N-confused porphyrin-bearing meso-perfluorophenyl groups: a potential agent that forms stable square-planar complexes with Cu(II) and Ag(III).
[reaction: see text] N-Confused porphyrin (NCP) bearing pentafluorophenyl groups at meso-positions, which were obtained from N-confused dipyrromethane in ca. 20% yield, can form Cu(II) complex as well as Ag(III), Ni(II), and Pd(II) complexes. The square-planar structures of all these metal complexes were elucidated by X-ray single-crystal analyses.
Maeda
Hiromitsu
H
Department of Chemistry, Graduate School of Science, Kyoto University, Kyoto 606-8502, Japan.
Osuka
Atsuhiro
A
Ishikawa
Yuichi
Y
Aritome
Isao
I
Hisaeda
Yoshio
Y
Furuta
Hiroyuki
H