CSe2-free synthesis of [1,3]diselenole-2-thione and its application to syntheses of iodinated tetraselenafulvalenes (TSeFs).
We developed a new CSe2-free protocol for the synthesis of [1,3]diselenole-2-thione and converted it to tetraselenafulvalene derivatives without any selenium-sulfur exchange side reactions.
Imakubo
Tatsuro
T
Imakubo Initiative Research Unit, RIKEN, 2-1 Hirosawa, Wako, Saitama, 351-0198, Japan. imakubo@postman.riken.go.jp
Shirahata
Takashi
T