A new type of three-dimensional framework constructed from dodecanuclear cadmium(II) macrocycles.
A new type of three-dimensional framework based on dodecanuclear Cd(II) macrocycles [[Cd2(dpa)(pya)]6(pya)6(dpe)3]n (1) (H2dpa = diphenic acid; Hpya = isonicotinic acid, dpe = 1,2-di(4-pyridyl)ethylene) was prepared by the hydrothermal reaction and in situ synthesis of pya from dpe precursor.
State Key Laboratory of Structural Chemistry, Fujian Institute of the Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
Ruihu
R
Wang
Maochun
M
Hong
Junhua
J
Luo
Rong
R
Cao
Jiabao
J
Weng