A distance-controlled oligopeptide linker as a novel photo-induced energy transfer switch by secondary structural transition.
By using an oligopeptide chain as a functional linker and introducing coumarin 2 and coumarin 343 at the chain ends, an effective photo-induced energy transfer system was constructed and energy transfer from coumarin 2 to coumarin 343 was switched on and off by a solvent-induced helix-coil secondary transition of the oligopeptide chain.
Kishimoto
Akira
A
Institute of Industrial Science, University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505, Japan.
Mutai
Toshiki
T
Araki
Koji
K
D002942:Circular Dichroism; D003374:Coumarins / Q000737:chemistry; D004735:Energy Transfer; D009842:Oligopeptides / Q000737:chemistry*; D010777:Photochemistry; D017433:Protein Structure, Secondary; D012997:Solvents / Q000737:chemistry; D013050:Spectrometry, Fluorescence
D003374:Coumarins; D009842:Oligopeptides; D012997:Solvents