A versatile synthesis of new pyrimidinyl nitronyl nitroxides.
Pyrimidinyl nitronyl nitroxides where the bis-N-oxy fragment is included in a six-membered ring were prepared from diacetonamine by a sequence of reactions including a Grignard reaction, a Ritter reaction and oxidation of the intermediate pyrimidine; the properties of the 2-phenyl-substituted representative are fully described.
Brough
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Département de Recherche Fondamentale sur la Matiére Condensée, Service de Chimie Inorganique et Biologique, (UMR CNRS 5046), 17 Rue des Martyrs F38054, Grenoble Cedex 09, France.
Chiarelli
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R
Pécaut
J
J
Rassat
A
A
Rey
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