[Corrosion rate measurements of biomedical TiNi shape memory alloy and cobalt alloys].
The corrosion rates of TiNi, CoCrNiW and CoCrNiMo were measured in Tyrode's solution with potentiodynamic linear polarization, fore-point weak polarization, Cao Chunan weak polarization, transient linear polarization and atomic absorption spectroscopy. Results indicated that corrosion rates of these three alloys were very low due to their excellent corrosion resistance and the corrosion resistance of CoCrNiMo was the best. Corrosion rates of TiNi, CoCrNiW and CoCrNiMo were 0.691, 0.0595, 0.0490 micron/a and 0.0528, 0.0383, 0.0387 micron/a, respectively. The results measured by the first three methods were about ten times of those by the latter two methods, this was related to the applicability of each method and the alloy surface state. Transient linear polarization technique can determine low corrosion rate conveniently and quickly. Atomic absorption spectroscopy method, determining directly the concentration of ion in solution, and thus provide reference for material biocompatibility. And these two methods are properly used in measuring corrosion rates for biomedical materials.
Guo
Haixia
H
Dalian University of Technology, School of Chemical Engineering, Dalian 116012.
Liang
Chenghao
C
D001672:Biocompatible Materials / Q000737:chemistry*; D003035:Cobalt / Q000737:chemistry*; D003343:Corrosion; D008422:Materials Testing / Q000379:methods*; D009532:Nickel / Q000737:chemistry*; D013054:Spectrophotometry, Atomic; D014025:Titanium / Q000737:chemistry*
D001672:Biocompatible Materials; C093972:titanium-nickel-cobalt alloy; D003035:Cobalt; D009532:Nickel; D014025:Titanium