X-ray diffraction and high-resolution NMR spectroscopy of methyl 3-azido-2,3-dideoxy-alpha-D-lyxo-hexopyranoside.
The single-crystal X-ray diffraction and high-resolution 1H and 13C NMR spectral data for the title compound are reported. The influence of the ring oxygen atom on the J(1,2e) and J(4,5) coupling constants for 2-deoxy-D-lyxo- and -D-xylo-hexopyranosides is discussed.
Liberek
Beata
B
Faculty of Chemistry, University of Gdansk, Sobieskiego 18, PL-80-952 Gdansk, Poland. beatal@chemik.chem.univ.gda.pl
Sikorski
Artur
A
Melcer
Anna
A
Konitz
Antoni
A
D001386:Azides / Q000737:chemistry*; D002236:Carbohydrate Conformation; D003837:Deoxy Sugars / Q000737:chemistry*; D006601:Hexoses / Q000737:chemistry*; D006860:Hydrogen Bonding; D008958:Models, Molecular; D015394:Molecular Structure; D019906:Nuclear Magnetic Resonance, Biomolecular; D014961:X-Ray Diffraction
D001386:Azides; D003837:Deoxy Sugars; D006601:Hexoses