1,5-asymmetric induction of chirality using pi-allyltricarbonyliron lactone complexes: highly diastereoselective synthesis of alpha-functionalised carbonyl compounds.
Silyl enol ethers derived from ketone functionalised rho-allyltricarbonyliron lactone complexes undergo highly diastereoselective carbon-fluorine and carbon-oxygen bond formation reactions with excellent control at the alpha-stereogenic centre.
Hollowood
Christopher J
CJ
Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK CB2 1EW.
Ley
Steven V
SV
Wright
Edward A
EA
D002244:Carbon / Q000737:chemistry; D004987:Ethers / Q000737:chemistry; D005461:Fluorine / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D007783:Lactones / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008956:Models, Chemical; D008958:Models, Molecular; D010100:Oxygen / Q000737:chemistry
D004987:Ethers; D007783:Lactones; D005461:Fluorine; D002244:Carbon; D007501:Iron; D010100:Oxygen