title: Addition of electron-rich aromatics to azafullerenium carbocation. A stepwise electrophilic substitution mechanism.
abstract: [reaction: see text] The reaction between the C(59)N(+) carbocation and the electron-rich aromatic compounds toluene and anisole has been mechanistically studied. The measured intermolecular kinetic isotope effects are consistent with an electrophilic aromatic substitution mechanism in which the arenium cation is formed by electrophilic attack of C(59)N(+) on the aromatic ring in the first step of the reaction, followed by hydrogen abstraction in a rate-determining second step.
authors: Department of Chemistry, University of Crete, 71409 Iraklion, Greece.
authors: Georgios C
authors: GC
authors: Vougioukalakis
authors: Nikos
authors: N
authors: Chronakis
authors: Michael
authors: M
authors: Orfanopoulos