title: Biologically active metabolites from fungi, 17. 8-alpha-acetoxyverrol, a new member of the trichothecene sesquiterpenes.
abstract: 8-alpha-Acetoxyverrol (4), the first open chain example of the trichothecenes with oxygenation at C-8, was isolated from cultures of Aphanocladium spectabile. The compound doses the biosynthetic gap to the macrocyclic verrucarins.
authors.affiliation: Fachbereich Chemie und Chemietechnik der Universität Paderborn, Warburger Str. 100 D-33098 Paderborn, Germany.
authors.forename: Karsten
authors.initials: K
authors.lastname: Krohn
authors.forename: Klaus
authors.initials: K
authors.lastname: Steingröver
authors.forename: Hans-Jürgen
authors.initials: HJ
authors.lastname: Aust
authors.forename: Siegfried
authors.initials: S
authors.lastname: Draeger
authors.forename: Barbara
authors.initials: B
authors.lastname: Schulz
mesh_terms: D002850:Chromatography, Gel; D003904:Mitosporic Fungi / Q000737:chemistry*; D019906:Nuclear Magnetic Resonance, Biomolecular; D009904:Optical Rotation; D013055:Spectrophotometry, Infrared; D013056:Spectrophotometry, Ultraviolet; D014255:Trichothecenes / Q000737:chemistry / Q000302:isolation & purification*
chemical_list: D014255:Trichothecenes