Comparison of various models describing the adsorption of surfactant molecules capable of interfacial reorientation.
The thermodynamic model for describing the adsorption of surfactant molecules in different adsorption states, the reorientation model, is reconsidered on a more rigorous level. The resulting model equations are used to describe experimental surface pressure data published in the literature. The new model proposed contains three physical parameters and describes the experimental dependencies Pi(c) for oxethylated alcohols very accurately.
Medical Physicochemical Centre, Donetsk Medical University, 16 Ilych Avenue, Donetsk 83003, Ukraine.
V B
VB
Fainerman
S A
SA
Zholob
E H
EH
Lucassen-Reynders
R
R
Miller