title: Swelling-induced modulation of static and dynamic fluctuations in polyacrylamide gels observed by scanning microscopic light scattering.
abstract: The nature of inhomogeneities in vinylpolymer gels has hardly been clarified yet. Inhomogeneities on submicron and nanometer scales in polyacrylamide gels have been investigated by using a scanning microscopic light-scattering system and applying a general formula for an ensemble-averaged correlation function. The network structure of the gels is modified by varying the preparation conditions and can be roughly divided into two types. Swelling-induced modulation of inhomogeneities depends on the type of the network structure. At low monomer concentrations in preparation, both submicron- and nanometer-scale inhomogeneities increase with swelling. At high monomer concentrations in preparation, submicron-scale inhomogeneities increase with swelling, but nanometer-scale inhomogeneities decrease anomalously. This behavior is explained by a model of inhomogeneous network structure of vinylpolymer gels, where macrogel is formed from a large number of microgel particles.
authors.affiliation: Department of Organic and Polymer Materials Chemistry, Tokyo University of Agriculture and Technology, 2-24-16 Naka-cho, Koganei-shi, Tokyo 184-8588, Japan. hfurukaw@cc.tuat.ac.jp
authors.forename: Hidemitsu
authors.initials: H
authors.lastname: Furukawa
authors.forename: Kazuyuki
authors.initials: K
authors.lastname: Horie
authors.forename: Ryunosuke
authors.initials: R
authors.lastname: Nozaki
authors.forename: Mamoru
authors.initials: M
authors.lastname: Okada