Stannyl radical addition-cyclization of oxime ethers connected with olefins.
Stannyl radical addition-cyclization of oxime ethers connected with olefin moieties was studied. The radical reactions proceeded effectively by the use of triethylborane as a radical initiator to provide the functionalized pyrrolidines via a carbon-carbon bond-forming process.
Miyabe
Hideto
H
Kobe Pharmaceutical University, Motoyamakita, Higashinada-ku, Kobe 658-8558, Japan.
Tanaka
Hirotaka
H
Naito
Takeaki
T
D000475:Alkenes / Q000737:chemistry*; D001880:Boranes / Q000737:chemistry; D002855:Chromatography, Thin Layer; D003500:Cyclization; D004987:Ethers / Q000737:chemistry; D005609:Free Radicals; D007202:Indicators and Reagents; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry; D010091:Oximes / Q000737:chemistry*; D011759:Pyrrolidines / Q000737:chemistry; D013055:Spectrophotometry, Infrared; D017550:Spectroscopy, Fourier Transform Infrared; D014001:Tin / Q000737:chemistry*
D000475:Alkenes; D001880:Boranes; D004987:Ethers; D005609:Free Radicals; D007202:Indicators and Reagents; D010091:Oximes; D011759:Pyrrolidines; D014001:Tin; C079756:triethylborane