Analysis by laser-induced breakdown spectroscopy of complex solids, liquids, and powders with an echelle spectrometer.
One of the most promising approaches to laser-induced breakdown spectroscopy (LIBS) experiments involves the use of an echelle spectrometer coupled with an intensified CCD. Even if drawbacks remain with its use, the echelle spectrometer facilitates a multielemental analysis that is more rapid than can be obtained with the more-conventional Czerny-Turner spectrometer and, moreover, does not sacrifice reliability. Quantitative results obtained with such apparatus for solids, liquids, powders, and gases are described and when possible compared with results from Czerny-Turner spectrometers. Liquid analysis by LIBS with echelle spectrometers has allowed a spectral database to be compiled. Once the qualitative spectra of pure elements in aqueous solutions, are obtained, they can be used for qualitative analysis of unknown samples.
Fichet
Pascal
P
Commissariat à l'Energie Atomique Saclay, Fuel Cycle Division, Laboratoire d'Analyse par Laser et d'Etude de Surface, Bâtiment 391, 91191 Gif Sur Yvette, France. fichet@carnac.cea.fr
Menut
Denis
D
Brennetot
René
R
Vors
Evelyne
E
Rivoallan
Annie
A