title: Investigation on downwind short-range transport of pesticides after application in agricultural crops.
abstract: For the assessment of potential risks from total exposure to both spray drift and volatilised pesticides, field experiments in barley were carried out with insecticide application in May and June 2000. Pesticide concentrations in the air at the edge of the treated plot and at various distances in downwind direction were determined. The concentrations at 10 m distance were 0.29 and 0.58 microg/m(3) (lindane), 0.07 and 0.12 microg/m(3) (parathion) or <0.02 and 0.04 microg/m(3) (pirimicarb) after 1 d. To quantify the exposure of aquatic ecosystems, water containers simulating surface waters were placed in downwind direction of the plot at distances of 10 and 50 m. Lindane as the most volatile and most persistent of the investigated active substances showed the highest entries in surface water with 35 and 153 microg/m(2) after 1 d at a distance of 10 m, attributable to a larger extent to deposition of volatilised compound than to spray drift when drift reducing nozzles were used. Similar results were obtained for parathion, but at a lower level. Mainly due to its photolytic instability in water, pirimicarb decayed in surface water, where a maximum deposition was measured 2 h after application.
authors.affiliation: Federal Biological Research Centre for Agriculture and Forestry (BBA), Chemistry Division Braunschweig, Messeweg 11-12, D-38104 Braunschweig, Germany. j.siebers@bba.de
authors.forename: Johannes
authors.initials: J
authors.lastname: Siebers
authors.forename: Rainer
authors.initials: R
authors.lastname: Binner
authors.forename: Klaus-Peter
authors.initials: KP
authors.lastname: Wittich
mesh_terms: D000383:Agriculture; D000393:Air Pollutants / Q000032:analysis*; D000397:Air Pollution / Q000517:prevention & control; D000704:Analysis of Variance; D002219:Carbamates / Q000032:analysis; D018556:Crops, Agricultural; D006297:Health Services Accessibility; D001556:Hexachlorocyclohexane / Q000032:analysis; D001467:Hordeum / Q000737:chemistry; D006801:Humans; D008685:Meteorological Concepts; D010278:Parathion / Q000032:analysis; D010575:Pesticides / Q000032:analysis*; D011743:Pyrimidines; D012995:Solubility; D013997:Time Factors; D014835:Volatilization; D014874:Water Pollutants, Chemical / Q000032:analysis*; D014877:Water Pollution, Chemical / Q000517:prevention & control
chemical_list: D000393:Air Pollutants; D002219:Carbamates; D010575:Pesticides; D011743:Pyrimidines; D014874:Water Pollutants, Chemical; C011994:pirimicarb; D001556:Hexachlorocyclohexane; D010278:Parathion