title: [Combustion temperature measurement of pyrotechnic composition using remote sensing Fourier transform infrared spectrometry].
abstract: In this paper, combustion characterization of pyrotechnic composition is investigated using a remote sensing Fourier transform infrared spectrometry. The emission spectra have been recorded between 4,700 and 740 cm-1 with a spectral resolution of 4 cm-1. The combustion temperature can be determined remotely from spectral line intensity distribution of the fine structure of the emission fundamental band of gaseous products such as HF. The relationship between combustion temperature and combustion time has been given. Results show that there is a violent mutative temperature field with bigger temperature gradient near combustion surface. It reveals that the method of temperature measurement using remote sensing FTIR for flame temperature of unstable, violent and short time combustion on real time is a rapid, accurate and sensitive technique without interference the flame temperature field. Potential prospects of temperature measurement, gas product concentration measurement and combustion mechanism are also revealed.
authors.affiliation: School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.
authors.forename: Xin-li
authors.initials: XL
authors.lastname: Zhou
authors.forename: Yan
authors.initials: Y
authors.lastname: Li
authors.forename: Zu-liang
authors.initials: ZL
authors.lastname: Liu
authors.forename: Chang-jiang
authors.initials: CJ
authors.lastname: Zhu
authors.forename: Jun-de
authors.initials: JD
authors.lastname: Wang
authors.forename: Chun-xu
authors.initials: CX
authors.lastname: Lu
mesh_terms: D005466:Fluorocarbons / Q000032:analysis*; D005740:Gases / Q000032:analysis; D008274:Magnesium / Q000032:analysis*; D000644:Quaternary Ammonium Compounds / Q000032:analysis; D017550:Spectroscopy, Fourier Transform Infrared / Q000379:methods*; D013686:Telemetry; D013696:Temperature; D013997:Time Factors
chemical_list: D005466:Fluorocarbons; D005740:Gases; D000644:Quaternary Ammonium Compounds; D008274:Magnesium; C015531:tetrafluoroethylene