Manganese/Bicarbonate-catalyzed epoxidation of lipophilic alkenes with hydrogen peroxide in ionic liquids.
[reaction: see text] Effective epoxidation of lipophilic alkenes using hydrogen peroxide was accomplished with the manganese sulfate/bicarbonate catalytic system in an ionic liquid at room temperature.
Tong
Kit-Ho
KH
Department for Applied Biology and Chemical Technology and the Open Laboratory for Chiral Technology, Institute of Molecular Technology for Drug Discovery and Synthesis, The Hong Kong Polytechnic University, Hung Hom, Hong Kong SAR, China.
Wong
Kwok-Yin
KY
Chan
Tak Hang
TH
D000475:Alkenes / Q000737:chemistry*; D001639:Bicarbonates / Q000737:chemistry; D001881:Borates / Q000737:chemistry; D002384:Catalysis; D004777:Environment; D004852:Epoxy Compounds / Q000138:chemical synthesis*; D006861:Hydrogen Peroxide / Q000737:chemistry*; D007093:Imidazoles / Q000737:chemistry; D017895:Manganese Compounds / Q000737:chemistry; D015394:Molecular Structure; D012997:Solvents / Q000737:chemistry; D013431:Sulfates / Q000737:chemistry; D013696:Temperature
C419324:1-butyl-3-methylimidazolium tetrafluoroborate; D000475:Alkenes; D001639:Bicarbonates; D001881:Borates; D004852:Epoxy Compounds; D007093:Imidazoles; D017895:Manganese Compounds; D012997:Solvents; D013431:Sulfates; D006861:Hydrogen Peroxide; C039798:manganese sulfate