A route to the thapsigargins from (S)-carvone providing a substrate-controlled total synthesis of trilobolide, nortrilobolide, and thapsivillosin F.
Oliver
Steven F
SF
University Chemical Laboratory, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, UK.
Högenauer
Klemens
K
Simic
Oliver
O
Antonello
Alessandra
A
Smith
Martin D
MD
Ley
Steven V
SV
D052176:Azulenes; D002087:Butyrates / Q000138:chemical synthesis*; D000081005:Cyclohexane Monoterpenes; D005663:Furans / Q000138:chemical synthesis*; D039821:Monoterpenes; D012717:Sesquiterpenes / Q000138:chemical synthesis*; D045789:Sesquiterpenes, Guaiane; D013729:Terpenes / Q000737:chemistry*
D052176:Azulenes; D002087:Butyrates; D000081005:Cyclohexane Monoterpenes; D005663:Furans; D039821:Monoterpenes; D012717:Sesquiterpenes; D045789:Sesquiterpenes, Guaiane; D013729:Terpenes; C483991:thapsivillosin F; C070242:nortrilobolide; C086352:trilobolide; C006923:carvone