[Infrared spectroscopic investigation on complexes formed from cupric fluoborate and cupric butyrate with Bis (diphenylphosphino) alkane ligands].
The Bis (diphenylphosphino) alkane series ligands and its series of complexes formed from Cu(BF4)2 and Cu(C3H7COO)2 respectively were studied by infrared spectral analysis. This paper discusses the spectral classification and the change regularity of related spectra before and after the Cu(I) complexes were formed. The possible structure model of the formed complexes was discussed, based on the element analysis, powder X-ray diffraction analysis, and thermal gravity analysis.
Cao
Jian
J
Henan Institnte of Chemistry, Zhengzhou 450002, China.
Liu
Qing
Q
Zhang
Guo-bao
GB
Wang
Ying
Y
Zou
Wei-hua
WH
Yang
Rui-na
RN
Zhao
Gen-suo
GS
D001881:Borates / Q000737:chemistry*; D001896:Boron Compounds / Q000737:chemistry; D002087:Butyrates / Q000737:chemistry*; D002614:Chelating Agents / Q000737:chemistry; D055598:Chemical Phenomena; D002627:Chemistry, Physical; D003300:Copper / Q000737:chemistry*; D008956:Models, Chemical; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry; D009943:Organophosphorus Compounds / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D017550:Spectroscopy, Fourier Transform Infrared
D001881:Borates; D001896:Boron Compounds; D002087:Butyrates; D002614:Chelating Agents; D009942:Organometallic Compounds; D009943:Organophosphorus Compounds; D003300:Copper; C023604:phenylphosphonic acid; C098759:fluoroboric acid