Efficient and selective synthesis of glycofuranosyl azides and nucleosides from cyclic 1,2-thiocarbonate sugars.
[reaction: see text] Cyclic 1,2-thiocarbonate sugars are convenient starting materials for the selective and efficient preparation of glycofuranosyl azides and nucleosides by regio- and stereoselective thiocarbonate ring-opening.
Alvarez de Cienfuegos
Luis
L
Departamento de Química Orgánica, Facultad de Ciencias, Universidad de Granada, Campus de Fuentenueva s/n, 18071 Granada, Spain.
Rodríguez
Concepción
C
Mota
Antonio J
AJ
Robles
Rafael
R
D001386:Azides / Q000138:chemical synthesis* / Q000737:chemistry; D002254:Carbonates / Q000737:chemistry*; D005663:Furans / Q000138:chemical synthesis* / Q000737:chemistry; D006027:Glycosides / Q000737:chemistry*; D008968:Molecular Conformation; D009705:Nucleosides / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism; D013457:Sulfur Compounds / Q000737:chemistry*
D001386:Azides; D002254:Carbonates; D005663:Furans; D006027:Glycosides; D009705:Nucleosides; D013457:Sulfur Compounds