First synthesis of perfluorinated corrole and its mn=o complex.
A novel perfluorinated corrole, 2,3,7,8,12,13,17,18-octafluoro-5,10,15-tris(pentafluorophenyl)corrole, and its manganese(III) and oxomanganese(V) derivatives have been synthesized. The perfluorinated manganese corrolate exhibited excellent reactivity and stability in the catalytic oxidation of alkenes with iodosylbenzene.
Liu
Hai-Yang
HY
Department of Chemistry, Lab of Chemical Biology, Inst. of Molecular Technology for Drug Discovery and Synthesis, Hong Kong Univ. of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China.
Lai
Tat-Shing
TS
Yeung
Lam-Lung
LL
Chang
Chi K
CK