Alkoxyamine-mediated radical cyclizations.
[reaction: see text] We present a new "conjunctive" radical cyclization process that involves the reaction of a 1,6-diene with the Tordo alkoxyamine, an agent originally developed for the radical polymerization of certain olefins through the "persistent radical effect".
Leroi
Corinne
C
Laboratoire de Synthèse et Méthodologie Organiques, CNRS UMR 5078, France.
Fenet
Bernard
B
Couturier
Jean-Luc
JL
Guerret
Olivier
O
Ciufolini
Marco A
MA