The electronic spectrum of Re2Cl8 2-: a theoretical study.
One of the prototype compounds for metal-metal multiple bonding, the Re(2)Cl(8)(2)(-) ion, has been studied theoretically using multiconfigurational quantum chemical methods. The molecular structure of the ground state has been determined. It is shown that the effective bond order of the Re-Re bond is close to three, due to the weakness of, in particular, the delta bond. The electronic spectrum has been calculated with the inclusion of spin-orbit coupling. Observed spectral features have been reproduced with good accuracy, and a number of new assignments are suggested.
Gagliardi
Laura
L
Dipartimento di Chimica Fisica F. Accascina, Viale delle Scienze-Parco d'Orleans II, I-90128 Palermo, Italy. laurag@ciam.unibo.it
Roos
Björn O
BO