Trimethyltriazacyclohexane as bridging ligand for triangular Cu3 units and C-H hydride abstraction into a Cu6 cluster.
Reaction of [Cu(MeCN)4](BF4) with N,N',N"-trimethyl-1,3,5-triazacyclohexane in CH2Cl2 leads to two Cu6 clusters containing the triazacyclohexane as a ligand to triangular Cu3 units with the abstraction and incorporation of chloride and hydride.
Köhn
Randolf D
RD
Department of Chemistry, University of Bath, Bath, UK BA2 7AY. r.d.kohn@bath.ac.uk
Pan
Zhida
Z
Mahon
Mary F
MF
Kociok-Köhn
Gabriele
G