Oxidative heck-type reaction involving cleavage of a carbon-phosphorus bond of arylphosphonic acids.
Cleavage of a carbon-phosphorus bond is achieved under palladium catalysis in an oxidative Heck-type reaction which exploits arylphosphonic acids. The reaction of arylphosphonic acids with alkenes provides arylation products in good yields in the presence of TBAF with trimethylamine oxide as an oxidant.
Inoue
Atsushi
A
Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 606-8501, Japan.
Shinokubo
Hiroshi
H
Oshima
Koichiro
K