Synthesis and structure of an asymmetric copper(I) dimer with two-coordinate and four-coordinate copper(I) sites.
An asymmetric copper(I) dimer Cu(1)2(pip)2 [pip = (2-picolyliminomethyl)pyrrole anion] with both two-coordinate and four-coordinate copper(I) sites was synthesized and studied by X-ray diffraction and DFT calculations.
Liao
Yi
Y
Department of Chemistry, University of Utah, Salt Lake City, UT 84112-0850, USA.
Novoa
Juan J
JJ
Arif
Atta
A
Miller
Joel S
JS