Effect of temperature and surfactant on the control release of microencapsulated dye in lecithin liposomes. I.
The objective of our work has been the microencapsulation of dyes with lecithin from soybean, with the formation of liposomes, as a substitute for synthetic auxiliaries so as to improve the quality of the effluent. Current scenarios promote the disintegration and leakage of the liposomes, such as, changes in temperature, pH and the use of surfactants. Since dyeing process is a mix of all these parameters, we pretended to study each one separately. Rhodamine 6G fluorescence is known to be concentration quenched through the formation of non-fluorescent dimmers and, additionally, through the energy transfer from rhodamine monomer to these dimmers (Baptista ALF, Coutinho PJG, Real Oliveira MECD, Gomes JINR. Proceedings of 13th International Symposium of Surfactants, SIS 2000, Gainesville, USA, 2000). The temperature, the surfactant and pH induce a release of the encapsulated dye resulting in rhodamine dilution and consequently alterations in the dimerization/binding equilibrium. The experimental spectra indicate that rhodamine binds almost completely to liposomes. The decomposition of the rhodamine fluorescence spectra allowed us to determine the percentage of released dye during a simulated dyeing process, and allowed us to conclude that the dimerization process occurs mainly at the inner interfaces. The amount of dye released induced by temperature changes was greater in the presence of surfactant.
Baptista
A L F
AL
Departamento de Engenharia Têxtil, Universidade do Minho, Guimarães, Portugal.
Coutinho
P J G
PJ
Real Oliveira
M E C D
ME
Gomes
J I N Rocha
JI
D004339:Drug Compounding; D005456:Fluorescent Dyes; D006863:Hydrogen-Ion Concentration; D008081:Liposomes / Q000737:chemistry*; D008433:Mathematics; D010713:Phosphatidylcholines / Q000737:chemistry; D012235:Rhodamines / Q000737:chemistry*; D013025:Glycine max / Q000737:chemistry; D013050:Spectrometry, Fluorescence; D013501:Surface-Active Agents; D013696:Temperature
D005456:Fluorescent Dyes; D008081:Liposomes; D010713:Phosphatidylcholines; D012235:Rhodamines; D013501:Surface-Active Agents; C026188:rhodamine 6G