Aldol- and Mannich-type reactions via in situ olefin migration in ionic liquid.
An aldol-type and a Mannich-type reaction via the cross-coupling of aldehydes and imines with allylic alcohols catalyzed by RuCl(2)(PPh(3))(3) was developed with ionic liquid as the solvent. The solvent/catalyst system could be reused for at least five times with no loss of reactivity.
Yang
Xiao-Fan
XF
Department of Chemistry, Tulane University, New Orleans, Louisiana 70118, USA.
Wang
Mingwen
M
Varma
Rajender S
RS
Li
Chao-Jun
CJ
D000475:Alkenes / Q000138:chemical synthesis / Q000737:chemistry* / Q000378:metabolism; D000818:Animals; D040761:Biomimetic Materials / Q000737:chemistry*; D001643:Bridged Bicyclo Compounds / Q000138:chemical synthesis* / Q000378:metabolism; D008974:Mollusca / Q000737:chemistry / Q000378:metabolism; D011753:Pyrones / Q000138:chemical synthesis* / Q000378:metabolism
D000475:Alkenes; D001643:Bridged Bicyclo Compounds; D011753:Pyrones