High yield of pure multiwalled carbon nanotubes from the catalytic decomposition of acetylene on in-situ formed cobalt nanoparticles.
For the first time, multiwalled carbon nanotubes (MWNTs) could be formed selectively in a high yield, free of any disordered carbon by-product, from the catalytic decomposition of acetylene at 600 degrees C on a CoxMg(1-x)O solid solution. Starting from 1 g of catalytic substrate, 4 g of pure MWNTs were obtained after its dissolution in boiling concentrated HCl, without any additional purification in strongly oxidizing medium, as is required for other methods of nanotube production. In situ reduction of CoO by dihydrogen liberated from acetylene decomposition allows highly divided metal particles to be continuously produced as synthesis proceeds. This is undoubtedly the reason for the good performance of the catalyst and for the ability to produce nanotubes in a narrow diameter range, namely from 10 to 15 nm. With the use of acetylene instead of methane, the synthesis proceeds at low temperature, which prevents the growth of carbon shells, in which the metal particles are generally embedded, decreasing their activity. Because of the very low specific surface area of the catalyst support, the amount of disordered carbon by-product formed is negligible.
Delpeux
Sandrine
S
CRMD, CNRS-University, 1B, rue de la Férollerie, 45071 Orléans, France.
Szostak
Katarzyna
K
Frackowiak
Elzbieta
E
Bonnamy
Sylvie
S
Béguin
François
F
D000114:Acetylene / Q000737:chemistry*; D002384:Catalysis; D003035:Cobalt / Q000737:chemistry*; D003460:Crystallization / Q000379:methods*; D008277:Magnesium Oxide / Q000737:chemistry; D008854:Microscopy, Electron; D008855:Microscopy, Electron, Scanning; D008968:Molecular Conformation; D037742:Nanotubes, Carbon / Q000737:chemistry* / Q000145:classification / Q000302:isolation & purification*; D011786:Quality Control; D013499:Surface Properties; D014961:X-Ray Diffraction
D037742:Nanotubes, Carbon; D008277:Magnesium Oxide; D003035:Cobalt; D000114:Acetylene