title: Synthetic approaches to an isostructural series of redox-active, metal tris(bipyridine) core dendrimers.
abstract: Several types of six-armed, metal tris(bipyridine) core dendrimers were synthesized. Bis-4,4'-alkoxy bipyridine dendrons were prepared and employed to make tris(bipyridine) dendrimers. Although the ruthenium-centered and iron-centered dendrimers displayed quasi-reversible cyclic voltammetry, the analogous cobalt-centered complex did not. The synthesis of 4,4'-disubstituted bipyridines containing -CH(2)OR groups proceeded in low yield. The reactions of the dicarbanion of 4,4'-dimethyl bipyridine prepared with LDA and mesylate, triflate, and bromide groups were found to result in no or poor yields of carbon-carbon bond formation. Use of KDA in place of LDA resulted in much higher yields of dendritic bipyridines.
authors: Department of Chemistry, North Carolina State University, Box 8204, Raleigh, NC 27695-8204, USA.
authors: Young-Rae
authors: YR
authors: Hong
authors: Christopher B
authors: CB
authors: Gorman