Sulfur isotopic composition of H2S and SO4(2-) from mineral springs in the Polish Carpathians.
A number of springs in Carpathian Mts. contain dissolved H2S and SO4(2-) in concentrations above 10 mg/dm3. In this study we have investigated the sulfur isotope composition (delta34S) of the dissolved sulfur species in the springs from the flysch area in the Carpathian Mts. along the tectonic dislocation. It is believed that some of these springs may carry a major fraction of dissolved sulfur species of extremely deep sulfur (of mantle origin), which is subjected to SO4(2-)-H2S isotope exchange at high temperatures. The original isotopic compositions may be modified by reduction/oxidation at low temperatures and by admixture of sulfur from other sources. In order to distinguish the sulfur of mantle origin we investigated delta34S of dissolved sulfide and sulfate and on the basis of known concentrations we calculated delta34S of total dissolved sulfur. The isotope fractionation between sulfate and sulfide helped to distinguish the sulfur origin. Evaluating the sulfur isotope exchange, we selected 4 springs which likely have only weakly disturbed sulfur of mantle origin.
Rajchel
L
L
Academy of Mining and Metallurgy, Chair of Stratigraphy and Regional Geology, 30-059 Krakow, Poland.
Rajchel
J
J
Szaran
J
J
Halas
S
S
D000393:Air Pollutants / Q000032:analysis*; D006862:Hydrogen Sulfide / Q000032:analysis*; D011044:Poland; D012995:Solubility; D013431:Sulfates / Q000032:analysis; D013440:Sulfides / Q000032:analysis; D013460:Sulfur Isotopes / Q000032:analysis; D013696:Temperature; D014881:Water Supply
D000393:Air Pollutants; D013431:Sulfates; D013440:Sulfides; D013460:Sulfur Isotopes; D006862:Hydrogen Sulfide