title: The first structurally characterized aluminum compound with two SH groups: [LAl(SH)(2)] (L = N(Ar)C(Me)CHC(Me)N(Ar), Ar = 2,6-i-Pr(2)C(6)H(3)) and the catalytic properties of the sulfur P(NMe(2))(3) system.
abstract: Surprisingly stable is the bis(hydrogen sulfide) of aluminum LAl(SH)(2) with two terminal arranged SH groups. The insertion of sulfur into the Al-H bonds is catalyzed by SP(NMe(2))(3). A possible mechanism is discussed.
authors.affiliation: Institute of Inorganic Chemistry, University of Goettingen, Tammannstrasse 4, D-37077 Goettingen, Germany.
authors.forename: Vojtech
authors.initials: V
authors.lastname: Jancik
authors.forename: Ying
authors.initials: Y
authors.lastname: Peng
authors.forename: Herbert W
authors.initials: HW
authors.lastname: Roesky
authors.forename: Jiyang
authors.initials: J
authors.lastname: Li
authors.forename: Dante
authors.initials: D
authors.lastname: Neculai
authors.forename: Ana M
authors.initials: AM
authors.lastname: Neculai
authors.forename: Regine
authors.initials: R
authors.lastname: Herbst-Irmer