Application of host-guest chemistry in nanotube-based device fabrication: photochemically controlled immobilization of azobenzene nanotubes on patterned alpha-CD monolayer/Au substrates via molecular recognition.
Azobenzene-functionalized nanotubes recognized and attached onto well-defined complementary regions of thiolated alpha-CD SAM/Au substrates via host-guest molecular recognition. The binding between the azobenzene nanotubes and the alpha-CD SAM/Au substrates was controlled by UV irradiation. The light-induced attachment-detachment of the azobenzene nanotubes on the alpha-CD SAMs was reversible. Some of the nanotubes were capable of interconnecting two Au substrates. This smart building block may be applied to build photoactive nanometer-sized mechanical switches in electronics.
Banerjee
Ipsita A
IA
Department of Chemistry and Biochemistry at Hunter College and the Graduate Center, The City University of New York, New York 10021, USA.
Yu
Lingtao
L
Matsui
Hiroshi
H
D001391:Azo Compounds / Q000737:chemistry*; D003505:Cyclodextrins / Q000737:chemistry*; D004988:Ethers, Cyclic; D006046:Gold / Q000737:chemistry*; D006860:Hydrogen Bonding; D047028:Macrocyclic Compounds; D036103:Nanotechnology / Q000379:methods*; D010455:Peptides / Q000737:chemistry*; D010777:Photochemistry; D010795:Phthalic Acids / Q000737:chemistry; D013056:Spectrophotometry, Ultraviolet; D047391:alpha-Cyclodextrins
D001391:Azo Compounds; D003505:Cyclodextrins; D004988:Ethers, Cyclic; D047028:Macrocyclic Compounds; D010455:Peptides; D010795:Phthalic Acids; D047391:alpha-Cyclodextrins; C452303:bis(metacyclophane)bolaamphiphile; D006046:Gold; C009850:azobenzene; C032613:alpha-cyclodextrin