Dioxygen activation by a dinuclear nickel thiolate complex: structural characterization of the ligand oxidized product.
A (mu-SR)2-nickel(II) dimer derived from a ligand with carboxamido nitrogen and thiolato sulfur donors reacts with O2 to afford an oxidized product in which phenyl groups of the ligand frames are oxidized to nickel-bound phenolates.
Harrop
Todd C
TC
Department of Chemistry and Biochemistry, University of California, Santa Cruz, CA 95064, USA.
Olmstead
Marilyn M
MM
Mascharak
Pradip K
PK
D018360:Crystallography, X-Ray; D019281:Dimerization; D008024:Ligands; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*
D008024:Ligands; D009942:Organometallic Compounds; D009532:Nickel; D010100:Oxygen