title: Conformational and electronic engineering of twisted diphenylacetylenes.
abstract: [structure: see text] Three tethered diphenylacetylene derivatives were prepared by alkyne metathesis. In these cycles, the twist angle between the two benzene rings is variable and determined by the nature of the linker. The engineering of the twist angle leads to a change of the UV-vis spectra of the cycles. The larger the twist angle in the macrocycles, the more blue shifted their lambda(max) (UV-vis), the lower their fluorescence quantum yield, and the lower field shifted their (13)C NMR signals of the alkyne carbons are.
authors.affiliation: School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia 30332-0400, USA.
authors.forename: Glen
authors.initials: G
authors.lastname: Brizius
authors.forename: Kelvin
authors.initials: K
authors.lastname: Billingsley
authors.forename: Mark D
authors.initials: MD
authors.lastname: Smith
authors.forename: Uwe H F
authors.initials: UH
authors.lastname: Bunz