title: Light scattering studies of the solution properties of chitosans of varying degrees of acetylation.
abstract: The use of two techniques, differential interferometry and quasi-elastic light scattering (QELS), allowed us to study solutions of chitosan varying in degree of acetylation (DA), degree of dissociation (alpha), and concentration (C(p)). With the first technique, we demonstrated the modification of the electric polarizability of the polymer chains, through a law of behavior of the variation of the refractive index increment dn/dC with DA and alpha. This brought us information on the various kinds of interactions (H-bonds, electrostatic, and hydrophobic) involved in the evolution of the solution properties. QELS experiments performed in dilute regime showed the presence of supramolecular structures depending on DA and alpha. The topology and the nature of these objects are discussed. The typical presence of aggregates and their evolution with concentration was also demonstrated in semidilute regime.
authors.affiliation: Laboratoire des Matériaux Polymères et des Biomatériaux, UMR CNRS 5627, bat ISTIL, Domaine Scientifique de la Doua, 15, Bd. Latarjet, 69 622 Villeurbanne Cedex, France.
authors.forename: Pierre
authors.initials: P
authors.lastname: Sorlier
authors.forename: Cyrille
authors.initials: C
authors.lastname: Rochas
authors.forename: Isabelle
authors.initials: I
authors.lastname: Morfin
authors.forename: Christophe
authors.initials: C
authors.lastname: Viton
authors.forename: Alain
authors.initials: A
authors.lastname: Domard
mesh_terms: D000107:Acetylation; D002686:Chitin / Q000031:analogs & derivatives* / Q000737:chemistry* / Q000302:isolation & purification; D048271:Chitosan; D008027:Light; D012542:Scattering, Radiation; D012996:Solutions
chemical_list: D012996:Solutions; D002686:Chitin; D048271:Chitosan