title: Lead sorption onto ferrihydrite. 1. A macroscopic and spectroscopic assessment.
abstract: In this research, traditional macroscopic studies were complemented with XAS analyses to elucidate the mechanisms controlling Pb(II) sorption onto ferrihydrite as a function of pH, ionic strength, and adsorbate concentrations. Analyses of XANES and XAFS studies demonstrate that Pb(II) ions predominantly sorb onto ferrihydrite via inner-sphere complexation, not retaining their primary hydration shell upon sorption. At higher pH values (pH > or = 5.0), edge-sharing bidentate complexes are mainly formed on the oxide surface with two Fe atoms located at approximately 3.34 A. In contrast, XAS studies on Pb(II) sorption onto ferrihydrite, at pH 4.5, reveal two distinct Pb-Fe bond average radial distances of 3.34 and 3.89 A, suggestive of a mixture of monodentate and bidentate sorption complexes present at the oxide surface. Interestingly, at constant pH, the configuration of the sorption complex is independent of the adsorbate concentration. Hence, Pb(II) sorption to a highly disordered adsorbent such as ferrihydrite can be described by one average type of mechanism. Overall, this information will aid scientists and engineers in improving the current models that predict and manage the fate of toxic metals, such as Pb(II), in the aquatic and soil environments.
authors.affiliation: Department of Plant and Soil Sciences, University of Delaware, Newark, Delaware 19717, USA. paras@udel.edu
authors.forename: Paras
authors.initials: P
authors.lastname: Trivedi
authors.forename: James A
authors.initials: JA
authors.lastname: Dyer
authors.forename: Donald L
authors.initials: DL
authors.lastname: Sparks
mesh_terms: D000327:Adsorption; D004738:Engineering; D005290:Ferric Compounds; D005293:Ferritins / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D007854:Lead / Q000737:chemistry*; D008962:Models, Theoretical; D012989:Soil Pollutants; D013057:Spectrum Analysis; D014873:Water Pollutants
chemical_list: D005290:Ferric Compounds; D012989:Soil Pollutants; D014873:Water Pollutants; D007854:Lead; C092844:ferric oxyhydroxide; D005293:Ferritins