title: Speciation of mercury in soil and sediment by selective solvent and acid extraction.
abstract: In order to characterize the mercury hazard in soil, a sequential extraction scheme has been developed to classify mercury species based on their environmental mobility and/or toxicity for either routine lab analysis or on-site screening purposes. The alkyl mercury species and soluble inorganic species that contribute to the major portion of potential mercury toxicity in the soil are extracted by an acidic ethanol solution (2% HCl+10% ethanol solution) from soil matrices as "mobile and toxic" species. A High-Performance Liquid Chromatography (HPLC) system coupled with Inductively Coupled Plasma Mass Spectrometry (ICP-MS) detection has been developed to further resolve the species information into soluble inorganic species (Hg(2+)), methylmercury(II) (MeHg(+)) and ethylmercury(II) (EtHg(+)) species. Alternatively, these species can be separated into "soluble inorganic mercury" and "alkyl mercury" sub-categories by Solid-Phase Extraction (SPE). A custom Sulfydryl Cotton Fiber (SCF) material is used as the solid phase medium. Optimization of the SCF SPE technique is discussed. Combined with a direct mercury analyzer (DMA-80), the SCF SPE technique is a promising candidate for on-site screening purposes. Following the ethanol extraction, the inorganic mercury species remaining in soil are further divided into "semi-mobile" and "non-mobile" sub-categories by sequential acid extractions. The "semi-mobile" mercury species include mainly elemental mercury (Hg) and mercury-metal amalgams. The non-mobile mercury species mainly include mercuric sulfide (HgS) and mercurous chloride (Hg(2)Cl(2)).
authors.affiliation: Metara Inc., 1225 East Arques Ave, Sunnyvale, CA 94085, USA. yehan@metarainc.com
authors.forename: Y
authors.initials: Y
authors.lastname: Han
authors.forename: H M
authors.initials: HM
authors.lastname: Kingston
authors.forename: H M
authors.initials: HM
authors.lastname: Boylan
authors.forename: G M M
authors.initials: GM
authors.lastname: Rahman
authors.forename: S
authors.initials: S
authors.lastname: Shah
authors.forename: R C
authors.initials: RC
authors.lastname: Richter
authors.forename: D D
authors.initials: DD
authors.lastname: Link
authors.forename: S
authors.initials: S
authors.lastname: Bhandari
mesh_terms: D005591:Chemical Fractionation / Q000379:methods; D002851:Chromatography, High Pressure Liquid; D019015:Geologic Sediments / Q000032:analysis; D006851:Hydrochloric Acid; D008628:Mercury / Q000032:analysis / Q000737:chemistry* / Q000302:isolation & purification*; D017942:Nitric Acid; D012987:Soil / Q000032:analysis*; D012989:Soil Pollutants / Q000032:analysis / Q000302:isolation & purification; D012997:Solvents
chemical_list: D012987:Soil; D012989:Soil Pollutants; D012997:Solvents; D017942:Nitric Acid; D008628:Mercury; D006851:Hydrochloric Acid