title: Photophysical properties of ruthenium(II) polyazaaromatic compounds: a theoretical insight.
abstract: Quantum-chemical methods are applied to study the nature of the excited states relevant in the photophysical processes (absorption and emission) of a series of polyazaaromatic-ligand-based ruthenium(II) complexes. The electronic and optical properties of the free polyazaaromatic ligands and their corresponding ruthenium(II) complexes are determined on the basis of correlated Hartree-Fock semiempirical approaches. While the emission of complexes containing small-size ligands, such as 1,10-phenanthroline or 2,2'-bipyridine, arises from a manifold of metal-to-ligand charge-transfer triplet states ((3)MLCTs), an additional ligand-centered triplet state ((3)L) is identified in the triplet manifold of complexes containing a pi-extended ligand such as dipyrido[3,2-a:2',3'-c]phenazine, tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2''',3'''-j]phenazine, and 1,10-phenanthrolino[5,6-b]-1,4,5,8,9,12-hexaazatriphenylene. Recent experimental data are interpreted in light of these theoretical results; namely, the origin for the abnormal solvent- and temperature-dependent emission measured in pi-extended Ru complexes is revisited.
authors.affiliation: Laboratory for Chemistry of Novel Materials, University of Mons-Hainaut, 20 Place du Parc, B-7000 Mons, Belgium.
authors.forename: Geoffrey
authors.initials: G
authors.lastname: Pourtois
authors.forename: David
authors.initials: D
authors.lastname: Beljonne
authors.forename: Cécile
authors.initials: C
authors.lastname: Moucheron
authors.forename: Stephan
authors.initials: S
authors.lastname: Schumm
authors.forename: Andrée
authors.initials: A
authors.lastname: Kirsch-De Mesmaeker
authors.forename: Roberto
authors.initials: R
authors.lastname: Lazzaroni
authors.forename: Jean-Luc
authors.initials: JL
authors.lastname: Brédas