De novo design of non-hydrogen-bonded helical pseudopeptides composed of oxanipecotic acid oligomers.
Ab initio calculation and circular dichroism experiments reveal that Oxa-oligomers adopted pronounced non-hydrogen-bonded helical structures.
Lee
Myung-ryul
MR
Department of Chemistry, Yonsei University, Seoul 120-749, Korea.
Kim
Kwang-Yon
KY
Cho
Ung-In
UI
Boo
Doo Wan
DW
Shin
Injae
I
D040761:Biomimetic Materials / Q000737:chemistry; D002942:Circular Dichroism; D008958:Models, Molecular; D009557:Nipecotic Acids / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D017433:Protein Structure, Secondary; D013237:Stereoisomerism; D013816:Thermodynamics
D009557:Nipecotic Acids; D011108:Polymers; C030278:nipecotic acid