3,6-dioxypyridazine bridged tungsten-tungsten quadruple bonds. Comparisons of electron delocalisation with oxalate bridged compounds.
The preparation and characterisation of the tungsten-tungsten quadruply bonded, 3,6-dioxypyridazine bridged complex [((t)BuCO(2))(3)W(2)](2)([micro sign]-H(2)C(4)N(2)O(2)) and its single electron oxidised radical cation are reported and, when compared with related bridged dimolybdenum complexes, reveal a different mechanism of electronic coupling from that seen in related oxalate bridged systems.
Chisholm
Malcolm H
MH
Department of Chemistry, The Ohio State University, 100 W. 18th Avenue, Columbus, OH 43210-1173, USA. chisholm@chemistry.ohio-state.edu.
Clark
Robin J H
RJ
Hadad
Christopher M
CM
Patmore
Nathan J
NJ