One-electron oxidized nickel(II)-(disalicylidene)diamine complex: temperature-dependent tautomerism between Ni(III)-phenolate and Ni(II)-phenoxyl radical states.
The one-electron oxidized species of a Ni(II)-phenolate complex has been shown to be in the Ni(II)-phenoxyl radical state at room temperature and the Ni(III)-phenolate state at < -120 degrees C, indicating that the oxidation state is temperature dependent.
Shimazaki
Yuichi
Y
Institute for Materials Chemistry and Engineering, Kyushu University, Higashi-ku, Fukuoka 812-8581, Japan.
Tani
Fumito
F
Fukui
Kôichi
K
Naruta
Yoshinori
Y
Yamauchi
Osamu
O