The importance of capillary electrophoresis, capillary electrochromatography, and ion chromatography in separations of inorganic ions.
The importance of capillary electrophoresis (CE), capillary electrochromatography (CEC), and ion chromatography (IC) in inorganic ion analyses is outlined. Methods for improving the reliability of the CE measurements are briefly described. Selectivity optimization in CE analyses of inorganic cations and anions is discussed. Using the Peakmaster program, CE system peaks (system zones, eigenmobilites) and some important CE parameters, such as effective mobilities, electromigration dispersion, indirect UV, and direct conductivity signals, are predicted and compared with experimental analyses.
Pacáková
Věra
V
Department of Analytical Chemistry.
Coufal
Pavel
P
Department of Analytical Chemistry.
Štulík
Karel
K
Department of Analytical Chemistry.
Gaš
Bohuslav
B
Department of Physical Chemistry, Charles University, CZ-Prague, Czech Republic.
D002853:Chromatography, Liquid / Q000379:methods*; D020374:Chromatography, Micellar Electrokinetic Capillary / Q000379:methods*; D019075:Electrophoresis, Capillary / Q000379:methods*; D007287:Inorganic Chemicals / Q000302:isolation & purification*; D007477:Ions; D012680:Sensitivity and Specificity
D007287:Inorganic Chemicals; D007477:Ions