title: A zeolitic organo-metallophosphate hybrid material with bimodal porosity.
abstract: The first metal carboxylatophosphate, NTHU-2, contains inorganic ZnHPO4 layers linked by BDC units (BDC = 1,4-benzene dicarboxylate or terephthalic anion); the three-dimensional anionic framework has large pores with the smallest diameter being 1.36 nm; N2 sorption isotherms reveal both micro- and mesoporosity; the new material is photoluminescent and disassembles in water wherein the discharged organic fragments form mixed crystals.
authors.affiliation: Department of Chemistry, National Tsing Hua University, Hsinchu 30043, Taiwan.
authors.forename: Yueh-Chun
authors.initials: YC
authors.lastname: Liao
authors.forename: Fen-Ling
authors.initials: FL
authors.lastname: Liao
authors.forename: Wei-Kuo
authors.initials: WK
authors.lastname: Chang
authors.forename: Sue-Lein
authors.initials: SL
authors.lastname: Wang