Ni(III) vs. Ni(II)-thiyl radical: charge-delocalisation in a binuclear Ni(III)Ni(II)-dithiolate complex.
Multi-frequency EPR spectroscopy on 61Ni-labelled samples of [Ni2(L)]3+ confirms extensive charge-delocalisation between the Ni(III) centre and thiolate donors in the Ni(II)Ni(III) complex.
Branscombe
Neil D J
ND
School of Chemistry, The University of Nottingham, Nottingham, UK NG7 2RD.
Atkins
Andrew J
AJ
Marin-Becerra
Armando
A
McInnes
Eric J L
EJ
Mabbs
Frank E
FE
McMaster
Jonathan
J
Schröder
Martin
M