The use of a germene for the synthesis of esters of alpha-germyl-substituted alpha-amino acid and alpha-aminophosphonic acid.
The first alpha-germyl-substituted alpha-amino ester and alpha-germyl-substituted alpha-aminophosphonic ester have been synthesized by a one-pot reaction between the germene Mes2Ge=CR2 (CR2 = fluorenylidene) and the iminoester or iminophosphonate Ph(H)C=NCH2-Y (Y = COOMe, P(O)(OEt)2).
El Kettani
S Ech-Cherif
SE
Université Sidi Mohamed Ben Abdellah, Faculté des Sciences Dhar El Mehrez, BP 1796 Atlas-Fès, Morocco.
Escudié
J
J
Couret
C
C
Ranaivonjatovo
H
H
Lazraq
M
M
Soufiaoui
M
M
Gornitzka
H
H
Nemes
G Cretiu
GC
D000596:Amino Acids / Q000138:chemical synthesis*; D004952:Esters; D005857:Germanium / Q000737:chemistry*; D063065:Organophosphonates / Q000138:chemical synthesis*
D000596:Amino Acids; D004952:Esters; D063065:Organophosphonates; D005857:Germanium