Germanium-rich pentaruthenium carbonyl clusters including Ru(5)(CO)(11)(mu-GePh(2))(4)(mu(5)-C) and its reactions with hydrogen.
The reaction of Ru(5)(CO)(15)(mu(5)-C), 1, with Ph(3)GeH at 150 degrees C has yielded two new germanium-rich pentaruthenium cluster complexes: Ru(5)(CO)(11)(mu-CO)(mu-GePh(2))(3)(mu(5)-C), 2; Ru(5)(CO)(11)(mu;-GePh(2))(4)(mu(5)-C), 3. Both compounds contain square pyramidal Ru(5) clusters with GePh(2) groups bridging three and four of the edges of the Ru(5) square base, respectively. When treated with 1 equiv of Ph(3)GeH at 150 degrees C compound 2 is converted to 3. Reaction of 3 with H(2) at 150 degrees C yielded Ru(5)(CO)(10)(mu-GePh(2))(4)(mu(5)-C)(mu-H)(2), 4, containing two hydride ligands and one less CO ligand. Reaction of 4 with hydrogen at 150 degrees C yielded the compound Ru(5)(CO)(10)(mu-GePh(2))(2)(mu(3)-GePh)(2)(mu(3)-H)(mu(4)-CH), 5, by loss of benzene and conversion of two of the bridging GePh(2) groups into triply bridging GePh groups. Compound 5 contains one triply bridging hydride ligand and a quadruply bridging methylidyne ligand formed by addition of one hydrogen atom to the carbido carbon atom.
Adams
Richard D
RD
Department of Chemistry and Biochemistry and USC NanoCenter, University of South Carolina, Columbia, South Carolina 29208, USA.
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