Unprecedented double C-C bond cleavage of a cyclopentadienyl ligand.
Double C-C bond cleavage of a cyclopentadienyl ligand proceeded to titanacyclopentadienes when 2 equiv of nitriles were added and the resulting two-carbon unit and three-carbon unit were converted into a benzene derivative and a pyridine derivative, respectively, in one-pot.
Xi
Zhenfeng
Z
Peking University--Hokkaido University Joint Lab, Department of Chemistry, Peking University, Beijing 100871, China.
Sato
Kimihiko
K
Gao
Ye
Y
Lu
Jianming
J
Takahashi
Tamotsu
T