Copper hydroperoxo species activated by hydrogen-bonding interaction with its distal oxygen.
A novel copper(II)[bond]OOH complex with functional ligand that can form a hydrogen bond with the distal oxygen of hydroperoxide has been designed and prepared as a structural/functional model of dopamine beta-hydroxylases, whose spectroscopic characterization and decomposition rates have indicated that the hydroperoxide is activated through the hydrogen-bonding interaction with the distal oxygen.
Yamaguchi
Syuhei
S
Department of Applied Chemistry, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan.
Nagatomo
Shigenori
S
Kitagawa
Teizo
T
Funahashi
Yasuhiro
Y
Ozawa
Tomohiro
T
Jitsukawa
Koichiro
K
Masuda
Hideki
H
D003300:Copper / Q000737:chemistry*; D004578:Electron Spin Resonance Spectroscopy; D006860:Hydrogen Bonding; D006861:Hydrogen Peroxide / Q000737:chemistry*; D008958:Models, Molecular; D010100:Oxygen / Q000737:chemistry*
D003300:Copper; D006861:Hydrogen Peroxide; D010100:Oxygen