An air and thermally stable one- component catalyst for the amination of aryl chlorides.
[reaction: see text] In this paper we report a new, highly efficient palladacyclic precatalyst that is air, moisture, and thermally stable and obviates the need to employ a glovebox. We have developed a convenient one-component precatalyst for the amination of aryl chlorides that overcomes many of the limitations of those previously described.
Zim
Danilo
D
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.
Buchwald
Stephen L
SL
D000388:Air; D000588:Amines / Q000737:chemistry*; D002712:Chlorides / Q000737:chemistry*; D006358:Hot Temperature
D000588:Amines; D002712:Chlorides