Efficient oxidative decarboxylation of carboxylic acids with sodium periodate catalyzed by supported manganese (III) porphyrin.
Oxidative decarboxylation of carboxylic acids by a supported manganese (III) porphyrin was investigated. In the chemical system using 5,10,15,20-tetrakis(4-aminophenyl)porphyrinatomanganese (III) chloride supported on crosslinked chloromethylated polystyrene, [Mn(H(2)NTPP)-CMP], as catalyst, carboxylic acids are converted to the corresponding carbonyl compounds via oxidative decarboxylation with sodium periodate.
D002264:Carboxylic Acids / Q000737:chemistry*; D002384:Catalysis; D010084:Oxidation-Reduction; D010504:Periodic Acid / Q000737:chemistry*; D011166:Porphyrins / Q000737:chemistry*
D002264:Carboxylic Acids; D011166:Porphyrins; D010504:Periodic Acid; C009288:metaperiodate