Highly enantioselective construction of a chiral tertiary carbon center by alkynylation of a cyclic N-acyl ketimine: an efficient preparation of HIV therapeutics.
Jiang
Biao
B
Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, P.R. China. jiangb@mail.sioc.ac.cn
Si
Yu-Gui
YG
D000480:Alkynes / Q000737:chemistry*; D019380:Anti-HIV Agents / Q000138:chemical synthesis* / Q000737:chemistry; D002244:Carbon / Q000737:chemistry*; D013237:Stereoisomerism
D000480:Alkynes; D019380:Anti-HIV Agents; D002244:Carbon