Solution complexation between potassium iodide and lariat ethers having pi-donor sidearms.
Experimental evidence is presented for the interaction of triple bond pi-donors with potassium cation in acetonitrile solution.
Department of Chemistry, Washington University School of Medicine, Campus Box 8103, 660 S. Euclid Ave., St. Louis, MO 63110, USA.
Jiaxin
J
Hu
George W
GW
Gokel
D000097:Acetonitriles / Q000737:chemistry; D000480:Alkynes / Q000737:chemistry*; D004988:Ethers, Cyclic / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D015394:Molecular Structure; D011193:Potassium Iodide / Q000737:chemistry*; D012996:Solutions / Q000737:chemistry
D000097:Acetonitriles; D000480:Alkynes; D004988:Ethers, Cyclic; D012996:Solutions; D011193:Potassium Iodide