An active-site model of prostaglandin H synthase: an iron "twin-coronet" porphyrin with an aryloxyl radical overhang and its catalytic oxygenation of 1,4-diene.
Matsui
Eiki
E
Institute for Fundamental Research of Organic Chemistry, Kyushu University, Higashi-ku, Fukuoka 812-8581, Japan.
Naruta
Yoshinori
Y
Tani
Fumito
F
Shimazaki
Yuichi
Y
D000475:Alkenes / Q000737:chemistry; D001665:Binding Sites; D002384:Catalysis; D004578:Electron Spin Resonance Spectroscopy; D008958:Models, Molecular; D010100:Oxygen / Q000737:chemistry*; D011451:Prostaglandin-Endoperoxide Synthases / Q000737:chemistry*; D011487:Protein Conformation
D000475:Alkenes; D011451:Prostaglandin-Endoperoxide Synthases; D010100:Oxygen