title: Asymmetric synthesis of the putative structure of (-)-oryzoxymycin.
abstract: [reaction: see text] A short asymmetric synthesis of (2'S,5R,6R)-2'-[6-amino-5-hydroxy-1,3-cyclohexadiene-1-carbonyloxy]propionic acid, the enantiomer of the reported structure of (+)-oryzoxymycin is described. The reported spectral data does not match that obtained for synthetic "oryzoxymycin".
authors.affiliation: Department of Chemistry, University of Durham, South Road, Durham DH1 3LE, UK.
authors.forename: Mark E
authors.initials: ME
authors.lastname: Bunnage
authors.forename: Thota
authors.initials: T
authors.lastname: Ganesh
authors.forename: Ishmael B
authors.initials: IB
authors.lastname: Masesane
authors.forename: Darren
authors.initials: D
authors.lastname: Orton
authors.forename: Patrick G
authors.initials: PG
authors.lastname: Steel
mesh_terms: D003509:Cyclohexanecarboxylic Acids / Q000138:chemical synthesis* / Q000737:chemistry*; D053138:Cyclohexenes; D015394:Molecular Structure
chemical_list: D003509:Cyclohexanecarboxylic Acids; D053138:Cyclohexenes; C002624:oryzoxymycin