[Photoinduced enzymatic epimerization of glucose].
The possibility was examined whether weak external electromagnetic radiation can affect the parameters of enzymic reactions. It was found that, in a system involving an aqueous solution of concanavalin A, glucose, and erbium salt exposed to helium-neon laser light of a wavelength of 633 nm, epimers of glucose: allosa, mannose, and galactose are formed. The effect observed was found to represent a photoinduced enzymic reaction in which the protein dissolved in water converts the glucose associated with it into epimers by the action of electromagnetic radiation. The photoepimerase activity of concanavalin A was established for the first time.
Chudnovskiĭ
V M
VM
Il'ichev Pacific Oceanological Institute, Far East Division, Russian Academy of Sciences, ul. Baltiiskaya 43, Vladivostok, 690041 Russia.
Iusupov
V I
VI
Kurika
A V
AV
Glazunov
V P
VP
D002849:Chromatography, Gas; D003208:Concanavalin A / Q000737:chemistry; D005947:Glucose / Q000737:chemistry / Q000528:radiation effects*; D007536:Isomerism; D010777:Photochemistry
D003208:Concanavalin A; D005947:Glucose