Crystal growth and structure determination of barium rhodates: stepping stones toward 2H-BaRhO3.
Single crystals of two new barium rhodates were grown from a molten potassium carbonate flux. The new rhodates, Ba(11)Rh(10)O(30) and Ba(32)Rh(29)O(87), are structurally related to the 2H-hexagonal perovskite structure and are characterized by pseudo one-dimensional chains of alternating face-sharing trigonal prisms and octahedra. The structures of Ba(11)Rh(10)O(30) and Ba(32)Rh(29)O(87) were solved using the 4D superspace group approach in Jana2000. Ba(11)Rh(10)O(30), with a repeat of nine RhO(6) octahedra followed by one RhO(6) trigonal prism, contains the longest chain sequence of face-sharing octahedra known for this 2H-perovskite related family of oxides. A structural analysis of these two compounds revealed clear trends in metal-metal distances and octahedral heights not previously identified for this family of oxides. The application of these trends toward the structure of the all-octahedra-containing end member of the structural series, the hypothetical 2H-BaRhO(3), enabled a prediction of its rhodium-rhodium distance, octahedral height, and lattice parameters.
Stitzer
Katharine E
KE
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina 29208, USA.
El Abed
Ahmed
A
Darriet
Jacques
J
zur Loye
Hans-Conrad
HC