mu4-Dicarbyne complex with a dimetallacyclobutatriene core: a new binding mode of C2 species.
Reaction of a permetallated ethene, (mu4-C=C)Fe2R-mu2Cp*2(CO)10, with diphenylacetylene affords the adduct with a new C2-binding mode, a mu4-dicarbyne complex, (mu4-C-C)Fe2Ru2Cp*2(CO)6(mu-Ph-C[triple bond]C-Ph), containing a dimetallacyclobutariene core.
Terada
Masako
M
Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan.
Higashihara
Gou
G
Inagaki
Akiko
A
Akita
Munetaka
M