Adhesion of in situ precipitated calcium carbonate in the presence and absence of magnetic field in quiescent conditions on different solid surfaces.
Deposition of in situ precipitated calcium carbonate from Na(2)CO(3) and CaCl2 solutions on different substrates, i.e. stainless steel, copper, aluminium, and glass, was investigated at different temperatures, 20 degrees C, 40 degrees C, 60 degrees C and 80 degrees C, both in the absence and presence of S-S 0.1T magnetic field (MF). It was found that in quiescent conditions during 2h the amounts deposited firmly on the surfaces decreased with increasing temperature. If MF was present the deposition was reduced at all temperatures, and depended on the nature of the substrate. The largest MF effect was found on glass at 60 degrees C, which amounted 50% reduction of the deposit. However, at 80 degrees C no deposition was found in the presence of MF on aluminium surface. At this temperature the reproducibility of the experiments was poor, and an additional effect due to the metal surface corrosion (especially that of aluminium and copper) may be thought in alkaline environment of the experiments (pH ca. 10). Based on optical microscope photographs, it was concluded that the amounts of crystallographic forms of CaCO3 depended on the nature of substrate on which the precipitation and then the adhesion took place. To some extent the ratios of CaCO3 forms precipitated were different in the bulk phase than on the substrate surfaces at the same temperature, and this conclusion was based on the X-ray diffractograms. Some possible mechanisms causing MF effects are discussed.
Department of Physical Chemistry-Interfacial Phenomena, Faculty of Chemistry, Maria Curie-Sklodowska University, Lublin 20-031, Poland. emil@hermes.umcs.lublin.pl
Emil
E
Chibowski
Lucyna
L
Hołysz
Aleksandra
A
Szcześ
D000535:Aluminum / Q000737:chemistry; D002119:Calcium Carbonate / Q000737:chemistry*; D002122:Calcium Chloride / Q000737:chemistry; D002254:Carbonates / Q000737:chemistry; D011232:Chemical Precipitation; D003300:Copper / Q000737:chemistry; D005898:Glass / Q000737:chemistry; D008280:Magnetics; D013232:Steel / Q000737:chemistry; D013696:Temperature; D014867:Water / Q000737:chemistry
D002254:Carbonates; D014867:Water; D013232:Steel; C005686:sodium carbonate; D003300:Copper; D000535:Aluminum; D002119:Calcium Carbonate; D002122:Calcium Chloride