title: Selective and shape-selective Baeyer-Villiger oxidations of aromatic aldehydes and cyclic ketones with Sn-beta zeolites and H2O2.
abstract: Sn-Beta is used as a heterogeneous catalyst for the Baeyer-Villiger reaction with hydrogen peroxide. Cyclic ketones are transformed into the corresponding lactones, while unsaturated ketones are oxidized to the corresponding unsaturated lactones with very high chemoselectivity. The catalyst is also selective for the oxidation of aromatic aldehydes with H2O2, producing the formate ester or the corresponding hydrolyzed product, that is the alcohol. Shape-selective oxidations are observed for isomeric reactants with different molecular shapes. The catalytic Sn sites have been characterized by 119Sn MAS-NMR spectroscopy, and tetrahedral incorporation into the zeolite framework has been demonstrated. In situ IR spectroscopy and 18O labeling experiments have shown that the oxidation mechanism involves an intermediate of the Criegee type.
authors.affiliation: Instituto de Tecnología Química, UPV-CSIC Universidad Politécnica de Valencia Avenida de los Naranjos s/n, 46022 Valencia, Spain.
authors.forename: Michael
authors.initials: M
authors.lastname: Renz
authors.forename: Teresa
authors.initials: T
authors.lastname: Blasco
authors.forename: Avelino
authors.initials: A
authors.lastname: Corma
authors.forename: Vicente
authors.initials: V
authors.lastname: Fornés
authors.forename: Robert
authors.initials: R
authors.lastname: Jensen
authors.forename: Laszlo
authors.initials: L
authors.lastname: Nemeth