UV/Vis, IR and 1H NMR spectroscopic studies of bisazo-dianil compounds based on 5-(2-carboxyphenyl azo)-salicylaldehyde and primary diamines.
The electronic absorption and emission spectra of the titled biazo-dianils are studied in organic solvents of different polarity as well as in aqueous buffer solutions of varying pH. The important bands in the IR spectra as well as the main signals of the 1H NMR spectra are assigned. The observed UV/Vis absorption bands are assigned to the corresponding electronic transitions. The fluorescence quantum yield and pK(a)(-) values in the ground and excited states are determined.
Issa
Raafat M
RM
Chemistry Department, Faculty of Science, Tanta University, Tanta, Egypt.
El-Daly
Samy A
SA
El-Wakiel
Nadia A
NA
D000447:Aldehydes / Q000032:analysis* / Q000737:chemistry; D001391:Azo Compounds / Q000032:analysis* / Q000737:chemistry; D004396:Coloring Agents / Q000737:chemistry; D003959:Diamines / Q000032:analysis*; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D008956:Models, Chemical; D013050:Spectrometry, Fluorescence; D013053:Spectrophotometry / Q000379:methods; D013055:Spectrophotometry, Infrared / Q000379:methods*; D014466:Ultraviolet Rays
C479532:5-(2-carboxyphenyl azo)-salicylaldehyde; D000447:Aldehydes; D001391:Azo Compounds; D004396:Coloring Agents; D003959:Diamines; C013243:salicylaldehyde