Unusual reaction of beta-hydroxy alpha-diazo carbonyl compounds with Cl3CCN/NaH and Rh(II)-catalyzed reaction of beta-trichloroacetylamino alpha-diazo carbonyl compounds.
The hydroxyl group was directly converted into the trichloroacetylamino group by reacting beta-hydroxy alpha-diazo carbonyl compounds with Cl(3)CCN and NaH. Rh(II)-catalyzed reactions of the beta-amino alpha-diazo carbonyl compounds were discussed. [reaction: see text]
Shi
Weifeng
W
Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, Department of Chemical Biology, College of Chemistry, Peking University, Beijing 100871, China.
Jiang
Nan
N
Zhang
Shiwei
S
Wu
Weiming
W
Du
Daming
D
Wang
Jianbo
J