Novel titanium complexes of a multidentate dicarbollide ligand. Synthesis and structural characterization of a constrained geometry complex.
The multidentate dicarbollide ligand nido-7,8-(NMe2CH2)2-7,8-C2B9H11 has been prepared, structurally characterized, and employed in the preparation of the novel mono- and trimetallic titanium complexes [eta5:eta1-(NMe2CH2)C2B9H9CH2NMe2]Ti(NMe2)2 and [eta5:eta1-[(NMe2CH2)C2B9H9CH2NMe2]Ti(NMe2)]2-mu3-O-Ti(NMe2)2.
Lee
Young-Joo
YJ
Department of Chemistry, Korea University, 208 Seochang, Chochiwon, Chung-nam 339-700, Korea.
Lee
Jong-Dae
JD
Ko
Jaejung
J
Kim
Sang-Hern
SH
Kang
Sang Ook
SO