title: Inhibited chelation in the new gamma-phosphino-beta-diketiminate to give phosphine --> arsine coordination.
abstract: A gamma-diphenylphosphino-beta-diketimine has been synthesised and the 31P NMR handle allows for in situ analysis of reaction mixtures revealing unprecedented reactivity with AsCl3 to give a novel phosphinoarsine intramolecular coordination complex.
authors.affiliation: Department of Chemistry, Dalhousie University, Halifax, Nova Scotia B3H 4J3, Canada.
authors.forename: Paul J
authors.initials: PJ
authors.lastname: Ragogna
authors.forename: Neil
authors.initials: N
authors.lastname: Burford
authors.forename: Mark
authors.initials: M
authors.lastname: D'eon
authors.forename: R
authors.initials: R
authors.lastname: McDonald