title: Mechanochemical assembly of hydrogen bonded organic-organometallic solid compounds.
abstract: Solvent-free reactions with molecular systems have been exploited to prepare hybrid organic-organometallic solids: grinding of the complex [Fe(eta 5-C5H4COOH)2] with solid bases B generates quantitatively the corresponding hydrogen bonded salts [Fe(eta 5-C5H4COOH)(eta 5-C5H4COO)][HB] (B = 1,4-diazabicyclo[2.2.2]octane, 1,4-phenylenediamine); gas-solid reactions are also possible with volatile bases.
authors.affiliation: Dipartimento di Chimica G. Ciamician, Università di Bologna, Via Selmi 2, 40126 Bologna, Italy. dbraga@ciam.unibo.it
authors.forename: Dario
authors.initials: D
authors.lastname: Braga
authors.forename: Lucia
authors.initials: L
authors.lastname: Maini
authors.forename: Marco
authors.initials: M
authors.lastname: Polito
authors.forename: Laurent
authors.initials: L
authors.lastname: Mirolo
authors.forename: Fabrizia
authors.initials: F
authors.lastname: Grepioni