Novel efficient synthesis of dibromoalkenes. A first example of catalytic olefination of aliphatic carbonyl compounds.
A new simple and efficient one pot transformation of various aliphatic carbonyl compounds to the corresponding dibromoalkenes is described. A wide range of hydrazones of aldehydes and ketones, prepared in situ, were easily converted into dibromoalkenes by treatment with carbon tetrabromide in the presence of CuCl. The reaction proceeds under mild conditions to give the target products in good to high yields.
Korotchenko
Vasily N
VN
Moscow State University, Department of Chemistry, Leninskie Gory, Moscow 119992, Russia.
Shastin
Alexey V
AV
Nenajdenko
Valentine G
VG
Balenkova
Elizabeth S
ES