Direct carbamoylation of alkenyl halides.
Alkenyl chlorides and bromides are converted into tertiary enamides by treatment with a carbamoylsilane in toluene at 110 degrees C in the presence of phosphine-palladium(0) catalysts. [reaction: see text]
Cunico
Robert F
RF
Department of Chemistry and Biochemistry, Northern Illinois University, DeKalb, IL 60115, USA. rfc@marilyn.chem.niu.edu
Maity
Bikash C
BC