Synthesis and structure of the hexameric, dodecanuclear metallamacrocycle [(5-methyl-3-phenylpyrazole)2Zn2(OCH2CH2S)]6.
A metallamacrocycle containing twelve Zn2+ ions, making it the largest member of a family of pyrazole-bridged cyclic metal clusters, has been synthesized and structurally characterized from the reaction of [Zn(ClO4)2] with 5-methyl-3-phenylpyrazole, 2-mercaptoethanol, and NaOH.
Puerta
David T
DT
Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California, USA.
Cohen
Seth M
SM
D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D017967:Zinc Compounds / Q000138:chemical synthesis / Q000737:chemistry*
D009942:Organometallic Compounds; D017967:Zinc Compounds