title: Lanthanide complexes derived from (R)-1,1'-binaphthyl-2,2'-bis(neopentylamine)--(Li(THF)4)(Ln[(R)-C20H12N2(C10H22)]2) (Ln = Sm, Yb)--novel catalysts for enantioselective intramolecular hydroamination.
abstract: The complexes (Li(THF)4)(Ln[(R)-C20H12N2(C10H22)]2) (Ln = Sm, Yb) have been synthesized, fully characterized and found to be efficient and enantioselective catalysts for intramolecular hydroamination of 1-(aminomethyl)-1-allylcyclohexane.
authors.affiliation: Laboratoire de Catalyse Moléculaire, ICMMO, Université Paris-Sud, 91405 Orsay, France. jacollin@icmo.u-psud.fr
authors.forename: Jacqueline
authors.initials: J
authors.lastname: Collin
authors.forename: Jean-Claude
authors.initials: JC
authors.lastname: Daran
authors.forename: Emmanuelle
authors.initials: E
authors.lastname: Schulz
authors.forename: Alexander
authors.initials: A
authors.lastname: Trifonov