Ferromagnetic ordering and metamagnetism in malonate bridged 3D diamond-like and honeycomb-like networks: [Cu(mal)(DMF)]n and [[Cu(mal)(0.5pyz)].H2O]n (mal = Malonate Dianion, DMF = N,N-dimethylformamide, pyz = Pyrazine).
Two three-dimensional (3D) malonate bridged networks, [Cu(mal)(DMF)](n) (1) and [[Cu(mal)(0.5pyz)].H(2)O](n) (2), have been synthesized in H(2)O-DMF solution. Compound 1 exhibits ferromagnetic ordering below 2.6 K (T(c)), and 2 displays a metamagnetic behavior below 3.2 K (T(N)).
Liu
Tian-Fu
TF
College of Chemistry and Molecular Engineering, State Key Laboratory of Rare Earth Materials Chemistry and Applications, Peking University, Beijing 100871, P.R. China.
Sun
Hao-Ling
HL
Gao
Song
S
Zhang
Shi-Wei
SW
Lau
Tai-Chu
TC