[Synthesis and spectral characterization of U(VI) and Th(IV) complexes of thenoylpyrazolone-ethylenediamine].
Two novel bis-schiff base complexes [UO2 (PMTHP)2en] and [Th(PMTHP)2en(NO3)2] have been synthesized, where (PMTHP)2en = N,N'-bis[(1-phenyl-3-methyl-5-oxo-5-pyrazolinyl)- 2-thenoylmethylidyne] ethylenediamine, and characterized by elemental analysis, IR, UV-Vis, 1H NMR, 13C NMR and molar conductance measurements. The results show that the bis-schiff base is a quadridentate ligand and the nitrate a bidentate ligand, and the uranyl and thorium ions exhibit coordination of six and eight in the complexes, respectively.
Li
Jin-zhou
JZ
Department of Chemistry, Harbin Normal University, Harbin 150080, China.
An
Yu-mei
YM
Yu
Wen-jin
WJ
Sha
Jing-quan
JQ
D002614:Chelating Agents / Q000138:chemical synthesis / Q000737:chemistry; D005029:Ethylenediamines / Q000737:chemistry*; D011720:Pyrazoles / Q000737:chemistry*; D047069:Pyrazolones; D012545:Schiff Bases; D013053:Spectrophotometry; D013910:Thorium / Q000737:chemistry*; D017970:Thorium Compounds / Q000737:chemistry; D014501:Uranium / Q000737:chemistry*
D002614:Chelating Agents; D005029:Ethylenediamines; D011720:Pyrazoles; D047069:Pyrazolones; D012545:Schiff Bases; D017970:Thorium Compounds; C038362:pyrazolone; D014501:Uranium; C031234:ethylenediamine; D013910:Thorium