A facile synthesis of novel cyclodextrin derivatives incorporating one beta-(1,4)-glucosidic bond and their unique inclusion ability.
Novel cyclodextrin derivatives incorporating one (1,4)-glucosidic bond are easily synthesized in three steps from permethylated alpha- and beta-cyclodextrins, and such host molecules show inclusion selectivity for sodium m-nitrobenzoate over the corresponding p-isomer, in contrast to the cases of the parent permethylated alpha- and beta-cyclodextrins.
Kida
Toshiyuki
T
Department of Molecular Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.
Kikuzawa
Akira
A
Nakatsuji
Yohji
Y
Akashi
Mitsuru
M
D003505:Cyclodextrins / Q000138:chemical synthesis / Q000737:chemistry*; D004355:Drug Stability; D005960:Glucosides / Q000737:chemistry*; D007536:Isomerism; D009579:Nitrobenzoates / Q000737:chemistry
D003505:Cyclodextrins; D005960:Glucosides; D009579:Nitrobenzoates