title: Real-time measurements of polychlorinated biphenyls using laser ionization time-of-flight mass spectrometry.
abstract: Polychlorinated biphenyls (PCBs) are hazardous compounds for which there are few methods involving real-time measurement. Recently, the development of the pulsed-laser technique has enabled us to measure aromatic hydrocarbons quite rapidly. In particular, the LI-TOFMS (laser ionization time of flight mass spectrometry) technique is expected to be a powerful method for on-line, selective and sensitive measurements. In the context of developing a highly selective and sensitive technique, the effective laser wavelength and pulse duration for laser ionization of 2-4 chlorinated PCBs are considered. Excitation at lambda = 266 nm was found to be substantially more effective than at lambda = 280, 300 or 320 nm. Also, picosecond excitation for PCBs underwent more efficient ionization (by a factor of over 10) and less fragmentation than nanosecond excitation. The achievable sensitivity for trichlorinated biphenyl in a real-time (1 min) measurement using the LI-TOFMS technique was estimated to be in the sub-ppbV range (< 0.01 mg/Nm3).
authors.affiliation: Nagasaki Research and Development Center Mitsubishi Heavy Industries Ltd., 5-717-1 Fukahori-machi, Nagasaki 851-0392, Japan. shinsaku_dobashi@mhi.co.jp
authors.forename: Shinsaku
authors.initials: S
authors.lastname: Dobashi
authors.forename: Yoshihiro
authors.initials: Y
authors.lastname: Deguchi
authors.forename: Takahiro
authors.initials: T
authors.lastname: Kubota
authors.forename: Katsuhiko
authors.initials: K
authors.lastname: Shinoda