Probing the molecular environment using spin-resolved photoelectron spectroscopy.
Angle- and spin-resolved photoelectron spectroscopy with linearly and circularly polarized synchrotron radiation were used to study the electronic structure of model triatomic molecules, hydrogen sulfide, and carbonyl sulfide. The spin-polarization measurements of the molecular field split components of the S 2p photolines revealed a strong effect of the different molecular environments. The validity of simple atomic models to explain the results is discussed.
Turri
G
G
Department of Physics, Western Michigan University, Kalamazoo, Michigan 49008, USA.
Snell
G
G
Langer
B
B
Martins
M
M
Kukk
E
E
Canton
S E
SE
Bilodeau
R C
RC
Cherepkov
N
N
Bozek
J D
JD
Kilcoyne
A L
AL
Berrah
N
N