title: Photoinduced interaction between fluorescein ester derivatives and CdS colloid.
abstract: The photoinduced interaction of fluorescein ester derivatives, fluorescein's butyl ester (FL4) and fluorescein's anthraquinone-methyl ester (FL-AQ), and colloidal CdS was examined by absorption, fluorescence spectroscopy, and photoinduced ESR spectroscopy. It is found that FL4 and FL-AQ molecules are adsorbed on the surfaces of CdS colloid by an electrostatic interaction forming the surface complex of the type CdS-FL4 or CdS-FL-AQ. The apparent association constant (K(app)) and the degree of association (alpha) of CdS-FL4 obtained from absorption spectra are 2.25 x 10(4) M(-1) and 0.78, respectively. The values of K(app) and alpha of CdS-FL4 as determined from fluorescence spectra are 1.54 x 10(4) M(-1) and 0.82, respectively, which matches well with that determined from the absorption spectra changes. And the values of K(app) and alpha of CdS-FL-AQ obtained from absorption spectra are 4.18 x 10(4) M(-1) and 0.83, respectively. These data indicate that there is a strong interaction between the dye and the CdS particle surface. But there was no evidence for interfacial electron transfer from FL4 or FL-AQ to colloidal CdS by photoinduced ESR experiments. The fluorescence quenching is due to the formation of a nonfluorescent complex. The related phenomena are discussed in this paper.
authors.affiliation: Molecular Science Center, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, People's Republic of China.
authors.forename: Haiping
authors.initials: H
authors.lastname: Zhang
authors.forename: Yalin
authors.initials: Y
authors.lastname: Zhou
authors.forename: Manhua
authors.initials: M
authors.lastname: Zhang
authors.forename: Tao
authors.initials: T
authors.lastname: Shen
authors.forename: Yuliang
authors.initials: Y
authors.lastname: Li
authors.forename: Daoben
authors.initials: D
authors.lastname: Zhu