title: [Molecular structures and spectroscopic properties of octa-nuclear clusters with [V2M6S6O2](M = Cu, Ag) core].
abstract: The syntheses and molecular structures of two octa-nuclear [V2M6S6O2](M = Cu, Ag) clusters derived from [VS4]3- have been reported in this paper. Their infrared, 51V NMR and electronic spectra have also been assigned and discussed. The formation mechanism of octa-nuclear [V2Cu6S6O2] cluster has been explored by means of active IR capture technique.
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002 Fuzhou.
authors.forename: F
authors.initials: F
authors.lastname: Zheng
authors.forename: G
authors.initials: G
authors.lastname: Guo
authors.forename: X
authors.initials: X
authors.lastname: Zhang
authors.forename: Y
authors.initials: Y
authors.lastname: Zheng
authors.forename: I
authors.initials: I
authors.lastname: Huang