Mechanistic aspects of acetone addition to metalloaromatic complexes of iridium: a DFT investigation.
DFT calculations were used to reveal the unexpected reactivity and mechanism of the addition of acetone to metallabenzene, metallapyrylium and metallathiabenzene complexes of iridium.
Iron
Mark A
MA
Department of Organic Chemistry, Weizmann Institute of Science, 76100 Rehovot, Israel.
Martin
Jan M L
JM
van der Boom
Milko E
ME