title: [Kinetics and mechanism of oxygen atom transfer reactions between iron (II) isocyanide complexes and (CH3)3NO].
abstract: Kinetics and mechanism of reactions between iron (II) isocyanide complexes [FeL5 (CN)] Br (1, L = -CNCH2Ph); trans- [FeL4 (CN)2] 2, L = -CNCH2Ph) and oxygen atom transfer agent (CH3)3NO have been investigated in dichloromethane by UV-visible and Infrared spectrophotometers at different temperatures. The results revealed that the reactions proceed with second order and the rate law is rate = k2 [isocyanide complex] x [(CH3)3NO]. delta S not equal to and delta H not equal to for the reaction between complex 1 and (CH3)3NO are -25.34 +/- 1.67 cal.(mol.K)-1 and 12.71 +/- 0.49 kcal.mol-1 respectively. However, there is no reaction between 2 and (CH3)3NO. The reaction mechanism was proposed and the factors affecting the reaction rate were also discussed.
authors.affiliation: College of Materials Science and Technology, National Huaqiao University, Quanzhou 362011, China.
authors.forename: Hong-shan
authors.initials: HS
authors.lastname: He
authors.forename: Yi-ci
authors.initials: YC
authors.lastname: Gao
authors.forename: Qi-zhen
authors.initials: QZ
authors.lastname: Shi
mesh_terms: D001965:Bromides / Q000737:chemistry; D002614:Chelating Agents / Q000737:chemistry*; D003486:Cyanides / Q000737:chemistry*; D004579:Electron Transport; D007501:Iron / Q000737:chemistry*; D007700:Kinetics; D008752:Methylene Chloride; D009569:Nitric Oxide / Q000737:chemistry; D010100:Oxygen / Q000737:chemistry; D013055:Spectrophotometry, Infrared; D013056:Spectrophotometry, Ultraviolet; D013696:Temperature
chemical_list: D001965:Bromides; D002614:Chelating Agents; D003486:Cyanides; D009569:Nitric Oxide; D008752:Methylene Chloride; D007501:Iron; D010100:Oxygen