title: Biocatalytic synthesis of the conjugated bridging ligand tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2'",3'"-j]phenazine (tpphz) and a dinuclear ruthenium complex.
abstract: We have synthesized a fully conjugated aromatic bridging ligand, tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2' ",3'"-j]phenazine (tpphz), and a dinuclear ruthenium complex using Hematin as a biocatalyst.
authors.affiliation: Center for Advanced Materials, University of Massachusetts Lowell, 265 Riverside Street, Lowell, Massachusetts 01854, USA.
authors.forename: Ravi
authors.initials: R
authors.lastname: Mosurkal
authors.forename: Lynne A
authors.initials: LA
authors.lastname: Samuelson
authors.forename: Jayant
authors.initials: J
authors.lastname: Kumar
mesh_terms: D002384:Catalysis; D008024:Ligands; D008958:Models, Molecular; D010619:Phenazines / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry*; D017975:Ruthenium Compounds / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet
chemical_list: D008024:Ligands; D010619:Phenazines; D011725:Pyridines; D017975:Ruthenium Compounds; C482776:tetrapyrido(3,2-a:2',3'-c:3'',2''-h:2''',3'''-j)phenazine