A three dimensional porous metal-organic framework [Fe4L6.(DMF)3.(H2O)10] constructed from neutral discrete Fe4L6 pyramids [H2L = 1,3-benzodihydroxamix acid].
A 3-D porous zeolite-like metal-organic framework surviving guest removal is assembled from a well-defined tetrahedral Fe(4)L(6) cavity by the cooperativity of hydrogen bonds and [small pi]-[small pi] stacking.
Bai
Yan
Y
Coordination Chemistry Institute, The State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P. R. China.
Guo
Dong
D
Duan
Chun-Ying
CY
Dang
Dong-Bin
DB
Pang
Ke-Liang
KL
Meng
Qing-Jin
QJ