title: Facile preparation and photophysics of near-infrared luminescent lanthanide(III) monoporphyrinate complexes.
abstract: The synthesis, characterization, and single crystal X-ray diffraction structures of a series of monoporphyrinate, trivalent lanthanide complexes with the monoanionic ligands hydridotris(1-pyrazolyl)borate (Tp) and (cyclopentadienyl)tris(diethylphosphinito)cobaltate (L(OEt)) having the general formulas M(TPP)(L) (M = Yb, Tm, Er, Ho, Nd, Pr; TPP = 5,10,15,20-tetraphenylporphyrinate; L = Tp, L(OEt)) are described. The photophysical properties of these complexes are also presented including their absorption, emission, and transient absorption properties.
authors.affiliation: Department of Chemistry and Center for Macromolecular Science and Engineering, University of Florida, Gainesville, Florida 32611-7200, USA.
authors.forename: Timothy J
authors.initials: TJ
authors.lastname: Foley
authors.forename: Benjamin S
authors.initials: BS
authors.lastname: Harrison
authors.forename: Alison S
authors.initials: AS
authors.lastname: Knefely
authors.forename: Khalil A
authors.initials: KA
authors.lastname: Abboud
authors.forename: John R
authors.initials: JR
authors.lastname: Reynolds
authors.forename: Kirk S
authors.initials: KS
authors.lastname: Schanze
authors.forename: James M
authors.initials: JM
authors.lastname: Boncella