Spectroscopic study on variations in illite surface properties after acid-base titration.
FT-IR, Raman microscopy, XRD, 29Si and 27Al MAS NMR, were used to investigate changes in surface properties of a natural illite sample after acid-base potentiometric titration. The characteristic XRD lines indicated the presence of surface Al-Si complexes, preferable to Al(OH)3 precipitates. In the microscopic Raman spectra, the vibration peaks of Si-O and Al-O bonds diminished as a result of treatment with acid, then increased after hydroxide back titration. The varied ratio of signal intensity between (IV)Al and (VI)Al species in 27Al MAS NMR spectra, together with the stable BET surface area after acidimetric titration, suggested that edge faces and basal planes in the layer structure of illite participated in dissolution of structural components. The combined spectroscopic evidence demonstrated that the reactions between illite surfaces and acid-leaching silicic acid and aluminum ions should be considered in the model description of surface acid-base properties of the aqueous illite.
Liu
Wen-xin
WX
SKLEAC, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China. wxliu@urban.pku.edu.cn
Coveney
R M
RM
Tang
Hong-xiao
HX
D000535:Aluminum / Q000737:chemistry; D055598:Chemical Phenomena; D002627:Chemistry, Physical; D006863:Hydrogen-Ion Concentration; D008422:Materials Testing; D008903:Minerals / Q000032:analysis / Q000737:chemistry*; D012824:Silicic Acid / Q000737:chemistry; D013057:Spectrum Analysis; D017186:Titrimetry
D008903:Minerals; C099089:illite; D012824:Silicic Acid; D000535:Aluminum