title: An unprecedented 8-fold interpenetrating diamondoid-like coordination polymer containing a Cu+(4)(RCO2)(4) cluster as connecting node.
abstract: The reaction of Cu(I)(CH(3)CN)(4)BF(4) with 4-pyridylacrylic acid (4-HPYA) affords an unprecedented 8-fold interpenetrating diamondoid-like coordination polymer network [Cu(I)(3)(4-PYA)(2)(H(2)O)(BF(4)) ] (1) with a Cu(+)(4)(CO(2))(4) cluster as connecting node. The interpenetration in metal coordination polymers is the highest degree ever found within diamondoid nets containing a cluster as connecting note. Its fluorescent property was also reported.
authors.affiliation: Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P. R. China.
authors.forename: Xi-Sen
authors.initials: XS
authors.lastname: Wang
authors.forename: Hong
authors.initials: H
authors.lastname: Zhao
authors.forename: Zhi-Rong
authors.initials: ZR
authors.lastname: Qu
authors.forename: Qiong
authors.initials: Q
authors.lastname: Ye
authors.forename: Jing
authors.initials: J
authors.lastname: Zhang
authors.forename: Ren-Gen
authors.initials: RG
authors.lastname: Xiong
authors.forename: Xiao-Zeng
authors.initials: XZ
authors.lastname: You
authors.forename: Hoong-Kun
authors.initials: HK
authors.lastname: Fun