title: Dioxygen activation by a dinuclear nickel thiolate complex: structural characterization of the ligand oxidized product.
abstract: A (mu-SR)2-nickel(II) dimer derived from a ligand with carboxamido nitrogen and thiolato sulfur donors reacts with O2 to afford an oxidized product in which phenyl groups of the ligand frames are oxidized to nickel-bound phenolates.
authors.affiliation: Department of Chemistry and Biochemistry, University of California, Santa Cruz, CA 95064, USA.
authors.forename: Todd C
authors.initials: TC
authors.lastname: Harrop
authors.forename: Marilyn M
authors.initials: MM
authors.lastname: Olmstead
authors.forename: Pradip K
authors.initials: PK
authors.lastname: Mascharak
mesh_terms: D018360:Crystallography, X-Ray; D019281:Dimerization; D008024:Ligands; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*
chemical_list: D008024:Ligands; D009942:Organometallic Compounds; D009532:Nickel; D010100:Oxygen