Tris(3,5-dimethyl-1H-pyrazole-1-thiocarboxamidato-kappa(2)N(2),N)cobalt(III).
In the crystal structure of the title complex, [Co(C(6)H(8)N(3)S)(3)], the Co(III) atom is octahedrally coordinated by three monodeprotonated bidentate 3,5-dimethyl-1H-pyrazole-1-thiocarboxamide ligands with two thiocarboxamide N atoms in axial positions. The asymmetric unit contains two molecules (A and B) and these molecules are arranged in chains in an alternating fashion connected by N-H...S interactions.
Jaćimović
Zeljko K
ZK
Faculty of Metallurgy and Technology, University of Montenegro, 81000 Podgorica, Serbia and Montenegro.
Tomić
Zoran D
ZD
Giester
Gerald
G
Leovac
Vukadin M
VM