title: Electrocatalytic oxidation of formic acid at an ordered intermetallic PtBi surface.
abstract: The electrocatalytic oxidation of formic acid at a PtBi ordered intermetallic electrode surface has been investigated using cyclic voltammetry, rotating disk electrode (RDE) voltammetry and differential electrochemical mass spectrometry (DEMS). The results are compared to those at a polycrystalline platinum electrode surface. The PtBi electrode exhibits superior properties when compared to polycrystalline platinum in terms of oxidation onset potential, current density, and a much diminished poisoning effect by CO. Using the RDE technique, a value of 1.4 x 10(-4) cm s-1 was obtained for the heterogeneous charge transfer rate constant. The PtBi surface did not appear to be poisoned when exposed to a CO saturated solution for periods exceeding 0.5 h. The results for PtBi are discussed within the framework of the dual-path mechanism for the electrocatalytic oxidation of formic acid, which involves formation of a reactive intermediate and a poisoning pathway.
authors.affiliation: Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, NY 14853-1301, USA.
authors.forename: Emerilis
authors.initials: E
authors.lastname: Casado-Rivera
authors.forename: Zoltán
authors.initials: Z
authors.lastname: Gál
authors.forename: A C D
authors.initials: AC
authors.lastname: Angelo
authors.forename: Cora
authors.initials: C
authors.lastname: Lind
authors.forename: Francis J
authors.initials: FJ
authors.lastname: DiSalvo
authors.forename: Héctor D
authors.initials: HD
authors.lastname: Abruña