Capillary force on a nanoscale tip in dip-pen nanolithography.
Monte Carlo simulation has been used to characterize the capillary force due to the condensation of a liquid meniscus between a tip with a nanoscale asperity and a flat surface. To consider both hydrophobic and hydrophilic molecules coating the tip as a model of dip-pen nanolithography, tips with various wettabilities are studied. The capillary force due to the meniscus is calculated for various saturations (humidities). We have implemented a thermodynamic integration technique that can project the force into energetic and entropic contributions. In most cases, the force is mainly energetic in origin. At the snap-off separation where the meniscus disappears, the tip feels a significant entropic force at high saturation. Our calculation shows nonmonotonic behavior of the pull-off force as a function of saturation, which is in qualitative accord with experiments.
Department of Chemistry, Materials Research Center/Center for Nanofabrication and Molecular Self Assembly, Northwestern University, Evanston, IL 60208, USA.
Joonkyung
J
Jang
George C
GC
Schatz
Mark A
MA
Ratner