[Correction for the spectral interferences of rare-earth matrix to the determination of calcium by spectral fitting matrix projection-Kalman filter method].
The spectral interferences of trace elements from high purity rare earth will seriously affect the analytical accuracy in the ICP-AES analysis. In this work, spectral fitting matrix projection-Kalman filter method was developed and applied to correction of spectral interferences produced by rare earth matrix peaks with simple shapes in determination of calcium, and it was applied to correct spectral interferences caused by terbium oxide and dysprosium oxide respectively, and satisfactory results were obtained.
Ni
Y
Y
Department of Chemistry, Nanchang University, 330047 Nanchang.
Wu
Y
Y
Liu
W
W
D002118:Calcium / Q000737:chemistry*; D004419:Dysprosium / Q000737:chemistry*; D005374:Filtration / Q000379:methods; D013058:Mass Spectrometry / Q000379:methods; D008674:Metals, Rare Earth / Q000737:chemistry*; D013054:Spectrophotometry, Atomic / Q000379:methods; D013725:Terbium / Q000737:chemistry
D008674:Metals, Rare Earth; D013725:Terbium; D004419:Dysprosium; D002118:Calcium; C030582:dysprosium oxide