title: Evaluation of photoinduced changes in stability constants for metal-ion complexes of crowned spirobenzopyran derivatives by electrospray ionization mass spectrometry.
abstract: The photoinduced changes of metal-ion complexing ability of crowned spirobenzopyran derivatives were studied by using electrospray ionization mass spectrometry (ESI-MS). Stability constants for the complexation with various metal ions in methanol under visible-irradiation conditions were determined for the first time by ESI-MS. It was found that the stability constants of crowned bis(spirobenzopyran) derivatives with metal ions are decreased dramatically by visible irradiation due to the disappearance of powerful ionic interaction between phenolate anion(s) of the merocyanine form of their spirobenzopyran moiety and a metal ion bound to their crown ether moiety, and the decrease in the stability constants is more pronounced for the multivalent metal-ion complexes. A theoretical consideration was also made to attain reliable values of stability complexes for metal-ion complexes of crown compounds.
authors.affiliation: Department of Applied Chemistry, Faculty of Systems Engineering, Wakayama University, Sakae-dani 930, Wakayama 640-8510, Japan.
authors.forename: Makoto
authors.initials: M
authors.lastname: Nakamura
authors.forename: Kenta
authors.initials: K
authors.lastname: Takahashi
authors.forename: Takeshi
authors.initials: T
authors.lastname: Fujioka
authors.forename: Shinpei
authors.initials: S
authors.lastname: Kado
authors.forename: Hidefumi
authors.initials: H
authors.lastname: Sakamoto
authors.forename: Keiichi
authors.initials: K
authors.lastname: Kimura