[In-situ FTIR study of hybrid copper-cobalt hexacyanoferrate film modified electrode].
The study on the in-situ FTIR spectroelectrochemistry of a hybrid copper-cobalt hexacyanoferrate film modified platinum electrode was carried out. The variation of the FTIR spectra was well correlated to the redox process of CuCoHCF. The relative contribution of Cu(II) and Co(II) to the stretching vibration of CN was found to vary with the applied potential.
Cui
Xing-pin
XP
Department of Chemistry, University of Science and Technology of China, Hefei 230026, China.
Wang
Xia-yan
XY
Lin
Xiang-qin
XQ
D003035:Cobalt / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D004563:Electrochemistry; D004566:Electrodes; D005295:Ferrocyanides / Q000737:chemistry*; D010084:Oxidation-Reduction; D010984:Platinum; D017550:Spectroscopy, Fourier Transform Infrared
D005295:Ferrocyanides; C116383:ferrocyn; D003035:Cobalt; D010984:Platinum; D003300:Copper