title: Molecular tectonics. Use of the hydrogen bonding of boronic acids to direct supramolecular construction.
abstract: Tetraboronic acids 1 and 2 have four -B(OH)(2) groups oriented tetrahedrally by cores derived from tetraphenylmethane and tetraphenylsilane. Crystallization produces isostructural diamondoid networks held together by hydrogen bonding of the -B(OH)(2) groups, in accord with the tendency of simple arylboronic acids to form cyclic hydrogen-bonded dimers in the solid state. Five-fold interpenetration of the networks is observed, but 60% and 64% of the volumes of crystals of tetraboronic acids 1 and 2, respectively, remain available for the inclusion of disordered guests. Guests occupy two types of interconnected channels aligned with the a and b axes; those in crystals of tetraphenylmethane 1 measure approximately 5.9 x 5.9 A(2) and 5.2 x 8.6 A(2) in cross section at the narrowest points, whereas those in crystals of tetraphenylsilane 2 are approximately 6.4 x 6.4 A(2) and 6.4 x 9.0 A(2). These channels provide access to the interior and permit guests to be exchanged quantitatively without loss of crystallinity. Because the Si-C bonds at the core of tetraboronic acid 2 are longer (1.889(3) A) than the C-C bonds at the core of tetraboronic acid 1 (1.519(6) A), the resulting network is expanded rationally. By associating to form robust isostructural networks with predictable architectures and properties of porosity, compounds 1 and 2 underscore the usefulness of molecular tectonics as a strategy for making ordered materials.
authors.affiliation: Département de Chimie, Université de Montréal, Montréal, Québec H3C 3J7 Canada.
authors.forename: Jean-Hugues
authors.initials: JH
authors.lastname: Fournier
authors.forename: Thierry
authors.initials: T
authors.lastname: Maris
authors.forename: James D
authors.initials: JD
authors.lastname: Wuest
authors.forename: Wenzhuo
authors.initials: W
authors.lastname: Guo
authors.forename: Elena
authors.initials: E
authors.lastname: Galoppini