A 3D network of helicates fully assembled by pi-stacking interactions.
The neutral dinuclear dihelicate [Cu2(L)2] x 2CH3CN (1) forms a unique 3D network in the solid state due to pi-stacking interactions, which are responsible for intermolecular antiferromagnetic coupling between Cu(II) ions.
Vázquez
Miguel
M
Laboratorio di Chimica Supramolecolare, Dipartimento di Chimica Generale, Università di Pavia, 27100 Pavia, Italy. miguel.vazquez@unipv.it
Taglietti
Angelo
A
Gatteschi
Dante
D
Sorace
Lorenzo
L
Sangregorio
Claudio
C
González
Ana M
AM
Maneiro
Marcelino
M
Pedrido
Rosa M
RM
Bermejo
Manuel R
MR