alpha-Selective glycosylation with 5-thioglucopyranosyl donors; synthesis of an isomaltotetraoside mimic composed of 5-thioglucopyranose units.
A general method for alpha-selective glycosylation with 5-thioglucopyranosyl donors followed by efficient deprotection of the resulting products was developed. This methodology was utilized in the synthesis of an isomaltotetraoside analogue.
Matsuda
Hiroko
H
The United Graduate School of Agricultural Sciences, Iwate University, Bunkyo-Cho 3, Hirosaki 036-8561, Japan.
Ohara
Keiichiro
K
Morii
Yasuharu
Y
Hashimoto
Masaru
M
Miyairi
Kazuo
K
Okuno
Toshikatsu
T
D002240:Carbohydrate Sequence; D005947:Glucose / Q000031:analogs & derivatives* / Q000737:chemistry*; D006031:Glycosylation; D007202:Indicators and Reagents; D008958:Models, Molecular; D018716:Molecular Mimicry; D008969:Molecular Sequence Data; D009005:Monosaccharides / Q000737:chemistry*; D009844:Oligosaccharides / Q000737:chemistry*
D007202:Indicators and Reagents; D009005:Monosaccharides; D009844:Oligosaccharides; C047512:isomaltotetraose; C003002:5-thio-D-glucose; D005947:Glucose