[Quantitative determination of glass content in monazite glass-ceramics by IR technique].
Monazite glass-ceramics consist of both monazite and metaphoshate glass phases. The absorption bands of both phases do not overlap each other, and the absorption intensities of bands 1,275 and 616 cm-1 vary with the glass contents. The correlation coefficient between logarithmic absorbance ratio of the two bands and glass contents was r = 0.9975 and its regression equation was y = 48.356 + 25.93x. The absorbance ratio of bands 952 and 616 cm-1 also varied with different ratios of Ce2O3/La2O3 in synthetic monazites, with r = 0.9917 and a regression equation y = 0.2211 exp (0.0221x). High correlation coefficients show that the IR technique could find new application in the quantitative analysis of glass content in phosphate glass-ceramics.
He
Yong
Y
Material Science and Chemical Engineering College, China University of Geosciences, Wuhan 430074, China.
Zhang
Bao-min
BM
D002516:Ceramics / Q000032:analysis*; D005898:Glass / Q000737:chemistry*; D008674:Metals, Rare Earth / Q000032:analysis*; D010757:Phosphorous Acids / Q000737:chemistry; D013055:Spectrophotometry, Infrared
D008674:Metals, Rare Earth; D010757:Phosphorous Acids; C015370:monazite; C043639:metaphosphoric acid