Synthesis and characterization of cross-linked reverse micelles.
The design and synthesis of a new cross-linkable amphiphile is reported. Solutions of the amphiphile in a toluene/water mixture form reverse micelles as indicated by dynamic light scattering and NMR spectroscopy. As indicated by dynamic light scattering, TEM, and NMR spectroscopy data, these reverse micelles can be cross-linked without drastically changing the radius of the reverse micelles. Mixed reverse micelles are also characterized and cross-linked. The cross-linked reverse micelles are demonstrated to facilitate phase transfer and can be used to site isolate a catalyst.
Department of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14853-1301, USA.
Hyun M
HM
Jung
Kristin E
KE
Price
D Tyler
DT
McQuade