Synthesis of (pyridin-2-yl)hydrazine conjugates as bifunctional chelates using the Suzuki-Miyaura reaction.
Palladium catalyzed C-C couplings were used to connect (pyridin-2-yl)hydrazine to organic substrates, including a phenylalanine derivative, providing a new method for introducing this important ligand.
Arterburn
Jeffrey B
JB
Department of Chemistry & Biochemistry MSC 3C, New Mexico State University, Box 30001, Las Cruces, New Mexico 88003, USA. jarterbu@nmsu.edu
Bryant
Bj K
BK
Chen
DaJun
D
D001880:Boranes / Q000737:chemistry; D001897:Boronic Acids / Q000737:chemistry; D002384:Catalysis; D002614:Chelating Agents / Q000737:chemistry*; D002625:Chemistry, Organic / Q000379:methods*; D006834:Hydrazines / Q000138:chemical synthesis* / Q000737:chemistry; D008956:Models, Chemical; D010165:Palladium / Q000737:chemistry; D011725:Pyridines / Q000138:chemical synthesis* / Q000737:chemistry
D001880:Boranes; D001897:Boronic Acids; D002614:Chelating Agents; D006834:Hydrazines; D011725:Pyridines; D010165:Palladium