Crystal structure of (5,14-methyl-7,12-dimethyl-1,4,8,11-tetraazadiiminecyclotetradecylene-N,N',N'',N''')nickel(II) bis(diisopropyldithiophosphate) complex.
The macrocyclic tetradentate Ni(II) compound was obtained in a reaction and determined by X-ray diffraction. The crystal structure shows that the molecule is centrosymmetric, and Ni atom located in a square planar coordination environment. The two [(iPrO)2PS2]- anions are outside the macrocycle complex to balance. The Ni-N bond lengths are in the range of 1.906(2) to 1.950(2)A.
New Materials & Function Coordination Chemistry Laboratory, Qingdao University of Science and Technology, Qingdao, 266042, PR China.
Fangfang
F
Jian
Kui
K
Jiao
Faqian
F
Liu
Qingxiang
Q
Wang