Tetranuclear nickel(II) complexes with genuine mu3-1,1,3 and mu4-1,1,3,3 azide bridges.
Unique tetranickel(II) complexes have been synthesized which incorporate genuine mu3-1,1,3 or mu4-1,1,3,3 bridging azido ligands. Identification of two distinct isomeric mu4-1,1,3,3 binding modes confirms the structural flexibility of the quadruply bridging azide.
Meyer
Franc
F
Institut für Anorganische Chemie, Georg-August-Universität, Tammannstrasse 4, D-37077 Göttingen, Germany. franc.meyer@chemie.uni-goettingen.de
Kircher
Peter
P
Pritzkow
Hans
H