3 beta,7 alpha,12 alpha-triformyloxy-24-nor-5 beta-chol-22-ene.
The title compound, alternatively called 24-nor-5 beta-chol-22-ene-3 beta,7 alpha,12 alpha-triyl triformate, C(26)H(38)O(6), has a cis junction between two of the six-membered rings. All three of the six-membered rings have chair conformations that are slightly flattened and the five-membered ring has a 13 beta,14 alpha-half-chair conformation. The 3 beta, 7 alpha and 12 alpha ring substituents are axial and the 17 beta group is equatorial. The 3 beta-formyloxy group is involved in one weak intermolecular C-H...O bond, which links the molecules into dimers in a head-to-head fashion.
Andrade
L C R
LC
CEMDRX, Departamento de Física, Faculdade de Ciências e Tecnologia, Universidade de Coimbra, P-3004-516 Coimbra, Portugal.
Paixão
J A
JA
de Almeida
M J M
MJ
da Silva
E J Tavares
EJ
Sá e Melo
M L
ML
Roleira
F M Fernandes
FM