trans-Diaquabis(thiosemicarbazido-kappa2N,S)nickel(II) dimaleate dihydrate.
In the title compound, [Ni(CH(5)N(3)S)(2)(H(2)O)(2)](C(4)H(3)O(4))(2).2H(2)O, the Ni atom lies on a center of symmetry and is coordinated by N and S atoms from two thiosemicarbazide ligands and the O atoms of two water molecules in a distorted octahedral geometry. In the asymmetric unit, the three components are linked together by one O-H...O and two N-H...O hydrogen bonds. The packing is built from molecular ribbons parallel to the b direction, stabilized by intramolecular hydrogen bonds, and by one N-H...S and two N-H...O intermolecular hydrogen bonds. The ribbons are further connected into columns by N-H...O interactions and then into a three-dimensional network by three O-H...O hydrogen bonds.
Department of Applied Chemistry, University of Science and Technology of China, Hefei 230026, People's Republic of China.
Sheng-Li
SL
Li
Anwar
A
Usman
Ibrahim A
IA
Razak
Hoong-Kun
HK
Fun
Jie-Ying
JY
Wu
Yu-Peng
YP
Tian
Min-Hua
MH
Jiang
Zu-Yao
ZY
Chen