title: Ruthenium catalyzed regioselective hydrophosphination of propargyl alcohols.
abstract: Catalytic hydrophosphination of propargyl alcohols by ruthenium complexes RuCl(cod)(C5Me5) and RuCl(PPh3)2(C5Me5) leads to the formation of functionalized vinylphosphines, with linkage of the phosphorus atom to the terminal alkyne carbon, via a ruthenium vinylidene intermediate.
authors.affiliation: Institut de Chimie de Rennes, UMR 6509-CNRS-Université de Rennes, Organométalliques et Catalyse, Campus de Beaulieui 35042, Rennes, France.
authors.forename: François
authors.initials: F
authors.lastname: Jérôme
authors.forename: Florian
authors.initials: F
authors.lastname: Monnier
authors.forename: Hania
authors.initials: H
authors.lastname: Lawicka
authors.forename: Sylvie
authors.initials: S
authors.lastname: Dérien
authors.forename: Pierre H
authors.initials: PH
authors.lastname: Dixneuf