An EPR study of the intramolecular dynamics in o-semiquinonic nickel complexes with a diphosphorous pincer ligand.
Square pyramidal o-semiquinonic nickel complexes with 2,6-bis(diphenylphosphinomethyl)phenyl have a flexible coordination sphere and exist in solution as the mixture of tautomers rapidly, according to EPR time scale, interconverting at room temperature.
Kozhanov
Konstantin A
KA
G. A. Razuvaev Institute of organometallic chemistry of Russian Academy of Sciences, 49, Tiropinina str. 603950 Nizhny Novgorod, Russian Federation.
Bubnov
Michael P
MP
Cherkasov
Vladimir K
VK
Fukin
Georgy K
GK
Abakumov
Gleb A
GA