title: Phosphonoacetic acid as a building block in supramolecular chemistry: salts with organic polyamines.
abstract: Phosphonoacetic acid, (HO)(2)P(O)CH(2)COOH, forms adducts with a range of amines. The acid component in these adducts may be the neutral molecule C(2)H(5)O(5)P, the mono-anion (C(2)H(4)O(5)P)(-) or the di-anion (C(2)H(3)O(5)P)(2-). The substructure formed by the acid component takes the form of simple chains in compounds (1)-(3), which are the 1:1 adducts formed with 1,4-diazabicyclo[2.2.2]octane, 4,4'-bipyridyl and 1,3-trimethylenedipiperidine, respectively. These adducts contain C(2)H(5)O(5)P, (C(2)H(4)O(5)P)(-) and (C(2)H(3)O(5)P)(2-), respectively, although (3) is solvated by a mixture of methanol and water. The (C(2)H(4)O(5)P)(-) anion substructure in (4), which is the adduct formed with meso-5,5,7,12,12,14-hexa-C-methyl-1,4,8,11-tetraazacyclotetradecane, is a chain of spiro-fused rings, while the substructure in (5), which is the adduct formed with 2,2'-dipyridylamine, is a chain of edge-fused rings. In (6), the adduct formed with 1,2-bis(4'-pyridyl)ethane, the anion substructure is two-dimensional. The chain substructures are linked by the amine units into two-dimensional structures in (1) and (4) and into three-dimensional frameworks in (2), (3) and (5), while the anion sheets in (6) are likewise linked by the amine units into a three-dimensional framework.
authors.affiliation: School of Chemistry, University of St Andrews, St Andrews, Fife KY16 9ST, UK.
authors.forename: Katharine F
authors.initials: KF
authors.lastname: Bowes
authors.forename: George
authors.initials: G
authors.lastname: Ferguson
authors.forename: Alan J
authors.initials: AJ
authors.lastname: Lough
authors.forename: Choudhury M
authors.initials: CM
authors.lastname: Zakaria
authors.forename: Christopher
authors.initials: C
authors.lastname: Glidewell