Biocatalytic synthesis of the conjugated bridging ligand tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2'",3'"-j]phenazine (tpphz) and a dinuclear ruthenium complex.
We have synthesized a fully conjugated aromatic bridging ligand, tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2' ",3'"-j]phenazine (tpphz), and a dinuclear ruthenium complex using Hematin as a biocatalyst.
Mosurkal
Ravi
R
Center for Advanced Materials, University of Massachusetts Lowell, 265 Riverside Street, Lowell, Massachusetts 01854, USA.
Samuelson
Lynne A
LA
Kumar
Jayant
J
D002384:Catalysis; D008024:Ligands; D008958:Models, Molecular; D010619:Phenazines / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry*; D017975:Ruthenium Compounds / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet
D008024:Ligands; D010619:Phenazines; D011725:Pyridines; D017975:Ruthenium Compounds; C482776:tetrapyrido(3,2-a:2',3'-c:3'',2''-h:2''',3'''-j)phenazine