Synthesis and spectral characterization of novel compounds derived from 1,10-phenanthroline, lead(II) and tetrabutylammonium tetrafluoroborate.
On interacting 1,10-phenanthroline (phen) with tetrabutylammonium tetrafluoroborate (Bu4N*BF4) two novel compounds have been obtained. These are the 1:1 adduct (phen)*(Bu4N*BF4) and the complex Pb(phen)(Bu4N*BF4)3(NO3)2. The synthesized substances have been characterized by UV, IR and Raman spectroscopy as well as by 1H- and 19F-NMR spectroscopy.
Atanassova
Maria S
MS
Department of Organic Chemistry, University of Chemical Technology and Metallurgy, 1756, Sofia, Bulgaria.
Dimitrov
Georgi D
GD
D001881:Borates / Q000138:chemical synthesis / Q000737:chemistry*; D007854:Lead / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D010618:Phenanthrolines / Q000737:chemistry*; D000644:Quaternary Ammonium Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D013056:Spectrophotometry, Ultraviolet; D013059:Spectrum Analysis, Raman
D001881:Borates; D009942:Organometallic Compounds; D010618:Phenanthrolines; D000644:Quaternary Ammonium Compounds; D007854:Lead; C087244:tetrabutylammonium tetrafluoroborate; C025205:1,10-phenanthroline