Optimized conditions for hydrocarbon group type analysis of base oils by thin-layer chromatography-flame ionisation detection.
The results of research on the optimization of the thin-layer chromatography-flame ionisation detection for the determination of group composition of natural base oils, including separation of the aromatics into subgroups, are presented. Neutral base oils obtained in several steps of refining from vacuum distillation petroleum fractions are the most difficult to analyze by hydrocarbon group type analysis (HGTA) because of the high content of aliphatic fragments in their molecules. Factors affecting the accuracy and precision of the results were identified. The paper presents the analytical procedure, including two different calibration methods, as well as the results of studies on the reproducibility of HGTA of typical base oils of different viscosity classes under the optimized conditions. The same conditions were found suitable for HGTA of other high-boiling petroleum fractions by TLC with flame ionisation detection. The paper also introduces a new procedure for reproducible determination of polar fractions in base oils utilizing solid-phase extraction columns, and presents a corrected procedure for the determination of saturated compounds and aromatics (mono-, bi- and polycyclic) in base oils by column liquid chromatography.
Quality Control Department, Rafineria Gdańsk SA, Elblaska 135, 80-718 Gdańsk, Poland. marian.kaminski@rgsa.pl
Marian
M
Kamiński
Joanna
J
Gudebska
Tadeusz
T
Górecki
Rafał
R
Kartanowicz
D002138:Calibration; D002855:Chromatography, Thin Layer / Q000379:methods*; D005410:Flame Ionization / Q000379:methods*; D006838:Hydrocarbons / Q000737:chemistry*; D009821:Oils / Q000737:chemistry*; D015203:Reproducibility of Results
D006838:Hydrocarbons; D009821:Oils