Controlling dimensionality of silver(I) coordination networks with rigid aliphatic amino ligands: from a 2D to a 3D network of unprecedented topology comprising helical channels.
Ligand-directed 2D and 3D Ag(I) coordination networks are self-assembled from the rigid, topologically related tri-amino ligands cis-3,5-diaminopiperidine (cis-dapi) and cis,trans-1,3,5-triaminocyclohexane (trans-tach), yielding two networks of differing dimensionality including a 3D network of unprecedented topology comprising helical channels.
Seeber
Georg
G
Department of Chemistry, The University of Glasgow, University Avenue, Glasgow, UK G12 8QQ.
Pickering
Alexandra L
AL
Long
De-Liang
DL
Cronin
Leroy
L