Qualitative and quantitative solid-phase microextraction gas chromatographic-mass spectrometric determination of the low-molecular-mass compounds released from poly(vinyl chloride)/polycaprolactone-polycarbonate during ageing.
A solid-phase microextraction (SPME) method was developed to quantitatively determine the amount of 6-hydroxyhexanoic acid in aqueous solutions. The SPME method in combination with GC-MS was then applied to identify and quantify the low-molecular-mass compounds migrating from a new poly(vinyl chloride) (PVC) material, PVC/polycaprolactone-polycarbonate (PCL-PC) during ageing in water. It was shown that only a small amount of 6-hydroxyhexanoic acid, the final hydrolysis product of PCL-PC, migrated from the blend during ageing at 37 and 70 degrees C. If, however, the temperature was raised to 100 degrees C rapid hydrolysis of PCL-PC resulted. In addition to 6-hydroxyhexanoic acid, 6-hydroxyhexanoic acid dimer, caprolactone, different carboxylic acids, acetophenone and phenol were identified. SPME-GC-MS was also applied to monitor the low-molecular-mass compounds migrating from the PVC/PCL-PC blend during thermo-oxidation.
D002138:Calibration; D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods*; D008970:Molecular Weight; D011076:Polycarboxylate Cement / Q000737:chemistry*; D011091:Polyesters / Q000737:chemistry*; D011143:Polyvinyl Chloride / Q000737:chemistry*; D012680:Sensitivity and Specificity
D011076:Polycarboxylate Cement; D011091:Polyesters; C016240:polycaprolactone; C005506:polycarbonate; D011143:Polyvinyl Chloride