title: An efficient synthesis of vinylsilanes from acylsilanes and alkyl 1-phenyl-1H-tetrazol-5-yl sulfones. Brook vs Smiles rearrangement.
abstract: [reaction: see text] Vinylsilanes are formed in high yields in the reaction of representative acyl(trimethyl)silanes with anions generated from Kocienski's sulfones.
authors.affiliation: Institute of Organic Chemistry, Polish Academy of Sciences, Ul. Kasprzaka 44, 01-224 Warsaw, Poland.
authors.forename: Paweł
authors.initials: P
authors.lastname: Jankowski
authors.forename: Krzysztof
authors.initials: K
authors.lastname: Pleśniak
authors.forename: Jerzy
authors.initials: J
authors.lastname: Wicha