title: Microenvironmental effects in the excited state properties of p-dimethylaminobenzonitrile complexed to alpha- and beta-cyclodextrin.
abstract: The steady state and time resolved fluorescence and the triplet-triplet absorption of p-dimethylaminobenzonitrile (DMABN) in presence of alpha- and beta-cyclodextrin (CD) were investigated at various host and guest concentrations and temperatures. The formation of 1:1 and 1:2 DMABN:alpha-CD and 1:1 and 2:2 complexes DMABN:beta-CD complexes was ascertained by applying global analysis methods. The "pure" fluorescence spectra as well as the emission quantum yields and lifetimes and the triplet properties of the various associates were determined. The role of environmental features in the radiative and non-radiative deactivation of the LE and ICT excited states of the complexed DMABN was elucidated.
authors.affiliation: Istituto per la Sintesi Organica e la Fotoreattività del CNR, I-40129 Bologna, Italia. monti@isof.cnr.it
authors.forename: Sandra
authors.initials: S
authors.lastname: Monti
authors.forename: Pietro
authors.initials: P
authors.lastname: Bortolus
authors.forename: Francesco
authors.initials: F
authors.lastname: Manoli
authors.forename: Giancarlo
authors.initials: G
authors.lastname: Marconi
authors.forename: Gottfried
authors.initials: G
authors.lastname: Grabner
authors.forename: Gottfried
authors.initials: G
authors.lastname: Köhler
authors.forename: Bernd
authors.initials: B
authors.lastname: Mayer
authors.forename: Wojciech
authors.initials: W
authors.lastname: Boszczyk
authors.forename: Krystyna
authors.initials: K
authors.lastname: Rotkiewicz