Charge-transfer band shifts in iron(III) hexacyanoferrate(II) by electro-intercalated cations via ground state-energy/lattice-energy link.
It is currently important to achieve and understand adjustments of optical properties: "guest cation" induced CT spectral shifts in Prussian Blue are shown to be driven (via its specific effect on the Fe(CN)6 CT-donor entity) by the cation lattice-energy interaction, as inferred from microgravimetry of introduced alkali-metal ions, and from independent solubility correlations for other intercalated cations.
Rosseinsky
David R
DR
Singapore Institute of Mfg. Technology, 71 Nanyang Drive, Singapore 638075. d.r.rosseinsky@ex.ac.uk
Lim
Hanyong
H
Zhang
Xiao
X
Jiang
Hongjin
H
Chai
Jian Wei
JW