[Molecular structures and spectroscopic properties of octa-nuclear clusters with [V2M6S6O2](M = Cu, Ag) core].
The syntheses and molecular structures of two octa-nuclear [V2M6S6O2](M = Cu, Ag) clusters derived from [VS4]3- have been reported in this paper. Their infrared, 51V NMR and electronic spectra have also been assigned and discussed. The formation mechanism of octa-nuclear [V2Cu6S6O2] cluster has been explored by means of active IR capture technique.
Zheng
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F
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002 Fuzhou.
Guo
G
G
Zhang
X
X
Zheng
Y
Y
Huang
I
I