"Magic rod" rotaxanes: the hydrogen bond-directed synthesis of molecular shuttles under thermodynamic control.
[reaction: see text] Peptide [2]- and [3]rotaxanes are assembled in high yields under thermodynamic control using hydrogen bonding interactions and reversible cross olefin metathesis.
Hannam
Jeffrey S
JS
School of Chemistry, University of Edinburgh, The Kings Buildings, West Mains Road, Edinburgh EH9 3JJ, United Kingdom.
Kidd
Timothy J
TJ
Leigh
David A
DA
Wilson
Andrew J
AJ