title: [Synthesis and spectral characterization of a new molybdenum phosphate compound (NH3CH2CH2NH3)7H2[NaMo12O30(PO4)2(HPO4)5(H2PO4)].7H2O].
abstract: The paper reports a new molybdenum phosphate (NH3CH2CH2NH3)7H2[NaMo12O30(PO4)2(HPO4)5(H2PO4)].7H2O containing Mo(V) which is hydrothermally synthesized and spectrally characterized by FTIR, Raman and UV/Vis DRS. The result indicates long Mo(V)-O bonds and innumerable hydrogen bonds in compound cause the red shift of characteristic vibrations in IR spectrum of title compound.
authors.affiliation: Chemistry Department, Fuzhou University, State Key Laboratory of Structural Chemistry, Fuzhou 350002, China.
authors.forename: Zheng-zhong
authors.initials: ZZ
authors.lastname: Lin
authors.forename: Han-hui
authors.initials: HH
authors.lastname: Zhang
authors.forename: Chang-cang
authors.initials: CC
authors.lastname: Huang
authors.forename: Rui-qing
authors.initials: RQ
authors.lastname: Sun
authors.forename: Xiao-lin
authors.initials: XL
authors.lastname: Zheng
mesh_terms: D008982:Molybdenum / Q000737:chemistry*; D010710:Phosphates / Q000737:chemistry*; D010756:Phosphoric Acids / Q000138:chemical synthesis / Q000737:chemistry; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared; D013059:Spectrum Analysis, Raman
chemical_list: D010710:Phosphates; D010756:Phosphoric Acids; D008982:Molybdenum; C003125:phosphomolybdic acid