature and therefore isolable. The key step of the synthesis consists of the thermal benzannulation reaction of these novel pentacarbonyl dienyl Fischer complexes, which is an unprecedented transformation for these kinds of complexes. The unexpected behavior of (alkenylcyclobutenyl)carbene complexes has been rationalized in terms of their geometries.
authors.affiliation: Instituto Universitario de Química Organometálica Enrique Moles, Unidad Asociada al CSIC, Universidad de Oviedo, Julián Clavería 8, Spain. barluenga@sauron.quimica.uniovi.es
authors.forename: José
authors.initials: J
authors.lastname: Barluenga
authors.forename: Fernando
authors.initials: F
authors.lastname: Aznar
authors.forename: M Angel
authors.initials: MA
authors.lastname: Palomero