Electrostatic interaction between ion-penetrable membranes in a salt-free medium.
A set of coupled equations is given which determines the distributions of the electric potential and counterions in a system of two interacting identical ion-penetrable membranes of thickness d at separation h immersed in a salt-free medium containing only counterions. The solution to these coupled equations also gives the electrostatic repulsive force between the membranes. It is shown that the interaction force remains finite at h-->0, unlike the case of the interaction between two planar charged surfaces (d-->0), and that the interaction force becomes independent of the membrane fixed charge and membrane thickness d at very large h. Finally, an approximate single transcendental equation giving the solution to the coupled equations is derived.
Ohshima
Hiroyuki
H
Faculty of Pharmaceutical Sciences, Science University of Tokyo, 12 Ichigaya Funagawara-machi, Shinjuku-ku, Tokyo 162-0826, Japan. ohshima@ps.kagu.sut.ac.jp