title: Trans-dichloro-cis-bis(3,6-dimethylcarbazolyl)-cis-bis(tetrahydrofuran)zirconium(IV) benzene sesquisolvate.
abstract: In the title compound, [ZrCl(2)(C(14)H(12)N)(2)(C(4)H(8)O)(2)].1.5C(6)H(6), the Zr atom is pseudo-octahedral, with two Cl atoms in trans positions and two tetrahydrofuran molecules in cis positions. The two 3,6-dimethylcarbazolyl ligands are in cis positions and are canted with respect to one another. The two Zr-N distances are 2.1148 (18) and 2.1236 (18) A, and the N-Zr-N angle is 95.08 (7)degrees. The title compound crystallizes as the benzene solvate, with one of the benzene molecules positioned on an inversion center.
authors.affiliation: Department of Chemistry, 406 Buehler Hall, University of Tennessee, Knoxville, TN 37996, USA.
authors.forename: Cara L
authors.initials: CL
authors.lastname: Nygren
authors.forename: M E T
authors.initials: ME
authors.lastname: Bragg
authors.forename: John F C
authors.initials: JF
authors.lastname: Turner