Point-defect-induced forbidden reflections in resonant X-ray scattering.
Point defects in crystals cause displacements of neighbouring atoms and hence become the source of an additional anisotropy of the X-ray resonant scattering amplitude. This anisotropy can induce 'forbidden' Bragg reflections near absorption edges, called point-defect-induced (PDI) reflections, which are absent in non-resonant X-ray scattering and in resonant X-ray scattering by perfect crystals. The deformation of external electron shells is the physical reason for this phenomenon. Some examples of crystals are considered in which the PDI reflections could be observed.
Dmitrienko
Vladimir E
VE
A. V. Shubnikov Institute of Crystallography, 119333 Moscow, Russia.
Ovchinnikova
Elena N
EN
D003198:Computer Simulation; D007501:Iron / Q000737:chemistry; D008958:Models, Molecular; D008968:Molecular Conformation; D012542:Scattering, Radiation; D014961:X-Ray Diffraction / Q000379:methods*; D015018:Ytterbium / Q000737:chemistry
D007501:Iron; D015018:Ytterbium