Dislodgeable copper, chromium and arsenic from CCA-treated wood surfaces.
Chromated copper arsenate (CCA) is commonly used to preserve wood, but its use poses risk of arsenic exposure. In order to evaluate the extent of exposure to As from physical contact with CCA-treated wood, dislodgeable As from treated wood surfaces (as well as Cu and Cr) was determined as a function of weathering time using dampened polyester wipe materials. Six sets of 2.5-m-long CCA-treated boards, three-four boards per set, were purchased from lumber yards and cut into 30- or 60-cm coupons. A total of 44 such coupons were placed outdoors and the dislodgeable CCA components from the surfaces of the wooden coupons were periodically determined over a 1- or 2-year period by a systematic wipe method followed by nitric acid extraction of the CCA components from the cloth. In all 316 samples, appreciable amounts of the three elements, Cu, Cr and As, were detected. The amounts of surface-dislodgeable As, the most potentially hazardous element and the one of major concern in this study, varied from 5 to 122 microg/100 cm(2) with an average value of 37+/-22 microg/100 cm(2). There was considerable variation in As dislodged among coupons, boards, sets and time. Test coupons that tended to release relatively higher (or lower amounts) over time initially, continued to do so over time. However, the amounts of arsenic dislodged over time did not follow a simple pattern. While the As dislodged tended to decrease with time during the first year, it approached the initial value or increased somewhat during the second year, presumably due to surface rejuvenation effects caused by erosion and weathering. When all the data were normalized to the initial values, no trend emerged, as indicated by the average normalized value of 1.0+/-0.4 for As dislodged over time. Apparently, on installations constructed with CCA-treated wood, arsenic may remain available for a number of years.
Stilwell
David
D
Department of Analytical Chemistry and Soil and Water, The Connecticut Agricultural Experiment Station, P.O. Box 1106, New Haven, CT 06514, USA. david.stilwell@po.state.ct.us
Toner
Michael
M
Sawhney
Brij
B
D001149:Arsenates / Q000737:chemistry*; D001151:Arsenic / Q000032:analysis*; D001682:Biological Availability; D002857:Chromium / Q000032:analysis*; D002980:Climate; D003252:Construction Materials; D003300:Copper / Q000032:analysis*; D004781:Environmental Exposure; D004784:Environmental Monitoring; D006801:Humans; D014934:Wood
D001149:Arsenates; D002857:Chromium; C040890:chromated copper arsenate; D003300:Copper; D001151:Arsenic