Structural characterisation of the first mononuclear bismuth porphyrin.
A single carboxylate picket bismuth porphyrin has been characterised in the solid state as the first instance of a non-dimeric structure; the carboxylate picket, bent over the macrocycle, is coordinated to the bismuth, inducing a significant distortion of the porphyrin core.
Boitrel
Bernard
B
Université de Rennes1, Institut de Chimie, UMR CNRS 6509, 35042 Rennes Cedex, France. Bernard.Boitrel@univ-rennes1.fr
Halime
Zakaria
Z
Michaudet
Lydie
L
Lachkar
Mohamed
M
Toupet
Loïc
L