Dissipation of sulfosulfuron in soil and wheat plant under predominant cropping conditions and in a simulated model ecosystem.
Environmental fate and dissipation of the sulfonylurea herbicide sulfosulfuron was investigated in soil (inceptisol) and wheat plant under predominant cropping conditions. Studies were conducted in natural field conditions and in a simulated model ecosystem. Thirty days after the wheat seeds had been sown, sulfosulfuron [N-[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]-2-(ethylsulfonyl)imidazo[1,2-a]pyridine-3-sulfonamide] 75% w/w WG formulation was applied once in the field. The dosages were 25 and 50 g of active ingredient (ai)/ha. Studies were conducted in significantly separated individual plots to avoid contamination. In a predetermined interval, soil samples were collected and analyzed for the residues of sulfosulfuron. At harvest, wheat grain, straw, and soil samples were analyzed for the residues. Similar experiments were conducted in a model ecosystem. Apart from this, after harvest, the succeeding crops coriander (Coriandrum sativum) and edible amaranth (Amaranthus mangostanus L.) were raised in the model ecosystem and studied for the residues. No residues were detected in wheat grain, straw, and soil samples collected at harvest from both experiments or in the succeeding crops coriander and edible amaranth in the model ecosystem when tested at the minimum detection level of 0.001 microg/g. The dissipation of sulfosulfuron was found to have first-order kinetics in soil and plant in both studies. The dissipation data of sulfosulfuron in the model ecosystem were compared with those from the natural field conditions.
Department of Pesticide Chemistry, International Institute of Bio-Technology and Toxicology, Padappai, Chennai 601 301, Tamil Nadu, India. raamesh_a@hotmail.com
Atmakuru
A
Ramesh
Sinthalapadi Thulasiramaraja
ST
Maheswari
D027721:Amaranthus / Q000737:chemistry; D028526:Coriandrum / Q000737:chemistry; D017753:Ecosystem; D007700:Kinetics; D008954:Models, Biological; D010573:Pesticide Residues / Q000032:analysis*; D018514:Plant Structures / Q000737:chemistry; D011743:Pyrimidines / Q000032:analysis* / Q000737:chemistry; D012987:Soil / Q000032:analysis*; D013449:Sulfonamides / Q000032:analysis* / Q000737:chemistry; D014908:Triticum / Q000737:chemistry*
D010573:Pesticide Residues; D011743:Pyrimidines; D012987:Soil; D013449:Sulfonamides; C439268:sulfosulfuron