Removal of hexavalent chromium from wastewater using a new composite chitosan biosorbent.
A new composite chitosan biosorbent was prepared by coating chitosan, a glucosamine biopolymer, onto ceramic alumina. The composite bioadsorbent was characterized by high-temperature pyrolysis, porosimetry, scanning electron microscopy, and X-ray photoelectron spectroscopy. Batch isothermal equilibrium and continuous column adsorption experiments were conducted at 25 degrees C to evaluate the biosorbent for the removal of hexavalent chromium from synthetic as well as field samples obtained from chrome plating facilities. The effect of pH, sulfate, and chloride ion on adsorption was also investigated. The biosorbent loaded with Cr(VI) was regenerated using 0.1 M sodium hydroxide solution. A comparison of the results of the present investigation with those reported in the literature showed that chitosan coated on alumina exhibits greater adsorption capacity for chromium(VI). Further, experimental equilibrium data were fitted to Langmuir and Freundlich adsorption isotherms, and values of the parameters of the isotherms are reported. The ultimate capacity obtained from the Langmuir model is 153.85 mg/g chitosan.
U.S. Army Construction Engineering Research Laboratories, Champaign, Illinois 61826-9005, USA. veera.boddu@erdc.usace.army.mil
Veera M
VM
Boddu
Krishnaiah
K
Abburi
Jonathan L
JL
Talbott
Edgar D
ED
Smith
D000327:Adsorption; D000537:Aluminum Oxide / Q000737:chemistry; D002274:Carcinogens, Environmental / Q000302:isolation & purification*; D002614:Chelating Agents / Q000737:chemistry*; D002686:Chitin / Q000031:analogs & derivatives* / Q000737:chemistry*; D048271:Chitosan; D002857:Chromium / Q000302:isolation & purification*; D008962:Models, Theoretical; D013696:Temperature; D018508:Water Purification / Q000379:methods*
D002274:Carcinogens, Environmental; D002614:Chelating Agents; D002857:Chromium; D002686:Chitin; C074702:chromium hexavalent ion; D048271:Chitosan; D000537:Aluminum Oxide