[Selective excitation spectra and energy level structure of Dy3+:ThO2 crystal].
Dy3+:ThO2 crystal was grown by the flux technique for the first time. The emission spectra, excitation spectra and fluorescence decay curves were measured and discussed. By using emission spectra obtained under selective dye laser excitation at 12 K, together with the crystal-field theory, the site symmetry of Dy3+ ions in ThO2 was determined as C3 nu and its energy level structure was tabulated. The lifetime of radiative level 4F9/2 was also determined as 0.40 ms.
Yin
M
M
Department of Physics, University of Science and Technology of China, 230026 Hefei.
Krupa
J C
JC
D055598:Chemical Phenomena; D002627:Chemistry, Physical; D003460:Crystallization; D004419:Dysprosium / Q000737:chemistry*; D004735:Energy Transfer; D005456:Fluorescent Dyes; D007834:Lasers; D049449:Luminescence; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry; D013050:Spectrometry, Fluorescence; D013696:Temperature; D013910:Thorium / Q000737:chemistry; D013911:Thorium Dioxide / Q000737:chemistry*
D005456:Fluorescent Dyes; D009942:Organometallic Compounds; D004419:Dysprosium; D013910:Thorium; D013911:Thorium Dioxide