title: Mesoporous silicates as nanoreactors for carbon nanotube production in the absence of transition metal catalysts.
abstract: Carbon nanotubes were produced from either a template or the polymer-filled pore systems of mesoporous silicates of various structures and dimensions by heat treatment in the absence of air. Successful synthesis was done when the template molecules contained little or no oxygen. For SBA-15 material, where the structure-directing molecule used for synthesis of mesoporous silicate was polyethylene oxide-polypropylene oxide-polyethylene oxide triblock copolymer, no carbon nanostructures were formed. A peculiar carbon nanostructure was generated from the template for pore expanded MCM-41. To demonstrate carbon nanotube formation from polymer in the mesoporous silicates, the mesopores of MCM-41, MCM-48, and SBA-15 silicates were filled with divinyl-benzene polymer and then graphitized at 1300 K. The polymer was successfully transformed into carbon nanotubes for the MCM class silicate but not the SBA-15 silicate.
authors.affiliation: Applied and Environmental Chemistry Department, University of Szeged, Szeged, Hungary.
authors.forename: Mónika
authors.initials: M
authors.lastname: Urbán
authors.forename: Zoltán
authors.initials: Z
authors.lastname: Kónya
authors.forename: Dóra
authors.initials: D
authors.lastname: Méhn
authors.forename: Ji
authors.initials: J
authors.lastname: Zhu
authors.forename: Imre
authors.initials: I
authors.lastname: Kiricsi
mesh_terms: D002384:Catalysis; D003460:Crystallization / Q000379:methods*; D008422:Materials Testing; D008670:Metals / Q000737:chemistry; D008968:Molecular Conformation; D036103:Nanotechnology / Q000379:methods*; D037742:Nanotubes, Carbon / Q000737:chemistry* / Q000302:isolation & purification*; D010539:Permeability; D016062:Porosity; D017640:Silicates / Q000737:chemistry*; D013499:Surface Properties; D013696:Temperature; D028561:Transition Elements / Q000737:chemistry
chemical_list: D008670:Metals; D037742:Nanotubes, Carbon; D017640:Silicates; D028561:Transition Elements