title: Novel titanium complexes of a multidentate dicarbollide ligand. Synthesis and structural characterization of a constrained geometry complex.
abstract: The multidentate dicarbollide ligand nido-7,8-(NMe2CH2)2-7,8-C2B9H11 has been prepared, structurally characterized, and employed in the preparation of the novel mono- and trimetallic titanium complexes [eta5:eta1-(NMe2CH2)C2B9H9CH2NMe2]Ti(NMe2)2 and [eta5:eta1-[(NMe2CH2)C2B9H9CH2NMe2]Ti(NMe2)]2-mu3-O-Ti(NMe2)2.
authors.affiliation: Department of Chemistry, Korea University, 208 Seochang, Chochiwon, Chung-nam 339-700, Korea.
authors.forename: Young-Joo
authors.initials: YJ
authors.lastname: Lee
authors.forename: Jong-Dae
authors.initials: JD
authors.lastname: Lee
authors.forename: Jaejung
authors.initials: J
authors.lastname: Ko
authors.forename: Sang-Hern
authors.initials: SH
authors.lastname: Kim
authors.forename: Sang Ook
authors.initials: SO
authors.lastname: Kang