The homogeneity of heavy metal deposition on glass fibre filters collected using a high-volume sampler in the vicinity of an opencast chrome mine complex at Kemi, Northern Finland.
The homogeneity of heavy metal (Cr, Ni, Cu, Fe and Cd) distribution on glass fibre filters (Munktell MG 160, 203 x 254 mm, 75 g m(-2)) collected using a high-volume sampler (Wedding & Associates) at an opencast chrome mine complex at Kemi, Northern Finland was studied. The heavy metals in the total suspended particulate (TSP) material were analysed by inductively coupled plasma atomic emission spectrometry (ICP-AES) or graphite furnace atomic absorption spectrometry (GFAAS). The glass fibre filters were digested in a microwave oven using a mixture of aqua regia+HF acids. There was significant non-uniform distribution of heavy metals on glass fibre filters. The TSP material containing chromite was very difficult to dissolve by acid digestion. The results from X-ray fluorescence spectrometry (XRF), and from energy filtering transmission electron microscope (EFTEM) equipped with energy dispersive X-ray spectrometer (EDS), showed that insoluble residue left after microwave oven digestion with aqua regia+HF acids was probably partly due to chemical reactions occurring during microwave heating.
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Meri-Lappi Institute, Centre for Environmental Technology, University of Oulu, Tietokatu 6, 94600, Kemi, Finland. risto.poykio@kemi.fi
Perämäki
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Rönkkömäki
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D000393:Air Pollutants / Q000032:analysis; D002857:Chromium / Q000032:analysis; D004784:Environmental Monitoring / Q000379:methods*; D005374:Filtration; D005387:Finland; D005898:Glass; D007220:Industrial Waste / Q000032:analysis; D019216:Metals, Heavy / Q000032:analysis*; D013052:Spectrometry, X-Ray Emission; D013057:Spectrum Analysis
D000393:Air Pollutants; D007220:Industrial Waste; D019216:Metals, Heavy; C009753:fiberglass; D002857:Chromium