Environmentally benign and stereoselective formation of beta-mannosidic linkages utilizing 2,3-di-O-benzyl-4,6-O-benzylidene-protected mannopyranosyl phosphite and montmorillonite K-10.
An environmentally benign and stereoselective beta-mannopyranosylation has been developed employing 4,6-O-benzylidene-protected mannopyranosyl diethyl phosphite as a glycosyl donor and montmorillonite K-10 as an activator.
Nagai
Hideyuki
H
Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama 223-852, Japan.
Matsumura
Shuichi
S
Toshima
Kazunobu
K
D001546:Bentonite / Q000737:chemistry*; D001597:Benzylidene Compounds / Q000737:chemistry*; D002236:Carbohydrate Conformation; D008358:Mannose / Q000031:analogs & derivatives / Q000737:chemistry*; D008968:Molecular Conformation; D017905:Phosphites / Q000737:chemistry*
C483164:2,3-di-O-benzyl-4,6-O-benzylidene mannopyranosyl phosphite; D001597:Benzylidene Compounds; D017905:Phosphites; D001546:Bentonite; D008358:Mannose