A new synthesis of 1,3-dihydrobenzo[1,2]oxasiloles by a novel rearrangement of a pentavalent silicon intermediate.
A new synthesis of benzo[1,2]oxasiloles is described, wherein an unprecedented intramolecular allylic transposition takes place probably involving a pentavalent silicon intermediate.
Bashiardes
George
G
Departement de Chimie, Université de Poitiers, SFA-UMR 6514, 40 avenue du Recteur Pineau, 86022 Poitiers cedex, France. george.bashiardes@univ-poitiers.fr
Chaussebourg
Vanessa
V
Laverdan
Géraldine
G
Pornet
Jacques
J