title: Charge-transfer band shifts in iron(III) hexacyanoferrate(II) by electro-intercalated cations via ground state-energy/lattice-energy link.
abstract: It is currently important to achieve and understand adjustments of optical properties: "guest cation" induced CT spectral shifts in Prussian Blue are shown to be driven (via its specific effect on the Fe(CN)6 CT-donor entity) by the cation lattice-energy interaction, as inferred from microgravimetry of introduced alkali-metal ions, and from independent solubility correlations for other intercalated cations.
authors.affiliation: Singapore Institute of Mfg. Technology, 71 Nanyang Drive, Singapore 638075. d.r.rosseinsky@ex.ac.uk
authors.forename: David R
authors.initials: DR
authors.lastname: Rosseinsky
authors.forename: Hanyong
authors.initials: H
authors.lastname: Lim
authors.forename: Xiao
authors.initials: X
authors.lastname: Zhang
authors.forename: Hongjin
authors.initials: H
authors.lastname: Jiang
authors.forename: Jian Wei
authors.initials: JW
authors.lastname: Chai