title: X-ray diffraction and high-resolution NMR spectroscopy of methyl 3-azido-2,3-dideoxy-alpha-D-lyxo-hexopyranoside.
abstract: The single-crystal X-ray diffraction and high-resolution 1H and 13C NMR spectral data for the title compound are reported. The influence of the ring oxygen atom on the J(1,2e) and J(4,5) coupling constants for 2-deoxy-D-lyxo- and -D-xylo-hexopyranosides is discussed.
authors.affiliation: Faculty of Chemistry, University of Gdansk, Sobieskiego 18, PL-80-952 Gdansk, Poland. beatal@chemik.chem.univ.gda.pl
authors.forename: Beata
authors.initials: B
authors.lastname: Liberek
authors.forename: Artur
authors.initials: A
authors.lastname: Sikorski
authors.forename: Anna
authors.initials: A
authors.lastname: Melcer
authors.forename: Antoni
authors.initials: A
authors.lastname: Konitz
mesh_terms: D001386:Azides / Q000737:chemistry*; D002236:Carbohydrate Conformation; D003837:Deoxy Sugars / Q000737:chemistry*; D006601:Hexoses / Q000737:chemistry*; D006860:Hydrogen Bonding; D008958:Models, Molecular; D015394:Molecular Structure; D019906:Nuclear Magnetic Resonance, Biomolecular; D014961:X-Ray Diffraction
chemical_list: D001386:Azides; D003837:Deoxy Sugars; D006601:Hexoses