[Studies on the formation of cyclodextrin nanotube by fluorescence and anisotropy measurements].
Steady-state fluorescence and anisotropy measurements have been used to investigate the interaction of 2,2'-biquinoline (BQ) and 1,1'-(methylenedi-1,4-phenylene)bismaleimide (MDP-BMI) with alpha-, beta-, and gamma-cyclodextrins (CDs). It was found that the reaction patterns between fluorescence molecules and CDs are remarkably different. They can form a simple inclusion complex with alpha-CD, while nanotubes can be formed in the presence of gamma-CD. Moreover, MDP-BMI can form nanotube with beta-CD at higher concentration.
Zhang
Chun-fen
CF
Institute of Applied Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.
Shen
Xing-hai
XH
Gao
Hong-cheng
HC
D016880:Anisotropy; D002482:Cellulose / Q000737:chemistry; D003505:Cyclodextrins / Q000737:chemistry*; D005453:Fluorescence; D008301:Maleimides / Q000737:chemistry; D043942:Nanotubes / Q000737:chemistry*; D011804:Quinolines / Q000737:chemistry; D013050:Spectrometry, Fluorescence; D047391:alpha-Cyclodextrins; D047392:beta-Cyclodextrins
D003505:Cyclodextrins; D008301:Maleimides; D011804:Quinolines; D047391:alpha-Cyclodextrins; D047392:beta-Cyclodextrins; C041953:cyclodextrin polymer; C419881:2,2'-biquinoline; D002482:Cellulose; C031215:betadex; C032613:alpha-cyclodextrin