Novel one-pot synthesis of aryltris(trimethylsilyl)silanes.
The simple combination of tris(trimethylsilyl)potassium, ArMgBr, and ArBr provides a novel "one-pot" synthesis of aryl(tristrimethylsilyl)silanes. A mechanistic rationale for this conversion is proposed.
Sanganee
Mahesh J
MJ
Department of Chemistry, University of Durham, Science Laboratories, South Road, Durham DH1 3LE, U.K.
Steel
Patrick G
PG
Whelligan
Daniel K
DK