Water-soluble supramolecular bowls formed by intra-clipping of resorcin[4]arene-based ligands with Pd(II) ions.
Bowl-shaped superstructures have been constructed by intra-clipping of resorcin[4]arene derivatives with two equivalents of (en)Pd(NO3)2 in water. The binding phenomena of the aromatic carboxylates were proven to be both enthalpically and entropically favoured.
Park
Seong Jin
SJ
School of Chemistry, College of Natural Sciences, Seoul National University, Seoul 151-747, Korea.
Shin
Dong Mok
DM
Sakamoto
Shigeru
S
Yamaguchi
Kentaro
K
Chung
Young Keun
YK
Lah
Myoung Soo
MS
Hong
Jong-In
JI