Synthesis of 2,3,6-trideoxysugar-containing disaccharides by cyclization and glycosidation through the sequential activation of sulfoxide and methylsulfanyl groups in a one-pot procedure.
Amaya
Toru
T
Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro, Tokyo 152-8552, Japan.
Takahashi
Daisuke
D
Tanaka
Hiroshi
H
Takahashi
Takashi
T
D000478:Alkylation; D003500:Cyclization; D004187:Disaccharides / Q000138:chemical synthesis* / Q000737:chemistry; D006027:Glycosides / Q000138:chemical synthesis* / Q000737:chemistry; D006031:Glycosylation; D008698:Mesylates / Q000737:chemistry*; D015394:Molecular Structure; D013454:Sulfoxides / Q000737:chemistry*
D004187:Disaccharides; D006027:Glycosides; D008698:Mesylates; D013454:Sulfoxides; C012077:trifluoromethanesulfonic acid