Structural revision of epoxyrollins A and B, biosynthetic precursors of annonaceous acetogenins.
Chemical structural elucidation of epoxyrollins A and B, representatives of biosynthetic precursors of tetrahydrofuran and tetrahydropyran annonaceous acetogenins, is described. These chemical structures were diepoxyreticanin 1 (4) and diepoxymuricanin A (6) by a (13)C-NMR and mass spectral study of the natural and synthetic sample data.
Konno
Hiroyuki
H
Department of Biological Science and Technology, Faculty of Engineering, University of Tokushima, 2-1 Minamijosanjimacho, Tokushima 770-8506, Japan. konno@bio.tokushima-u.ac.jp
Makabe
Hidefumi
H
D015107:4-Butyrolactone / Q000031:analogs & derivatives / Q000737:chemistry*; D029061:Annonaceae / Q000737:chemistry*; D042967:Electron Transport Complex I / Q000037:antagonists & inhibitors; D004791:Enzyme Inhibitors / Q000737:chemistry; D004852:Epoxy Compounds / Q000737:chemistry*; D013058:Mass Spectrometry; D015394:Molecular Structure; D009097:Multienzyme Complexes / Q000037:antagonists & inhibitors; D009247:NADH, NADPH Oxidoreductases / Q000037:antagonists & inhibitors; D019906:Nuclear Magnetic Resonance, Biomolecular
D004791:Enzyme Inhibitors; D004852:Epoxy Compounds; D009097:Multienzyme Complexes; C483685:epoxyrollin A; C483686:epoxyrollin B; C023107:NADH oxidase; D009247:NADH, NADPH Oxidoreductases; D042967:Electron Transport Complex I; D015107:4-Butyrolactone