Room-temperature ionic liquids as new solvents for organic electrosynthesis. The first examples of direct or nickel-catalysed electroreductive coupling involving organic halides.
Direct or Ni-catalysed electroreductive homocouplings of organic halides and couplings of organic halides with activated olefins are efficiently conducted by constant current electrolyses in an undivided cell in room-temperature ionic liquids as the solvent-electrolyte media.
Barhdadi
Rachid
R
Laboratoire d'Electrochimie Catalyse et Synthèse Organique (UMR 7582), CNRS-Université Paris 12 Val de Marne, 2 rue Henry Dunant, 94320 Thiais, France. barhdadi@glvt-cnrs.fr
Courtinard
Coralie
C
Nédélec
Jean Yves
JY
Troupel
Michel
M