title: Spectrofluorimetric determination of formaldehyde by a flow-injection method based on its catalytic effect on the acridine yellow-bromate reaction.
abstract: A flow-injection configuration for the determination of formaldehyde is proposed. The method is based on the enhancing effect of formaldehyde on the oxidation of acridine yellow by bromate in acidic medium. The proposed procedure is simple, inexpensive, sensitive and suitable for concentrations of formaldehyde between 1 and 56 microg mL(-1). A sampling-rate of 60 samples h(-1) was achieved. The effect of several organic and inorganic species was studied. The method was applied to the determination of formaldehyde in pharmaceuticals, milk and air in work environments. The accuracy of the method was confirmed by comparing the results with those obtained using the standard acetylacetone method.
authors.affiliation: Department of Analytical Chemistry, Faculty of Chemistry, University of Murcia, 30071 Murcia, Spain. tpr@um.es
authors.forename: T
authors.initials: T
authors.lastname: Pérez-Ruíz
authors.forename: C
authors.initials: C
authors.lastname: Martínez-Lozano
authors.forename: V
authors.initials: V
authors.lastname: Tomás
authors.forename: J
authors.initials: J
authors.lastname: Fenoll
mesh_terms: D000393:Air Pollutants / Q000032:analysis*; D000609:Aminoacridines / Q000737:chemistry*; D001959:Bromates / Q000737:chemistry*; D002384:Catalysis; D017022:Flow Injection Analysis / Q000379:methods*; D005557:Formaldehyde / Q000032:analysis*; D007202:Indicators and Reagents / Q000737:chemistry*; D013050:Spectrometry, Fluorescence / Q000379:methods*
chemical_list: D000393:Air Pollutants; D000609:Aminoacridines; D001959:Bromates; D007202:Indicators and Reagents; D005557:Formaldehyde; C025902:acridine yellow