The first observation of four-electron reduction in [60]fullerene-metal cluster self-assembled monolayers (SAMs).
Self-assembled monolayers (SAMs) of a mu 3-eta 2:eta 2:eta 2-C60 triosmium cluster complex Os3(CO)8(CN(CH2)3Si(OEt)3)(mu 3-eta 2:eta 2:eta 2-C60) (2) on ITO or Au surface exhibit ideal, well-defined electrochemical responses and remarkable electrochemical stability being reducible up to tetranionic species in their cyclic voltammograms.
Cho
Youn-Jaung
YJ
Department of Chemistry, School of Molecular Science (BK21), Korea Advanced Institute of Science and Technology, Daejeon 305-701, Korea.
Song
Hyunjoon
H
Lee
Kwangyeol
K
Kim
Kyuwon
K
Kwak
Juhyoun
J
Kim
Sehun
S
Park
Joon T
JT