Electrochemistry of P450cin: new insights into P450 electron transfer.
Electrochemistry of bacterial cytochrome P450cin (CYP176A) reveals that, unusually, substrate binding does not affect the heme redox potential, although a marked pH dependence is consistent with a coupled single electron/single proton transfer reaction in the range 6 < pH < 10.
Aguey-Zinsou
Kondo-François
KF
Department of Chemistry, University of Queensland, Brisbane 4072, Australia.
Bernhardt
Paul V
PV
De Voss
James J
JJ
Slessor
Kate E
KE
D003577:Cytochrome P-450 Enzyme System / Q000737:chemistry*; D004563:Electrochemistry; D004579:Electron Transport / Q000502:physiology; D010084:Oxidation-Reduction
D003577:Cytochrome P-450 Enzyme System