Cation-pi interactions as a tool to enhance the power of a chiral auxiliary during asymmetric photoreactions within zeolites.
Owing to the existence of cation-pi interactions, aryl chiral auxiliaries perform far better than alkyl chiral auxiliaries during asymmetric photoreaction.
Kaanumalle
Lakshmi S
LS
Department of Chemistry, Tulane University, New Orleans, LA 70118, USA.
Sivaguru
J
J
Arunkumar
N
N
Karthikeyan
S
S
Ramamurthy
V
V