[A method of following analysis for glutaraldehyde preparation].
A GC method for the products in cyclopentene oxidation to form glutaraldehyde in a liquid-liquid phase transfer reactive extraction process, which was a new process, is presented. A model GC-103 gas chromatograph equipped with FID was used. The column is a SS tube(phi 3 mm x 4 m) packed with 13% SE-30 coated on 101 white silanized support and a SS tube(phi 3 mm x 2 m) packed with 9.1% PEG-20M coated on the same support. Operating parameters: column temperature programming, 70 degrees C(4 min), then 10 degrees C/min to 140 degrees C(6 min); injector temperature, 185 degrees C; detector temperature, 185 degrees C; N2, 45 mL/min; H2, 65 mL/min; air, 300 mL/min. By using this method, cyclopentene, intermediates, solvents, glutaraldehyde, and byproducts were separated properly. The yield of glutaraldehyde determined by this method is more reliable than that determined by the chemical method.
Shan
Y
Y
Department of Chemical Engineering, Jiangsu Institute of Petrochemical Technology, Changzhou 213016, China.
Wu
G
G
D002849:Chromatography, Gas / Q000379:methods*; D003517:Cyclopentanes / Q000032:analysis; D005976:Glutaral / Q000032:analysis* / Q000138:chemical synthesis; D010084:Oxidation-Reduction; D012997:Solvents; D013696:Temperature
D003517:Cyclopentanes; D012997:Solvents; D005976:Glutaral