A novel bilayer cobalt(II)-organic framework with nanoscale channels accommodating large organic molecules.
A unique noninterpenetrated 2D bilayer cobalt(II)-organic framework, [[Co(dpe)(NO(2)-BDC)].0.5(dpe)](n).nH(2)O (1), possessing nanoscale rectangular channels that clathrate large organic molecules, has been hydrothermally synthesized by reaction of cobalt(II) salt with 5-nitro-1,3-benzenedicarboxylic acid (NO(2)-H(2)BDC) and 1,2-bis(4-pyridyl)ethylene (dpe).
Luo
Junhua
J
State Key Laboratory of Structural Chemistry, Fujian Institute of the Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China.
Hong
Maochun
M
Wang
Ruihu
R
Cao
Rong
R
Han
Lei
L
Yuan
Daqiang
D
Lin
Zhenzhong
Z
Zhou
Youfu
Y