Metallo-phosphorylation of alkynes: reaction of alkynes with Cp2Zr(1-butene)(PR3) and chlorophosphate.
Reaction of alkynes with Cp2ZrBu2 and chlorophosphate in the presence PR3 to form zircono-alkenylphosphonates, which can be converted into various beta-functionalized alkenylphosphonates.
Lai
Chunbo
C
Key Laboratory for Bioorganic Phosphorus Chemistry of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China.
Xi
Chanjuan
C
Chen
Chao
C
Ma
Mingming
M
Hong
Xiaoyin
X