A general model for biosorption of Cd2+, Cu2+ and Zn2+ by aerobic granules.
Aerobic granules are microbial aggregates with a strong and compact structure. This study looked into the feasibility of aerobic granules as a novel type of biosorbent for the removal of individual Cd(2+), Cu(2+) and Zn(2+) from aqueous solution. Based on the thermodynamics of biosorption reaction, a general model was developed to describe the equilibrium biosorption of individual Cd(2+), Cu(2+) and Zn(2+) by aerobic granules. This model provides good insights into the thermodynamic mechanisms of biosorption of heavy metals. The model prediction was in good agreement with the experimental data obtained. It was further demonstrated that the Langmuir, Freundlich and Sips or Hill equations were particular cases of the proposed model. The biosorption capacity of individual Cd(2+), Cu(2+) and Zn(2+) on aerobic granules was 172.7, 59.6 and 164.5 mgg(-1), respectively. These values may imply that aerobic granules are effective biosorbent for the removal of Cd(2+), Cu(2+) and Zn(2+) from industrial wastewater.
Liu
Yu
Y
Environmental Engineering Research Centre, School of Civil and Environmental Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore. cylui@ntu.edu.sg
Xu
Hui
H
Yang
Shu-Fang
SF
Tay
Joo-Hwa
JH
D000327:Adsorption; D000332:Aerobiosis; D001420:Bacteria, Aerobic / Q000737:chemistry / Q000166:cytology / Q000378:metabolism*; D001422:Bacterial Adhesion; D018441:Biofilms; D019149:Bioreactors / Q000382:microbiology; D002104:Cadmium / Q000737:chemistry / Q000493:pharmacokinetics*; D003198:Computer Simulation; D003300:Copper / Q000737:chemistry / Q000493:pharmacokinetics*; D005240:Feasibility Studies; D008863:Microspheres; D008954:Models, Biological; D008956:Models, Chemical; D010316:Particle Size; D014865:Waste Disposal, Fluid / Q000379:methods; D014874:Water Pollutants, Chemical / Q000493:pharmacokinetics; D015032:Zinc / Q000493:pharmacokinetics*
D014874:Water Pollutants, Chemical; D002104:Cadmium; D003300:Copper; D015032:Zinc