title: Correlations in the chemical composition of rural background atmospheric aerosol in the UK determined in real time using time-of-flight mass spectrometry.
abstract: An aerosol time-of-flight mass spectrometer (ATOFMS) was used to determine, in real time, the size and chemical composition of individual particles in the atmosphere at the remote inland site of Eskdalemuir, Scotland. A total of 51,980 particles, in the size range 0.3-7.4 microm, were detected between the 25th and 30th June 2001. Rapid changes in the number density, size and chemical composition of the atmospheric aerosol were observed. These changes are attributed to two distinct types of air mass; a polluted air mass that had passed over the British mainland before reaching Eskdalemuir, interposed between two cleaner air masses that had arrived directly from the sea. Such changes in the background aerosol could clearly be very important to studies of urban aerosols and attempts at source apportionment. The results of an objective method of data analysis are presented. Correlations were sought between the occurrence of: lithium, potassium, rubidium, caesium, beryllium, strontium, barium, ammonium, amines, nitrate, nitrite, boron, mercury, sulfate, phosphate, fluorine, chlorine, bromine, iodine and carbon (both elemental and organic hydrocarbon) in both fine (d < 2.5 microm) and coarse (d > 2.5 microm) particle fractions. Several previously unreported correlations were observed, for instance between the elements lithium, beryllium and boron. The results suggest that about 2 in 3 of all fine particles (by number rather than by mass), and 1 in 2 of all coarse particles containing carbon, consisted of elemental carbon rather than organic hydrocarbon (although a bias in the sensitivity of the ATOFMS could have affected these numbers). The ratio of the number of coarse particles containing nitrate anions to the number of particles containing chloride anions exceeded unity when the air mass had travelled over the British mainland. The analysis also illustrates that an air mass of marine origin that had travelled slowly over agricultural land can accumulate amines and ammonium.
authors.affiliation: School of Chemistry, University of Edinburgh, West Mains Road, Edinburgh, UK EH9 3JJ.
authors.forename: David C S
authors.initials: DC
authors.lastname: Beddows
authors.forename: Robert J
authors.initials: RJ
authors.lastname: Donovan
authors.forename: Roy M
authors.initials: RM
authors.lastname: Harrison
authors.forename: Mathew R
authors.initials: MR
authors.lastname: Heal
authors.forename: Robert P
authors.initials: RP
authors.lastname: Kinnersley
authors.forename: Martin D
authors.initials: MD
authors.lastname: King
authors.forename: David H
authors.initials: DH
authors.lastname: Nicholson
authors.forename: Katherine C
authors.initials: KC
authors.lastname: Thompson
mesh_terms: D000336:Aerosols / Q000032:analysis*; D000383:Agriculture; D000392:Air Movements; D000393:Air Pollutants / Q000032:analysis*; D000588:Amines / Q000032:analysis*; D013058:Mass Spectrometry / Q000379:methods; D010316:Particle Size; D000644:Quaternary Ammonium Compounds / Q000032:analysis*; D012623:Seawater; D006113:United Kingdom
chemical_list: D000336:Aerosols; D000393:Air Pollutants; D000588:Amines; D000644:Quaternary Ammonium Compounds