Synthesis and relationships between the structures and properties of monodisperse star-shaped oligofluorenes.
[structure: see text] A convenient approach to a series of star-shaped pi-conjugated organic materials with oligofluorenes (OF) as the branches and a benzene ring as the core has been developed. The optical properties of these materials are liable to be tuned by introduction of more fluorene rings. The investigation of the structure-property relationship of these materials has indicated differences between star-shaped oligofluorenes and linear oligofluorenes, as well as polyfluorenes.
Zhou
Xing-Hua
XH
The Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.
Yan
Ji-Chao
JC
Pei
Jian
J
D003432:Cross-Linking Reagents / Q000737:chemistry; D005449:Fluorenes / Q000138:chemical synthesis*; D009682:Magnetic Resonance Spectroscopy; D008956:Models, Chemical; D011108:Polymers / Q000138:chemical synthesis*; D019032:Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization / Q000379:methods; D013237:Stereoisomerism
D003432:Cross-Linking Reagents; D005449:Fluorenes; D011108:Polymers