Preparation and reactivity of O2-sulfonated diazeniumdiolates.
We report the facile preparation of O2-sulfonated diazeniumdiolates and mechanistic investigation of their reactions with representative nucleophiles. This new class of compounds extends the range of O2-substituted diazeniumdiolates available for potential applications in research and medicine.
D'Sa
Raechelle A
RA
Department of Chemistry, Johns Hopkins University, 3400 North Charles Street, Baltimore, Maryland 21218, USA.
Wang
Yuhong
Y
Ruane
Patrick H
PH
Showalter
Brett M
BM
Saavedra
Joseph E
JE
Davies
Keith M
KM
Citro
Michael L
ML
Booth
Melissa N
MN
Keefer
Larry K
LK
Toscano
John P
JP
D000476:Alkanesulfonates / Q000138:chemical synthesis* / Q000737:chemistry*; D001391:Azo Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D002384:Catalysis; D015394:Molecular Structure; D010100:Oxygen / Q000737:chemistry*; D014105:Tosyl Compounds / Q000737:chemistry
D000476:Alkanesulfonates; D001391:Azo Compounds; D014105:Tosyl Compounds; C452539:diazeniumdiolate; D010100:Oxygen