Synthesis and inclusion properties of a novel macrocyclic hexaketone monohydrate with a hemiacetal structure.
A macrocyclic hexaketone monohydrate was synthesized by the oxidation of either tribenzohexadehydro[12]annulene or tribenzotetradehydro[12]annulene-1,2-dione with ruthenium catalysts; the hexaketone monohydrate incorporates small molecules with a hydroxy, carbonyl or ether group in the crystalline lattice to form inclusion complexes.
Ohkoshi
Masanori
M
Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo, 192-0397, Japan.
Horino
Takeru
T
Yoshida
Masato
M
Iyoda
Masahiko
M