Aqueous organometallic reactions of rhodium porphyrins: equilibrium thermodynamics.
The reactivity and equilibrium thermodynamic studies of tetra-p-sulfonatophenyl porphyrin rhodium hydride ([(TSPP)Rh-D]-4) with CO, aldehydes and olefins that produce formyl, alpha-hydroxyalkyl and alkyl complexes have been explored in water and compared with the related reactions in non-aqueous media.
Fu
Xuefeng
X
Department of Chemistry, University of Pennsylvania, Philadelphia, PA 19104-6323, USA.
Basickes
Leah
L
Wayland
Bradford B
BB