A self-assembling polymer-bound rotaxane under thermodynamic control.
The thermodynamically controlled self-assembly of a neutral donor-acceptor rotaxane, stoppered via porphyrin coordination and bound to polystyrene beads is described, and the dynamic equilibrium between solid and solution phases has been examined by HR MAS nmr spectroscopy.
Johnstone
Ken D
KD
School of Biological, Biomedical and Molecular Sciences, University of New England, Armidale, NSW 2351, Australia.
Bampos
Nick
N
Sanders
Jeremy K M
JK
Gunter
Maxwell J
MJ