Ferromagnetic behavior of formyl-group-carrying stable thioaminyl radicals.
Four formyl-group-carrying thioaminyl radicals were generated, and one radical could be isolated as radical crystals. Magnetic susceptibility measurements of the isolated radical showed a ferromagnetic regular linear-chain interaction of 2J/k(B) = 3.2 K, which was explained in terms of the X-ray crystallographic results.
Miura
Yozo
Y
Department of Applied Chemistry, Graduate School of Engineering, Osaka City University, Sumiyoshi-ku, Osaka 558-8585, Japan. miura@a-chem.eng.osaka-cu.ac.jp
Nakamura
Shogo
S
Teki
Yoshio
Y