Two-dimensional metamagnet composed of cyano-bridged CuII-WV bimetallic assembly.
Two-dimensional cyanide-bridged copper(II) octacyanotungstates(V), [(Cu(3-CNpy)2(H2O))2(Cu(3-CNpy)2(H2O)2)(W(CN)8)2] (3-CNpy = 3-cyanopyridine) (1) and [(Cu(4-CNpy)2)2(Cu(4-CNpy)2(H2O)2)(W(CN)8)2] x 6H2O (4-CNpy = 4-cyanopyridine) (2), were prepared and these compounds exhibited metamagnetic behavior with Néel temperatures of 8.0 K (1) and 4.4 K (2).
Ohkoshi
Shin-ichi
S
Research Center for Advanced Science and Technology, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8904, Japan.
Arimoto
Yoichi
Y
Hozumi
Toshiya
T
Seino
Hidetake
H
Mizobe
Yasushi
Y
Hashimoto
Kazuhito
K