Mass spectrometric studies of some novel sulfonamides.
A recent paper described the overall 5-endo cyclisation of homoallylic sulfonamides to give pyrrolidines. This reaction was also used to prepare polycyclic systems. Mass spectrometric analysis using classical electron ionisation spectra and accurate mass measurement played a vital role in confirming the proposed structures for the products. These materials were not amenable to newer mass spectrometric methods and this study shows the continuing importance of older techniques.
Haskins
Charlotte M
CM
Chemistry Department, Cardiff University, Cardiff CF10 3TB, UK.
Haskins
Neville J
NJ
Knight
David W
DW
D003461:Crystallography / Q000379:methods*; D013058:Mass Spectrometry / Q000379:methods*; D008968:Molecular Conformation; D008970:Molecular Weight; D015203:Reproducibility of Results; D012680:Sensitivity and Specificity; D021241:Spectrometry, Mass, Electrospray Ionization / Q000379:methods; D013449:Sulfonamides / Q000032:analysis* / Q000737:chemistry* / Q000145:classification
D013449:Sulfonamides