Assessment of adsorption behavior of dibutyltin (DBT) to clay-rich sediments in comparison to the highly toxic tributyltin (TBT).
The sorption behavior of dibutyltin (DBT) to four types of natural clay-rich sediments as a function of pH and salinity was studied. The strongest affinity of DBT was found to the montmorillonite-rich sediment, which is characterized by the highest specific surface area and cation exchange capacity of the four used sediments. Kd values range between 12 and 40 (l/kg) on simulated marine conditions (pH 8, salinity 32%). A maximum of DBT adsorption was found at a salinity of 0% and pH 6. Desorption occurred over the entire studied pH range (4-8) when contaminated sediments interact with butyltin-free water. The maximum of desorption coincided with the minimum of adsorption, and vice versa. The results of DBT adsorption are compared with tributyltin (TBT), and the mechanism of the adsorption process is discussed.
Hoch
Marion
M
Lehrstuhl für Angewandte Geologie, Universität Erlangen-Nürnberg, Schlossgarten 5, Germany. mhoch@geol.uni-erlangen.de
Alonso-Azcarate
Jacinto
J
Lischick
Martin
M
D000327:Adsorption; D000538:Aluminum Silicates; D000077215:Clay; D019015:Geologic Sediments / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D009947:Organotin Compounds / Q000737:chemistry*; D012623:Seawater / Q000737:chemistry; D012965:Sodium Chloride / Q000737:chemistry; D014220:Trialkyltin Compounds / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000032:analysis*
D000538:Aluminum Silicates; D009947:Organotin Compounds; D014220:Trialkyltin Compounds; D014874:Water Pollutants, Chemical; C056189:di-n-butyltin; D012965:Sodium Chloride; C011559:tributyltin; D000077215:Clay