Novel, stereoselective tricyclization of a dienyne by titanium aryloxide centers.
Titanium centers supported by aryloxide ligation mediate the tricyclization of a dienyne via intramolecular insertion of an olefin into the titanium-vinyl bond of a titanacyclopent-2-ene.
Himes
Richard A
RA
Department of Chemistry, Purdue University, 1393 Brown Building, West Lafayette, IN 47907-1393, USA.
Fanwick
Phillip E
PE
Rothwell
Ian P
IP