title: Novel heteroleptic cis-(C--N)2Pd(II) chelates for the preparation of enantiopure planar chiral cyclopalladated 2-[tricarbonyl(eta6-phenyl)chromium]pyridine.
abstract: In the presence of large amounts of [Me4N]Cl, the reaction of ortho-chloromercurated 2-[(eta6-phenyl)tricarbonylchromium]pyridine with mu-chloro cyclopalladated aromatic compounds yields a series of new heteroleptic heterodinuclear cis-(C--N)2Pd(II) complexes, which are valuable precursors of planar chiral cyclopalladated (eta6-arene)Cr(CO)3 complexes.
authors.affiliation: Laboratoire de Synthèses Métallo-Induites, UMR 7513 CNRS, 4 rue Blaise Pascal, F-67070 Strasbourg Cedex, France.
authors.forename: Alexsandro
authors.initials: A
authors.lastname: Berger
authors.forename: Jean-Pierre
authors.initials: JP
authors.lastname: Djukic
authors.forename: Michel
authors.initials: M
authors.lastname: Pfeffer
authors.forename: André
authors.initials: A
authors.lastname: de Cian
authors.forename: Nathalie
authors.initials: N
authors.lastname: Kyritsakas-Gruber
authors.forename: Jérôme
authors.initials: J
authors.lastname: Lacour
authors.forename: Laurent
authors.initials: L
authors.lastname: Vial