Removal of hexavalent chromium with a lignocellulosic substrate extracted from wheat bran.
In this paper, a new recovery system of the toxic hexavalent chromium Cr(VI) is proposed that uses a lignocellulosic substrate derived from the industrial treatment process of wheat bran. We studied the adsorption mechanism of Cr(VI) onto the lignocellulosic substrate and showed that the adsorption reaction consumes a large amount of protons goes along the reduction of Cr(VI) into Cr(III). The oxidation of lignin moieties takes place concurrently to the chromium reduction and leads to the formation of hydroxyl and carboxyl functions. The latter contribute to an increase in the number of ion-exchange sites for the reduced chromium. The maximum adsorption capacity for hexavalent chromium was found at about 35 mg g(-1) in an acidic medium. This is comparable to other natural substrates and ordinary adsorbents.
Dupont
L
L
GRECI (Groupe de Recherche En Chimie Inorganique), Université de Reims Champagne-Ardenne, BP 1039, F-51687 Reims 2, France. laurent.dupont@univ-reims.fr
Guillon
E
E
D000327:Adsorption; D001673:Biodegradation, Environmental; D002274:Carcinogens, Environmental / Q000737:chemistry / Q000302:isolation & purification*; D002482:Cellulose / Q000737:chemistry*; D002857:Chromium / Q000737:chemistry / Q000302:isolation & purification*; D004043:Dietary Fiber; D007220:Industrial Waste; D007474:Ion Exchange; D008031:Lignin / Q000737:chemistry*; D010084:Oxidation-Reduction
D002274:Carcinogens, Environmental; D004043:Dietary Fiber; D007220:Industrial Waste; D002857:Chromium; C036909:lignocellulose; C074702:chromium hexavalent ion; D002482:Cellulose; D008031:Lignin