title: Two-dimensional metamagnet composed of cyano-bridged CuII-WV bimetallic assembly.
abstract: Two-dimensional cyanide-bridged copper(II) octacyanotungstates(V), [(Cu(3-CNpy)2(H2O))2(Cu(3-CNpy)2(H2O)2)(W(CN)8)2] (3-CNpy = 3-cyanopyridine) (1) and [(Cu(4-CNpy)2)2(Cu(4-CNpy)2(H2O)2)(W(CN)8)2] x 6H2O (4-CNpy = 4-cyanopyridine) (2), were prepared and these compounds exhibited metamagnetic behavior with Néel temperatures of 8.0 K (1) and 4.4 K (2).
authors.affiliation: Research Center for Advanced Science and Technology, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8904, Japan.
authors.forename: Shin-ichi
authors.initials: S
authors.lastname: Ohkoshi
authors.forename: Yoichi
authors.initials: Y
authors.lastname: Arimoto
authors.forename: Toshiya
authors.initials: T
authors.lastname: Hozumi
authors.forename: Hidetake
authors.initials: H
authors.lastname: Seino
authors.forename: Yasushi
authors.initials: Y
authors.lastname: Mizobe
authors.forename: Kazuhito
authors.initials: K
authors.lastname: Hashimoto