A study of the elemental leachability and retention capability of compost.
In this work a comparison is made between the different approaches that can be taken to evaluate the mobility of elements in compost. The practical consequences of the results obtained are also discussed in terms of methods for cleaning up compost and using compost in environmental remediation. The mobility of potentially toxic elements in compost is evaluated by leaching with four selected eluents, i.e. diluted sulfuric acid, oxalate, citrate and EDTA. In contrast to the chelating agents, diluted sulfuric acid was found to generally have a low leaching capability for removal of heavy metals from compost. This implies that the risk of heavy metal leaching caused by natural rainfall is likely to be low. The results obtained in the leaching experiment were compared with previous results obtained from sequential fractionation. This comparison confirmed that both methods gave similar results for predicting the lability of elements in compost. A non-linear regression analysis of the leaching curves was also conducted. The leaching curves for elements with high lability could be fitted with a two components model. The labile components identified by the kinetic model are approximately in accordance with the fractions obtained from the first step of the sequential extraction method. The kinetic speciation method is shown to be a relatively rapid and simple procedure for compost which gives more information about element lability than simple leaching experiments. The leaching reagents used in this work were not effective enough to be used for cleaning up compost with a high metal content. Compost was however shown to have a high affinity for heavy metals, with the order of affinity of metal for the compost being very similar to that seen for humic acid. Compost may therefore prove to be a good remediation material for metal contaminated waste.
Song
Qi Jun
QJ
Department of Chemistry, University of Hull, Cottingham Road, Hull, HU6 7RX, UK.
Greenway
Gillian M
GM
D002614:Chelating Agents / Q000737:chemistry; D004492:Edetic Acid / Q000737:chemistry; D004784:Environmental Monitoring; D007700:Kinetics; D008962:Models, Theoretical; D012037:Refuse Disposal; D012989:Soil Pollutants / Q000032:analysis*; D014872:Water Movements; D014873:Water Pollutants / Q000032:analysis*
D002614:Chelating Agents; D012989:Soil Pollutants; D014873:Water Pollutants; D004492:Edetic Acid