Tandem RCM-Pauson-Khand reaction for access to tricycles in one step.
Starting from conveniently designed dienynes complexed to cobalt, a tandem RCM-intramolecular Pauson-Khand reaction yields tricyclic compounds. The methodology allows the synthesis of 6,5,5 and 7,5,5 systems.
Rosillo
Marta
M
Departamento de Química, Facultad de CC, Experimentales y de la Salud, Universidad San Pablo-CEU, Boadilla del Monte, 28668-Madrid, Spain.
Casarrubios
Luis
L
Domínguez
Gema
G
Pérez-Castells
Javier
J