Adsorption of nickel(II) from aqueous solution onto activated carbon prepared from almond husk.
Activated carbon was prepared from almond husk by activating without (MAC-I) and with (MAC-II) H(2)SO(4) at different temperatures. The ability of the activated carbon to remove nickel(II) ions from aqueous solutions by adsorption has been investigated under several conditions such as pH, carbonisation temperature of husk, initial concentration of metal ions, contact time, and adsorbent concentration. Optimal conditions were pH 5.0, the carbonisation temperature of 700 degrees C, 50 min of contact time and adsorbent concentration of 5 g/l. The results indicate that the effective uptake of Ni(II) ions was obtained by activating the carbon, prepared from almond husk at 700 degrees C, through the addition of H(2)SO(4). The removal of Ni(II) were found to be 97.8% at initial concentration of 25mg/l and the adsorbent concentration of 5 g/l. When the adsorbent concentration was increased up to 40 g/l, the adsorption density decreased from 4.89 to 0.616 mg/g for MAC-II. In the isotherm studies, the experimental adsorption data fitted reasonably well the Langmuir isotherm for both MAC-I and MAC-II.
Hasar
Halil
H
Department of Environmental Engineering, Faculty of Engineering, Firat University, 23119, Elazig, Turkey. hhasar@firat.edu.tr
D000327:Adsorption; D001673:Biodegradation, Environmental; D002244:Carbon / Q000737:chemistry*; D004736:Energy-Generating Resources; D004787:Environmental Pollution / Q000517:prevention & control; D006863:Hydrogen-Ion Concentration; D007220:Industrial Waste; D008669:Metallurgy; D009532:Nickel / Q000737:chemistry*; D027861:Prunus; D012639:Seeds; D013696:Temperature
D007220:Industrial Waste; D002244:Carbon; D009532:Nickel