Polymer-supported haloarene chromium dicarbonyl isonitrile complexes: a study of their synthesis and reactivity.
Different arene Cr(CO)(3) complexes were supported on a polystyrene isonitrile resin by photochemical-promoted replacement of a chromium carbonyl ligand by the NC group. The supported complexes proved to be stable and were successfully used for further transformations. In particular, the reactivity of dichlorobenzene complexes to different nucleophiles was investigated and found to be comparable with that of the parent Cr(CO)(3) complexes.
Baldoli
Clara
C
Dipartimento di Chimica Organica e Industriale, Istituto di Scienze e Tecnologie Molecolari, Centro di Eccellenza CISI, University of Milan and CNR, Via C. Golgi 19, I-20133 Milan, Italy. clara.baldoli@istm.cnr.it
Maiorana
Stefano
S
Licandro
Emanuela
E
Casiraghi
Laura
L
Zinzalla
Giovanna
G
Seneci
Pierfausto
P
De Magistris
Elisabetta
E
Paio
Alfredo
A
Marchioro
Carla
C
D017608:Chromium Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry; D013678:Technology, Pharmaceutical / Q000379:methods*
D017608:Chromium Compounds; D011108:Polymers