A two-step field-induced magnetic transition in a novel layered cobalt diphosphonate.
Compound Na6Co7(hedp)2(hedpH)4(H2O)4 x 8H2O (hedp = 1-hydroxyethylidenediphosphonate) with a novel layer structure is reported in this paper. The layer maybe viewed as made up from two types of chains each of composition Co3(hedp)2 and Co2(hedpH)2. Magnetic measurements at 1.8 K reveal a metamagnetic transition at ca. 6.5 kOe, followed by a second transition to a ferromagnetic state at ca. 30 kOe.
Yin
Ping
P
State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093, PR China.
Gao
Song
S
Zheng
Li-Min
LM
Wang
Zheming
Z
Xin
Xin-Quan
XQ