title: Synthesis of novel chiral phosphinocyrhetrenyloxazoline ligands and their application in asymmetric catalysis.
abstract: Several novel planar chiral phosphinocyrhetrenyloxazolines have been synthesized, and their catalytic activities have been evaluated in a variety of asymmetric catalytic reactions. Preferable effects as compared to their ferrocenyl analogues have been observed in asymmetric allylic amination and asymmetric hydrosilylation, and up to 97% ee and 72% ee were reached, respectively. The Lewis basicity of the phosphorus on the ferrocene and the cyrhetrene, which contributes to their different behavior in catalysis, has been deduced by 31P NMR spectroscopy analysis, as indicated by 1J(77Se-31P) in the corresponding phosphine selenides.
authors.affiliation: Institut für Organische Chemie der RWTH Aachen, Professor-Pirlet-Strasse 1, 52056 Aachen, Germany. carsten.bolm@oc.rwth-aachen.de
authors.forename: Carsten
authors.initials: C
authors.lastname: Bolm
authors.forename: Li
authors.initials: L
authors.lastname: Xiao
authors.forename: Martin
authors.initials: M
authors.lastname: Kesselgruber