title: Feasibility of constructed wetlands for removing chlorothalonil and chlorpyrifos from aqueous mixtures.
abstract: Chlorpyrifos (an insecticide) and chlorothalonil (a fungicide) are transported in stormwater runoff and can be lethal to receiving aquatic system biota. This study determined removal rates of chlorpyrifos and chlorothalonil in simulated stormwater runoff treated in constructed wetland mesocosms. Using sentinel species, Ceriodaphnia dubia and Pimephales promelas, observed declines in toxicity of the simulated runoff after treatment were 98 and 100%, respectively. First order removal rates were 0.039/h for chlorpyrifos and 0.295/h for chlorothalonil in these experiments. Constructed wetland mesocosms were effective for decreasing concentrations of chlorpyrifos and chlorothalonil in simulated stormwater runoff, and decreasing P. promelas and C. dubia mortality resulting from these exposures. The results from this study indicate that constructed wetlands could be part of an efficient mitigation strategy for stormwater runoff containing these pesticides.
authors.affiliation: Earth Tech, 675 North Washington Street, Suite 300, Alexandria, VA 22314, USA.
authors.forename: R M
authors.initials: RM
authors.lastname: Sherrard
authors.forename: J S
authors.initials: JS
authors.lastname: Bearr
authors.forename: C L
authors.initials: CL
authors.lastname: Murray-Gulde
authors.forename: J H
authors.initials: JH
authors.lastname: Rodgers
authors.forename: Y T
authors.initials: YT
authors.lastname: Shah
mesh_terms: D000818:Animals; D004390:Chlorpyrifos / Q000633:toxicity; D003621:Daphnia; D003666:Decontamination / Q000379:methods; D004787:Environmental Pollution; D005659:Fungicides, Industrial / Q000633:toxicity; D007306:Insecticides / Q000633:toxicity; D009570:Nitriles / Q000633:toxicity; D010575:Pesticides / Q000633:toxicity*; D014872:Water Movements; D014874:Water Pollutants, Chemical / Q000633:toxicity*; D018508:Water Purification
chemical_list: D005659:Fungicides, Industrial; D007306:Insecticides; D009570:Nitriles; D010575:Pesticides; D014874:Water Pollutants, Chemical; C005806:tetrachloroisophthalonitrile; D004390:Chlorpyrifos