Mild oxidation of alcohols with o-iodoxybenzoic acid (IBX) in water/acetone mixture in the presence of beta-cyclodextrin.
A mild and efficient oxidation of alcohols with o-iodoxybenzoic acid (IBX) catalyzed by beta-cyclodextrin in a water/acetone mixture (86:14) has been developed. A series of alcohols were oxidized at room temperature in excellent yields.
Surendra
K
K
Organic Chemistry Division-I, Indian Institute of Chemical Technology, Hyderabad-500 007, India.
Krishnaveni
N Srilakshmi
NS
Reddy
M Arjun
MA
Nageswar
Y V D
YV
Rao
K Rama
KR
D000096:Acetone / Q000737:chemistry; D000438:Alcohols / Q000737:chemistry*; D002384:Catalysis; D003505:Cyclodextrins / Q000737:chemistry*; D007462:Iodobenzenes / Q000737:chemistry*; D015394:Molecular Structure; D010084:Oxidation-Reduction; D013696:Temperature; D014867:Water / Q000737:chemistry
D000438:Alcohols; D003505:Cyclodextrins; D007462:Iodobenzenes; D014867:Water; D000096:Acetone; C476101:o-iodoxybenzoic acid