Electroanalytical and spectroscopic characterization of poly(o-phenylenediamine) grown on highly oriented pyrolytic graphite.
The polymerization of ortho-phenylenediamine (o-PD) on Highly Oriented Pyrolytic Graphite (HOPG) at different pH (1,3,5,7) was investigated by electroanalytical and spectroscopic methods. Cyclic voltammetry was used both to polymerize o-PD and to study the electroactivity of the resulting poly(ortho-phenylenediamine) (PPD) film. A redox couple associated to the PPD electroactivity, deeply influenced by the pH adopted during polymerization, was recorded. A correlation between this feature and the electrochemistry shown by the oligomers of o-PD, generated in solution during the polymer synthesis, was also found. A comparison between the absorption spectra, in the visible region, of the soluble oligomers and of the PPD films was also performed, suggesting that changes in both the polymer and the oligomer structure occur and are highly related to the polymerization pH. In particular, a higher degree of conjugation is exhibited by the PPD films electrosynthesised at lower pH and this likely explains the higher conductivity as well as the higher electroactivity shown by the material obtained in these conditions.
De Giglio
Elvira
E
Dipartimento di Chimica, Universita' degli Studi di Bari, Via E. Orabona 4,1-70126 Bari.
Losito
Ilario
I
Torsi
Luisa
L
Sabbatini
Luigia
L
Zambonin
Pier Giorgio
PG
D015374:Biosensing Techniques; D004563:Electrochemistry / Q000379:methods*; D005295:Ferrocyanides / Q000737:chemistry; D006108:Graphite / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D008567:Membranes, Artificial; D010084:Oxidation-Reduction; D010655:Phenylenediamines / Q000737:chemistry*; D011108:Polymers / Q000138:chemical synthesis / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet
D005295:Ferrocyanides; D008567:Membranes, Artificial; D010655:Phenylenediamines; D011108:Polymers; D006108:Graphite; C034193:1,2-diaminobenzene; C020354:hexacyanoferrate II