An outer-sphere ligand for uranyl carbonate.
A novel supramolecular host for the uranyl carbonate complex has been designed and synthesized. The modified cyclodextrin host binds uranyl carbonate in water with a stability of 253 M(-1).
Prudden
Anthony R
AR
Department of Chemistry, University of Iowa, Iowa City, IA 52242-1294, USA.
Lien
Nathan R
NR
Telford
Jason R
JR
D002254:Carbonates / Q000032:analysis / Q000737:chemistry*; D003505:Cyclodextrins / Q000737:chemistry*; D005029:Ethylenediamines / Q000737:chemistry; D005618:Fresh Water / Q000737:chemistry; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy; D011485:Protein Binding; D011522:Protons; D012623:Seawater / Q000737:chemistry; D013816:Thermodynamics; D014501:Uranium / Q000737:chemistry*
D002254:Carbonates; D003505:Cyclodextrins; D005029:Ethylenediamines; D008024:Ligands; D011522:Protons; D014501:Uranium; C031234:ethylenediamine