Beta-elimination of a phosphonate group from an alkoxy radical: an intramolecular acylation approach using an acylphosphonate as a carbonyl group acceptor.
On the basis of facile beta-elimination of a phosphonate group from an alkoxy radical, intramolecular acylation reaction has been developed, in which an acylphosphonate is used as an excellent carbonyl group radical acceptor.
Kim
Sunggak
S
Center for Molecular Design and Synthesis and Department of Chemistry, School of Molecular Science, Korea Advanced Institute of Science and Technology, Taejon 305-701, Korea. skim@kaist.ac.kr
Cho
Chang Ho
CH
Lim
Chae Jo
CJ