From supramolecular block copolymers to advanced nano-objects.
The formation of asymmetric bis-complexes, based on terpyridine ligands and ruthenium ions, is described as a powerful tool for the self-assembly of polymer blocks end-functionalized with terpyridine units. This is illustrated in this contribution for the synthesis of amphiphilic metallo-supramolecular block copolymers, which are further used to produce aqueous micelles. Finally, the reversibility of the supramolecular bond opens new avenues for the preparation and manipulation of these nano-objects.
Gohy
Jean-François
JF
Laboratory of Macromolecular Chemistry and Nanoscience, Center for Nanomaterials (cNM), Eindhoven University of Technology and Dutch Polymer Institute, P.O. Box 513, 5600 MB Eindhoven, The Netherlands.
Lohmeijer
Bas G G
BG
Schubert
Ulrich S
US