[Bis[(S)-2-(4-tert-butyl-4,5-dihydrooxazol-2-yl)phenyl]phenylphoshine-kappa(2)N,P](1,3-dimethyl-pi-allyl-kappa(3)C)palladium(II) hexafluorophosphate and (S)(P)-[bis[(S)-2-(4-tert-butyl-4,5-dihydrooxazol-2-yl)phenyl]phenylphosphine-kappa(2)N,P]dichloropalladium(II).
In the structures of the title compounds, [Pd(C(5)H(9))(C(32)H(37)N(2)O(2)P)]PF(6) and [PdCl(2)(C(32)H(37)N(2)O(2)P)], the bis(dihydrooxazolyl)phosphine ligand is N,P-bidentate, with S chirality on the P atom. In the allyl complex, the pi-allyl ligand ligates in a syn-syn-kappa(3)C manner.
Masui
Dai
D
Department of Applied Chemistry, Graduate Course of Engineering, Tokyo Metropolitan University, 1-1 Minami-Osawa, Tokyo 192-0397, Japan. masuidai@comp.metro-u.ac.jp
Ohnuki
Masatoshi
M
Yamaguchi
Motowo
M
Yamagishi
Takamichi
T