title: Adsorption of catechol and comparative solutes on hydroxyapatite.
abstract: Contemporary medical and dental adhesives often have difficulty sticking to wet surfaces or weaken with long-term exposure to water. Substantial research has been dedicated to finding a means of achieving adhesion in an aqueous environment. A study evaluates the adsorption of catechol relative to other chemical groups as means of gauging how effective they may be as adsorptive groups in adhesives. Contact angle and surface-tension measurements of solutions of catechols and other chemical groups were used to determine their works of adhesion. Adsorption isotherms were also constructed to ascertain Langmuir constants. Solutes containing catechol groups were compared to solutes containing other polar groups to see how well catechol adsorbs to hydroxyapatite, the mineral component of bones and teeth, relative to other chemical groups found in adhesives. The results of this study show that catechol and molecules containing catechol groups have higher rates and energies of adsorption to hydroxyapatite than do groups such as alcohols, amines, and carboxylic acids.
authors.affiliation: Macromolecular Science and Engineering and Department of Biologic and Materials Science, University of Michigan, Ann Arbor, Michigan 47109, USA.
authors.forename: William M
authors.initials: WM
authors.lastname: Chirdon
authors.forename: William J
authors.initials: WJ
authors.lastname: O'Brien
authors.forename: Richard E
authors.initials: RE
authors.lastname: Robertson
mesh_terms: D000327:Adsorption; D001672:Biocompatible Materials / Q000737:chemistry; D002396:Catechols / Q000737:chemistry*; D006882:Hydroxyapatites / Q000737:chemistry*; D008433:Mathematics; D012996:Solutions
chemical_list: D001672:Biocompatible Materials; D002396:Catechols; D006882:Hydroxyapatites; D012996:Solutions; C034221:catechol