[Glucosides from Pleurospermum rivulorum].
OBJECTIVE
To study the chemical constituents of Pleurospermum rivulorum.


METHODS
To separate the constituents of P. rivulorum by using various kinds of chromatography and identify their structures on the basis of spectral analysis.


RESULTS
Four glucosides were isolated from P. rivulorum. Their structures were established as marmesinin (I), tert-O-beta-D-glucopyranosyl-heraclenol (II), 1'-O-beta-D-glucopyranosyl (2R, 3S)-3-hydroxynodakenetin (III) and 8-hydroxy-5-O-beta-D-glucopyranosyl-psoralen (IV) based on the analysis of spectral data of IR, UV, MS, 1D and 2D-NMR.


CONCLUSIONS
Compounds III and IV are new compounds. All of the four compounds were isolated from this plant for the first time.
Xiao
Y Q
YQ
Institute of Chinese Materia Medica, China Academy of Traditional Chinese Medicine, Beijing 100700, China.
Li
L
L
Masahiko
T
T
Kimiye
B
B
D019661:Apiaceae / Q000737:chemistry*; D011564:Furocoumarins / Q000737:chemistry / Q000302:isolation & purification*; D005960:Glucosides / Q000737:chemistry / Q000302:isolation & purification*; D015394:Molecular Structure; D018517:Plant Roots / Q000737:chemistry; D010946:Plants, Medicinal / Q000737:chemistry*
C481918:1'-O-glucopyranosyl 3-hydroxynodakenetin; C481919:8-hydroxy-5-O-glucopyranosylpsoralen; D011564:Furocoumarins; D005960:Glucosides