Photocatalytic treatment of diuron by solar photocatalysis: evaluation of main intermediates and toxicity.
The technical feasibility, mechanisms, and performance of degradation of aqueous diuron (22 mg/L) have been studied at pilot scale in two well-defined photocatalytic systems of special interest because natural UV light can be used: heterogeneous photocatalysis with titanium dioxide and homogeneous photocatalysis by photo-Fenton. Equivalent pilot-scale (made up of Compound Parabolic Collectors (CPCs) specially designed for solar photocatalytic applications) and field conditions used for both allowed adequate comparison of the degree of mineralization and toxicity achieved as well as the transformation products generated en route to mineralization by both systems. Total disappearance of diuron is attained by both phototreatments in 45 min. 100% of chlorine was recovered as chloride, but total recovery of nitrogen as inorganic ions was not attained. 90% of mineralization was reached after 200 min of photocatalytic treatment, but toxicity measured by two different bioassays (Daphnia magna and a Microalga) was reduced to below the threshold (EC50%) in a shorter time. Transformation products evaluated by LC-IT-MS by direct injection of the samples were the same in both cases. The main differences between the two processes were in the amount of transformation products (DPs) generated, not in the DPs detected, which were always the same.
Malato
S
S
Plataforma Solar de Almería-CIEMAT, Ctra. Senés Km. 4, 04200-Tabernas, Almería, Spain. Sixto.Malato@psa.es
Cáceres
J
J
Fernández-Alba
A R
AR
Piedra
L
L
Hernando
M D
MD
Agüera
A
A
Vial
J
J
D000818:Animals; D001681:Biological Assay; D002384:Catalysis; D004396:Coloring Agents / Q000737:chemistry; D003621:Daphnia; D004237:Diuron / Q000032:analysis / Q000737:chemistry* / Q000633:toxicity; D056890:Eukaryota; D006540:Herbicides / Q000032:analysis / Q000737:chemistry* / Q000633:toxicity; D006861:Hydrogen Peroxide; D007501:Iron; D007928:Lethal Dose 50; D010777:Photochemistry; D014025:Titanium / Q000737:chemistry; D014466:Ultraviolet Rays
D004396:Coloring Agents; C045076:Fenton's reagent; D006540:Herbicides; C009495:titanium dioxide; D004237:Diuron; D006861:Hydrogen Peroxide; D014025:Titanium; D007501:Iron