title: Design of a new and highly effective chiral auxiliary for Diels-Alder reaction of 1-aminodiene.
abstract: A theoretical investigation of the facial selectivity of optically active oxazolidin-2-one-substituted dienes has been realized. This analysis enabled the development of (R)-4-phenyloxazolidin-2-thione as a very effective chiral auxiliary for cycloaddition of 1-aminodiene.
authors.affiliation: Unité de Chimie organique et médicinale, Université catholique de Louvain, Place L. Pasteur 1, B-1348 Louvain-la-Neuve, Belgium.
authors.forename: Raphaël
authors.initials: R
authors.lastname: Robiette
authors.forename: Karima
authors.initials: K
authors.lastname: Cheboub-Benchaba
authors.forename: Daniel
authors.initials: D
authors.lastname: Peeters
authors.forename: Jaqueline
authors.initials: J
authors.lastname: Marchand-Brynaert