Pressure evolution of the excess wing in a type-B glass former.
Glass formers are defined as "type B" when they exhibit a distinct Johari-Goldstein (JG) relaxation, but lack an excess loss ("excess wing," EW) in their structural relaxation peak. By studying the dielectric spectra of a well-known type-B glass former under high pressure, we unequivocally show the existence of an EW, simultaneously with the JG relaxation. Moreover, at very high pressures (0.6 GPa), the EW becomes a distinct relaxation peak, although correlated with the structural relaxation. The implication is that the EW, rather than the higher frequency relaxation ascribed to the JG process, is perhaps a universal feature of glass formers, albeit not always discernible at ambient pressure. Our findings may reconcile all opposing points of view present in the literature, as well as indicate that the type-A or type-B classification of glass formers should be modified or even discontinued.
Casalini
Riccardo
R
Naval Research Laboratory, Code 6120, Washington, DC 20375-5342, USA. casalini@ccs.nrl.navy.mil
Roland
C Michael
CM