title: Lipid molarity affects liquid/liquid aroma partitioning and its dynamic release from oil/water emulsions.
abstract: Initial dynamic flavor release from oil/water emulsions containing different TAG phases was studied using a computerized apparatus and thermodesorption GC. A significant influence of lipid molarity on liquid/liquid partitioning and release of some flavor compounds was found. The release of the least hydrophobic compounds was not affected by any type of lipid. Hydrophobic compounds showed a positive correlation between their release and decreasing molarity of the lipid phase, that is, with increasing number of lipid molecules; only the most hydrophobic compounds did not show such a correlation. A strong linear correlation between low-melting TAG/water partition coefficients and lipid phase molarity was validated by volatile partition data of C6, C11, and C16 alkane/water systems. Lipid phase transition from the liquid to solid state did not affect flavor partitioning and release. Neither experimental nor theoretical octanol/water partition coefficients agreed with experimental TAG/water and alkane/water partition coefficients.
authors.affiliation: Institut für Lebensmittelchemie im Zentrum Angewandte Chemie der Universität Hannover, 30453 Hannover, Germany.
authors.forename: Swen
authors.initials: S
authors.lastname: Rabe
authors.forename: Ulrich
authors.initials: U
authors.lastname: Krings
authors.forename: Holger
authors.initials: H
authors.lastname: Zorn
authors.forename: Ralf G
authors.initials: RG
authors.lastname: Berger
mesh_terms: D004655:Emulsions / Q000493:pharmacokinetics*; D008055:Lipids / Q000493:pharmacokinetics; D009822:Oils, Volatile / Q000493:pharmacokinetics*; D014835:Volatilization; D014867:Water / Q000378:metabolism*
chemical_list: D004655:Emulsions; D008055:Lipids; D009822:Oils, Volatile; D014867:Water