Oxidative addition of phenylacetylene through C-H bond cleavage to form the MgII-dpp-bian complex: molecular structure of [Mg[dpp-bian(H)](C[triplebond]CPh)(thf)2] and its diphenylketone insertion product [Mg(dpp-bian)*-[OC(Ph2)C[triplebond]CPh](thf)].
G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Tropinina 49, 603950 Nizhny Novgorod GSP-445, Russia. igorfed@imoc.sinn.ru
Igor L
IL
Fedushkin
Natalie M
NM
Khvoinova
Alexandra A
AA
Skatova
Georgy K
GK
Fukin