title: Electrochemical potential tuned solar water splitting.
abstract: As a fundamental step towards a clean, renewable source of H2, a novel physical chemical process within molten NaOH in which an external single, small bad gap photosentizer, such as Si, can drive the energetics of water cleavage is demonstrated, and is accomplished by tuning (decreasing) the water splitting electrochemical potential, EH2O, rather than tuning the photosensitizer band gap; this diminished potential is due to (i) a thermodynamic temperature induced decrease of EH2O with increasing temperature, and (ii) a partial recombination of the cleavage products.
authors.affiliation: Department of Chemistry, University of Massachusetts Boston, Boston 32000, USA. stuart.licht@umb.edu
authors.forename: Stuart
authors.initials: S
authors.lastname: Licht
authors.forename: Leonid
authors.initials: L
authors.lastname: Halperin
authors.forename: Michael
authors.initials: M
authors.lastname: Kalina
authors.forename: Martina
authors.initials: M
authors.lastname: Zidman
authors.forename: Nadezhda
authors.initials: N
authors.lastname: Halperin