title: Dopant incorporation into garnet solid solutions--a breakdown of Goldschmidt's first rule.
abstract: Atomistic simulations suggest trace elements are more soluble in a 50:50 pyrope (Mg3Al2Si3O12)-grossular (Ca3Al2Si3O12) garnet mixture than in either end-member; consistent with partitioning experiments, and, contrary to Goldschmidt's first rule, large trace element cations may substitute for Mg2+, small trace elements for Ca2+.
authors.affiliation: Geophysical Laboratory, Carnegie Institution of Washington, DC 20015, USA.
authors.forename: W
authors.initials: W
authors.lastname: van Westrenen
authors.forename: N L
authors.initials: NL
authors.lastname: Allan
authors.forename: J D
authors.initials: JD
authors.lastname: Blundy
authors.forename: M Yu
authors.initials: MY
authors.lastname: Lavrentiev
authors.forename: B R
authors.initials: BR
authors.lastname: Lucas
authors.forename: J A
authors.initials: JA
authors.lastname: Purton