Ruthenium catalyzed regioselective hydrophosphination of propargyl alcohols.
Catalytic hydrophosphination of propargyl alcohols by ruthenium complexes RuCl(cod)(C5Me5) and RuCl(PPh3)2(C5Me5) leads to the formation of functionalized vinylphosphines, with linkage of the phosphorus atom to the terminal alkyne carbon, via a ruthenium vinylidene intermediate.
Jérôme
François
F
Institut de Chimie de Rennes, UMR 6509-CNRS-Université de Rennes, Organométalliques et Catalyse, Campus de Beaulieui 35042, Rennes, France.
Monnier
Florian
F
Lawicka
Hania
H
Dérien
Sylvie
S
Dixneuf
Pierre H
PH