title: Preparation and reactivity of O2-sulfonated diazeniumdiolates.
abstract: We report the facile preparation of O2-sulfonated diazeniumdiolates and mechanistic investigation of their reactions with representative nucleophiles. This new class of compounds extends the range of O2-substituted diazeniumdiolates available for potential applications in research and medicine.
authors.affiliation: Department of Chemistry, Johns Hopkins University, 3400 North Charles Street, Baltimore, Maryland 21218, USA.
authors.forename: Raechelle A
authors.initials: RA
authors.lastname: D'Sa
authors.forename: Yuhong
authors.initials: Y
authors.lastname: Wang
authors.forename: Patrick H
authors.initials: PH
authors.lastname: Ruane
authors.forename: Brett M
authors.initials: BM
authors.lastname: Showalter
authors.forename: Joseph E
authors.initials: JE
authors.lastname: Saavedra
authors.forename: Keith M
authors.initials: KM
authors.lastname: Davies
authors.forename: Michael L
authors.initials: ML
authors.lastname: Citro
authors.forename: Melissa N
authors.initials: MN
authors.lastname: Booth
authors.forename: Larry K
authors.initials: LK
authors.lastname: Keefer
authors.forename: John P
authors.initials: JP
authors.lastname: Toscano
mesh_terms: D000476:Alkanesulfonates / Q000138:chemical synthesis* / Q000737:chemistry*; D001391:Azo Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D002384:Catalysis; D015394:Molecular Structure; D010100:Oxygen / Q000737:chemistry*; D014105:Tosyl Compounds / Q000737:chemistry
chemical_list: D000476:Alkanesulfonates; D001391:Azo Compounds; D014105:Tosyl Compounds; C452539:diazeniumdiolate; D010100:Oxygen