title: Pore mouth versus intracrystalline adsorption of isoalkanes on ZSM-22 and ZSM-23 zeolites under vapour and liquid phase conditions.
abstract: Methylbranched C5-C9 alkanes do not adsorb in the intracrystalline void space of ZSM-23, neither from the vapour nor the liquid phase, but are adsorbed in ZSM-22, if only from the liquid phase, and this despite the small difference in pore size.
authors.affiliation: Dienst Chemische Ingenieurstechniek, Vrije Universiteit Brussel, Pleinlaan 2, B-1050, Brussels, Belgium. Joeri.Denayer@vub.ac.be
authors.forename: J F
authors.initials: JF
authors.lastname: Denayer
authors.forename: A R
authors.initials: AR
authors.lastname: Ocakoglu
authors.forename: W
authors.initials: W
authors.lastname: Huybrechts
authors.forename: J A
authors.initials: JA
authors.lastname: Martens
authors.forename: J W
authors.initials: JW
authors.lastname: Thybaut
authors.forename: G B
authors.initials: GB
authors.lastname: Marin
authors.forename: G V
authors.initials: GV
authors.lastname: Baron
mesh_terms: D000327:Adsorption; D000473:Alkanes / Q000737:chemistry*; D055598:Chemical Phenomena; D002627:Chemistry, Physical; D003460:Crystallization; D016062:Porosity; D012997:Solvents; D014835:Volatilization; D017641:Zeolites / Q000737:chemistry*
chemical_list: D000473:Alkanes; D012997:Solvents; D017641:Zeolites