First example of a taxane-derived propellane in Taxus canadensis needles.
The first example of a propellane isolated from the needles of a yew is reported; the biogenesis from a putative taxane precursor is proposed.
Shi
Qing Wen
QW
Human Health Research Center, INRS-Institut Armand-Frappier, Université du Quebec, 531 Boulevard des Prairies, Laval, Quebec, Canada H7V 1B7.
Sauriol
Françoise
F
Mamer
Orval
O
Zamir
Lolita O
LO
D001952:Bridged-Ring Compounds / Q000737:chemistry* / Q000302:isolation & purification*; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D015394:Molecular Structure; D018515:Plant Leaves / Q000737:chemistry; D016339:Spectrometry, Mass, Fast Atom Bombardment; D013237:Stereoisomerism; D043823:Taxoids; D020946:Taxus / Q000737:chemistry*
C473965:2alpha,9alpha,10beta-triacetoxy-5alpha-hydroxy-3,11-cyclo-12,20-cyclotaxa-13-one; D001952:Bridged-Ring Compounds; D043823:Taxoids; C080625:taxane