title: Generation and intramolecular reactivity of acyl radicals from alkynylthiol esters under reducing tin-free conditions.
abstract: [reaction: see text] The radical chain reaction of benzenethiol with alkynylthiol esters provides a new, valuable protocol for the tin-free generation of acyl radicals that arise from intramolecular substitution at sulfur by the initial sulfanylvinyl radicals.
authors.affiliation: Dipartimento di Chimica Organica A. Mangini, Università di Bologna, Viale Risorgimento 4, I-40136 Bologna, Italy.
authors.forename: Luisa
authors.initials: L
authors.lastname: Benati
authors.forename: Gianluca
authors.initials: G
authors.lastname: Calestani
authors.forename: Rino
authors.initials: R
authors.lastname: Leardini
authors.forename: Matteo
authors.initials: M
authors.lastname: Minozzi
authors.forename: Daniele
authors.initials: D
authors.lastname: Nanni
authors.forename: Piero
authors.initials: P
authors.lastname: Spagnolo
authors.forename: Samantha
authors.initials: S
authors.lastname: Strazzari