High tetraalkylaluminate fluxionality in half-sandwich complexes of the trivalent rare-earth metals.
Steric factors govern the formation of half-sandwich complexes (C5Me4R)Ln[N(SiHMe2)2]2 according to acid-base reactions utilising Ln[N(SiHMe2)2)3(thf)2 and substituted cyclopentadienes. Subsequent trimethylaluminium-promoted silylamide elimination produces the first half-sandwich bis(tetramethylaluminate) complexes (C5Me4R)Ln(AlMe4)2.
Anwander
Reiner
R
Anorganisch-chemisches Institut, Technische Universität Miinchen, Lichtenbergstrasse 4, D-85747 Garching, Germany. reiner.anwander@ch.tum.de
Klimpel
Michael G
MG
Dietrich
H Martin
HM
Shorokhov
Dmitry J
DJ
Scherer
Wolfgang
W