Mechanochemical assembly of hydrogen bonded organic-organometallic solid compounds.
Solvent-free reactions with molecular systems have been exploited to prepare hybrid organic-organometallic solids: grinding of the complex [Fe(eta 5-C5H4COOH)2] with solid bases B generates quantitatively the corresponding hydrogen bonded salts [Fe(eta 5-C5H4COOH)(eta 5-C5H4COO)][HB] (B = 1,4-diazabicyclo[2.2.2]octane, 1,4-phenylenediamine); gas-solid reactions are also possible with volatile bases.
Braga
Dario
D
Dipartimento di Chimica G. Ciamician, Università di Bologna, Via Selmi 2, 40126 Bologna, Italy. dbraga@ciam.unibo.it
Maini
Lucia
L
Polito
Marco
M
Mirolo
Laurent
L
Grepioni
Fabrizia
F