Zero-valent iron reduction of nitrate in the presence of ultraviolet light, organic matter and hydrogen peroxide.
This paper describes the use of metallic iron (Fe(0)) powder for nitrate removal in a well-mixed batch reactor. Important variables explored include Fe(0) dosage (1-3g/L), UV light intensity (64-128 W), and the presence of propanol (20 mg/L as DOC) and H(2)O(2) (100-200 mg/L). Accumulation of ferrous ions released from the Fe(0) surface can be expressed by an S-curve, which involves lag growth phase, exponential phase, rate-declining phase, and saturation phase. The removal of nitrate increases with increasing Fe(0) dosage; however, the removal makes no difference as the Fe(0) dosage is greater than 2 g/L. UV irradiation retards the dissolution of ferrous ion and the removal of nitrate. The species of propanol, which has a functional group of -OH, plays a role of organic inhibitor for Fe(0) corrosion. The presence of H(2)O(2) appears to inactivate all reactions as the Fe(0) of 10 microm was used; the final H(2)O(2) remains intact throughout the entire reaction period, and there were no removal of nitrate and no dissolution of ferrous ion. Surprisingly, with the use of a larger Fe(0) particle size of 150 microm, the H(2)O(2) was seen to decompose rapidly through Fenton reaction. Nevertheless, the rate of ferrous accumulation or nitrate removal is slow.
Liao
Chih-Hsiang
CH
Department of Environmental Engineering and Health, Chia-Nan University of Pharmacy and Science, Tainan, Taiwan. chliao@mail.chna.edu.tw
Kang
Shyh-Fang
SF
Hsu
Yu-Wei
YW
D006861:Hydrogen Peroxide / Q000737:chemistry; D007501:Iron / Q000737:chemistry*; D009566:Nitrates / Q000737:chemistry* / Q000302:isolation & purification; D016877:Oxidants / Q000737:chemistry; D010084:Oxidation-Reduction; D014466:Ultraviolet Rays; D018508:Water Purification / Q000379:methods*
D009566:Nitrates; D016877:Oxidants; D006861:Hydrogen Peroxide; D007501:Iron