Stereoselective formation of dinuclear complexes with anomalous CD spectra.
A novel chiral tetradentate Schiff base ligand forms dinuclear lambda,lambda-[M2L2Cl2]2+ complexes with high diastereoselectivity; the complexes exhibit anomalous CD spectra due to exciton coupling of chromophores located on different metal centres.
Telfer
Shane G
SG
JST ERATO Kuroda Chiromorphology Project, Park Bldg., 4-7-6 Komaba, Meguro-ku, Tokyo 153-0041, Japan. shane.telfer@chiromor2.erato.rcast.u-tokyo.ac.jp
Kuroda
Reiko
R
Sato
Tomohiro
T