Water-soluble supramolecular bowls formed by intra-clipping of resorcin[4]arene-based ligands with Pd(II) ions.
Bowl-shaped superstructures have been constructed by intra-clipping of resorcin[4]arene derivatives with two equivalents of (en)Pd(NO3)2 in water. The binding phenomena of the aromatic carboxylates were proven to be both enthalpically and entropically favoured.
School of Chemistry, College of Natural Sciences, Seoul National University, Seoul 151-747, Korea.
Seong Jin
SJ
Park
Dong Mok
DM
Shin
Shigeru
S
Sakamoto
Kentaro
K
Yamaguchi
Young Keun
YK
Chung
Myoung Soo
MS
Lah
Jong-In
JI
Hong