[Fluorescence spectra of the rare earth complex-PAA-g-PE films].
The acrylic acid (AA) was grafted onto the PE film surface through UV photograft polymerization. With certain pH value, the grafted films were made to react with the alcohol-water solution of Eu3+ and alpha-thenoyltrifluoroacetone (TTA) or with the chloroform-water solution of Tb3+ and acetyl actone (AcAc), thus causing the preparation of the red or green fluorescent films. As compared with the corresponding Eu(TTA)3.(H2O)2 or Tb(AcAc)3.(H2O)2 solid complexes, both the excitation and emission spectra of the fluorescent films changed remarkably. It's predictable that chemical bond combination has occurred between the rare earth complexes and the macromolecular material. In addition, the IR spectra of the fluorescent films were also observed.
Li
J
J
Department of Chemical Engineering, Beijing Technology and Business University, 100037 Beijing.
Zeng
H
H
Yu
Q
Q
Cao
Y
Y
Wen
P
P
D000179:Acrylates / Q000737:chemistry*; D002614:Chelating Agents / Q000737:chemistry*; D005063:Europium / Q000737:chemistry*; D005453:Fluorescence; D006863:Hydrogen-Ion Concentration; D049449:Luminescence; D008674:Metals, Rare Earth / Q000737:chemistry*; D011108:Polymers; D013050:Spectrometry, Fluorescence; D013056:Spectrophotometry, Ultraviolet / Q000379:methods; D013499:Surface Properties; D013725:Terbium / Q000737:chemistry*; D013804:Thenoyltrifluoroacetone / Q000737:chemistry
D000179:Acrylates; D002614:Chelating Agents; D008674:Metals, Rare Earth; D011108:Polymers; D013725:Terbium; D013804:Thenoyltrifluoroacetone; D005063:Europium; C036658:acrylic acid