title: Synergy between spin crossover and metallophilicity in triple interpenetrated 3D nets with the NbO structure type.
abstract: Self-assembly of [Ag(CN)2]-, 3-cyanopyridine, and iron(II) gives triple interpenetration of three-dimensional spin crossover (SCO) networks with the NbO topology, which interact each other via argentophilic interactions. Superposition of the networks along the c-axis defines an infinite mosaic of trigonal and hexagonal cross-sectional tubes where water molecules are installed. The structural changes associated with the SCO tune the homoatomic interactions and induce an uncommon change of the lattice volume.
authors: Departament de Física Aplicada, Universitat Politècnica de València, Camino de Vera s/n, 46022 València, Spain.
authors: Ana
authors: A
authors: Galet
authors: Virginie
authors: V
authors: Niel
authors: M Carmen
authors: MC
authors: Muñoz
authors: José A
authors: JA
authors: Real