New triterpenoid saponins from the roots of Sinocrassula asclepiadea.
Five new triterpenoid monodesmosides (sinocrassulosides I-V, 1-5) and six bisdesmosides (sinocrassulosides VI-XI, 6-11), in which 2-11 possess different acyl groups in the glycosidic moieties, were isolated from the roots of Sinocrassula asclepiadea FRANCH. Sinocrassulosides VI (4) and V (5) also contained a novel A-seco aglycone in their structures. All of the structures were determined on the basis of spectroscopic and physicochemical evidence.
Zhao
Jing
J
Department of Metabolic Engineering, Institute of Natural Medicine, Toyama Medical and Pharmaceutical University, Toyama, Japan.
Nakamura
Norio
N
Hattori
Masao
M
Yang
Xiu-Wei
XW
Komatsu
Katsuko
K
Qiu
Ming-Hua
MH
D029748:Caryophyllaceae / Q000737:chemistry*; D004365:Drugs, Chinese Herbal / Q000302:isolation & purification*; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D018517:Plant Roots / Q000737:chemistry; D012503:Saponins / Q000302:isolation & purification*; D014315:Triterpenes / Q000302:isolation & purification*
D004365:Drugs, Chinese Herbal; D012503:Saponins; D014315:Triterpenes