title: Three highly oxygenated caryophyllene sesquiterpenes from Pestalotiopsis sp., a fungus isolated from bark of Pinus taeda.
abstract: A Pestalotiopis sp. was isolated from the trunk bark of Pinus taeda. The fungus was cultivated in liquid medium and produced three highly oxygenated caryophyllene sequiterpene derivatives, named pestalotiopsolide A, taedolidol and 6-epitaedolidol, respectively. The sesquiterpenes were isolated by silica gel based chromatographic procedures and their structures were elucidated by NMR spectroscopic data.
authors.affiliation: Departmento de Química, Universidade Federal de São Carlos, CP 676, Sao Carlos-SP, Brazil.
authors.forename: Rodrigo F
authors.initials: RF
authors.lastname: Magnani
authors.forename: Edson
authors.initials: E
authors.lastname: Rodrigues-Fo
authors.forename: Cristina
authors.initials: C
authors.lastname: Daolio
authors.forename: A Gilberto
authors.initials: AG
authors.lastname: Ferreira
authors.forename: Antônia Q L
authors.initials: AQ
authors.lastname: de Souza
mesh_terms: D000894:Anti-Inflammatory Agents, Non-Steroidal / Q000737:chemistry / Q000302:isolation & purification; D003904:Mitosporic Fungi / Q000737:chemistry* / Q000302:isolation & purification; D008958:Models, Molecular; D008968:Molecular Conformation; D028223:Pinus / Q000382:microbiology*; D041603:Pinus taeda; D024301:Plant Bark / Q000382:microbiology*; D000081223:Polycyclic Sesquiterpenes; D012717:Sesquiterpenes / Q000737:chemistry* / Q000302:isolation & purification
chemical_list: D000894:Anti-Inflammatory Agents, Non-Steroidal; D000081223:Polycyclic Sesquiterpenes; D012717:Sesquiterpenes; C024714:caryophyllene