title: [A synthesis of dolichyl fluorophosphate].
abstract: An improved method for the synthesis of dolichyl H-phosphonate was developed using 2-chloro-4H-1,3,2-benzodioxaphosphorin-4-one (salicyl chlorophosphite) as a reagent. Dolichyl phosphorofluoridate was for the first time synthesized from dolichyl H-phosphonate by its treatment with chlorotrimethylsilane, oxidation with iodine, and subsequent interaction with fluoride ion in pyridine.
authors.affiliation: Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, Moscow, 119991 Russia.
authors.forename: O V
authors.initials: OV
authors.lastname: Sizova
authors.forename: S D
authors.initials: SD
authors.lastname: Mal'tsev
authors.forename: V N
authors.initials: VN
authors.lastname: Shibaev
mesh_terms: D004288:Dolichol Phosphates / Q000138:chemical synthesis* / Q000737:chemistry; D005461:Fluorine; D009682:Magnetic Resonance Spectroscopy
chemical_list: D004288:Dolichol Phosphates; D005461:Fluorine