Determination of 4-nonylphenol and 4-nonylphenol ethoxylates in river sediments by microwave assisted solvent extraction.
The efficiency of Microwave Assisted Solvent Extraction (MASE) for the simultaneous determination of nonylphenol (NP) and nonylphenol ethoxylates (NPE) in river sediments has been evaluated. An optimisation study was carried out in order to identify the variables having the greatest influence on the extraction efficiency. The comparison between the solvents (methanol and acetone-hexane 1:1) shows that the more polar solvent (i.e. methanol) allows a more effective extraction of NP and NPE from sediments. Analytical results show that there is not a considerable improvement by doubling extraction time, while the increase of solvent volume is significant. The comparative study with Soxhlet and pressurised liquid extraction (PLE) methods demonstrates that Microwave Assisted Solvent Extraction is a suitable alternative extraction method for the 4-NP and 4-NPE determination in river sediments, showing an accuracy and precision comparable to those obtained with PLE and better than those obtained with Soxhlet.
Croce
Valeria
V
CNR-IRSA, via Mornera 25,1-20047 Brugherio (MI), Italy.
Paggio
Stefano
S
Pagnoni
Andrea
A
Polesello
Stefano
S
Valsecchi
Sara
S
D002851:Chromatography, High Pressure Liquid; D004785:Environmental Pollutants / Q000032:analysis*; D005026:Ethylene Glycols / Q000032:analysis*; D005618:Fresh Water; D019015:Geologic Sediments / Q000737:chemistry*; D008872:Microwaves; D010636:Phenols / Q000032:analysis*; D012997:Solvents; D014874:Water Pollutants, Chemical / Q000032:analysis*
D004785:Environmental Pollutants; D005026:Ethylene Glycols; D010636:Phenols; D012997:Solvents; D014874:Water Pollutants, Chemical; C021754:terics; C041594:4-nonylphenol