Neutral and dianionic iron and ruthenium 1,4-diphosphabutadiene complexes.
Reaction of a tetraphenyl-1,2-diphosphinyl dianion with [FeCl2(THF)1.5] or [Ru(COD)(acac)2] yields dianionic complexes which further react with Ph3SnCl to afford the corresponding bis(1,4-diphosphabutadiene) complexes.
Moores
Audrey
A
Department of Chemistry, Hétéroéléments et Coordination, UMR CNRS 7653, Ecole Polytechnique, 91128, Palaiseau Cedex, France.
Mézailles
Nicolas
N
Ricard
Louis
L
Mathey
François
F
Le Floch
Pascal
P