title: Solid-supported cyclohexane-1,3-dione (CHD): a "capture and release" reagent for the synthesis of amides and novel scavenger resin.
abstract: [reaction: see text] A three-step synthesis of cyclohexane-1,3-dione (CHD) resin 6 on polystyrene resin is described. Resin 6 was used to prepare an amide library of high purity by microwave-assisted serial "capture and release" and can be recycled for this purpose. High-loading CHD resin 10 was also shown to scavenge allyl cations in solution.
authors.affiliation: Department of Chemistry, University of Edinburgh, Kings Buildings, West Mains Road, Edinburgh, EH9 3JJ, UK.
authors.forename: Cara E
authors.initials: CE
authors.lastname: Humphrey
authors.forename: Morag A M
authors.initials: MA
authors.lastname: Easson
authors.forename: Jason P
authors.initials: JP
authors.lastname: Tierney
authors.forename: Nicholas J
authors.initials: NJ
authors.lastname: Turner