The synthesis of a novel cyclo-Se3-bridged trinuclear Ru complex.
The reaction of [[RuCl[P(OCH3)3]2]2(mu-Se2)(mu-Cl)2] with four equivalents of NaPF6 gave [[Ru[P(OCH3)3]2(CH3CN)3]2(mu-Se2)](PF6)3 and [[Ru[P(OCH3)3]2(CH3CN)(mu-Cl)]2(mu-cyclo-Se3)[Ru[P(OCH3)3]2(CH3CN)3]](PF6)4. The former is a Ru(II) Ru(III) mixed-valent paramagnetic compound. The X-ray structural analysis of the latter compound revealed that it has a novel mu-cyclo-Se3 neutral ligand and three Ru(II) atoms.
Hatemata
Shiho
S
Department of Chemistry, Advanced Research Center for Science and Engineering, Waseda University, 3-4-1 Ohkubo, Shinjuku, Tokyo 169-8555, Japan.
Sugiyama
Hiroyasu
H
Mizutani
Jun
J
Matsumoto
Kazuko
K