title: Detection and removal of dissolved hydrogen sulphide in flow-through systems via the sulphidation of hydrous iron (III) oxides.
abstract: A novel automated warning and removal system for hydrogen sulphide in aqueous flow-through systems has been developed based on the sulphidation of ferrihydrite sorbed to zeolite substrate. The system consists of a small flow-through reaction cartridge with photo-sensors positioned at the base. During the reaction, sulphide is initially oxidised to elemental sulphur by the ferrihydrite, and Fe2+ is subsequently released to solution. This Fe2+ then reacts with additional dissolved sulphide to form solid phase iron monosulphide. The colour change from orange ferrihydrite to black iron monosulphide is continuously monitored by the photo-sensors, which provide a rapid and reproducible response (via a voltage change) to pulses of sulphidic water. The response of the photo-sensors is linear with respect to inflowing sulphide concentration, while the most rapid response to dissolved sulphide occurs at a flow rate of approximately 200 ml min(-1) (equivalent to a hydraulic loading rate of 21 cm min(-1). The presence of phosphate in solution substantially decreases reaction rates due to adsorption to reactive surface sites. However, the response time of the photo-sensors remains sufficient to provide a rapid indication of sulphidic conditions even in systems with high concentrations of dissolved phosphate. The cartridge has the advantage of partially or completely removing sulphide (depending on flow rate and substrate mass) from an initial pulse of water. At the optimal flow rate for the successful use of the cartridge as a sulphide warning system (200 ml min(-1)), required substrate masses for the complete removal of dissolved sulphide (over the experimental range of 0-1000 microM) are relatively small (0.5-2 kg).
authors.affiliation: School of Earth Sciences, University of Leeds, Leeds LS2 9JT, UK.
authors.forename: S W
authors.initials: SW
authors.lastname: Poulton
authors.forename: M D
authors.initials: MD
authors.lastname: Krom
authors.forename: J
authors.initials: J
authors.lastname: van Rijn
authors.forename: R
authors.initials: R
authors.lastname: Raiswell
authors.forename: R
authors.initials: R
authors.lastname: Bows
mesh_terms: D000327:Adsorption; D001331:Automation; D004784:Environmental Monitoring; D005290:Ferric Compounds / Q000737:chemistry; D006862:Hydrogen Sulfide / Q000302:isolation & purification*; D007220:Industrial Waste; D010777:Photochemistry; D013440:Sulfides / Q000737:chemistry; D014865:Waste Disposal, Fluid; D017641:Zeolites
chemical_list: D005290:Ferric Compounds; D007220:Industrial Waste; D013440:Sulfides; D017641:Zeolites; C000499:ferric oxide; D006862:Hydrogen Sulfide