title: The determination of trace metals in estuarine and coastal waters using a voltammetric in situ profiling system.
abstract: This work presents the optimisation, validation and field deployment of a voltammetric in situ profiling (VIP) system for the simultaneous determinations of dynamic Cd(II), Cu(II) and Pb(II) in estuarine and coastal waters. Systematic studies in NaNO3 (as a supporting electrolyte) and seawater, indicated that variations in ionic strength, pH and dissolved oxygen did not affect the response of the instrument, whereas an Arrhenius type temperature response was observed. The VIP instrument allows the determination of 2-3 samples h(-1), and has a detection limit (defined as 3sigma) in seawater for Cd(II): 23 pM, Cu(II): 1.13 nM, and Pb(II): 23 pM. The VIP system accurately measured the total dissolved concentrations of Cd(II), Cu(II) and Pb(II) in two certified reference materials; SLRS-3, a river water, and SLEW-2, an estuarine water. Field evaluation of the instrumentation and analytical methods was achieved through a series of surveys in the Plym Estuary (Devon, UK), from which environmental data are presented.
authors.affiliation: School of Environmental Sciences, Plymouth Environmental Research Centre, University of Plymouth, Plymouth, UK PL4 8AA.
authors.forename: Kate A
authors.initials: KA
authors.lastname: Howell
authors.forename: Eric P
authors.initials: EP
authors.lastname: Achterberg
authors.forename: Charlotte B
authors.initials: CB
authors.lastname: Braungardt
authors.forename: Alan D
authors.initials: AD
authors.lastname: Tappin
authors.forename: David R
authors.initials: DR
authors.lastname: Turner
authors.forename: Paul J
authors.initials: PJ
authors.lastname: Worsfold
mesh_terms: D004563:Electrochemistry / Q000295:instrumentation / Q000379:methods; D005618:Fresh Water; D012623:Seawater; D014131:Trace Elements / Q000032:analysis*; D014874:Water Pollutants, Chemical / Q000032:analysis*
chemical_list: D014131:Trace Elements; D014874:Water Pollutants, Chemical