Synthesis of 2-silyl substituted phospharuthenocenes and an elaboration into the first phospharuthenocene-phosphine.
A [1,5] shift protocol transiently hindering the 2-position of phospholide anions provides an access to sterically unencumbered phospharuthenocenes and the first phospharuthenocene-phosphine.
Carmichael
Duncan
D
Laboratoire Hétéroéléments et Coordination, UMR CNRS 7653, DCPH Ecole Polytechnique, 91128 Palaiseau, France. Duncanc@mars.polytechnique.fr
Mathey
François
F
Ricard
Louis
L
Seeboth
Nicolas
N