title: Intermolecular radical addition and addition/cyclization reactions of alkoxyamines onto nonactivated alkenes.
abstract: [reaction: see text] Alkoxyamines A, which are readily prepared from commercially available starting materials, undergo efficient thermal radical carboaminoxylations onto various nonactivated alkenes to provide 1,4-functionalized malonates B in good to excellent yields. The experiments are very easy to conduct. The carboaminoxylations can be combined with radical cyclization and fragmentation processes.
authors.affiliation: Department of Chemistry, Philipps-University Marburg, 35032 Marburg, Germany.
authors.forename: Christian
authors.initials: C
authors.lastname: Wetter
authors.forename: Katja
authors.initials: K
authors.lastname: Jantos
authors.forename: Katharina
authors.initials: K
authors.lastname: Woithe
authors.forename: Armido
authors.initials: A
authors.lastname: Studer