Identification of new homoterpene esters from Dufour's gland of the ponerine ant Gnamptogenys striatula.
Extracts of Dufour's gland of the ponerine ant, Gnamptogenys striatula, were analyzed by using the combination of gas chromatography and mass spectrometry. Series of esters of the new homoterpenoids (2E,6)-3,4,7-trimethyl-2,6-octadiene-1-ol (4-methylgeraniol) and (2E,6)-3,4,7-trimethyl-2,6-nonadiene-1-ol (bishomogeraniol) with unbranched medium-chain fatty acids were identified. Transformation of the chiral natural products into 1,4-di (trifluoroacetoxy)-3-methylpentane and comparison of its gas chromatographic retention time on a modified cyclodextrin phase with that of synthetic optically active reference samples proved the stereogenic center to keep (S)-configuration. (2E,4S,6)-3,4,7-Trimethyl-2,6-octadien-1-yl decanoate and the corresponding dodecanoate are the main volatiles in the extracts.
Schulz
Claudia M
CM
Institut für Organische Chemie, Universität Hamburg, Martin-Luther-King-Platz 6, D-20146 Hamburg, Germany.
Lehmann
Lutz
L
Blatrix
Rumsaïs
R
Jaisson
Pierre
P
Hefetz
Abraham
A
Francke
Wittko
W
D000818:Animals; D001000:Ants / Q000737:chemistry*; D004952:Esters; D005088:Exocrine Glands / Q000737:chemistry; D008401:Gas Chromatography-Mass Spectrometry; D013729:Terpenes / Q000737:chemistry* / Q000302:isolation & purification
D004952:Esters; D013729:Terpenes