In situ UV-visible spectroelectrochemical evidences for conducting copolymer formation between diphenylamine and m-methoxyaniline.
Electrochemical copolymerization of diphenylamine (DPA) with m-methoxy aniline (MA) was carried out in 4 M H(2)SO(4) by cyclic voltammetry (CV). Cyclic voltammograms (CVs) of the copolymer films were recorded in monomer-free background electrolyte. In situ sepectroelectrochemical studies were carried out on an optically transparent electrode (Indium tin oxide (ITO) coated glass) in 4 M H(2)SO(4) for different feed ratios of the comonomers. Constant potential and potential sweep methods were employed for performing polymerization. UV-visible absorption spectra were collected continuously and concurrently during the copolymerization in both the cases. The results from constant potential electropolymerisation indicated the formation of an intermediate with an absorption peak at 576 nm. Derivative cyclic voltabsorptogram (DCVA) was deduced from the results of cyclic spectrovoltammetry. The DCVA derived at 576 nm confirms the intermediates formed during the electrochemical copolymerization. The compositional changes of the two monomers in the copolymers with changes in feed composition of two monomers as predicted from in situ spectro electrochemical studies are evident from elemental analysis. A plausible copolymerization mechanism is suggested.
Thanneermalai
M
M
Department of Industrial Chemistry, Alagappa University, Karaikudi 630003, India.
Jeyaraman
T
T
Sivakumar
C
C
Gopalan
A
A
Vasudevan
T
T
Wen
T C
TC
D000814:Aniline Compounds / Q000737:chemistry*; D004159:Diphenylamine / Q000737:chemistry*; D004563:Electrochemistry; D011108:Polymers / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet
D000814:Aniline Compounds; D011108:Polymers; C416807:polyaniline; D004159:Diphenylamine