Anion specific adsorption on Fe2O3 and AlOOH nanoparticles in aqueous solutions: comparison with hematite and gamma-Al2O3.
The specific adsorption of radiolabeled sulfate and phosphate ions from perchlorate supporting electrolyte onto nano-AlOOH and nano-Fe(2)O(3) powder has been investigated. The pH dependence of the adsorption of anions onto nanopowders was compared with that of the same ions onto gamma-Al(2)O(3) and hematite. It was demonstrated that the character of the pH dependence of the adsorption is very similar in the comparable cases. It was found, however, that in contrast to the behavior of gamma-Al(2)O(3), nano-AlOOH dissolves at a significant rate at low pH values (pH<2). Thus the study of the pH dependence of the anion adsorption encounters difficulties at these pH values. Disregarding this fact, it can be concluded that no special effects can be observed in the anion adsorption onto the nano-oxides studied.
Horányi
G
G
Research Laboratory of Materials and Environmental Chemistry, Chemical Research Center, Hungarian Academy of Sciences, 1525, PO Box 17, Budapest, Hungary. hor34@ludens.elte.hu
Kálmán
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E