title: Formation of trinuclear palladium orthometalated complexes with unprecedented asymmetrical (mu 3-S)(mu 3-X) bridges (X = OH, SR, O2CR) from mu 2-hydroxo dimeric complexes and CS2.
abstract: Complexes [Pd(3)(mu(3)-S)(mu(3)-X)(L)(3)] (L = orthometalated imine), obtained by an unusual reaction of mu(2)-OH dimeric complexes and CS(2), are an unprecedented type of asymmetrical bridges between metallatriangles, which force an all-cis arrangement of the three orthometalated ligands relative to the metallatriangle.
authors.affiliation: Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Valladolid, 47005 Valladolid, Spain. espinet@qi.uva.es
authors.forename: Pablo
authors.initials: P
authors.lastname: Espinet
authors.forename: Celia
authors.initials: C
authors.lastname: Hernández
authors.forename: José M
authors.initials: JM
authors.lastname: Martín-Alvarez
authors.forename: Jesús A
authors.initials: JA
authors.lastname: Miguel