An unprecedented 8-fold interpenetrating diamondoid-like coordination polymer containing a Cu+(4)(RCO2)(4) cluster as connecting node.
The reaction of Cu(I)(CH(3)CN)(4)BF(4) with 4-pyridylacrylic acid (4-HPYA) affords an unprecedented 8-fold interpenetrating diamondoid-like coordination polymer network [Cu(I)(3)(4-PYA)(2)(H(2)O)(BF(4)) ] (1) with a Cu(+)(4)(CO(2))(4) cluster as connecting node. The interpenetration in metal coordination polymers is the highest degree ever found within diamondoid nets containing a cluster as connecting note. Its fluorescent property was also reported.
Wang
Xi-Sen
XS
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P. R. China.
Zhao
Hong
H
Qu
Zhi-Rong
ZR
Ye
Qiong
Q
Zhang
Jing
J
Xiong
Ren-Gen
RG
You
Xiao-Zeng
XZ
Fun
Hoong-Kun
HK