Controllable synthesis, characterization and catalytic properties of WO(3)/ZrO(2) mixed oxides nanoparticles.
Tungsten-promoted zirconia (WO(3)/ZrO(2)) nanoparticles were synthesized in reverse micelles of water/sodium bis(2-ethylexyl) sulfosuccinate/isooctane, which were compared with WO(3)/ZrO(2) prepared by incipient wetness impregnation and sol-gel method. The control of particle size was achieved by varying the process variables, such as water-to-surfactant molar ratio and reagent concentration. Their sizes, appearances, crystal structures, and thermochemical behavior were characterized by UV-vis, TEM, XRD and TG-DTA. NH(3)-TPD and Hammett indicator measurement were also employed to study the acidity of samples. The results revealed that samples prepared in reverse micelles had higher percentages of T-ZrO(2) and greater acid strength than those of other samples. The alkylation of butene with isobutane on WO(3)/ZrO(2) was carried out in a fixed-bed reactor. Samples synthesized in reverse micelles had better reaction performance than others. A parallel relationship could be drawn between the catalytic activity and the acid amounts as well as the acid strength of the catalysis.
Sun
Wendong
W
Department of Chemistry, Northeast Normal University, Changchun, 130024, People's Republic of China. chuying@nenu.edu.cn
Xu
Liping
L
Chu
Ying
Y
Shi
Wei
W