Unprecedented stabilisation of the Ag2(2+)-ion by two hydrido-iridium(III) complexes.
The complex [[(eta 5-C5Me5)(Ph3P)Ir(mu-H)2]2Ag2(OSO2CF3)2], containing the Ag2(2+)-ion, has been synthesized; crystallographic and spectroscopic data are described.
Gorol
Michael
M
Institut für Anorganische Chemie, Universität Göttingen, Tammannstr 4, D-37077 Göttingen, Germany.
Mösch-Zanetti
Nadia C
NC
Roesky
Herbert W
HW
Noltemeyer
Mathias
M
Schmidt
Hans-Georg
HG