Manganese antimony diselenide iodide, MnSbSe2I.
MnSbSe(2)I contains layers parallel to the bc plane that consist of edge- and corner-sharing MnSe(6/2) and MnSe(2/2)I(4/2) octahedra. Sb atoms are located between these layers and form SbSe(3) trigonal pyramids. Owing to the off-center placement of the Sb atom and the inequivalence of the two crystallographically independent Mn atoms, the monoclinic MnSbSe(2)I structure is a distorted variant of the orthorhombic UFeS(3) structure type.
Tougait
Olivier
O
Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208-3113, USA. olivier.tougait@univ-rennes1.fr
Ibers
James A
JA
Mar
Arthur
A