title: Hydrodynamic study of ion transfer at the liquid/liquid interface: the channel flow cell.
abstract: A hydrodynamic system based on the channel flow cell for voltammetric detection of ions at the liquid/liquid interface is reported. The current response for tetraethylammonium ion transfer across a membrane-supported liquid/liquid interface is shown to be consistent with existing theory for both the flow rate and voltage scan rate dependence of such processes, with no calibration factors or other adjustable parameters required. The analytical utility of such a device is discussed with specific regard to in situ measurements in flow systems.
authors.affiliation: Department of Chemistry, University of Manchester Institute of Science and Technology, PO Box 88, Sackville Street, Manchester M60 1QD, United Kingdom.
authors.forename: Simon S
authors.initials: SS
authors.lastname: Hill
authors.forename: Robert A W
authors.initials: RA
authors.lastname: Dryfe
authors.forename: Edward P L
authors.initials: EP
authors.lastname: Roberts
authors.forename: Adrian C
authors.initials: AC
authors.lastname: Fisher
authors.forename: Kamran
authors.initials: K
authors.lastname: Yunus
mesh_terms: D003956:Dialysis; D004563:Electrochemistry / Q000295:instrumentation / Q000379:methods; D007477:Ions / Q000737:chemistry*; D008567:Membranes, Artificial; D012212:Rheology
chemical_list: D007477:Ions; D008567:Membranes, Artificial