title: Application of single-drop microextraction and comparison with solid-phase microextraction and solid-phase extraction for the determination of alpha- and beta-endosulfan in water samples by gas chromatography-electron-capture detection.
abstract: Water contamination due to the wide variety of pesticides used in agriculture practices is a global environmental pollution problem. The 98/83 European Directive requires the measurement of pesticides residues at a target concentration of 1.0 microg/l in surface water and 0.1 microg/l in drinking water. In order to reach the level of detection required, efficient extraction techniques are necessary. The application of a new extraction technique: single-drop microextraction (SDME), followed by gas chromatography with electron-capture detection, was assessed for determining alpha-endosulfan and beta-endosulfan in water samples. Experimental parameters which control the performance of SDME, such as selection of microextraction solvent and internal standard, optimization of organic drop volume, effects of sample stirring, temperature and salt addition, and sorption time profiles were studied. Once SDME was optimized, analytical parameters such as linearity, precision, detection and quantitation limits, plus matrix effects were evaluated. The SDME method was compared with solid-phase microextraction and solid-phase extraction with the aim of selecting the most appropriate method for a certain application.
authors.affiliation: Nutrition and Bromatology Group, Analytical and Food Chemistry Department, Faculty of Food Science and Technology, University of Vigo, Ourense Campus, E-32004 Ourense, Spain.
authors.forename: M C
authors.initials: MC
authors.lastname: López-Blanco
authors.forename: S
authors.initials: S
authors.lastname: Blanco-Cid
authors.forename: B
authors.initials: B
authors.lastname: Cancho-Grande
authors.forename: J
authors.initials: J
authors.lastname: Simal-Gándara
mesh_terms: D002849:Chromatography, Gas / Q000379:methods*; D004726:Endosulfan / Q000032:analysis*; D006843:Hydrocarbons, Chlorinated; D007306:Insecticides / Q000032:analysis*; D015203:Reproducibility of Results; D012680:Sensitivity and Specificity; D012965:Sodium Chloride; D013696:Temperature; D014874:Water Pollutants, Chemical / Q000032:analysis*
chemical_list: D006843:Hydrocarbons, Chlorinated; D007306:Insecticides; D014874:Water Pollutants, Chemical; D012965:Sodium Chloride; D004726:Endosulfan