A dramatic push effect on the homolysis of FeIII(OOR) intermediates to form non-heme FeIV=O complexes.
Kaizer
József
J
Department of Chemistry and Center for Metals In Biocatalysis, University of Minnesota, 207 Pleasant Street SE, Minneapolis, MN 55455, USA.
Costas
Miquel
M
Que
Lawrence
L
D005290:Ferric Compounds / Q000737:chemistry*; D006418:Heme / Q000737:chemistry; D007501:Iron / Q000737:chemistry*; D015394:Molecular Structure; D010084:Oxidation-Reduction; D011725:Pyridines / Q000737:chemistry
D005290:Ferric Compounds; D011725:Pyridines; C431843:tris(2-pyridylmethyl)amine; C066317:ferryl iron; D006418:Heme; D007501:Iron