Molecular tectonics: from enantiomerically pure sugars to enantiomerically pure triple stranded helical coordination network.
The self-assembly between a bis-monodentate tecton based on two pyridine units connected to an enantiomerically pure isomannide stereoisomer and HgCl2 leads to the formation of an enantiomerically pure triple stranded helical infinite coordination network which was structurally characterised by X-ray diffraction on single crystal.
Grosshans
Philippe
P
Laboratoire de Chimie de Coordination Organique, Institut Le Bel, Université Louis Pasteur, 4, rue Blaise Pascal, 67000 Strasbourg, France.
Jouaiti
Abdelaziz
A
Bulach
Véronique
V
Planeix
Jean-Marc
JM
Hosseini
Mir Wais
MW
Nicoud
Jean-François
JF
D001665:Binding Sites; D002241:Carbohydrates / Q000737:chemistry*; D008024:Ligands; D046911:Macromolecular Substances; D008353:Mannitol / Q000031:analogs & derivatives*; D008627:Mercuric Chloride / Q000737:chemistry*; D008968:Molecular Conformation; D015394:Molecular Structure; D011725:Pyridines / Q000737:chemistry*; D013237:Stereoisomerism; D013329:Structure-Activity Relationship; D014961:X-Ray Diffraction
D002241:Carbohydrates; D008024:Ligands; D046911:Macromolecular Substances; D011725:Pyridines; D008353:Mannitol; D008627:Mercuric Chloride