Phase behavior and dynamics of fluids in mesoporous glasses.
Equilibrium and dynamical relaxation behavior of fluids confined in disordered mesoporous glasses such as Vycor are studied based on a lattice model using mean field theory and Monte Carlo simulations. Preferential attractive interactions between the solid surfaces and the fluid suppresses macroscopic phase separation, while making the relaxation rate increasingly slow. The free energy landscape characterized by the presence of the many metastable minima separated by finite barriers dominates both the static and dynamic behavior of fluids at low temperature. Our results provide additional insight into the nature of hysteresis in adsorption measurements of gases in porous glasses.
Woo
Hyung-June
HJ
Department of Chemical Engineering, University of Massachusetts, Amherst 01003, USA.
Monson
P A
PA