Synthesis of organic-inorganic hybrid fillers at the molecular level and their application to composite resin.
The objective of this study was to synthesize a hybrid type filler composed of an organic component with inorganic component at the molecular level and to examine the properties of the filler. The composite resin was prepared by mixing synthesized filler with monomer and its physical properties were also examined. An organic-inorganic hybrid filler was synthesized by using 3-methacryloxypropyltrimethoxysilane (3-MPTS), methyltriethyoxysilane (MTES) and methanol silica sol. Firstly, poly3-methacryloxypropyltrimethoxysilane (poly3-MPTS) was synthesized by polymerization of 3-MPTS. A gelation product was obtained by graft-polymerization of poly3-MPTS with condensed organopolysiloxane after the hydrolysis of 3-MPTS, MTES and methanol silica sol. The gelation product was dried and ground to a filler. From the results of thermogravimetry-differential thermal analysis (TG-DTA), the organic-inorganic hybrid filler was found to be composed of 16.5 wt% organic component, 83.1 wt% inorganic component and 0.4 wt% residual water. A trial composite resin was prepared by mixing 55 wt% dimethacryloxyethyl 2,2,4-trimethylhexamethylene diurethane (UDMA), 15 wt% triethyleneglycol dimethacrylate (TEGDMA), 30 wt% 1-fluoro-1,3,3,5,5-penta (methacryloxyethyleneoxy) cyclotriphosphazene [P3N3(F)1 (EMA)5] as a base monomer and then 32.0 wt% of this monomer was mixed with 68.0 wt % of synthesized filler and a photo initiator, comphorquinone (CQ), was added. Compressive strength of the trial visible-light cured composite resin showed 397.0 MPa, and flexural strength and elastic modulus showed 142.5 MPa and 11.5 GPa, respectively. From the results, it was demonstrated that the present organic-inorganic hybrid filler at the molecular level can be used as a composite resin filler.
Anzai
Misaki
M
Department of Dental Materials, Nihon University School of Dentistry, Tokyo 101-8310, Japan. anzai@dent.nihon-u.ac.jp
Ishikawa
Youichi
Y
Yoshihashi
Kazue
K
Hirose
Hideharu
H
Nishiyama
Minoru
M
D003188:Composite Resins / Q000737:chemistry*; D004055:Differential Thermal Analysis; D004548:Elasticity; D005780:Gelatin / Q000138:chemical synthesis; D006801:Humans; D006868:Hydrolysis; D008027:Light; D008422:Materials Testing; D008689:Methacrylates / Q000138:chemical synthesis* / Q000737:chemistry; D000432:Methanol / Q000138:chemical synthesis* / Q000737:chemistry; D009570:Nitriles / Q000737:chemistry; D017553:Phosphorus Compounds / Q000737:chemistry; D018583:Pliability; D011092:Polyethylene Glycols / Q000737:chemistry; D011108:Polymers / Q000138:chemical synthesis; D011109:Polymethacrylic Acids / Q000737:chemistry; D011140:Polyurethanes / Q000737:chemistry; D012821:Silanes / Q000138:chemical synthesis* / Q000737:chemistry; D012822:Silicon Dioxide / Q000138:chemical synthesis* / Q000737:chemistry; D012995:Solubility; D013314:Stress, Mechanical; D013729:Terpenes / Q000737:chemistry; D013818:Thermogravimetry; D014867:Water / Q000737:chemistry
D003188:Composite Resins; D008689:Methacrylates; D009570:Nitriles; D017553:Phosphorus Compounds; D011108:Polymers; D011109:Polymethacrylic Acids; D011140:Polyurethanes; D012821:Silanes; D013729:Terpenes; D014867:Water; C029824:urethane dimethacrylate luting resin; C020946:triethylene glycol dimethacrylate; C017492:methacryloxypropyltrimethoxysilane; C068226:cyclotriphosphazene ester; D011092:Polyethylene Glycols; C048339:camphoroquinone; D012822:Silicon Dioxide; D005780:Gelatin; D000432:Methanol