Unexpected isolation, and structural characterization, of a beta-hydrogen-containing sigma-alkylpalladium halide complex in the course of an intramolecular heck reaction. synthesis of polycyclic isoquinoline derivatives.
The isolation of a stable beta-hydrogen-containing R-PdLn-X complex (R = alkyl; X = halide) issued from a Heck reaction is reported together with some aspects of its reactivity.
Clique
Blandine
B
Laboratoire de Chimie Organique 1, CNRS UMR 5622, Université Claude Bernard, Lyon I, CPE. 43, Bd du 11 Noviembre 1918, 69622 Villeurbanne, France.
Fabritius
Charles-Henry
CH
Couturier
Cédric
C
Monteiro
Nuno
N
Balme
Geneviève
G