[Infrared and Raman spectra studies on isomultinuclear organometallic carbyne compounds].
The infrared and Raman spectra of five isomultinuclear organometallic carbyne compounds were studied. The results show that the introduction of N atom from TMEDA or P atom from DPPE to W atom (both N and P are strong sigma-donor and weak pi-acceptor) will decrease the bonding intensity of W identical to C. The pressure tunning IR and Raman spectra of compound III indicate the presence of pressure-induced phase-transition near 20 kbar in it. There are two effects on the nu (W identical to C) of this compound with increasing pressure: the normal increasing the nu (W identical to C) wavenumber due to the shorting W identical to C bond and increasing the W-CO pi backbonding to decrease the nu (W identical to C) wavenumber.
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State Key Laboratory of Rare Earth Material Chemistry and Applications, Department of Chemistry, Peking University, 100871 Beijing.
Mayr
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D002219:Carbamates / Q000737:chemistry*; D002244:Carbon; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D011312:Pressure; D013055:Spectrophotometry, Infrared; D013059:Spectrum Analysis, Raman; D014414:Tungsten / Q000737:chemistry*
D002219:Carbamates; D009942:Organometallic Compounds; C004359:barban; D002244:Carbon; D014414:Tungsten