title: Experimental observation of a nearly logarithmic decay of the orientational correlation function in supercooled liquids on the picosecond-to-nanosecond time scales.
abstract: Dynamics of five supercooled molecular liquids have been studied using optical heterodyne detected optical Kerr effect experiments. "Intermediate" time scale power law decays (approximately 2 ps to 1-10 ns) with temperature independent exponents close to -1 have been observed in all five samples from high temperature to approximately T(c), the mode-coupling theory (MCT) critical temperature. The amplitude of the intermediate power law increases with temperature as [(T-T(c))/T(c)](1/2). The results cannot be explained by standard MCT, and one possible explanation within MCT would require the higher order singularity scenario, thought to be highly improbable, to be virtually universal.
authors.affiliation: Department of Chemistry, Stanford University, Stanford, California 94305, USA.
authors.forename: Hu
authors.initials: H
authors.lastname: Cang
authors.forename: V N
authors.initials: VN
authors.lastname: Novikov
authors.forename: M D
authors.initials: MD
authors.lastname: Fayer