title: Trimeric perfluoro-ortho-phenylenemercury: a versatile Lewis acidic host.
abstract: Trimeric perfluoro-ortho-phenylenemercury (1) constitutes one of the simplest trifunctional Lewis acidic hosts. In addition to cooperative effects arising from the proximity of the mercury(II) centers, the electron-withdrawing properties of the backbone and the accessibility of the electrophilic sites lead to the facile complexation of neutral and electron rich substrates. The planarity of the structure as well as its overall polarizability compounded with relativistic effects at mercury also permits the occurrence of non-covalent interactions and accounts for the tendency of this compound to form cofacial dimers. Collectively, the Lewis acidic properties of 1 as well as its ability to engage in non-covalent interactions can be held responsible for its ability to form extended binary supramolecular stacks with arenes. The photoluminescence observed in some of these supramolecular complexes corresponds to the phosphorescence of the aromatic substrate and indicate the occurrence of a mercury heavy atom effect.
authors: Department of Chemistry, Texas A&M University, College Station, TX 77843-3255, USA.
authors: Mason R
authors: MR
authors: Haneline
authors: Robert E
authors: RE
authors: Taylor
authors: François P
authors: FP
authors: Gabbaï