Calix[4]arenes containing ferrocene amide as carboxylate anion receptors and sensors.
Calix[4]arene derivatives containing amide ferrocene units at the wide rim and ethyl ester groups at the narrow rim, L1-L3, were synthesized and their anion binding and sensing properties were investigated. It was found from (1)H NMR titrations that L1-L3 were able to bind selectively with carboxylate anions. Moreover, cyclic voltammetry and square wave voltammetry showed that L1-L3 were able to act as electrochemical sensors for carboxylate anions. [structure: see text]
Tomapatanaget
Boosayarat
B
Department of Chemistry, Faculty of Science, Chulalongkorn University, Bangkok 10330, Thailand.
Tuntulani
Thawatchai
T
Chailapakul
Orawon
O
D000577:Amides / Q000737:chemistry*; D000838:Anions / Q000032:analysis; D015374:Biosensing Techniques / Q000379:methods; D047250:Calixarenes; D002264:Carboxylic Acids / Q000032:analysis / Q000737:chemistry*; D004563:Electrochemistry / Q000379:methods; D005296:Ferrous Compounds / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D000075163:Metallocenes; D008958:Models, Molecular; D010636:Phenols / Q000737:chemistry*; D012680:Sensitivity and Specificity; D017186:Titrimetry / Q000379:methods
D000577:Amides; D000838:Anions; D002264:Carboxylic Acids; D005296:Ferrous Compounds; D000075163:Metallocenes; D010636:Phenols; C121325:calix(4)arene; D047250:Calixarenes; C004998:ferrocene