Polyacetylene glycosides from Pratia nummularia cultures.
Two polyacetylene glycosides, lobetyol 9-O-glc(6)-(1)rha (pratialin-A) and lobetyol 9-O-glc(6)-(1)glc(6)-(1)glc (pratialin-B), were isolated from Pratia nummularia (Campanulaceae) callus and hairy root cultures and their chemical structures were determined by analysis of spectroscopic data. From the methanol extract of the hairy root cultures, together with the known polyacetylene constituents lobetyol, lobetyolin, and lobetyolinin, tryptophan was also isolated. This report is the first example of the isolation and structure elucidation of rutinoside (pratialin-A) and triglucoside (pratialin-B) derivatives of polyacetylene constituents.
Ishimaru
Kanji
K
Department of Applied Biological Sciences, Faculty of Agriculture, Saga University, 1 Honjo, Saga 840-8502, Japan. kanji@cc.saga-u.ac.jp
Osabe
Maiko
M
Yan
Li
L
Fujioka
Toshihiro
T
Mihashi
Kunihide
K
Tanaka
Norie
N
D000114:Acetylene / Q000031:analogs & derivatives* / Q000737:chemistry*; D029422:Campanulaceae / Q000737:chemistry*; D004187:Disaccharides / Q000737:chemistry / Q000302:isolation & purification*; D005233:Fatty Alcohols / Q000737:chemistry / Q000302:isolation & purification*; D006027:Glycosides / Q000737:chemistry / Q000302:isolation & purification*; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D018517:Plant Roots / Q000737:chemistry; D011108:Polymers / Q000737:chemistry*; D053279:Polyynes; D013785:Thailand; D014312:Trisaccharides / Q000737:chemistry / Q000302:isolation & purification*
D004187:Disaccharides; D005233:Fatty Alcohols; D006027:Glycosides; D011108:Polymers; D014312:Trisaccharides; C472947:pratialin A; C472949:pratialin B; D053279:Polyynes; D000114:Acetylene