Dicationic [(BINAP)Pd(solvent)2]2+[TfO-]2: enantioselective hydroamination catalyst for alkenoyl-N-oxazolidinones.
Dicationic (BINAP)palladium(II) complex induced high enantioselectiviies in the addition of primary (and secondary) aromatic amines to alpha,beta-unsaturated oxazolidinones (up to 93% ee).
Li
Kelin
K
Department of Chemistry, King's College London, Strand, London WC2R 2LS, UK.
Hii
King Kuok
KK