Equivalent models of indanol isomers adsorption on cellulose tribenzoate.
The adsorption isotherm data of (R)- and (S)-1-indanol and of their racemic mixture on cellulose tribenzoate were measured by frontal analysis. The experimental data for each enantiomers were fitted to the single-component bilangmuir isotherm model. The competitive experimental data were fitted to the ideal adsorption solution model (IAS), the real adsorption solution model (RAS), and the bilangmuir thermodynamically consistent model (BTC). The mass transfer kinetic parameters were estimated from systematic comparisons between the experimental single-component band profiles and profiles calculated using the general rate model (GR) of chromatography coupled with the generalized Maxwell-Stefan equation (GMS). The validation of the isotherm model and of the mass transfer kinetic model was made by comparing the experimental band profiles obtained for solutions of the two enantiomers and those calculated with the competitive GR-GMS model. The excellent agreement observed proves that a combination of the BTC isotherm model and the GMS kinetic model, using the best values of the BTC and GMS parameters estimated from single component experiments, allows an excellent prediction of the binary isotherm and the binary mass transfer kinetics.
Kaczmarski
Krzysztof
K
Faculty of Chemistry, Rzeszów University of Technology, 35-959, Rzeszów, Poland.
Zhou
Dongmei
D
Gubernak
Małgorzata
M
Guiochon
Georges
G
D000327:Adsorption; D001565:Benzoates / Q000737:chemistry*; D002482:Cellulose / Q000737:chemistry*; D002853:Chromatography, Liquid / Q000379:methods*; D003198:Computer Simulation; D007189:Indans / Q000737:chemistry*; D007536:Isomerism; D008956:Models, Chemical; D013696:Temperature
D001565:Benzoates; D007189:Indans; D002482:Cellulose