Poly(9,9'-spirobifluorene-manganese porphyrin): a new catalytic material for oxidation of alkenes by iodobenzene diacetate and iodosylbenzene.
Anodic oxidation of tetraspirobifluorene-manganese porphyrin lead to the coating of the working electrode by insoluble electroactive poly(9,9'-spirobifluorene-manganese porphyrin) films for which electrochemical behaviour and physicochemical properties are described; these polymeric materials are able to catalyze the heterogeneous epoxidation of styrene with iodobenzene diacetate and iodosylbenzene.
Poriel
Cyril
C
Laboratoire de Chimie Organométallique et Biologique, UMR CNRS 6509, Université de Rennes 1, 35042 Rennes, France.
Ferrand
Yann
Y
le Maux
Paul
P
Raul-Berthelot
Joëlle
J
Simonneaux
Gerard
G