Studies directed toward the construction of the polypropionate fragment of superstolide A.
[reaction: see text] Highly stereoselective approaches directed toward the synthesis of the C18-C27 fragment of superstolide A are disclosed taking ketone 6 and aldehyde 7 as the only sources of chirality.
Solsona
Joan G
JG
Departament de Química Orgànica, Universitat de Barcelona, Martí i Franqués 1-11, 08028 Barcelona, Catalonia, Spain.
Romea
Pedro
P
Urpí
Fèlix
F
D000081:Acetamides / Q000138:chemical synthesis / Q000737:chemistry; D000818:Animals; D000970:Antineoplastic Agents / Q000138:chemical synthesis / Q000737:chemistry*; D018942:Macrolides / Q000138:chemical synthesis / Q000737:chemistry*; D015394:Molecular Structure; D011161:Porifera; D013764:Tetrahydronaphthalenes / Q000138:chemical synthesis / Q000737:chemistry*
D000081:Acetamides; D000970:Antineoplastic Agents; D018942:Macrolides; D013764:Tetrahydronaphthalenes; C091984:superstolide A