title: Novel synthesis of heterocycles having a functionalized carbon center via nickel-mediated carboxylation: total synthesis of erythrocarine.
abstract: Novel synthetic procedure of heterocycles was developed using nickel-mediated alkylative carboxylation, and the total synthesis of erythrocarine was achieved using this method and RCM of dienyne as the key steps. [reaction: see text]
authors.affiliation: Graduate School of Pharmaceutical Sciences, Hokkaido University, Sapporo 060-0812, Japan.
authors.forename: Kazuya
authors.initials: K
authors.lastname: Shimizu
authors.forename: Masanori
authors.initials: M
authors.lastname: Takimoto
authors.forename: Miwako
authors.initials: M
authors.lastname: Mori
mesh_terms: D000470:Alkaloids / Q000737:chemistry; D000480:Alkynes / Q000737:chemistry; D004895:Erythrina / Q000737:chemistry*; D006571:Heterocyclic Compounds / Q000737:chemistry*; D006576:Heterocyclic Compounds, 4 or More Rings / Q000138:chemical synthesis*; D009532:Nickel / Q000737:chemistry*
chemical_list: D000470:Alkaloids; D000480:Alkynes; D006571:Heterocyclic Compounds; D006576:Heterocyclic Compounds, 4 or More Rings; C478876:erythrocarine; D009532:Nickel