Regio- and stereoselective synthesis of novel (E)-1-alkenyl carbamate via carbocupration reaction.
The stereoselective carbocupration and copper-catalyzed carbomagnesiation reactions of alkynyl carbamates are described as a new and straightforward method for the preparation of (E)-alkenyl enol carbamates. [reaction: see text]
Chechik-Lankin
Helena
H
Department of Chemistry and Institute of Catalysis Science and Technology, Technion-Israel Institute of Technology, Technion City, Haifa 32000, Israel. chilanm@tx.technion.ac.il
Marek
Ilan
I