Lanthanide complexes derived from (R)-1,1'-binaphthyl-2,2'-bis(neopentylamine)--(Li(THF)4)(Ln[(R)-C20H12N2(C10H22)]2) (Ln = Sm, Yb)--novel catalysts for enantioselective intramolecular hydroamination.
The complexes (Li(THF)4)(Ln[(R)-C20H12N2(C10H22)]2) (Ln = Sm, Yb) have been synthesized, fully characterized and found to be efficient and enantioselective catalysts for intramolecular hydroamination of 1-(aminomethyl)-1-allylcyclohexane.
Collin
Jacqueline
J
Laboratoire de Catalyse Moléculaire, ICMMO, Université Paris-Sud, 91405 Orsay, France. jacollin@icmo.u-psud.fr
Daran
Jean-Claude
JC
Schulz
Emmanuelle
E
Trifonov
Alexander
A