title: Mannose derived hexacoordinated phosphate--a generally efficient chiral anion for asymmetric applications.
abstract: Mannose derived hexacoordinated phosphate--prepared in two steps from methyl-alpha-D-mannopyranoside--is a chiral anionic auxiliary with broad asymmetric efficiency.
authors.affiliation: Department of Organic Chemistry, University of Geneva, Quai Ernest Ansermet 30, CH-1211 Geneva 4, Switzerland.
authors.forename: Céline
authors.initials: C
authors.lastname: Pérollier
authors.forename: Samuel
authors.initials: S
authors.lastname: Constant
authors.forename: Jonathan J
authors.initials: JJ
authors.lastname: Jodry
authors.forename: Gérald
authors.initials: G
authors.lastname: Bernardinelli
authors.forename: Jérôme
authors.initials: J
authors.lastname: Lacour
mesh_terms: D000838:Anions / Q000138:chemical synthesis* / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008360:Mannosephosphates / Q000138:chemical synthesis* / Q000737:chemistry; D008766:Methylmannosides / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D010084:Oxidation-Reduction; D013237:Stereoisomerism
chemical_list: D000838:Anions; D008360:Mannosephosphates; D008766:Methylmannosides