Dodecanuclear and octanuclear manganese rods.
The reaction of the neutral triangle [Mn3O(O2CR)6(L)3] with 1,1,1-tris(hydroxymethyl)ethane (H3thme) affords novel dodecanuclear and octanuclear manganese complexes with unusual ladder-like cores built from edge-sharing triangles.
Brechin
Euan K
EK
Department of Chemistry, The University of Manchester, Oxford Road, Manchester, UK M13 9PL. euan.k.brechin@man.ac.uk
Soler
Monica
M
Christou
George
G
Helliwell
Madeleine
M
Teat
Simon J
SJ
Wernsdorfer
Wolfgang
W