title: Interdependence of redox state, hydrogen bonding, anion recognition and charge partition in crystals of (EDT-TTF-CONHMe)6 [Re6Se8(CN)6] (CH3CN)2(CH2Cl2)2.
abstract: Neutral pi-conjugated molecules and their radical cations co-exist in [(EDT-TTF-CONHMe+*)4(EDT-TTF-CONHMe0)2] [Re6Se8(CN)6]4- (CH3CN)2(CH2Cl2)2 whose crystal structure reveals that, upon one-electron oxidation, an activation of the N-H and C-H hydrogen bond donor ability is coupled to a deactivation of the hydrogen bond acceptor character of the carbonyl oxygen atom: this is expressed in the supramolecular hydrogen bond pattern and, ultimately, into charge localisation and partition in the solid state.
authors.affiliation: Laboratoire Chimie Inorganique, Matériaux et Interfaces, FRE 2447 CNRS-Université d'Angers, Bat K, 2 Boulevard Lavoisier, 49045 Angers, France.
authors.forename: Stéphane A
authors.initials: SA
authors.lastname: Baudron
authors.forename: Patrick
authors.initials: P
authors.lastname: Batail
authors.forename: Carme
authors.initials: C
authors.lastname: Rovira
authors.forename: Enric
authors.initials: E
authors.lastname: Canadell
authors.forename: Rodolphe
authors.initials: R
authors.lastname: Clérac