[Surface enhanced Raman scattering (SERS) spectra of AMP and DNA in silver sol].
Surface enhanced Raman scattering (SERS) spectra of AMP and DNA in silver sol were obtained. Comparing the SERS spectra with spectra of AMP and DNA in solid state, we found that although those two systems were very similar in the main, but there were still some differences between them. For example, the ring breathing modes of adenine in solid AMP at 715 cm-1 was enhanced very much and appears at 723 cm-1 in silver sol. The symmetric stretching mode of phosphate group at 813 cm-1 was disappeared in SERS spectra. The vibration mode of ribose in DNA was enhanced obviously in SERS spectra, four kinds bands of A, T, C, G were also enhanced in varying degrees. The possible adsorption model of AMP and DNA in silver sol and the structure change is proposed.
Shen
H B
HB
Shanghai Teachers University, Department of Chemistry, Shanghai 200234, China.
Xia
J F
JF
Zhang
F
F
Yang
H F
HF
Zhang
Z R
ZR
D000249:Adenosine Monophosphate / Q000737:chemistry*; D000327:Adsorption; D003102:Colloids; D004247:DNA / Q000737:chemistry*; D015394:Molecular Structure; D009690:Nucleic Acid Conformation; D012542:Scattering, Radiation; D012834:Silver; D013059:Spectrum Analysis, Raman / Q000379:methods*
D003102:Colloids; D012834:Silver; D000249:Adenosine Monophosphate; D004247:DNA