title: Light-induced aminocarbene to imine dyotropic rearrangement in a chromium(0) center: an unprecedented reaction pathway.
abstract: 1,2-Dyotropic rearrangement can be induced by irradiation of properly functionalized Fischer carbenes. This novel reaction takes place by a stepwise mechanism and with double inversion of configuration at the static scaffold. Good yields are obtained with both cyclic and acyclic structures, thus suggesting that this unprecedented transformation can be extended to other organometallic systems.
authors.affiliation: Departamento de Química Orgánica, Facultad de Química, Universidad Complutense, 28040-Madrid, Spain. sierraor@quim.ucm.es
authors.forename: Miguel A
authors.initials: MA
authors.lastname: Sierra
authors.forename: Israel
authors.initials: I
authors.lastname: Fernández
authors.forename: María J
authors.initials: MJ
authors.lastname: Mancheño
authors.forename: Mar
authors.initials: M
authors.lastname: Gómez-Gallego
authors.forename: M Rosario
authors.initials: MR
authors.lastname: Torres
authors.forename: Fernando P
authors.initials: FP
authors.lastname: Cossío
authors.forename: Ana
authors.initials: A
authors.lastname: Arrieta
authors.forename: Begoña
authors.initials: B
authors.lastname: Lecea
authors.forename: Ana
authors.initials: A
authors.lastname: Poveda
authors.forename: Jesús
authors.initials: J
authors.lastname: Jiménez-Barbero