Photocatalytic degradation of polystyrene plastic under fluorescent light.
Plastic is used widely all over the world, due to the fact that it is low cost, is easily processable, and has lightweight properties. However, the hazard of discarding waste plastic, so-called "white pollution", is becoming more and more severe. In this paper, solid-phase photocatalytic degradation of polystyrene (PS) plastic, one of the most common commercial plastics, over copper phthalocyanine (CuPc) sensitized TiO2 photocatalyst (TiO2/CuPc) has been investigated under fluorescent light irradiation in the air. UV-vis spectra show that TiO2/CuPc extends its photoresponse range to visible light, contrasting to only UV light absorption of pure TiO2. The PS photodegradation experiments exhibit that higher PS weight loss rate, lower PS average molecular weight, less amount of volatile organic compounds, and more CO2 can be obtained in the system of PS-(TiO2/CuPc), in comparison with the PS-TiO2 system. Therefore, PS photodegradation over TiO2 CuPc composite is more complete and efficient than over pure TiO2, suggesting the potential application of dye-sensitized TiO2 catalyst in the thorough photodegradation of PS plastic under fluorescent light. During the photodegradation of PS plastic, the reactive oxygen species generated on TiO2 or TiO2/CuPc particle surfaces play important roles in chain scission. The present study demonstrates that the combination of polymer plastic with dye-sensitized TiO2 catalyst in the form of thin film is a practical and useful way to photodegrade plastic contaminants in the sunlight.
Shang
Jing
J
Department of Chemistry and State Key Laboratory of C1 Chemical Technology, Tsinghua University, Beijing, 100084, PR China.
Chai
Ming
M
Zhu
Yongfa
Y
D002384:Catalysis; D004396:Coloring Agents / Q000737:chemistry; D004787:Environmental Pollution / Q000517:prevention & control*; D007211:Indoles / Q000737:chemistry; D008027:Light; D009942:Organometallic Compounds / Q000737:chemistry; D010777:Photochemistry; D011137:Polystyrenes / Q000737:chemistry*; D014025:Titanium / Q000737:chemistry
D004396:Coloring Agents; D007211:Indoles; D009942:Organometallic Compounds; D011137:Polystyrenes; C009495:titanium dioxide; C015445:copper phthalocyanine; D014025:Titanium