title: Chain elongations by three carbon atoms at a time in the boron-catalyzed polymerization of methallyltriphenylarsonium ylide.
abstract: Methallyltriphenylarsonium ylide polymerized in the presence of catalytic amounts of trialkylboranes. Linear polymers containing a terminal alcohol function were obtained after alkaline hydrogen peroxide oxidation. The chain of these polymers is constituted of methyl-substituted double bonds, separated by one methylene group. Their structure is related to that of natural rubber, in which the double bonds are separated by two methylene groups. These polymers arise from successive chain elongations of three carbon atoms at a time. A cyclic, polymeric ketone was also prepared from a cyclic trialkylborane. The mechanism, which involves a boratropic rearrangement after every insertion of a monomer, is discussed.
authors.affiliation: Service de Marquage Moléculaire et de Chimie Bioorganique, CEA-Saclay, Bât. 547, 91191 Gif-sur-Yvette, France.
authors.forename: Jean-Philippe
authors.initials: JP
authors.lastname: Goddard
authors.forename: Patricia
authors.initials: P
authors.lastname: Lixon
authors.forename: Thierry
authors.initials: T
authors.lastname: Le Gall
authors.forename: Charles
authors.initials: C
authors.lastname: Mioskowski