title: Determination of flash point in air and pure oxygen using an equilibrium closed bomb apparatus.
abstract: The standard closed testers for flash point measurements may not be feasible for measuring flash point in special atmospheres like oxygen because the test atmosphere cannot be maintained due to leakage and the laboratory safety can be compromised. To address these limitations we developed a new "equilibrium closed bomb" (ECB). The ECB generally gives lower flash point values than standard closed cup testers as shown by the results of six flammable liquids. The present results are generally in good agreement with the values calculated from the reported lower flammability limits and the vapor pressures. Our measurements show that increased oxygen concentration had little effect on the flash points of the tested flammable liquids. While generally regarded as non-flammable because of the lack of observed flash point in standard closed cup flash point testers, dichloromethane is known to form flammable mixtures. The flash point of dichloromethane in oxygen measured in the ECB is -7.1 degrees C. The flash point of dichloromethane in air is dependent on the type and energy of the ignition source. Further research is being carried out to establish the relationship between the flash point of dichloromethane and the energy of the ignition source.
authors.affiliation: Chilworth Technology, Inc., 11 Deer Park Dr., Monmouth Junction, NJ 08852, USA. dkong@chilworth.com
authors.forename: Dehong
authors.initials: D
authors.lastname: Kong
authors.forename: David J
authors.initials: DJ
authors.lastname: am Ende
authors.forename: Steven J
authors.initials: SJ
authors.lastname: Brenek
authors.forename: Neil P
authors.initials: NP
authors.lastname: Weston
mesh_terms: D001272:Atmosphere; D005107:Explosions; D015386:Hazardous Substances; D008422:Materials Testing; D008752:Methylene Chloride / Q000737:chemistry; D008962:Models, Theoretical; D010100:Oxygen / Q000737:chemistry
chemical_list: D015386:Hazardous Substances; D008752:Methylene Chloride; D010100:Oxygen