title: A novel cationic heteropolyoxovanadium(IV) cluster functionalized with organic ligands: synthesis and characterization of the fully reduced species [Mn(II)V(IV)6O6[(OCH2CH2)2N(CH2CH2OH)]6]Cl2.
abstract: The solvothermal reaction of (HOCH2CH2)3N with [(n-C4H9)4N]3[H3V10O28] and MnCl2 x 4H2O in CH3CN and CH3OH yields a novel cationic heteropolyoxovanadium(IV) cluster, [Mn(II)V(IV)6O6[(OCH2CH2)2N(CH2CH2OH)]6]2+, containing a fully reduced new cyclic [MnV6N6O18] core with the Anderson structure.
authors.affiliation: Department of Biological, Chemical and Physical Sciences, Illinois Institute of Technology, Chicago, IL 60616, USA. khan@iit.edu
authors.forename: M Ishaque
authors.initials: MI
authors.lastname: Khan
authors.forename: Saadia
authors.initials: S
authors.lastname: Tabussum
authors.forename: Robert J
authors.initials: RJ
authors.lastname: Doedens