Functionalized heteropolyanions: high-valent metal nitrido fragments incorporated into a Keggin polyoxometalate structure.
Three examples of nitrido-functionalized polyoxometalate species are reported, namely (n-Bu4N)4[PW11O39(OsN)] (1), (n-Bu4N)4[PW11O39(ReN)] (2), and (n-Bu4N)3[PW11O39(ReN)] (3), which feature the incorporation of [OsVI identical to N]3+, [ReVI identical to N]3+ and [ReVII identical to N]4+ fragments, respectively, into the framework of a Keggin-type heteropolyanion.
Kwen
Haidoo
H
Department of Chemistry, Kansas State University, Manhattan, Kansas 66506-3701, USA.
Tomlinson
Sean
S
Maatta
Eric A
EA
Dablemont
Céline
C
Thouvenot
René
R
Proust
Anna
A
Gouzerh
Pierre
P