Synthesis, characterization, inequivalency of methylene proton and proton lability in the amino ligand of trans-[dichloro[(N-ferrocenyl methyl)amine](eta2-ethene)platinum] complexes.
A series of complexes of the type trans-[PtCl(2)(eta(2)-ethene)(N-ferrocenyl methyl)amine)] complexes, N-ferrocenylmethylamine=[(eta(5)-C(5)-H(5))Fe(eta(5)-C(5)-H(4)CH(2)NHR], R=(Me, Pr(i), Bu(s), Bu(t), CH(2)Ph, (p-OCH(3))Ph, (o-(OCH(3))Ph, (p-CH(3))Ph, (o-CH(3))Ph, (m-CH(3))Ph, (p-Cl)Ph) have been synthesized and characterized on the basis of elemental analysis, IR, 1H and 13C NMR spectroscopic methods. The CpCH(2)NHR (Cp=(eta(5)-C(5)H(5))Fe(eta(5)-C(5)H(4)), region of the 1H NMR spectrum of the complexes has been investigated and shown to contain inequivalent methylene protons, NH-CH and 195Pt-N-CH coupling take place.
Al-Najjar
Ibrahim M
IM
Petroleum and Petrochemicals Research Institute, King Abdulaziz City for Science and Technology, P.O. Box 6086, 11442, Riyadh, Saudi Arabia. alnajjar@kacst.edu.sa
Abdulrahman
Abdullah M
AM
Al-Refai
Jamal K
JK
Al-Shabanah
Latifah A
LA
Al-Mutabagani
Laila A
LA
D002244:Carbon; D005296:Ferrous Compounds / Q000737:chemistry*; D006838:Hydrocarbons; D006859:Hydrogen; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry*; D008956:Models, Chemical; D010984:Platinum / Q000737:chemistry*; D011522:Protons; D012997:Solvents / Q000494:pharmacology
D005296:Ferrous Compounds; D006838:Hydrocarbons; D008024:Ligands; C479867:N-ferrocenylmethylamine; D011522:Protons; D012997:Solvents; C030011:carbene; D010984:Platinum; D002244:Carbon; D006859:Hydrogen; D008697:Methane