Sequential cross-metathesis/electrophilic fluorodesilylation: a novel entry to functionalized allylic fluorides.
Various allylic fluorides were prepared using a two-step process involving a cross-metathesis of allyltrimethylsilane with different olefinic partners followed by a fluorodesilylation of the corresponding functionalized allylsilanes with Selectfluor. [reaction: see text]
Thibaudeau
Sébastien
S
University of Oxford, The Dyson Perrins Laboratory, South Parks Road, OX1 3QY Oxford, U.K.
Gouverneur
Véronique
V