A metal-centered hydrophobic pocket recognizing pyridine over piperidine.
Two external spaces of an inorganic tennis ball are a novel type of metal-centered hydrophobic pocket where two hydrophobic trans-(+/-)-1,2-diaminocyclohexane groups stand perpendicularly to and around the metal coordination plane. The space recognizes pyridine over piperidine, and a novel supramolecule was obtained using such pyridine recognition properties.
Kim
Ki-Hyun
KH
Life Science Division, Korea Institute of Science and Technology, Seoul 130-650, Korea.
Song
Rita
R
Kim
Kwan Mook
KM
D003300:Copper / Q000737:chemistry*; D003514:Cyclohexylamines / Q000737:chemistry; D057927:Hydrophobic and Hydrophilic Interactions; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D010847:Picolines / Q000737:chemistry; D010880:Piperidines / Q000737:chemistry*; D010984:Platinum / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry*
D003514:Cyclohexylamines; D009942:Organometallic Compounds; D010847:Picolines; D010880:Piperidines; D011725:Pyridines; D010984:Platinum; C032727:piperidine; D003300:Copper; C030435:1,2-cyclohexanediamine; C023666:pyridine