title: Sol-gel-derived sensor materials that yield linear calibration plots, high sensitivity, and long-term stability.
abstract: Novel O2-sensing materials based on spin-coated n-octyltriethoxysilane (Octyl-triEOS)/tetraethylorthosilane (TEOS) composite xerogel films have been synthesized and investigated. These sensors are based on the O2 quenching of tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) ([Ru(dpp)3]2+) sequestered within the xerogels. Scanning electron microscopy and luminescence measurements (steady state and time resolved) have been used to investigate the structure of these films and their analytical figures of merit and determine the underlying reasons for their observed performance. The results show that certain [Ru(dpp)3]2+-doped Octyl-triEOS/TEOS composites form uniform, crack-free xerogel films that can be used to construct high-sensitivity O2 sensors that have linear calibration curves and excellent long-term stability. For example, an 11-month-old sensor based on 50 mol % Octyl-triEOS exhibits more than 4-fold greater sensitivity in comparison to an equivalent sensor based on pure TEOS. Over an 11-month time period, the sensitivity of a pure TEOS-based sensor drops by more than 400% whereas a sensor based on 50 mol % Octyl-triEOS remains stable (RSD = 4%).
authors.affiliation: Department of Chemistry, Natural Sciences Complex, University at Buffalo, The State University of New York, Buffalo, New York 14260-3000, USA.
authors.forename: Ying
authors.initials: Y
authors.lastname: Tang
authors.forename: Elizabeth C
authors.initials: EC
authors.lastname: Tehan
authors.forename: Zunyu
authors.initials: Z
authors.lastname: Tao
authors.forename: Frank V
authors.initials: FV
authors.lastname: Bright
mesh_terms: D015374:Biosensing Techniques / Q000379:methods*; D002138:Calibration; D005782:Gels / Q000737:chemistry*; D016014:Linear Models; D008855:Microscopy, Electron, Scanning; D010100:Oxygen / Q000032:analysis* / Q000737:chemistry; D015203:Reproducibility of Results; D012680:Sensitivity and Specificity; D013997:Time Factors
chemical_list: D005782:Gels; D010100:Oxygen