Coordination polymers based on square planar Co(II) node and linear spacer: solvent-dependent pseudo-polymorphism and an unprecedented interpenetrating structure containing both 2D and 3D topological isomers.
Reaction of Co(NCS)2 with 1-methyl-1'-(4-pyridyl)-2-(4-pyrimidyl)ethylene (mppe) in different solvents yields two kinds of novel coordination polymer structures of [Co(mppe)2(NCS)2]n: one of them shows an unprecedented interpenetrating structure with both 2D and 3D topological isomers.
Shin
Dong Mok
DM
School of Chemistry, Center for Molecular Catalysis, College of Natural Sciences, Seoul National University, Seoul 151-747, Korea.
Lee
In Su
IS
Chung
Young Keun
YK
Lah
Myoung Soo
MS