title: Chemical characterization of sanding dust and methylene chloride usage in automotive refinishing: implications for occupational and environmental health.
abstract: Surface preparation activities conducted during automotive refinishing present several potential human health and environmental risks. This study examines the chemical composition of vehicle sanding dust and the prevalence of methylene chloride use as a basis for evaluating potential chemical exposures in the work environment, fugitive environmental releases, and take-home toxics. This article reports on the findings of (1) a statewide technology and work practices survey of 353 licensed auto body shops and (2) laboratory analyses of sanding dust representing more than 200 vehicles, 10 commercial body filler compounds, and work shirts worn during vehicle sanding while using nonventilated equipment. Survey data revealed that the majority of shops (78%) do not use ventilated sanding equipment, that most workers (55%) take their work clothes and shoes home at the end of the workday, and that 17% of the respondents used a methylene chloride-based paint stripper as an adjunct to mechanical sanding. Laboratory results showed that Pb, As, Cr, Mn, and Ni were present in the sanding dust at every facility tested. Lead concentrations in sanding dust were found to be highest at facilities that performed complete vehicle refinishing (range 770 to 7300 ppm) and at a collision repair shop that used a high-lead content body filler compound (1800 ppm). Hexavalent chromium also was found in two vocational high school paint dust samples at concentrations of 54 and 710 ppm. When total lead and chromium concentrations reached 7300 and 2300 ppm, respectively, facility sanding dust samples failed the U.S. Environmental Protection Agency's Toxicity Characteristic Leaching Procedure for hazardous waste. Metals found in the sanding dust also were present on the work shirts of technicians-ranging from 0.06 (Cd) to 81 (Mg) microg/inch2 of cloth-who sanded on paint without ventilated equipment. Results suggest that sanding dust and methylene chloride paint strippers used in vehicle resurfacing operations pose a potential hazard to human health and the environment.
authors.affiliation: Rhode Island Department of Environmental Management, Office of Technical and Customer Assistance, Pollution Prevention Program, 235 Promenade St., Providence, RI 02908-5767, USA. renander@dem.state.ri.us
authors.forename: Richard T
authors.initials: RT
authors.lastname: Enander
authors.forename: David M
authors.initials: DM
authors.lastname: Gute
authors.forename: Howard J
authors.initials: HJ
authors.lastname: Cohen
authors.forename: Linfield C
authors.initials: LC
authors.lastname: Brown
authors.forename: Anne Marie C
authors.initials: AM
authors.lastname: Desmaris
authors.forename: Richard
authors.initials: R
authors.lastname: Missaghian
mesh_terms: D001336:Automobiles; D003020:Clothing; D004391:Dust / Q000032:analysis*; D006256:Hazardous Waste / Q000032:analysis; D006801:Humans; D008670:Metals / Q000032:analysis; D008752:Methylene Chloride / Q000737:chemistry*; D016273:Occupational Exposure; D012237:Rhode Island; D011795:Surveys and Questionnaires; D014481:United States; D014484:United States Environmental Protection Agency; D014835:Volatilization
chemical_list: D004391:Dust; D006256:Hazardous Waste; D008670:Metals; D008752:Methylene Chloride