title: Mechanisms affecting the infiltration and distribution of ethanol-blended gasoline in the vadose zone.
abstract: One- and two-dimensional experiments were conducted to examine differences in the behavior of gasoline and gasohol (10% ethanol by volume) as they infiltrate through the unsaturated zone and spread at the capillary fringe. Ethanol in the spilled gasohol quickly partitions into the residual water in the vadose zone and is retained there as the gasoline continues to infiltrate. Under the conditions tested, over 99% of the ethanol was initially retained in the vadose zone. Depending on the volume of gasoline spilled and the depth to the water table, this causes an increase in the aqueous-phase saturation and relative permeability, thus allowing the ethanol-laden water to drain into the gasoline pool. Under the conditions tested, the presence of ethanol does not have a significant impact on the overall size or shape of the resulting gasoline pool at the capillary fringe. Residual gasoline saturations in the vadose zone were significantly reduced however because of reduced surface and interfacial tensions associated with high ethanol concentrations. The flux of ethanol in the effluent of the column ranged from 1.4 x 10(-4) to 4.5 x 10(-7) g/(cm2 min) with the LNAPL and from 6 x 10(-3) to 3.0 x 10(-4) g/(cm2 min) after water was introduced to simulate rain infiltration. The experimental results presented here illustrate that the dynamic effects of ethanol partitioning into the aqueous phase in the vadose zone create an initial condition that is significantly different than previously understood.
authors.affiliation: Center for the Environment, Clarkson University, Potsdam, New York 13699-5710, USA.
authors.forename: Cory J
authors.initials: CJ
authors.lastname: McDowell
authors.forename: Susan E
authors.initials: SE
authors.lastname: Powers
mesh_terms: D002274:Carcinogens, Environmental / Q000032:analysis*; D004784:Environmental Monitoring; D000431:Ethanol / Q000032:analysis / Q000737:chemistry*; D005742:Gasoline / Q000032:analysis*; D010539:Permeability; D012989:Soil Pollutants / Q000032:analysis*; D012995:Solubility; D012997:Solvents / Q000032:analysis / Q000737:chemistry*; D014873:Water Pollutants / Q000032:analysis*; D014881:Water Supply
chemical_list: D002274:Carcinogens, Environmental; D005742:Gasoline; D012989:Soil Pollutants; D012997:Solvents; D014873:Water Pollutants; D000431:Ethanol