Charge assisted chiral hybrid H-bonded molecular networks.
The co-crystallisation of [Fe(CN)5NO]2- and cyclic achiral 1(2+) and chiral 2(2+) or 3(2+) bisamidinium tectons leads in the crystalline phase to the formation of 1-D H-bonded achiral and chiral molecular networks respectively. In all cases, the network is formed by mutual bridging of the anionic and cationic units through a chelate mode of H-bonding.
Ferlay
Sylvie
S
Laboratoire de Chimie de Coordination Organique, Service Commun des Rayons X, Université Louis Pasteur, F-67000 Strasbourg, France.
Holakovsky
Roman
R
Hosseini
Mir Wais
MW
Planeix
Jean-Marc
JM
Kyritsakas
Nathalie
N