title: Novel chiral sulfur-containing ferrocenyl ligands for palladium-catalyzed asymmetric allylic substitution.
abstract: New chiral ferrocenyl ligands having chiral sulfinyl and phosphinyl groups were prepared. The palladium-catalyzed allylic substitution reaction using these chiral ligands showed good enantioselectivity. The mechanism for the asymmetric reaction is proposed on the basis of the stereochemical outcome.
authors: Department of Applied Chemistry, Nagoya Institute of Technology, Nagoya, Japan.
authors: Shuichi
authors: S
authors: Nakamura
authors: Takeo
authors: T
authors: Fukuzumi
authors: Takeshi
authors: T
authors: Toru