Novel thermal reaction of Fischer carbene complexes with imines: synthesis of beta-methoxy allylic amine derivatives.
[formula: see text] Alkyl-substituted chromium Fischer carbene complexes were found to react with various N-tosylimines to give beta-methoxy allylic amine derivatives under thermal conditions. This result is essentially distinct from the photochemical outcome in which beta-lactam derivatives are obtained.
Sangu
Kenichiro
K
Department of Chemistry, Faculty of Science, Gakushuin University, 1-5-1 Mejiro, Toshima-ku, Tokyo 171-8588, Japan.
Kagoshima
Hirotaka
H
Fuchibe
Kohei
K
Akiyama
Takahiko
T