Spin-imposed stereoselection in the photocycloaddition of (Z)- and (E)-cyclooctene to aliphatic aldehydes.
The simple diastereoselectivity of the photocycloaddition of aliphatic aldehydes to (Z)- and (E)-cyclooctene was analyzed as a function of the substrate concentrations and applied to spin mapping.
Griesbeck
Axel G
AG
Institute of Organic Chemistry, University of Cologne, Greinstr. 4, D-50939 Köln, Germany. griesbeck@uni-koeln.de
Bondock
Samir
S