Structure and magnetism of a new pyrazolate bridged iron(II) spin crossover complex displaying a single HS-HS to LS-LS transition.
The dinuclear iron(II) complex [(pypzH)(NCSe)Fe([micro sign]-pypz)(2)Fe(NCSe)(pypzH)].2H(2)O displays a single, sharp spin crossover transition between the [HS-HS] and [LS-LS] states and is structurally characterised above and below the T(1/2)= 225 K value
Leita
Ben A
BA
School of Chemistry, Monash University, P.O Box 23, Clayton, Victoria, Australia.
Moubaraki
Boujemaa
B
Murray
Keith S
KS
Smith
Jonathan P
JP
Cashion
John D
JD