Secondary metabolites from the liverwort Tylimanthus renifolius.
Two new herbertane sesquiterpenoids, (-)-herbertene-1,12-diol and (-)-gamma-herbertenol, a new aromadendrane, 9-acetoxy-10-hydroxyaromadendrane, a new rosane diterpenoid, 5,15-rosadiene-3,11-dione and a new phytane, 2Z-phytene-1,15,20-triol, along with the known (-)-alpha-herbertenol have been isolated from the liverwort Tylimanthus renifolius. Several flavones and flavanones with an unsubstituted ring B were also identified. This is the first report of this class of flavonoids from the Hepaticae. All structures were elucidated by NMR spectroscopy.
Feld
Hildegard
H
FR 8.7, Pharmakognosie und Analytische Phytochemie der Universität des Saarlandes, D-66041, Saarbrücken, Germany.
Zapp
Josef
J
Becker
Hans
H
D004224:Diterpenes / Q000737:chemistry / Q000302:isolation & purification* / Q000378:metabolism; D044950:Flavanones / Q000737:chemistry / Q000302:isolation & purification / Q000378:metabolism; D005419:Flavonoids / Q000737:chemistry / Q000302:isolation & purification / Q000378:metabolism; D035926:Hepatophyta / Q000737:chemistry / Q000378:metabolism*; D015394:Molecular Structure; D019906:Nuclear Magnetic Resonance, Biomolecular; D012717:Sesquiterpenes / Q000737:chemistry / Q000302:isolation & purification* / Q000378:metabolism; D021241:Spectrometry, Mass, Electrospray Ionization
D004224:Diterpenes; D044950:Flavanones; D005419:Flavonoids; D012717:Sesquiterpenes; C008906:phytane