A new metal-organic open framework consisting of threefold parallel interwoven (6,3) nets.
Threefold parallel interwoven (6,3) nets were assembled from Ni(II) cyclam complex and 1,3,5-tris[2-(4-carboxyphenyl)-1-ethynyl]benzene. The network generates triangular voids of effective size ca. 18.4 x 14.7 x 9.5 A. It contains 35% free volume of the crystal volume and is stable up to 300 degrees C.
Suh
Myunghyun Paik
MP
School of Chemistry and Molecular Engineering, Center for Molecular Catalysis, Seoul National University, Seoul 151-747, Republic of Korea. mpsuh@plaza.snu.ac.kr
Choi
Hye Jin
HJ
So
Soon Mog
SM
Kim
B Moon
BM