Advanced ash management technologies for CFBC ash.
The combustion of high-sulphur coal demands the reduction of sulphur emissions. The sorbent most often used in sulphur capture technology is calcium-based. Ashes from technologies such as circulating fluidized bed combustion (CFBC), therefore, contain high calcium levels. The use and disposal of these ashes poses challenges, because of highly exothermic reactions with water, high-pH leachates, and excessive expansion of solidified materials. This paper looks at the potential of two post-combustion ash treatment processes, CERCHAR hydration and AWDS disposal, in solving these challenges. A high-sulphur coal-derived CFBC ash is examined, after CERCHAR hydration treatment, in conjunction with a conventionally hydrated ash, in a range of chemical, geotechnical and utilization scenarios. The ashes are used to make no-cement and roller-compacted concrete as well as Ash Water Dense Suspensions (AWDS). The solidified mortar paste from no-cement concrete is subjected to an extensive geochemical examination to determine how solidification progresses and strength develops, from a chemical point of view.
Anthony
E J
EJ
CANMET Energy Technology Centre, Natural Resources Canada, 1 Haanel Drive, Ottawa, Ontario, Canada K1A 1M1. banthony@nrcan.gc.ca
Berry
E E
EE
Blondin
J
J
Bulewicz
E M
EM
Burwell
S
S
D000397:Air Pollution / Q000517:prevention & control*; D003031:Coal; D017745:Incineration; D008422:Materials Testing; D008962:Models, Theoretical; D013455:Sulfur / Q000302:isolation & purification
D003031:Coal; D013455:Sulfur