Use of the second dimension in PGSE NMR studies of porous media.
2-dimensional methods based on PGSE NMR may be used to correlate or separate molecular dynamical properties, or to elucidate fluctuations. These may utilize either the gradient (q-vector) domain, in which molecular displacements are measured, or the time domain, in which relaxation is measured, and may be analyzed by combinations of inverse Fourier or Laplace transforms. Existing methodologies are reviewed and new experiments proposed. In particular the use of diffusion-diffusion exchange and correlation analysis is demonstrated using the case of water diffusion in a lamellar phase liquid crystal.
Callaghan
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MacDiarmid Institute for Advanced Materials and Nanotechnology, School of Chemical and Physical Sciences, Victoria University of Wellington, Wellington, New Zealand. paul.Callaghan@vuw.ac.nz
Godefroy
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Ryland
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BN
D016880:Anisotropy; D004058:Diffusion; D004143:Dioctyl Sulfosuccinic Acid / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D016062:Porosity; D012212:Rheology; D014867:Water
D014867:Water; D004143:Dioctyl Sulfosuccinic Acid