title: The first NH aldimine organometallic compound. Isolation and crystal structure.
abstract: The first NH aldimine organometallic derivative is unexpectedly formed by the cleavage of the nitrogen-carbon bond of the amino acid fragment of the Schiff base 2,4,6-Me3C6H2CH=NCH(CH2Ph)COOEt when the imine is treated with palladium acetate.
authors.affiliation: Departament de Química Inorgànica, Universitat de Barcelona, Diagonal 647, 08028 Barcelona, Spain.
authors.forename: Joan
authors.initials: J
authors.lastname: Albert
authors.forename: J Magali
authors.initials: JM
authors.lastname: Cadena
authors.forename: Asensio
authors.initials: A
authors.lastname: González
authors.forename: Jaume
authors.initials: J
authors.lastname: Granell
authors.forename: Xavier
authors.initials: X
authors.lastname: Solans
authors.forename: Mercè
authors.initials: M
authors.lastname: Font-Bardia
mesh_terms: D000588:Amines / Q000378:metabolism; D018360:Crystallography, X-Ray; D007097:Imines / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D008995:Monoamine Oxidase / Q000378:metabolism; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010165:Palladium
chemical_list: D000588:Amines; D007097:Imines; D009942:Organometallic Compounds; D010165:Palladium; D008995:Monoamine Oxidase