Construction of a square-planar hydroperoxo-copper(II) complex inducing a higher catalytic reactivity.
A novel hydroperoxo-copper(II) complex with a square-planar geometry has been prepared, which has exhibited a higher selectivity and catalytic reactivity for dimethyl sulfide, in contrast to that with a trigonal-bipyramidal one.
Fujii
Tatsuya
T
Department of Applied Chemistry, Nagoya Institute of Technology, Showa-ku, Nagoya 466-8555, Japan.
Naito
Asako
A
Yamaguchi
Syuhei
S
Wada
Akira
A
Funahashi
Yasuhiro
Y
Jitsukawa
Koichiro
K
Nagatomo
Shigenori
S
Kitagawa
Teizo
T
Masuda
Hideki
H