title: Polymer-supported haloarene chromium dicarbonyl isonitrile complexes: a study of their synthesis and reactivity.
abstract: Different arene Cr(CO)(3) complexes were supported on a polystyrene isonitrile resin by photochemical-promoted replacement of a chromium carbonyl ligand by the NC group. The supported complexes proved to be stable and were successfully used for further transformations. In particular, the reactivity of dichlorobenzene complexes to different nucleophiles was investigated and found to be comparable with that of the parent Cr(CO)(3) complexes.
authors: Dipartimento di Chimica Organica e Industriale, Istituto di Scienze e Tecnologie Molecolari, Centro di Eccellenza CISI, University of Milan and CNR, Via C. Golgi 19, I-20133 Milan, Italy. clara.baldoli@istm.cnr.it
authors: Clara
authors: C
authors: Baldoli
authors: Stefano
authors: S
authors: Maiorana
authors: Emanuela
authors: E
authors: Licandro
authors: Laura
authors: L
authors: Casiraghi
authors: Giovanna
authors: G
authors: Zinzalla
authors: Pierfausto
authors: P
authors: Seneci
authors: Elisabetta
authors: E
authors: De Magistris
authors: Alfredo
authors: A
authors: Paio
authors: Carla
authors: C
authors: Marchioro
mesh_terms: D017608:Chromium Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry; D013678:Technology, Pharmaceutical / Q000379:methods*
chemical_list: D017608:Chromium Compounds; D011108:Polymers