Catalytic wet oxidation: mathematical modeling of multicompound destruction.
A mathematical model of a three-phase catalytic reactor, CatReac, was developed for analysis and optimization of a catalytic oxidation reactor that is used in the International Space Station potable water processor. The packed-bed catalytic reactor, known as the volatile reactor assembly (VRA), is operated as a three-phase reactor and contains a proprietary catalyst, a pure-oxygen gas phase, and the contaminated water. The contaminated water being fed to the VRA primarily consists of acetic acid, acetone, ethanol, 1-propanol, 2-propanol, and propionic acid ranging in concentration from 1 to 10 mg/L. The Langmuir-Hinshelwood Hougen-Watson (L-H) (Hougen, 1943) expression was used to describe the surface reaction rate for these compounds. Single and multicompound short-column experiments were used to determine the L-H rate parameters and calibrate the model. The model was able to predict steady-state multicomponent effluent profiles for short and full-scale reactor experiments.
Yang
J
J
Institute of Paper Science and Technology, Atlanta, Georgia, USA.
Hand
D W
DW
Hokanson
D R
DR
Crittenden
J C
JC
Oman
E J
EJ
D002384:Catalysis; D008962:Models, Theoretical; D010084:Oxidation-Reduction