title: Unusual reaction of beta-hydroxy alpha-diazo carbonyl compounds with Cl3CCN/NaH and Rh(II)-catalyzed reaction of beta-trichloroacetylamino alpha-diazo carbonyl compounds.
abstract: The hydroxyl group was directly converted into the trichloroacetylamino group by reacting beta-hydroxy alpha-diazo carbonyl compounds with Cl(3)CCN and NaH. Rh(II)-catalyzed reactions of the beta-amino alpha-diazo carbonyl compounds were discussed. [reaction: see text]
authors.affiliation: Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, Department of Chemical Biology, College of Chemistry, Peking University, Beijing 100871, China.
authors.forename: Weifeng
authors.initials: W
authors.lastname: Shi
authors.forename: Nan
authors.initials: N
authors.lastname: Jiang
authors.forename: Shiwei
authors.initials: S
authors.lastname: Zhang
authors.forename: Weiming
authors.initials: W
authors.lastname: Wu
authors.forename: Daming
authors.initials: D
authors.lastname: Du
authors.forename: Jianbo
authors.initials: J
authors.lastname: Wang