title: Adsorption and desorption of atrazine, desethylatrazine, deisopropylatrazine, and hydroxyatrazine in vegetated filter strip and cultivated soil.
abstract: Adsorption and desorption of atrazine and its metabolites in vegetated filter strip soil (VFS) has not been evaluated, yet these data are needed to predict the transport of these compounds through the VFS. Adsorption and desorption parameters for atrazine, desethylatrazine (DEA), deisopropylatrazine (DIA), and hydroxyatrazine (HA) were compared between a cultivated Houston Black clay (CS) and an adjacent 12-year-old VFS established in a mixed stand of bermudagrass [Cynodon dactylon (L.) Pers.] and buffalograss [Buchloe dactyloides (Nutt. Engelm)]. Adsorption and desorption isotherms were determined by batch equilibrium. The evaluated chemical and physical properties of the VFS and CS were similar with the exception of a 1.7-fold increase in the organic carbon content of the VFS. Adsorption and desorption coefficients for atrazine were at least 59% higher in VFS than in CS. The adsorption coefficient for HA was 48% higher in VFS compared with CS, but desorption was not statistically different between soils. Adsorption and desorption coefficients for DEA and DIA were not statistically different between soils. The predicted order of mobility in CS is HA < atrazine = DIA = DEA. In VFS, the predicted order of mobility is HA < atrazine = DIA < DEA. These data indicate that the higher organic carbon in VFS will likely retard the transport of atrazine and HA to surface and ground waters; however, the transport rates of DEA and DIA will be similar between soils.
authors.affiliation: Department of Soil and Crop Sciences, Texas Agricultural Experiment Station, Texas A&M University, College Station, Texas 77843-2474. lkrutz@ag.tamu.edu
authors.forename: Larry Jason
authors.initials: LJ
authors.lastname: Krutz
authors.forename: Scott Allen
authors.initials: SA
authors.lastname: Senseman
authors.forename: Kevin Joseph
authors.initials: KJ
authors.lastname: McInnes
authors.forename: David Allen
authors.initials: DA
authors.lastname: Zuberer
authors.forename: Dennis Patrick
authors.initials: DP
authors.lastname: Tierney
mesh_terms: D000327:Adsorption; D000383:Agriculture; D001280:Atrazine / Q000737:chemistry*; D055598:Chemical Phenomena; D002627:Chemistry, Physical; D006540:Herbicides / Q000737:chemistry*; D006109:Poaceae / Q000254:growth & development; D012987:Soil / Q000032:analysis*; D014227:Triazines / Q000737:chemistry*
chemical_list: C445502:6-chloro-N-ethyl-1,3-5-triazine-2,4-diamine; D006540:Herbicides; D012987:Soil; D014227:Triazines; C405102:desethylatrazine; D001280:Atrazine