Determination of dysprosium by resonance light scattering technique in the presence of BPMPHD.
Dysprosium has been determined by resonance light scattering (RLS) method in the presence of 1,6-bi(1'-phenyl-3'-methyl-5'-pyrazolone-4'-)hexanedione (BPMPHD) at pH 5.5. The Dy-BPMPHD system has three characteristic peaks at 358, 399 and 450 nm, especially the peak at 358 nm, which is proportional to the concentration of Dy(3+) in the range of 1.0 x 10(-10)-1.0 x 10(-5) mol l(-1). The detection limit (S/N=2) is 5.6 x 10(-12) mol l(-1). Synthetic samples are determined satisfactorily. A new sensitive method for detection of dysprosium has been proposed.
Sun
Shuna
S
Key Lab for Colloid and Interface Chemistry of Education Ministry, Department of Chemistry, Shandong University, Jinan 250100, China.
Wu
Xia
X
Yang
Jinghe
J
Li
Lei
L
Wang
Yuebo
Y
D000818:Animals; D002417:Cattle; D004419:Dysprosium / Q000737:chemistry*; D007700:Kinetics; D008027:Light; D049449:Luminescence; D011189:Potassium Chloride / Q000737:chemistry; D011485:Protein Binding; D012542:Scattering, Radiation; D013696:Temperature
D004419:Dysprosium; D011189:Potassium Chloride