title: Toward an improved understanding of the unusual reactivity of Pd0/trialkylphosphane catalysts in cross-couplings of alkyl electrophiles: quantifying the factors that determine the rate of oxidative addition.
authors.affiliation: Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, USA.
authors.forename: Ivory D
authors.initials: ID
authors.lastname: Hills
authors.forename: Matthew R
authors.initials: MR
authors.lastname: Netherton
authors.forename: Gregory C
authors.initials: GC
authors.lastname: Fu
mesh_terms: D000478:Alkylation; D007700:Kinetics; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010165:Palladium / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*; D013237:Stereoisomerism; D013816:Thermodynamics
chemical_list: D010720:Phosphines; D010165:Palladium; C044646:phosphine