Polymerization of cardanol using soybean peroxidase and its potential application as anti-biofilm coating material.
Soybean peroxidase (20 mg) catalyzed the oxidative polymerization of cardanol in 2-propanol/phospate buffer solution (25 ml, 1:1 v/v) and yielded 62% polycardanol over 6 h. Cobalt naphthenate (0.5% w/w) catalyzed the crosslinking of polycardanol and the final hardness of crosslinked polycardanol film exceeded 9 H scale as pencil scratch hardness, which shows a high potential as a commercial coating material. In addition, it showed an excellent anti-biofouling activity to Pseudomonas fluorescens compared to other polymeric materials such as polypropylene.
Kim
Yong Hwan
YH
Korea Research Institute of Chemical Technology, P.O. Box 107, Yusong, Taejon 305-600, Korea. metalkim@krict.re.kr
An
Eun Suk
ES
Song
Bong Keun
BK
Kim
Dong Shik
DS
Chelikani
Rahul
R
D001422:Bacterial Adhesion / Q000502:physiology; D018441:Biofilms / Q000254:growth & development*; D020099:Coated Materials, Biocompatible / Q000138:chemical synthesis* / Q000737:chemistry; D004789:Enzyme Activation; D005240:Feasibility Studies; D008422:Materials Testing; D010084:Oxidation-Reduction; D009195:Peroxidase / Q000737:chemistry*; D010636:Phenols / Q000138:chemical synthesis / Q000737:chemistry*; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry; D011551:Pseudomonas fluorescens / Q000502:physiology* / Q000648:ultrastructure*; D013025:Glycine max / Q000737:chemistry* / Q000201:enzymology; D013499:Surface Properties
D020099:Coated Materials, Biocompatible; D010636:Phenols; D011108:Polymers; C038590:cardanol; D009195:Peroxidase