Toward an improved understanding of the unusual reactivity of Pd0/trialkylphosphane catalysts in cross-couplings of alkyl electrophiles: quantifying the factors that determine the rate of oxidative addition.
Hills
Ivory D
ID
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, USA.
Netherton
Matthew R
MR
Fu
Gregory C
GC
D000478:Alkylation; D007700:Kinetics; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010165:Palladium / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*; D013237:Stereoisomerism; D013816:Thermodynamics
D010720:Phosphines; D010165:Palladium; C044646:phosphine