Coordination-synchronized trans-cis photoisomerization of bipyridylazobenzene driven by a Cu(II)/Cu(I) redox change.
The trans-cis photoisomerization behavior of azobenzene-bipyridine ligand (dmpAB) was synchronized with coordination of the bipyridine moiety to copper. The coordination reaction can be reversibly controlled with reversible redox reaction of copper, to afford [Cu(dmpAB)(2)](+) in Cu(I) state and free dmpAB in Cu(II) state. UV irradiations to Cu(I) and Cu(II) samples form trans-rich and cis-rich compositions, respectively. The results enable us to control the trans-cis isomerization reversibly through Cu(II)/Cu(I) redox and a single UV light.
Kume
Shoko
S
Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Kurihara
Masato
M
Nishihara
Hiroshi
H