NMR evaluation of the configurational stability of Cu(I) complexes.
Association of chiral [CuL2]+ complexes (L = 2-R-phen, 6-R-bpy, and 2-iminopyridine) with TRISPHAT (tris(tetrachlorobenzenediolato)phosphate(V)) anion leads to NMR enantiodifferentiation, which can be used to determine the kinetics of racemization of the complexes.
Desvergnes-Breuil
Valérie
V
Département de Chimie Organique, Université de Genève, quai Ernest-Ansermet 30, CH-1211 Genève 4, Switzerland.
Hebbe
Virginie
V
Dietrich-Buchecker
Christiane
C
Sauvage
Jean-Pierre
JP
Lacour
Jérôme
J