title: OTDR fiber-optical chemical sensor system for detection and location of hydrocarbon leakage.
abstract: A distributed sensing system for apolar hydrocarbons is presented which is built from a polymer-clad silica fiber adapted to an optical time domain reflectometer (OTDR) set-up. OTDR measurements allow locating and detecting chemicals by measuring the time delay between short light pulses entering the fiber and discrete changes in the backscatter signals that are caused by local extraction of hydrocarbons into the fiber cladding. The light guiding properties of the fiber are affected by interaction of the extracted chemicals with the evanescent wave light field extending into the fiber cladding. Distributed sensing of pure liquid hydrocarbons (HC) and aqueous HC solutions with a commercially available mini-OTDR adapted to sensing fibers of up to 1km length could be demonstrated. A pulsed laser diode emitting at the 850 nm telecommunication wavelength was applied in the mini-OTDR to locate the HCs by analyzing the step drop (light loss) in the backscatter signal, which is induced by local refractive index (RI) increase in the silicone cladding due to the extracted HC. The prototype instrument can be applied for monitoring hydrocarbon leakage in large technical installations, such as tanks, chemical pipelines or chemical waste disposal containments.
authors.affiliation: Forschungszentrum Karlsruhe, Institut für Instrumentelle Analytik-IFIA, PO Box 3640, D-76021 Karlsruhe, Germany. jochen.buerck@ifia.fzk.de
authors.forename: J
authors.initials: J
authors.lastname: Buerck
authors.forename: S
authors.initials: S
authors.lastname: Roth
authors.forename: K
authors.initials: K
authors.lastname: Kraemer
authors.forename: H
authors.initials: H
authors.lastname: Mathieu
mesh_terms: D004784:Environmental Monitoring / Q000295:instrumentation*; D006838:Hydrocarbons / Q000032:analysis*; D055095:Optics and Photonics; D011108:Polymers; D012822:Silicon Dioxide; D012989:Soil Pollutants / Q000032:analysis*; D014873:Water Pollutants / Q000032:analysis*
chemical_list: D006838:Hydrocarbons; D011108:Polymers; D012989:Soil Pollutants; D014873:Water Pollutants; D012822:Silicon Dioxide