title: Amine elimination synthesis of a titanium(IV) N-heterocyclic carbene complex with short intramolecular Cl...C carbene contacts.
abstract: The reaction of 1,3-dimesitylimidazolium chloride with Ti(NMe(2))(4) results in the 1,3-dimesitylimadazol-2-ylidene complex of Ti(NMe(2))(2)Cl(2)(3); the X-ray crystal structure of 3 evidences short intramolecular Cl...C(carbene) contacts.
authors.affiliation: Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, TX 78712, USA.
authors.forename: Piyush
authors.initials: P
authors.lastname: Shukla
authors.forename: Jennifer A
authors.initials: JA
authors.lastname: Johnson
authors.forename: Dragoslav
authors.initials: D
authors.lastname: Vidovic
authors.forename: Alan H
authors.initials: AH
authors.lastname: Cowley
authors.forename: Colin D
authors.initials: CD
authors.lastname: Abernethy