title: An adamantane-based coordination framework with the first observation of discrete metal sulfonate clusters.
abstract: By employing a rigid adamantane-based unit as a spacer, a coordination solid with an open channel layered structure results showing the first observation of metal sulfonate clusters. The design approach employed enforces a structural mismatch of metal and ligand coordinative preferences.
authors.affiliation: Department of Chemistry, University of Calgary, Calgary, Alberta, T2N 1N4 Canada.
authors.forename: Dennis J
authors.initials: DJ
authors.lastname: Hoffart
authors.forename: Adrien P
authors.initials: AP
authors.lastname: Côté
authors.forename: George K H
authors.initials: GK
authors.lastname: Shimizu