Mechanistic studies on ethylene silylation with chlorosilanes catalysed by ruthenium complexes.
Silylation of ethylene by chlorosilanes is catalysed by ruthenium complexes. Mechanistic investigations reveal the presence of a complicated network of reactions leading to new sigma-silane, ethylene and silyl complexes.
Lachaize
Sébastien
S
Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 04, France.
Sabo-Etienne
Sylviane
S
Donnadieu
Bruno
B
Chaudret
Bruno
B