[Synthesis and spectral characterization of a new molybdenum phosphate compound (NH3CH2CH2NH3)7H2[NaMo12O30(PO4)2(HPO4)5(H2PO4)].7H2O].
The paper reports a new molybdenum phosphate (NH3CH2CH2NH3)7H2[NaMo12O30(PO4)2(HPO4)5(H2PO4)].7H2O containing Mo(V) which is hydrothermally synthesized and spectrally characterized by FTIR, Raman and UV/Vis DRS. The result indicates long Mo(V)-O bonds and innumerable hydrogen bonds in compound cause the red shift of characteristic vibrations in IR spectrum of title compound.
Lin
Zheng-zhong
ZZ
Chemistry Department, Fuzhou University, State Key Laboratory of Structural Chemistry, Fuzhou 350002, China.
Zhang
Han-hui
HH
Huang
Chang-cang
CC
Sun
Rui-qing
RQ
Zheng
Xiao-lin
XL
D008982:Molybdenum / Q000737:chemistry*; D010710:Phosphates / Q000737:chemistry*; D010756:Phosphoric Acids / Q000138:chemical synthesis / Q000737:chemistry; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared; D013059:Spectrum Analysis, Raman
D010710:Phosphates; D010756:Phosphoric Acids; D008982:Molybdenum; C003125:phosphomolybdic acid