Enantioselective total synthesis of (-)-heliannuol A.
An efficient and enantiocontrolled total synthesis of (-)-heliannuol A has been accomplished by employing ring closing metathesis and sequential diastereoselective epoxidation and regioselective reductive cleavage of the epoxide ring.
Kishuku
Hidetoshi
H
Institute for Medicinal Resources, University of Tokushima, 1-78 Sho-machi, Tokushima 770-8505, Japan.
Shindo
Mitsuru
M
Shishido
Kozo
K