Synthesis of tripodal [2]rotaxanes: high concentration principlet.
Symmetrical and non-symmetrical tripodal [2]rotaxanes (1) incorporating 1,1'-disubstituted-4,4'-bipyridinium cations (2) and 34-crown-10 (3) have been prepared directly from 4,4'-bipyridine or from monocationic intermediates in high yields at room temperature and atmospheric pressure under conditions that permit the use of high reagent concentrations (0.1-0.2 M, 150-200 g(-1)).
Nikitin
Kirill
K
Department of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland.
Long
Brenda
B
Fitzmaurice
Donald
D