Evaluation of activated carbon fiber filter for sampling of organochlorine pesticides in environmental water samples.
A simple method for quantitative analyses of organic chlorine pesticides (OCPs) in environmental water samples such as rainwater, river water and seawater using activated carbon fiber filters (ACFF) is described. ACFF was used as adsorbent to collect the chemicals in water samples. The collection of OCPs was completed almost for one day by stirring the mixture of the sample and the ACFF chips at room temperature. The adsorbed OCPs on the ACFF could be extracted easily with toluene-ethanol (4:1) mixed solvent. The purified extract by a florisil column chromatograph was followed by the analysis using high-resolution gas chromatograph/high-resolution mass spectrometer. Recoveries of OCPs spiked to actual samples such as rainwater, river water and seawater samples were approximately more than 80%, and the coefficients of variations were within 10%. This method was applied to the actual samples and was confirmed to be applicable for monitoring sub-ng/l level OCPs in environmental water samples.
Murayama
Hitoshi
H
Niigata Prefectural Institute of Public Health and Environmental Sciences, 314-1 Sowa, Niigata 950-2144, Japan. h.mura@d5.dion.ne.jp
Moriyama
Noboru
N
Mitobe
Hideko
H
Mukai
Hiroyuki
H
Takase
Yuuya
Y
Shimizu
Ken ichi
Ki
Kitayama
Yoshie
Y
D002606:Charcoal / Q000737:chemistry*; D002627:Chemistry, Physical / Q000379:methods; D002845:Chromatography / Q000379:methods; D005069:Evaluation Studies as Topic; D005374:Filtration / Q000295:instrumentation / Q000379:methods; D008401:Gas Chromatography-Mass Spectrometry; D006843:Hydrocarbons, Chlorinated; D007306:Insecticides / Q000032:analysis*; D017633:Magnesium Silicates / Q000737:chemistry; D015203:Reproducibility of Results; D014874:Water Pollutants, Chemical / Q000032:analysis*
D006843:Hydrocarbons, Chlorinated; D007306:Insecticides; D017633:Magnesium Silicates; D014874:Water Pollutants, Chemical; C005013:Florisil; D002606:Charcoal