[Determination of phthalic diesters in water by solid phase microextraction-capillary gas chromatography].
The solid phase microextraction (SPME) has the advantages of high efficiency, high sensitivity, simple operation and solvent free operation for analyzing environmental samples. An optical fiber coated with mixed stationary phase of polysiloxane and polymeric fullerene (in ratio of 4:1) was used to extract 5 phthalic diesters by HS-SPME-GC. The operating conditions of SPME such as the extraction temperature, ionic strength of solution, adsorption time and desorption time have been studied. It was compared with commercial polymer coating PDMS fiber through headspace SPME combined with GC. The results indicated that OV-1/PSO-C60 was better than PDMS in extracting high boiling point and semi-volatile phthalic diesters. For phthalic diesters, the detection limits were in the range of 0.331 ng/L-12.5 micrograms/L, and relative standard deviations were below 12% except for dinonyl phthalate.
Liu
Z L
ZL
Department of Chemistry, Wuhan University, Wuhan 430072, China.
Xiao
C H
CH
Wu
C Y
CY
Han
H M
HM
D002849:Chromatography, Gas / Q000379:methods; D002851:Chromatography, High Pressure Liquid / Q000379:methods; D003993:Dibutyl Phthalate / Q000032:analysis; D004051:Diethylhexyl Phthalate / Q000032:analysis*; D010795:Phthalic Acids / Q000032:analysis*; D012997:Solvents; D014873:Water Pollutants / Q000032:analysis*
D010795:Phthalic Acids; D012997:Solvents; D014873:Water Pollutants; D003993:Dibutyl Phthalate; C027387:di-n-hexyl phthalate; D004051:Diethylhexyl Phthalate; C007379:diethyl phthalate