Application of an isothermal, three-phase catalytic reactor model to predict unsteady-state fixed-bed performance.
CatReac, a three-phase catalytic mathematical model, was developed for analysis and optimization of the volatile reactor assembly used in International Space Station water processor. This wet oxidation process is used to remove low molecular weight contaminants such as acetic acid, acetone, ethanol, 1-propanol, 2-propanol, and propionic acid, which are not removed by the other treatment processes. The Langmuir-Hinshelwood (Hinshelwood, C. N. The Kinetics of Chemical Change in Gaseous Systems, 3rd ed.; Oxford: London, 1933; pp 301-347) isothermal adsorption expression was successfully used to describe the reaction kinetics of compounds on the catalyst surface for the compounds mentioned above. Small-column experiments combined with the use of the Arrhenius equation were successfully used to predict the Langmuir-Hinshelwood parameters under different temperatures for a temperature range from 93 to 149 degrees C. Full-scale and small-column experiments were successfully used to validate the model predictions for unsteady-state fixed-bed operations.
Yang
Ji
J
Department of Civil and Environmental Engineering, Michigan Technological University, 1400 Townsend Drive, Houghton, Michigan 49931, USA.
Hand
David W
DW
Hokanson
David R
DR
Crittenden
John C
JC
D002384:Catalysis; D003247:Conservation of Natural Resources; D005544:Forecasting; D008962:Models, Theoretical; D010084:Oxidation-Reduction; D018531:Spacecraft; D013696:Temperature; D014835:Volatilization; D018508:Water Purification / Q000379:methods*; D014881:Water Supply