Chemical bonding differences evidenced from J-coupling in solid state NMR experiments involving quadrupolar nuclei.
Small scalar J-coupling between quadrupolar nuclei and spin 1/2 can be measured in inorganic solids using J-Resolved experiments and further used to acquire 2D J-HQMC heteronuclear correlation, giving detailed insight into the chemical bonding scheme.
Massiot
Dominique
D
CRMHT-CNRS, 1D ave Recherche Scientifique 45071, Orléans cedex 2, France. massiot@cnrs-orleans.fr
Fayon
Franck
F
Alonso
Bruno
B
Trebosc
Julien
J
Amoureux
Jean-Paul
JP