title: Palladium-bacterial cellulose membranes for fuel cells.
abstract: Bacterial cellulose is a versatile renewable biomaterial that can be used as a hydrophilic matrix for the incorporation of metals into thin, flexible, thermally stable membranes. In contrast to plant cellulose, we found it catalyzed the deposition of metals within its structure to generate a finely divided homogeneous catalyst layer. Experimental data suggested that bacterial cellulose possessed reducing groups capable of initiating the precipitation of palladium, gold, and silver from aqueous solution. Since the bacterial cellulose contained water equivalent to at least 200 times the dry weight of the cellulose, it was dried to a thin membranous structure suitable for the construction of membrane electrode assemblies (MEAs). Results of our study with palladium-cellulose showed that it was capable of catalyzing the generation of hydrogen when incubated with sodium dithionite and generated an electrical current from hydrogen in an MEA containing native cellulose as the polyelectrolyte membrane (PEM). Advantages of using native and metallized bacterial cellulose membranes in an MEA over other PEMs such as Nafion 117 include its higher thermal stability to 130 degrees C and lower gas crossover.
authors.affiliation: Chemical Sciences Division, Oak Ridge National Laboratory, 4500N Bethel Valley Road, Oak Ridge, TN 37831-6194, USA. evansb@ornl.gov
authors.forename: Barbara R
authors.initials: BR
authors.lastname: Evans
authors.forename: Hugh M
authors.initials: HM
authors.lastname: O'Neill
authors.forename: Valerie P
authors.initials: VP
authors.lastname: Malyvanh
authors.forename: Ida
authors.initials: I
authors.lastname: Lee
authors.forename: Jonathan
authors.initials: J
authors.lastname: Woodward
mesh_terms: D001672:Biocompatible Materials; D001674:Bioelectric Energy Sources; D015374:Biosensing Techniques; D002482:Cellulose; D020576:Gluconobacter / Q000737:chemistry; D018625:Microscopy, Atomic Force; D010165:Palladium
chemical_list: D001672:Biocompatible Materials; D010165:Palladium; D002482:Cellulose