Intramolecular organocatalytic [3+2] dipolar cycloaddition: stereospecific cycloaddition and the total synthesis of (+/-)-hirsutene.
Wang
Jian-Cheng
JC
University of Texas at Austin, Department of Chemistry and Biochemistry, 1 University Station-A5300, Austin, TX 78712-1167, USA.
Krische
Michael J
MJ
D002384:Catalysis; D003517:Cyclopentanes / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D010720:Phosphines / Q000737:chemistry; D000081223:Polycyclic Sesquiterpenes; D012717:Sesquiterpenes / Q000138:chemical synthesis* / Q000737:chemistry*; D013237:Stereoisomerism
D003517:Cyclopentanes; D010720:Phosphines; D000081223:Polycyclic Sesquiterpenes; D012717:Sesquiterpenes; C486985:hirsutene; C034188:hirsutic acid C; C044646:phosphine