A multiscale wavelet data treatment for reliable localization of inflection points for analytical purposes.
Instrumental analysis techniques that employ measurements based on inflection points may have their accuracy compromised due to the need for signal differentiation, which is very sensitive to instrumental noise. This paper presents a strategy for localizing inflection points that exploits the multiscale processing capability of the Wavelet Transform and avoids the need for explicit signal differentiation. The strategy is illustrated in simulated examples and also in a real analytical problem involving the determination of Pb and Cd by potentiometric stripping analysis. In this application, the results were in good agreement with the expected values and were slightly better than those obtained from the first derivative of the curves after smoothing by a Windowed Fourier Transform.
Martins
Valdomiro Lacerda
VL
Departamento de Química Fundamental, Universidade Federal de Pernambuco, CCEN, CEP 50740-901 - Recife PE, Brazil.
de Almeida
Luciano Farias
LF
de Castro
Suzana Limeira
SL
Galvão
Roberto Kawakami Harrop
RK
de Araújo
Mário César Ugulino
MC
da Silva
Edvan Cirino
EC