title: Novel thermal reaction of Fischer carbene complexes with imines: synthesis of beta-methoxy allylic amine derivatives.
abstract: [formula: see text] Alkyl-substituted chromium Fischer carbene complexes were found to react with various N-tosylimines to give beta-methoxy allylic amine derivatives under thermal conditions. This result is essentially distinct from the photochemical outcome in which beta-lactam derivatives are obtained.
authors.affiliation: Department of Chemistry, Faculty of Science, Gakushuin University, 1-5-1 Mejiro, Toshima-ku, Tokyo 171-8588, Japan.
authors.forename: Kenichiro
authors.initials: K
authors.lastname: Sangu
authors.forename: Hirotaka
authors.initials: H
authors.lastname: Kagoshima
authors.forename: Kohei
authors.initials: K
authors.lastname: Fuchibe
authors.forename: Takahiko
authors.initials: T
authors.lastname: Akiyama