Comparison of photoelectron transfer in solution and the solid state for two intervalence radical cations.
[structure: see text] The optical diffuse reflectance and solution spectra of two bis-hydrazine radical cationic intervalence compounds have been compared. The results are consistent with an ion-pairing increase and an "effective polarity" in these crystals that is not far from that of acetonitrile or other polar solvents.
Nelsen
Stephen F
SF
Department of Chemistry, University of Wisconsin, Madison, Wisconsin 53706-1396, USA. nelsen@chem.wisc.edu
Konradsson
Asgeir E
AE
Clennan
Edward L
EL
Singleton
Jamie
J