3D porous and 3D interpenetrating triple framework structures constructed by aurophilicity-coordination interplay in [Mn[Au(CN)2]2(H2O)2]n and [KFe[Au(CN)2]3]n.
Two cyano-bridged heterobimetallic coordination polymers [Mn[Au(CN)2]2(H2O)2]n (1) and [KFe[Au(CN)2]3]n (2), have been synthesized from [Au(CN)2]- building blocks and structurally characterized. In both complexes aurophilicity play an important role in determining the 3D open microporous framework and the interpenetrating triple framework for 1 and 2, respectively. Both aqueous solutions of 1 and 2 display interesting luminescent properties.
Dong
Wen
W
Department of Chemistry, Nankai University, Tianjin 300071, PR China.
Zhu
Li-Na
LN
Sun
Ya-Qiu
YQ
Liang
Mao
M
Liu
Zhan-Quan
ZQ
Liao
Dai-Zheng
DZ
Jiang
Zong-Hui
ZH
Yan
Shi-Ping
SP
Cheng
Peng
P