Ethylene trimerization with a half-sandwich titanium complex bearing a pendant thienyl group.
A half-sandwich titanium complex with a pendant thienyl group, activated by methylalumoxane (MAO), can trimerize ethylene to 1-hexene with considerable activity and high selectivity; the coodination of the sulfur atom to the titanium center is proposed to be responsible for the selective trimerization of ethylene.
Huang
Jiling
J
The Laboratory of Organometallic Chemistry, East China University of Science and Technology, 130 Meilong Road, Shanghai, 200237, China. qianling@online.sh.cn
Wu
Tianzhi
T
Qian
Yanlong
Y