Crystal structure of bis(2-(2-thiazolylazo)-4-methylphenol)cobalt(III)chloride.
The reaction between CoCl2 x 6H2O and 2-1-(2-thiazolylazo)-p-cresol (TAC) in acetone resulted in six coordinated cobalt(III) complex, [Co(TAC)2]Cl3. Two TAC ligands coordinate with cobalt ion forming four five membered chelate rings. The cobalt ion is octahedrally coordinated by a phenolic oxygen, azo nitrogen and nitrogen in thiazole rings. Three chloride ions are disordered.
D002614:Chelating Agents / Q000737:chemistry*; D018360:Crystallography, X-Ray; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*
D002614:Chelating Agents; D009942:Organometallic Compounds; C481303:bis(2-(2-thiazolylazo)-4-methylphenol)cobalt(III)chloride