title: 1,5-asymmetric induction of chirality using pi-allyltricarbonyliron lactone complexes: highly diastereoselective synthesis of alpha-functionalised carbonyl compounds.
abstract: Silyl enol ethers derived from ketone functionalised rho-allyltricarbonyliron lactone complexes undergo highly diastereoselective carbon-fluorine and carbon-oxygen bond formation reactions with excellent control at the alpha-stereogenic centre.
authors.affiliation: Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK CB2 1EW.
authors.forename: Christopher J
authors.initials: CJ
authors.lastname: Hollowood
authors.forename: Steven V
authors.initials: SV
authors.lastname: Ley
authors.forename: Edward A
authors.initials: EA
authors.lastname: Wright
mesh_terms: D002244:Carbon / Q000737:chemistry; D004987:Ethers / Q000737:chemistry; D005461:Fluorine / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D007783:Lactones / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008956:Models, Chemical; D008958:Models, Molecular; D010100:Oxygen / Q000737:chemistry
chemical_list: D004987:Ethers; D007783:Lactones; D005461:Fluorine; D002244:Carbon; D007501:Iron; D010100:Oxygen