Crossover effects in the wetting of adsorbed films in linear wedges.
We have measured the growth of liquid Ar adsorbed on arrays of linear wedges structured in different ways. In the most regular patterns, a clear crossover from a planarlike to a geometry-dependent growth behavior is observed. This crossover is found to depend on the characteristic wedge size and its position, in the case of a regular pattern, agrees well with theoretical predictions. Near liquid-vapor bulk coexistence, the film mass is observed to diverge as a power law of the chemical potential difference from saturation with an exponent in very good agreement with the value of -2 expected for a linear wedge. This exponent is not affected by the opening angles of the wedges. The form of the next-to-leading order singular term in the asymptotic divergence of the mass has also been investigated. The experimentally determined value of the exponent is consistent with the expected theoretical result of -4/3.
Bruschi
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Istituto Nazionale per la Fisica della Materia and Dipartimento di Fisica G. Galilei, Università di Padova, via Marzolo 8, 35131 Padova, Italy.
Carlin
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Parry
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Mistura
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