title: Synthesis and physical properties of biquinoxalinyl bridged bis-porphyrins: models for aspects of photosynthetic reaction centres.
abstract: The synthesis of biquinoxalinyl-bridged bis-porphyrin 4 and metallated derivatives 5-11 was achieved in high yields. UV-visible spectroscopy and electrochemical experiments indicated weak orbital coupling of the two quinoxalinyl units but minimal orbital coupling between the two porphyrins. The weak electronic communication is attributed to non-planarity, on average, of the molecule because of rotation about the inter-quinoxalinyl connection. This, combined with poor coupling across the fused junctions between the porphyrin and quinoxalinyl units, results in minimal inter-porphyrin communication. As a result, the biquinoxalinyl linkage is appropriate for inclusion in more elaborate synthetic compounds, such as the tris-porphyrin 1, that are designed to model the charge-separation apparatus of Photosynthetic Reaction Centres.
authors.affiliation: School of Chemistry, The University of Sydney, NSW 2006, Australia. m.crossley@chem.usyd.edu.au
authors.forename: Maxwell J
authors.initials: MJ
authors.lastname: Crossley
authors.forename: Paul J
authors.initials: PJ
authors.lastname: Sintic
authors.forename: Robin
authors.initials: R
authors.lastname: Walton
authors.forename: Jeffrey R
authors.initials: JR
authors.lastname: Reimers