title: Unexpected isolation, and structural characterization, of a beta-hydrogen-containing sigma-alkylpalladium halide complex in the course of an intramolecular heck reaction. synthesis of polycyclic isoquinoline derivatives.
abstract: The isolation of a stable beta-hydrogen-containing R-PdLn-X complex (R = alkyl; X = halide) issued from a Heck reaction is reported together with some aspects of its reactivity.
authors.affiliation: Laboratoire de Chimie Organique 1, CNRS UMR 5622, Université Claude Bernard, Lyon I, CPE. 43, Bd du 11 Noviembre 1918, 69622 Villeurbanne, France.
authors.forename: Blandine
authors.initials: B
authors.lastname: Clique
authors.forename: Charles-Henry
authors.initials: CH
authors.lastname: Fabritius
authors.forename: Cédric
authors.initials: C
authors.lastname: Couturier
authors.forename: Nuno
authors.initials: N
authors.lastname: Monteiro
authors.forename: Geneviève
authors.initials: G
authors.lastname: Balme