Chemoselective building blocks for dendrimers from relative reactivity data.
Competition reactions for the substitution of monochlorotriazines with different amines provide relative reactivity data that can be used to identify new groups for the chemoselective syntheses of dendrimers based on melamine. Target 1 is prepared using a one-pot per generation strategy without protecting group manipulations or functional group interconversions.
Steffensen
Mackay B
MB
Department of Chemistry, Texas A&M University, College Station, TX 77843, USA.
Simanek
Eric E
EE
D000588:Amines / Q000737:chemistry; D016208:Databases, Factual; D006843:Hydrocarbons, Chlorinated / Q000737:chemistry; D011108:Polymers / Q000737:chemistry*; D012117:Resins, Synthetic; D014227:Triazines / Q000737:chemistry*
D000588:Amines; D006843:Hydrocarbons, Chlorinated; D011108:Polymers; D012117:Resins, Synthetic; D014227:Triazines; C011907:melamine