Synthesis and reactions of terminal osmium and ruthenium complexed phosphinidenes [(eta6-Ar)(L)Md=PMes*].
Novel, very stable ruthenium and osmium containing terminal phosphinidene complexes [(eta(6)-Ar)(L)M=Mes*] (Ar=benzene, p-cymene; L=PR(3), CO, and RNC) have been prepared by dehydrohalogenation of novel [(eta(6)-Ar)MX(2)(PH(2)Mes*)] complexes in the presence of a stabilizing ligand. Xray crystal structures are reported for [(eta(6)-C(6)H(6))(PPh(3))Rud=PMes*] (9) and [(eta(6)-pCy)(PPh(3))Os=PMes*] (4). Dehydrohalogenation in the absence of a stabilizing ligand resulted in the new P-spiroannulated Ru(2)P(2)-ring structure 16. Dehydrohalogenation in the presence of but-2-yne gave a novel phosphaallyl complex [(eta(6)-Ar)Ru(eta(3)-R(2)PC(Me)CHMe)] 26, for which an X-ray crystal structure is reported. The mechanism by which 16 and 26 are obtained is presumed to involve the intermediate formation of the 16-electron (eta(6)-benzene)Rud=PMes* phosphinidene complex.
Termaten
Arjan T
AT
Department of Organic and Inorganic Chemistry, Faculty of Sciences Vrije Universiteit, De Boelelaan 1083 1081 HV, Amsterdam, The Netherlands.
Nijbacker
Tom
T
Schakel
Marius
M
Lutz
Martin
M
Spek
Anthony L
AL
Lammertsma
Koop
K