title: Oxidatively robust monophenolate-copper(II) complexes as potential models of galactose oxidase.
abstract: Cupric complexes of a novel phenanthroline-phenolate ligand have strongly distorted coordination geometries and electrochemical properties conducive to modeling the spectroscopy and reactivity of the enzyme galactose oxidase.
authors.affiliation: Department of Chemistry, Stanford University, Stanford, CA 94305, USA.
authors.forename: Robertus J M Klein
authors.initials: RJ
authors.lastname: Gebbink
authors.forename: Masayuki
authors.initials: M
authors.lastname: Watanabe
authors.forename: Russell C
authors.initials: RC
authors.lastname: Pratt
authors.forename: T Daniel P
authors.initials: TD
authors.lastname: Stack
mesh_terms: D040761:Biomimetic Materials / Q000737:chemistry; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D004563:Electrochemistry; D004578:Electron Spin Resonance Spectroscopy; D004952:Esters / Q000737:chemistry*; D005692:Galactose Oxidase / Q000737:chemistry*; D018716:Molecular Mimicry; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D010618:Phenanthrolines / Q000737:chemistry; D010636:Phenols / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet
chemical_list: D004952:Esters; D009942:Organometallic Compounds; D010618:Phenanthrolines; D010636:Phenols; D003300:Copper; D005692:Galactose Oxidase