The mechanical and NIR studies on ultrafine calcium carbonate treated by four surface modifiers.
Calcium carbonate was surface treated by acrylic acid monomer, its polymerization with varied mean molecular weight and PS/PAA copolymer. Coating efficiencies for these four series of surface-treated calcium carbonate were investigated. They differ from each other in many aspects. We hypothesize that the treating molecules bond to and align on the particle surface in different ways before and after monolayer coverage was reached. NIR spectra of surface-treated samples studied not only reflected the amount of bonded treating agents by means of the value of absorbance, but also gave rich structural information of surface layer. This gave us a powerful means to investigate the interface of particle surface.
Shui
Miao
M
Department of Chemistry, College of Science, Ningbo University, Ningbo 315211, China. shuim@21cn.com
Yue
Linhai
L
Xu
Zhude
Z
D000179:Acrylates / Q000737:chemistry*; D002119:Calcium Carbonate / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry; D006859:Hydrogen / Q000737:chemistry; D008956:Models, Chemical; D013055:Spectrophotometry, Infrared / Q000379:methods*
D000179:Acrylates; D002244:Carbon; D006859:Hydrogen; D002119:Calcium Carbonate; C036658:acrylic acid