title: Study on self-assembled monolayers of functionalized azobenzene thiols on gold: XPS, electrochemical properties, and surface-enhanced Raman spectroscopy.
abstract: Self-assembled monolayers (SAMs) of 4-acetamino-4'-(4-mercaptobutoxy)azobenzene (CH3)CONH-ph-N=N-ph-O(CH2)(4)SH, abbr. aaAzoC4SH) and 4-mercaptobutoxy azobenzene (ph-N=N-ph-O(CH2)(4)SH, abbr. AzoC4SH) on a gold surface have been studied by X-ray photoelectron spectroscopy (XPS), FT Raman spectroscopy, and electrochemistry. A surface-enhanced Raman scattering (SERS)-active system with a "sandwiched" structure of Ag/R-Azo-C4S-/Au was conveniently obtained by the method of Tollen's test. The relationship between the SERS effect and the structural nature of the system indicates that the enhancement correlates to both the silver islands above and the gold substrate underneath. The redox behaviors of the self-assembly on gold electrodes showed that the SAMs of the two compounds exhibit well-behaved voltammetric responses in a Britton-Robinson buffer corresponding to the irreversible two-electron, two-proton reduction-oxidation of azobenzene. The apparent electron-transfer rate kinetics is very sluggish, and the rate constant k(app) of aaAzoC4SH/Au (1.34 x 10(-6) s(-1)) is lower than that of AzoC4SH/Au (1.63 x 10(-4) s(-1)), which may be attributed to the different spatial restriction of close-packing structures on the conformational change accompanied by electron and proton transfer in the SAMs.
authors.affiliation: Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, People's Republic of China.
authors.forename: Wen-Wei
authors.initials: WW
authors.lastname: Zhang
authors.forename: Xiao-Ming
authors.initials: XM
authors.lastname: Ren
authors.forename: Hai-Fang
authors.initials: HF
authors.lastname: Li
authors.forename: Chang-Sheng
authors.initials: CS
authors.lastname: Lu
authors.forename: Chuan-Jiang
authors.initials: CJ
authors.lastname: Hu
authors.forename: Hui-Zhen
authors.initials: HZ
authors.lastname: Zhu
authors.forename: Qing-Jin
authors.initials: QJ
authors.lastname: Meng