Studies of visible oscillating chemiluminescence with a luminol-H2O2-KSCN-CuSO4-NaOH system in batch reactor.
Oscillating chemical reactions are complex systems involving a large number of chemical species. In oscillating chemical reactions some species, usually reaction intermediates, exhibit fluctuation in concentration. Visible oscillating chemiluminescence, produced by the addition of luminol (3-aminophthalhydrazide) to the oscillating system H(2)O(2)-KSCN-CuSO(4)-NaOH, was investigated. In this study the effect of varying the concentration of H(2)O(2), KSCN, CuSO(4), NaOH and luminol was investigated in a batch reactor. We showed that the concentration of all components involved in the oscillating chemilumenscent reaction influenced the light intensity and the oscillation period.
Samadi-Maybodi
Abdolraouf
A
Department of Chemistry, Faculty of Basic Science, Mazandaran University, Babolsar, Iran. samadi@umz.ac.ir
Ourad
S M
SM
D019327:Copper Sulfate / Q000737:chemistry*; D004864:Equipment and Supplies; D006861:Hydrogen Peroxide / Q000737:chemistry*; D008163:Luminescent Measurements; D008165:Luminol / Q000737:chemistry*; D009991:Oscillometry; D010507:Periodicity; D012972:Sodium Hydroxide / Q000737:chemistry*; D013861:Thiocyanates / Q000737:chemistry*
D013861:Thiocyanates; D012972:Sodium Hydroxide; D008165:Luminol; D006861:Hydrogen Peroxide; D019327:Copper Sulfate; C009941:potassium thiocyanate