Effect of post-deposition heating temperature and the presence of water vapor during heat treatment on crystallinity of calcium phosphate coatings.
In this study, radiofrequency sputtered calcium phosphate (CaP) coatings were evaluated after 1h post-deposition heat treatment at either 350 degrees C, 400 degrees C, 450 degrees C, 500 degrees C or 600 degrees C in the presence or absence of water vapor. X-ray diffraction analyses indicated the as-sputtered coatings to be amorphous. With different post-deposition heat treatments used, in this study, crystallinity of CaP coatings was observed to be in the range of 0-68%. The 400 degrees C and 450 degrees C heat-treated CaP coatings in the absence of water vapor were poorly crystalline, exhibiting a crystallinity of 2+/-1%. In comparison to heat treatments at 450 degrees C in the absence of water vapor, the presence of water vapor at 450 degrees C heat treatment resulted in a significant increase in coating crystallinity. However, this effect was not observed at higher temperatures. A coating crystallinity of 60-68% was observed for coatings heat treated at 450 degrees C in the presence of water vapor, and at 500 degrees C and 600 degrees C in the presence or absence of water vapor. In addition, increases in the degree of coating crystallinity were observed to be consistent with the increasing number of PO(4) peaks observed as a result of different post-deposition heat treatments. It was concluded that the presence of water vapor at 450 degrees C post-deposition heat treatment significantly affect the crystallinity of CaP coatings, whereas an increase to temperature higher than 450 degrees C and in the presence of water vapor has no significant effect on crystallinity.
Health Science Center at San Antonio, Department of Restorative Dentistry, The University of Texas, MSC 7890, 7703 Floyd Curl Drive, San Antonio, TX 78229-3900, USA.
Yunzhi
Y
Yang
Kyo-Han
KH
Kim
C
C
Mauli Agrawal
Joo L
JL
Ong
D002130:Calcium Phosphates / Q000737:chemistry* / Q000528:radiation effects*; D020099:Coated Materials, Biocompatible / Q000737:chemistry* / Q000528:radiation effects*; D003460:Crystallization / Q000379:methods*; D005740:Gases / Q000737:chemistry; D006358:Hot Temperature; D008422:Materials Testing / Q000379:methods*; D008855:Microscopy, Electron, Scanning; D008968:Molecular Conformation; D017550:Spectroscopy, Fourier Transform Infrared; D014867:Water / Q000737:chemistry*; D014961:X-Ray Diffraction
D002130:Calcium Phosphates; D020099:Coated Materials, Biocompatible; D005740:Gases; D014867:Water; C020243:calcium phosphate