title: Synthesis of optically active atropisomeric anilide derivatives through diastereoselective N-allylation with a chiral Pd-pi-allyl catalyst.
abstract: N-Allylation of o-tert-butyl anilides derived from o-tert-butyl aniline and (S)-lactic acid or (S)-mandelic acid proceeded with high diastereoselectivity in the presence of a (BINAP)Pd-pi-allyl catalyst to give atropisomeric N-allyl o-tert-butyl anilide derivatives.
authors.affiliation: Tokyo University of Pharmacy and Life Science, 1432-1 Horinouchi, Hachioji, Tokyo 192-0392, Japan.
authors.forename: Osamu
authors.initials: O
authors.lastname: Kitagawa
authors.forename: Masashi
authors.initials: M
authors.lastname: Takahashi
authors.forename: Mitsuteru
authors.initials: M
authors.lastname: Kohriyama
authors.forename: Takeo
authors.initials: T
authors.lastname: Taguchi