Controlled haptotropic rearrangements--towards a stereospecific molecular switch based on chiral arene chromium complexes.
A stereospecific molecular switch has been designed based on a reversible thermo- or photo-induced haptotropic shift of a Cr(CO)3 fragment along a naphthohydroquinone skeleton.
Jahr
Holger C
HC
Kekulé-Institut für Organische Chemie und Biochemie, Rheinische Friedrich-Wilhelms-Universität, Gerhard-Domagk-Strasse 1, 53121 Bonn, Germany.
Nieger
Martin
M
Dötz
Karl Heinz
KH