Electronic contributions to the sigma(p) parameter of the Hammett equation.
A statistical procedure to obtain the intrinsic electronic contributions to the Hammett substituent constant sigma(p) is reported. The method is based on the comparison between the experimental sigma(p) values and the electronic electrophilicity index omega evaluated for a series of 42 functional groups commonly present in organic compounds.
Domingo
Luis R
LR
Instituto de Ciencia Molecular, Departamento de Química Orgánica, Universidad de Valencia, Dr. Moliner 50, 46100 Burjassot, Valencia, Spain. domingo@utopia.uv.es
Pérez
Patricia
P
Contreras
Renato
R