[New photoreactive cleavable reagents with (trifluoromethyl)diazirine group].
Photoreactive cross-linking reagents that simultaneously contain a trifluoromethyldiazirine and an o-nitrobenzyl groups were synthesized for the first time. Photochemical properties of the reagents were studied, and the possibility of separate activation of the diazirine group and o-nitrobenzyl linker was shown.
Mchedlidze
M T
MT
Faculty of Chemistry, Moscow State University, Vorob'evy gory, Moscow, 119899 Russia. manana_m@imail.ru
Sumbatian
N V
NV
Bondar'
D A
DA
Taranenko
M V
MV
Korshunova
G A
GA
D001671:Biochemistry / Q000379:methods; D003432:Cross-Linking Reagents / Q000138:chemical synthesis / Q000737:chemistry*; D003978:Diazomethane / Q000031:analogs & derivatives / Q000737:chemistry*; D009578:Nitrobenzenes / Q000737:chemistry; D010777:Photochemistry / Q000379:methods; D014466:Ultraviolet Rays
D003432:Cross-Linking Reagents; D009578:Nitrobenzenes; D003978:Diazomethane
Novye fotolabil'nye rasshchepliaemye reagenty, soderzhashchie (triftormetil)diazirinovyiu gruppu.