Tris[diphenyl(2-pyridyl)phosphine]-micro(3)-iodo-tri-micro(3)-sulfido-sulfidotrisilvertungsten dichloromethane hemisolvate.
The title compound, [Ag(3)WIS(4)(C(17)H(14)NP)(3)].0.5CH(2)Cl(2), is a cubane-type heterometallic cluster containing diphenyl(2-pyridyl)phosphine (Ph(2)PPy). The pyridyl group of Ph(2)PPy remains uncoordinated, so the Ph(2)PPy ligand is monodentate and coordinates to one Ag atom. The W atom and three Ag atoms form a distorted tetrahedral geometry, capped by one I atom and three S atoms.
Wang
Yan
Y
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, People's Republic of China.
Li
Yi-Zhi
YZ
Jin
Qiong-Hua
QH
Zheng
He-Gen
HG
Hu
Zheng
Z
Xin
Xin-Quan
XQ