Tandem N-alkylation-C-allylation reaction of alpha-imino esters with organoaluminums and allyltributyltin.
On treatment of various alpha-imino esters with organoaluminum reagents and allyltributyltin in the presence of benzoyl peroxide, the tandem reaction proceeded to give the N-alkylation-C-allylation products in good yields. The tandem N-alkyation-C-cyanation also proceeded using silyl or aluminum cyanide to give the aminonitrile in good yield.
Niwa
Yasuki
Y
Department of Chemistry for Materials, Mie University, Tsu, Japan.
Shimizu
Makoto
M