title: Vibrational characterization of the tertiary amide and thioamide group.
abstract: Force field calculations and vibrational spectra of (CH(3))(2)NCOCON(CH(3))(2) (TMO), (CH(3))(2)NCOCSN(CH(3))(2) (TMMTO) and (CH(3))(2)NCSCSN(CH(3))(2) (TMDTO) are discussed. The amide and thioamide fundamentals and those of other simple tertiary amides are compared. A characteristic pattern in infrared and Raman is proposed.
authors.affiliation: Department of Chemistry, University of Antwerp-RUCA, Groenenborgerlaan 171, B-2020 Antwerp, Belgium. jojans@ruca.ua.ac.be
authors.forename: H O
authors.initials: HO
authors.lastname: Desseyn
authors.forename: W A
authors.initials: WA
authors.lastname: Herrebout
authors.forename: K
authors.initials: K
authors.lastname: Clou
mesh_terms: D000577:Amides / Q000032:analysis / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry; D009584:Nitrogen / Q000737:chemistry; D013059:Spectrum Analysis, Raman / Q000379:methods*; D013696:Temperature; D013854:Thioamides / Q000032:analysis / Q000737:chemistry*
chemical_list: D000577:Amides; D013854:Thioamides; D002244:Carbon; D009584:Nitrogen