Stereospecific construction of contiguous quaternary and tertiary stereocenters by rearrangement from indoline-2-methanol to 2,2,3-trisubstituted tetrahydroquinoline: application to an efficient total synthesis of natural virantmycin.
Ori
Mayuko
M
Exploratory Chemistry Research Laboratories, Sankyo Co., Ltd., 1-2-58 Hiromachi, Shinagawa-ku, Tokyo 140-8710, Japan.
Toda
Narihiro
N
Takami
Kazuko
K
Tago
Keiko
K
Kogen
Hiroshi
H
D000998:Antiviral Agents / Q000138:chemical synthesis* / Q000737:chemistry*; D007211:Indoles / Q000737:chemistry*; D000432:Methanol / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D011804:Quinolines / Q000138:chemical synthesis* / Q000737:chemistry*; D013237:Stereoisomerism
D000998:Antiviral Agents; D007211:Indoles; D011804:Quinolines; C473420:benzastatin E; C057812:indoline; C030886:virantmycin; D000432:Methanol