title: Highly regioselective functionalization of aliphatic carbon-hydrogen bonds with a perbromohomoscorpionate copper(I) catalyst.
abstract: The complex Tp(Br3)Cu(NCMe) (1) is an excellent catalyst for the regioselective carbene transfer reaction to tertiary C-H bonds of hydrocarbons, at room temperature, using the readily available ethyl diazoacetate (EDA) as the carbene source.
authors.affiliation: Departamento de Química y Ciencia de Materiales, Universidad de Huelva, Campus de El Carmen, 21071-Huelva, Spain.
authors.forename: Ana
authors.initials: A
authors.lastname: Caballero
authors.forename: M Mar
authors.initials: MM
authors.lastname: Díaz-Requejo
authors.forename: Tomás R
authors.initials: TR
authors.lastname: Belderraín
authors.forename: M Carmen
authors.initials: MC
authors.lastname: Nicasio
authors.forename: Swiatoslaw
authors.initials: S
authors.lastname: Trofimenko
authors.forename: Pedro J
authors.initials: PJ
authors.lastname: Pérez