An EPR study of the intramolecular dynamics in o-semiquinonic nickel complexes with a diphosphorous pincer ligand.
Square pyramidal o-semiquinonic nickel complexes with 2,6-bis(diphenylphosphinomethyl)phenyl have a flexible coordination sphere and exist in solution as the mixture of tautomers rapidly, according to EPR time scale, interconverting at room temperature.
G. A. Razuvaev Institute of organometallic chemistry of Russian Academy of Sciences, 49, Tiropinina str. 603950 Nizhny Novgorod, Russian Federation.
Konstantin A
KA
Kozhanov
Michael P
MP
Bubnov
Vladimir K
VK
Cherkasov
Georgy K
GK
Fukin
Gleb A
GA
Abakumov