The use of extraction chromatography resins to concentrate actinides and strontium from soil for radiochromatographic analyses.
An analytical technique utilizing selective extractant resins to concentrate strontium and actinides from soil followed by separation with radiochromatography was evaluated. The technique was tested using uncontaminated soil samples spiked with a radionuclide tracer solution that were either microwave-aided acid digested or leached with a strong acid. Extraction of the strontium and actinides from the acidified solution was accomplished using a serial arrangement of Sr-Resin and TRU-Resin columns. The combined eluate solutions from the extraction resins were treated with HNO(3) and H(2)O(2) to oxidize residual extractant and eluates prior to separation and analysis of the radionuclides by radiochromatography. Chromatograms obtained with larger soil mass loadings resulted in either incomplete peak resolution of the tracers or had highly variable peak elution times, indicative of an ionic interfering constituent(s). Better separations (e.g., chromatograms that resolved all radioactive constituents) were obtained when the sample mass loading was decreased, but with a concurrent decreased sensitivity for the radionuclides. Elemental analyses of the soil were conducted to provide data on the ionic constituents in unprocessed soil and post-processed soil samples. These results identified aluminum as an interfering contributor to the poor performance exhibited by the radiochromatographic separations.
Roane
J E
JE
Department of Environmental Engineering and Science, Clemson University, Clemson, SC 29634-0919, USA.
DeVol
T A
TA
Leyba
J D
JD
Fjeld
R A
RA
D008671:Actinoid Series Elements / Q000032:analysis*; D002623:Chemistry Techniques, Analytical / Q000379:methods; D002845:Chromatography / Q000379:methods; D004784:Environmental Monitoring / Q000379:methods; D007475:Ion Exchange Resins; D012680:Sensitivity and Specificity; D012990:Soil Pollutants, Radioactive / Q000032:analysis*; D013324:Strontium / Q000032:analysis*
D008671:Actinoid Series Elements; D007475:Ion Exchange Resins; D012990:Soil Pollutants, Radioactive; D013324:Strontium