title: Identification and confirmation of traces of chlorinated fatty acids in fish downstream of bleached kraft pulp mills by gas chromatography with halogen-specific detection.
abstract: Methyl esters of threo-9,10-dichlorooctadecanoic, threo-7,8-dichlorohexadecanoic, and threo-5,6-dichlorotetradecanoic acids, present in transesterified extracts of filets, gonad, intestinal fat and carcass of white sucker (Catostomus commersoni) sampled in receiving waters of bleached kraft pulp mill effluents, were identified by gas chromatography with halogen-specific detection (XSD). Identification was based on (1) a comparison of the retention times of a sample peak with a prospective reference standard on two stationary phases of very different polarities by spiking, and (2) elution behavior of configurational and positional isomers of dichloro fatty acid methyl esters.
authors.affiliation: Department of Chemical Engineering and Applied Chemistry, University of Toronto, 200 College Street, Toronto, Ontario M5S 3E5, Canada. bzhuang@taro.ca
authors.forename: Wenshan
authors.initials: W
authors.lastname: Zhuang
authors.forename: Bruce
authors.initials: B
authors.lastname: McKague
authors.forename: Douglas
authors.initials: D
authors.lastname: Reeve
authors.forename: John
authors.initials: J
authors.lastname: Carey
mesh_terms: D000818:Animals; D002849:Chromatography, Gas / Q000379:methods*; D005227:Fatty Acids / Q000032:analysis* / Q000737:chemistry; D005260:Female; D005399:Fishes; D006843:Hydrocarbons, Chlorinated / Q000032:analysis*; D007220:Industrial Waste; D009682:Magnetic Resonance Spectroscopy; D008297:Male
chemical_list: D005227:Fatty Acids; D006843:Hydrocarbons, Chlorinated; D007220:Industrial Waste