[Preparation of titanium dioxide particles and properties for flue gas desulfurization].
Under different sintering temperatures(340 degrees C, 440 degrees C, 540 degrees C, 640 degrees C), four TiO2 particles were prepared. The crystal types of all four samples were found to possess anatase structures by XRD. It was obtained by N2 experimental adsorption at low temperature (77K) that their surface areas and average pore size were between 79 and 124 m2/g, 56.8 and 254.8 A respectively. The pore structure of TiO2 particles was characterized by scanning electron microscope (SEM). The tests of adsorption dynamics for FGD and the performance of SO2 removal were investigated in a fixed-bed system for different samples. The results show that SG540 sample which made at 540 degrees C sintering temperature had the most quality among the four samples. It can adsorb SO2 of 38.9 mg for one gram SG540 sample. Different operating conditions for SG540 such as adsorption temperature, SO2 concentration in flue gas and the superficial velocity of flue gas were investigated. TiO2 particles for FGD had more efficiency than other physical sorbents such as active carbon and zeolite. The mechanism for SO2 removal was demonstrated by infrared (IR) spectroscopy and desorption test results to be mainly physical adsorption.
Luo
Yonggang
Y
Key Laboratory of Educational Ministry on Clean Coal Power Generation and Combustion Technology, Southeast University, Nanjing 210096, China. luoyonggang@seu.edu.cn
Li
Daji
D
Huang
Zhen
Z
D000327:Adsorption; D013458:Sulfur Dioxide / Q000737:chemistry*; D013696:Temperature; D014025:Titanium / Q000737:chemistry*
D013458:Sulfur Dioxide; C009495:titanium dioxide; D014025:Titanium