title: Enantiospecific formal total syntheses of (-)-salicylihalamides A and B from D-glucose and L-rhamnose.
abstract: [reaction: see text] Two formal chiral pool syntheses of the (-)-salicylihalamides A and B were achieved from commercially available 1,2,5,6-diacetone-d-glucose and l-rhamnose.
authors.affiliation: Department of Medicinal Chemistry, Center for Cancer Experimental Therapeutics and Drug Discovery Program, Higuchi Biosciences Center, University of Kansas, 1251 Wescoe Hall Drive, Lawrence, Kansas 66045-7582, USA.
authors.forename: KyoungLang
authors.initials: K
authors.lastname: Yang
authors.forename: Torsten
authors.initials: T
authors.lastname: Haack
authors.forename: Burchelle
authors.initials: B
authors.lastname: Blackman
authors.forename: Wibke E
authors.initials: WE
authors.lastname: Diederich
authors.forename: Subho
authors.initials: S
authors.lastname: Roy
authors.forename: Srinivas
authors.initials: S
authors.lastname: Pusuluri
authors.forename: Gunda I
authors.initials: GI
authors.lastname: Georg
mesh_terms: D019086:Bridged Bicyclo Compounds, Heterocyclic / Q000138:chemical synthesis*; D005947:Glucose / Q000031:analogs & derivatives / Q000737:chemistry*; D015394:Molecular Structure; D012210:Rhamnose / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D019086:Bridged Bicyclo Compounds, Heterocyclic; C410986:salicylihalamide A; D005947:Glucose; D012210:Rhamnose