Perylene-tetrapalladium sandwich complexes.
Bis-perylene-tetrapalladium sandwich complexes are synthesized and structurally characterized. These are the first examples of bis-arene sandwich complexes having metal-metal bond chains. X-ray crystallographic analyses showed that the tetrapalladium chain is bound to perylene ligands at the C8 edge position.
Murahashi
Tetsuro
T
Department of Applied Chemistry and Frontier Research Center, Faculty of Engineering, Osaka University, Suita, Osaka, 565-0871, Japan. tetsu@chem.eng.osaka.u.ac.jp
Uemura
Tomohito
T
Kurosawa
Hideo
H