title: Synthesis and characterization of the monomeric imides Ar'MNAr' ' (M = Ga or In; Ar' or Ar' ' = terphenyl ligands) with two-coordinate gallium and indium.
abstract: Reaction of Ar'MMAr' (M = Ga or In) with N3Ar' ' (Ar' = C6H3-2,6-Dipp2, Dipp = C6H3-2,6-Pri2, Ar' ' = C6H3-2,6(Xyl-4-But)2) afforded the first monomeric imides of heavier group 13 elements with two-coordinate metals. Planar, trans-bent structures with short M-N bond distances were observed, which are consistent with lone pair character at both M and N and a bond order less than the formally expected triple one.
authors.affiliation: Department of Chemistry, University of California, Davis, One Shields Avenue, Davis, California 95616, USA.
authors.forename: Robert J
authors.initials: RJ
authors.lastname: Wright
authors.forename: Andrew D
authors.initials: AD
authors.lastname: Phillips
authors.forename: Thomas L
authors.initials: TL
authors.lastname: Allen
authors.forename: William H
authors.initials: WH
authors.lastname: Fink
authors.forename: Philip P
authors.initials: PP
authors.lastname: Power