Why [CpW(CO)3]+ reduces H2 to dihydride.
The [CpW(CO)3]+ complex, with three pi acceptor ligands and a positive charge, is shown to have an unexpected reducing ability towards H2 because of a low lying triplet state energy.
Lesnard
Hervé
H
Laboratoire de Chimie Physique, UMR 8000, Université Paris Sud 11, Centre d'Orsay, 91 405 Orsay Cedex, France.
Demachy
Isabelle
I
Jean
Yves
Y
Lledos
Agusti
A