Synthesis and electrochemical properties of novel tetrametallic macrocyclic Fischer carbene complexes.
[reaction: see text] Metallomacrocyclic compounds can be easily prepared by 1,4-addition of diamines to alpha,beta-unsaturated Fischer bis-carbene templates. This method allows the preparation of a new family of homo- and heterotetrametallic compounds having macrocyclic cyclophanic structures.
Fernández
Israel
I
Departamento de Química Orgánica, Facultad de Química, Universidad Complutense de Madrid, 28040 Madrid, Spain.
Mancheño
María José
MJ
Gómez-Gallego
Mar
M
Sierra
Miguel A
MA