Extraction and cleanup methods of dioxins in house dust from two cities in Japan using accelerated solvent extraction and a disposable multi-layer silica-gel cartridge.
A simple and rapid method for the extraction and cleanup of dioxins from house dust was developed using an accelerated solvent extraction (ASE) method and a multi-layer silica-gel cartridge. It was found that the WHO-TEQ levels of dioxins extracted from the house dust obtained by both a conventional soxhlet extraction and the ASE were almost equal, when the data obtained by both methods were compared. As for the cleanup method, a multi-layer silica-gel cartridge yielded higher dioxin recoveries than the alkaline digestion method. The average values of the dioxins in house dust from Kumagaya city and Sendai city in Japan (Sendai city is bigger than Kumagaya city with respect to the population and industry), were 15.6 pg TEQ/g (8.6-26.0 pg TEQ/g, n=5, Kumagaya city) and 16.0 pg TEQ/g (5.9-30.5 pg TEQ/g, n=5, Sendai city), respectively.
Saito
Koichi
K
Dioxin Research Group, Saitama Institute of Public Health, 639-1 Kamiokubo, 338-0824 Saitama, Japan. saitok@interlink.or.jp
Takekuma
Mikiko
M
Ogawa
Masahiko
M
Kobayashi
Susumu
S
Sugawara
Yukio
Y
Ishizuka
Masahiro
M
Nakazawa
Hiroyuki
H
Matsuki
Yasuhiko
Y
D016902:Air Pollution, Indoor; D002623:Chemistry Techniques, Analytical / Q000379:methods; D002850:Chromatography, Gel / Q000295:instrumentation / Q000379:methods; D004147:Dioxins / Q000032:analysis* / Q000737:chemistry; D004391:Dust / Q000032:analysis*; D006801:Humans; D007536:Isomerism; D007564:Japan; D012822:Silicon Dioxide / Q000737:chemistry*; D012997:Solvents
D004147:Dioxins; D004391:Dust; D012997:Solvents; D012822:Silicon Dioxide