Formation and structure of fac-[Mo(CO)3(C2H2[N(CH2But)]2Ge)3]: the first structurally characterized group 6 transition metal complex of an unsaturated diaminogermylene.
The title compound was obtained from the cyclic diaminogermylene C(2)H(2)[N(CH(2)Bu(t))](2)Ge and cis-[Mo(CO)(4)(NCEt)(2)] and its crystal structure determined revealing structural changes in the coordinated ligand indicative of strong pi-acceptor properties.
Kühl
Olaf
O
Institut für Chemie und Biochemie, Ernst-Moritz-Arndt-Universität Greifswald, Soldmannstrasse 16, D-17487 Greifswald, Germany. kuhl@uni-greifswald.de
Lönnecke
Peter
P
Heinicke
Joachim
J