Cs(6)Mo(27)S(31): a novel ternary reduced molybdenum sulfide containing Mo(9) and Mo(18) clusters.
The crystal structure of hexacaesium heptacosamolybdenum hentriacontasulfide, Cs(6)Mo(27)S(31), consists of a mixture of Mo(9)S(11)S(6) and Mo(18)S(20)S(6) cluster units in a 1:1 ratio. The units are connected through Mo-S bonds. Cs(+) cations occupy large voids between the different cluster units.
Picard
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Laboratoire de Chimie du Solide et Inorganique Moléculaire, URA CNRS No. 6511, Université de Rennes I, Avenue du Général Leclerc, 35042 Rennes CEDEX, France.
Salloum
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Gougeon
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Potel
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