Nitrophenyl derivatives of pyrrole 2,5-diamides: structural behaviour, anion binding and colour change signalled deprotonation.
Two new pyrrole 2,5-diamide clefts have been synthesized containing 4-nitrophenyl or 3,5-dinitrophenyl groups appended to the amide positions. The 3,5-dinitrophenyl derivative has been shown to deprotonate in the presence of fluoride, which in acetonitrile solution, gives rise to a deep blue colour.
Camiolo
Salvatore
S
School of Chemistry, University of Southampton, Southampton, UK SO17 1BJ.
Gale
Philip A
PA
Hursthouse
Michael B
MB
Light
Mark E
ME