Correlation of cadmium distribution coefficients to soil characteristics.
Cadmium (Cd) distribution between the soil solid phase and the soil solution is a key issue in assessing the environmental effect of Cd in the terrestrial environmental. Previous studies have shown that many individual minerals and other components found in soils can bind Cd, but most studies on whole soil samples have shown that pH is the main parameter controlling the distribution. To identify further the components that are important for Cd binding in soil we measured Cd distribution coefficients (Kd) at two fixed pH values and at low Cd loadings for 49 soils sampled in Denmark. The Kd values for Cd ranged from 5 to 3000 L kg(-1). The soils were described pedologically and characterized in detail (22 parameters) including determination of contents of the various minerals in the clay fraction. Correlating parameters were grouped and step-wise regression analysis revealed that the organic carbon content was a significant variable at both pH values. Cation exchange capacity (CEC) and gibbsite were important at the low pH (5.3) while iron oxides also were important at the high pH (6.7). None of the other clay minerals present in the soils (illite, smectite, kaolinite, hydroxy interlayered clay minerals [HIM], chlorite, quartz, microcline, plagioclase) were significant in explaining the Cd distribution coefficient.
Holm
Peter E
PE
Chemistry Dep., The Royal Veterinary and Agricultural University, Thorvaldsensvej 40, DK-1871 Frederiksberg C, Copenhagen, Denmark. peho@kvl.dk
Rootzén
Helle
H
Borggaard
Ole K
OK
Møberg
Jens Peter
JP
Christensen
Thomas H
TH
D000327:Adsorption; D000538:Aluminum Silicates; D001682:Biological Availability; D002104:Cadmium / Q000032:analysis / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry; D000077215:Clay; D006863:Hydrogen-Ion Concentration; D007474:Ion Exchange; D012989:Soil Pollutants / Q000032:analysis*
D000538:Aluminum Silicates; D012989:Soil Pollutants; D002104:Cadmium; D002244:Carbon; D000077215:Clay