[Quantitative determination of mass ratio of additives in special super-high pressure hydraulic oil].
Two additives, phenol, 2,6-bis(1,1-dimethylethyl)-4-methyl- and triphenyl phosphate with mass ratio of less than one thousandth in special super-high pressure hydraulic oil were determined by GC-MS. Tributyl phosphate ester was used as internal standard. The correction factor of each additive was determined before analysis. Each sample was analysed for 5 times to get good precision. It is satisfactory to use SIM as the detecting mode, and the CVs of correction factors and mass ratio were about 5%. The problems of how to select the monitoring ion in SIM mode and the sample size required are discussed in this paper. This method is satisfactory in analyzing low mass ratio constituents in a mixture.
Luo
H
H
Analytic Center, Tsignhua University, Beijing 100084, China.
Wu
Z P
ZP
Yang
C D
CD
Liu
M X
MX
D002084:Butylated Hydroxytoluene / Q000032:analysis*; D008401:Gas Chromatography-Mass Spectrometry; D010755:Organophosphates / Q000032:analysis*
D010755:Organophosphates; D002084:Butylated Hydroxytoluene; C005445:triphenyl phosphate