title: Glass-containing gunshot residue particles: a new type of highly characteristic particle?
abstract: In 0.22 caliber rimfire ammunition, the primer often contains lead or lead and barium compounds. As residues from these primers do not contain lead, barium, and antimony, they cannot be uniquely classified as gunshot residue (GSR) under ASTM designation E 1588-95. In many types of 0.22 caliber rimfire ammunition, the cartridge contains a primer sensitized with glass. In this paper we describe a previously unreported type of GSR particle consisting of glass fused with other primer components. As there appear to be few potential environmental or occupational sources of particles composed of lead and barium compounds fused to glass, particularly borosilicate glass, these particles may have high evidential value. Scanning electron microscopy with energy dispersive X-ray detection (SEM-EDX) and time-of-flight secondary ion mass spectrometry (TOF-SIMS) were evaluated for the characterization of glass-containing GSR particles. The occurrence of glass-containing GSR particles was established in the residue from various brands of 0.22 caliber ammunition, and several sub-types were identified.
authors.affiliation: Forensic Science Laboratory, Chemistry Centre (WA), 125 Hay Street, East Perth, Western Australia.
authors.forename: Peter
authors.initials: P
authors.lastname: Collins
authors.forename: John
authors.initials: J
authors.lastname: Coumbaros
authors.forename: Graham
authors.initials: G
authors.lastname: Horsley
authors.forename: Bernard
authors.initials: B
authors.lastname: Lynch
authors.forename: K Paul
authors.initials: KP
authors.lastname: Kirkbride
authors.forename: William
authors.initials: W
authors.lastname: Skinner
authors.forename: Gunter
authors.initials: G
authors.lastname: Klass