Ethylene-promoted intermolecular enyne metathesis.
[reaction: see text] Intermolecular enyne metathesis between functional group-rich alkynes and vinyl ethers was promoted by ethylene cometathesis. The concentration of ethylene was optimized to suppress the competing formation of butadiene through background ethylene metathesis. The role of ethylene appears to be both protective and rate enhancing.
Giessert
Anthony J
AJ
Department of Chemistry, University at Buffalo, the State University of New York, Amherst, New York 14260, USA.
Brazis
Nicholas J
NJ
Diver
Steven T
ST
D000466:Alkadienes / Q000138:chemical synthesis*; D000480:Alkynes / Q000737:chemistry*; D002384:Catalysis; D004987:Ethers / Q000737:chemistry; D005030:Ethylenes / Q000737:chemistry*; D008956:Models, Chemical; D015394:Molecular Structure; D017975:Ruthenium Compounds / Q000737:chemistry; D014753:Vinyl Compounds / Q000737:chemistry
D000466:Alkadienes; D000480:Alkynes; D004987:Ethers; D005030:Ethylenes; D017975:Ruthenium Compounds; D014753:Vinyl Compounds