title: Solid state structures of pentacoordinated lambda3-iodanes with a trigonal bipyramidal geometry: synthesis of diphenyl- and alkynyl(phenyl)-lambda3-iodane complexes with 1,10-phenanthroline.
abstract: The single crystal X-ray structure of the supramolecular complex formed between diphenyl-lambda3-iodane (Ph2IBF4) or 1-alkynyl(phenyl)-lambda3-iodane [Bu(t)CCI(Ph)BF4] and 1,10-phenanthroline indicates a hitherto unknown distorted trigonal bipyramidal geometry around iodine(III), in which 1,10-phenanthroline acts as a bidentate ligand and occupies equatorial sites.
authors.affiliation: Faculty of Pharmaceutical Sciences, University of Tokushima, 1-78 Shomachi, Tokushima 770-8505, Japan. mochiai@ph2.tokushima-u.ac.jp
authors.forename: Masahito
authors.initials: M
authors.lastname: Ochiai
authors.forename: Takashi
authors.initials: T
authors.lastname: Suefuji
authors.forename: Kazunori
authors.initials: K
authors.lastname: Miyamoto
authors.forename: Motoo
authors.initials: M
authors.lastname: Shiro