Mannose derived hexacoordinated phosphate--a generally efficient chiral anion for asymmetric applications.
Mannose derived hexacoordinated phosphate--prepared in two steps from methyl-alpha-D-mannopyranoside--is a chiral anionic auxiliary with broad asymmetric efficiency.
Pérollier
Céline
C
Department of Organic Chemistry, University of Geneva, Quai Ernest Ansermet 30, CH-1211 Geneva 4, Switzerland.
Constant
Samuel
S
Jodry
Jonathan J
JJ
Bernardinelli
Gérald
G
Lacour
Jérôme
J
D000838:Anions / Q000138:chemical synthesis* / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008360:Mannosephosphates / Q000138:chemical synthesis* / Q000737:chemistry; D008766:Methylmannosides / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D010084:Oxidation-Reduction; D013237:Stereoisomerism
D000838:Anions; D008360:Mannosephosphates; D008766:Methylmannosides