Unprecedented conversion of triethylamine and disulfur dichloride into a thienopentathiepin and a heptathiocane.
[reaction: see text] In a remarkable cascade reaction, triethylamine is converted into the thienopentathiepin 2a and the heptathiocane 3a by a preequilibrated solution of disulfur dichloride and DABCO in chloroform.
Konstantinova
Lidia S
LS
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospect, 47, 119991 Moscow, Russia.
Rakitin
Oleg A
OA
Rees
Charles W
CW
Souvorova
Ljudmila I
LI
Golovanov
Denis G
DG
Lyssenko
Konstantin A
KA