Effects of chlorine content and position of chlorinated phenols on their oxidation kinetics by potassium permanganate.
Chlorine content and position of chlorinated phenols have many significant effects on the reactivity of oxido-reduction. The effects of chlorine content and position of chlorinated phenols on their oxidation kinetics by potassium permanganate were evaluated through different kinetics studies. Since chlorine was an electron withdrawing atom, the substitution of chlorine on the aromatic ring decreased the oxidation rate constant by sigma-electron withdrawing conductive effect. The substitution of chlorine at ortho or para position on the aromatic ring increased the oxidation rate constant by pi-electron donating conjugative effect, and the conjugative effect could counteract the negative impact of the conductive effect to some extent. On the other hand, the substitution of chlorine at ortho position on the aromatic ring decreased the oxidation rate constant by steric hindrance effect. The oxidation rate constants of phenol and chlorinated phenol studied decreased as follow order: 4-chlorophenol > 2,4-dichlorophenol > phenol > 2,6-dichlorophenol.
Zhang
Jin
J
School of Environmental Science and Engineering, Dalian Maritime University, Dalian 116012, China. dlhsh-zhj@163.com
Li
Gui-Bai
GB
Jun
M A
MA
D017606:Chlorine Compounds / Q000737:chemistry*; D007700:Kinetics; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010636:Phenols / Q000737:chemistry*; D011196:Potassium Permanganate / Q000737:chemistry; D018508:Water Purification / Q000379:methods*
D017606:Chlorine Compounds; D010636:Phenols; D011196:Potassium Permanganate