title: An air and thermally stable one- component catalyst for the amination of aryl chlorides.
abstract: [reaction: see text] In this paper we report a new, highly efficient palladacyclic precatalyst that is air, moisture, and thermally stable and obviates the need to employ a glovebox. We have developed a convenient one-component precatalyst for the amination of aryl chlorides that overcomes many of the limitations of those previously described.
authors.affiliation: Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.
authors.forename: Danilo
authors.initials: D
authors.lastname: Zim
authors.forename: Stephen L
authors.initials: SL
authors.lastname: Buchwald
mesh_terms: D000388:Air; D000588:Amines / Q000737:chemistry*; D002712:Chlorides / Q000737:chemistry*; D006358:Hot Temperature
chemical_list: D000588:Amines; D002712:Chlorides