title: Impact of biogenic terpene emissions from Brassica napus on tropospheric ozone over Saxony (Germany): numerical investigation.
abstract: BACKGROUND
  The role of biogenic emissions in tropospheric ozone production is currently under discussion and major aspects are not well understood yet. This study aims towards the estimation of the influence of biogenic emissions on tropospheric ozone concentrations over Saxony in general and of biogenic emissions from brassica napus in special. MODELLING TOOLS: The studies are performed by utilizing a coupled numerical modelling system consisting of the meteorological model METRAS and the chemistry transport model MUSCAT. For the chemical part, the Euro-RADM algorithm is used. EMISSIONS: Anthropogenic and biogenic emissions are taken into account. The anthropogenic emissions are introduced by an emission inventory. Biogenic emissions, VOC and NO, are calculated within the chemical transport model MUSCAT at each time step and in each grid cell depending on land use type and on the temperature. The emissions of hydrocarbons from forest areas as well as biogenic NO especially from agricultural grounds are considered. Also terpene emissions from brassica napus fields are estimated. SIMULATION SETUP AND METEOROLOGICAL CONDITIONS: The simulations were performed over an area with an extension of 160 x 140 km2 which covers the main parts of Saxony and neighboring areas of Brandenburg, Sachsen-Anhalt and Thuringia. Summer smog with high ozone concentrations can be expected during high pressure conditions on hot summer days. Typical meteorological conditions for such cases were introduced in an conceptual way.
  
  
  RESULTS
  It is estimated that biogenic emissions change tropospheric ozone concentrations in a noticeable way (up to 15% to 20%) and, therefore, should not be neglected in studies about tropospheric ozone. Emissions from brassica napus do have a moderate potential to enhance tropospheric ozone concentrations, but emissions are still under consideration and, therefore, results vary to a high degree.
  
  
  CONCLUSIONS
  Summing up, the effect of brassica napus terpene emissions on ozone concentrations is noticeable, but not too pronounced. The results give a preliminary estimate on what the effect due to brassica napus emissions could be until better parameterizations can be derived from measurements.
authors.affiliation: Institute for Tropospheric Research, Permoserstr. 15, D-04318 Leipzig, Germany. renner@tropos.de
authors.forename: Eberhard
authors.initials: E
authors.lastname: Renner
authors.forename: Annette
authors.initials: A
authors.lastname: Münzenberg
mesh_terms: D000393:Air Pollutants / Q000032:analysis*; D001272:Atmosphere; D029688:Brassica napus / Q000378:metabolism*; D004784:Environmental Monitoring; D005858:Germany; D017752:Greenhouse Effect; D006801:Humans; D008962:Models, Theoretical; D009589:Nitrogen Oxides / Q000032:analysis; D010126:Ozone / Q000032:analysis*; D013729:Terpenes / Q000032:analysis*
chemical_list: D000393:Air Pollutants; D009589:Nitrogen Oxides; D013729:Terpenes; D010126:Ozone