The first NH aldimine organometallic compound. Isolation and crystal structure.
The first NH aldimine organometallic derivative is unexpectedly formed by the cleavage of the nitrogen-carbon bond of the amino acid fragment of the Schiff base 2,4,6-Me3C6H2CH=NCH(CH2Ph)COOEt when the imine is treated with palladium acetate.
Albert
Joan
J
Departament de Química Inorgànica, Universitat de Barcelona, Diagonal 647, 08028 Barcelona, Spain.
Cadena
J Magali
JM
González
Asensio
A
Granell
Jaume
J
Solans
Xavier
X
Font-Bardia
Mercè
M
D000588:Amines / Q000378:metabolism; D018360:Crystallography, X-Ray; D007097:Imines / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D008995:Monoamine Oxidase / Q000378:metabolism; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010165:Palladium
D000588:Amines; D007097:Imines; D009942:Organometallic Compounds; D010165:Palladium; D008995:Monoamine Oxidase