Asymmetric synthesis of the putative structure of (-)-oryzoxymycin.
[reaction: see text] A short asymmetric synthesis of (2'S,5R,6R)-2'-[6-amino-5-hydroxy-1,3-cyclohexadiene-1-carbonyloxy]propionic acid, the enantiomer of the reported structure of (+)-oryzoxymycin is described. The reported spectral data does not match that obtained for synthetic "oryzoxymycin".
Bunnage
Mark E
ME
Department of Chemistry, University of Durham, South Road, Durham DH1 3LE, UK.
Ganesh
Thota
T
Masesane
Ishmael B
IB
Orton
Darren
D
Steel
Patrick G
PG
D003509:Cyclohexanecarboxylic Acids / Q000138:chemical synthesis* / Q000737:chemistry*; D053138:Cyclohexenes; D015394:Molecular Structure
D003509:Cyclohexanecarboxylic Acids; D053138:Cyclohexenes; C002624:oryzoxymycin