Local mean-field study of capillary condensation in silica aerogels.
We apply local mean-field (i.e., density functional) theory to a lattice model of a fluid in contact with a dilute, disordered gel network. The gel structure is described by a diffusion-limited cluster aggregation model. We focus on the influence of porosity on both the hysteretic and the equilibrium behavior of the fluid as one varies the chemical potential at low temperature. We show that the shape of the hysteresis loop changes from smooth to rectangular as the porosity increases and that this change is associated with disorder-induced out-of-equilibrium phase transitions that differ in adsorption and in desorption. Our results provide insight in the behavior of 4He in silica aerogels.
Detcheverry
F
F
Laboratoire de Physique Théorique des Liquides, Université Pierre et Marie Curie, 4 place Jussieu, 75252 Paris Cedex 05, France.
Kierlik
E
E
Rosinberg
M L
ML
Tarjus
G
G