Synthesis of mannose-containing analogues of (1-->6)-branched (1-->3)-glucohexaose (I).
alpha-D-Manp-(1-->3)-[alpha-D-Manp-(1-->6)]-alpha-D-Glcp-(1-->3)-beta-D-Glcp-(1-->3)-[alpha-D-Manp-(1-->6)]-D-Glcp and alpha-D-Manp-(1-->3)-[beta-D-Glcp-(1-->6)]-alpha-D-Glcp-(1-->3)-beta-D-Glcp-(1-->3)[-alpha-D-Manp-(1-->6)]-D-Glcp were synthesized in a regio- and stereoselective way as the mannose-containing analogues of the immunomodulating beta-D-Glcp-(1-->3)-[beta-D-Glcp-(1-->6)]-alpha-D-Glcp-(1-->3)-beta-D-Glcp-(1-->3)-[beta-D-Glcp-(1-->6)]-D-Glcp.
Wu
Zicheng
Z
Research Center for Eco-Environmental Sciences, Academia Sinica, P.O. Box 2871, Beijing 100085, PR China.
Kong
Fanzuo
F
D002236:Carbohydrate Conformation; D002240:Carbohydrate Sequence; D005947:Glucose / Q000031:analogs & derivatives*; D006031:Glycosylation; D008358:Mannose / Q000031:analogs & derivatives*; D008969:Molecular Sequence Data; D009844:Oligosaccharides / Q000138:chemical synthesis*; D013237:Stereoisomerism
D009844:Oligosaccharides; D005947:Glucose; D008358:Mannose