Self-assembly between silver(I) and di- and tri-2-pyridines with flexible spacer: formation of discrete metallocycle versus coordination polymer.
The self-assembly of metallosupramolecules from reactions of flexible 2-pyridyl ligands and silver salts is described. When 1,3-bis(2-pyridyl)propane (L1), tris[(2-pyridyl)methyl]methane (L2), and 1,3-bis(2-pyridyl)-2-tolylpropane (L3) are used in combination with silver ions, novel discrete metallocyclic complexes are formed in crystals. Moreover, the self-assembly of 1,3-bis(2-pyridyl)-2-phenylpropane (L4) with silver nitrate yields a coordination polymer. The examination of its solution shows that this coordination polymer is formed via the solution-based discrete metallocyclic species.
Shin
Dong Mok
DM
School of Chemistry, Center for Molecular Catalysis, College of Natural Sciences, Seoul National University, Seoul 151-742, Korea.
Lee
In Su
IS
Lee
Young-A
YA
Chung
Young Keun
YK