Optimisation of stir bar sorptive extraction for the analysis of volatile phenols in wines.
An easy, fast and reliable analytical method is proposed for the determination of the concentration of volatile phenols (ethyl- and vinylphenols) in wines. The novel stir bar sorptive extraction (SBSE) technique is employed, following a simple and fast procedure that allows 15 samples to be extracted simultaneously using very small sample volume. Extracts are desorbed in a thermodesorption system (TDS) coupled on-line to a gas chromatograph-mass spectrometry system. The SBSE offers better recovery and linear regression coefficient (r2) for the four volatile phenols than solid-phase extraction (SPE). The mass spectrometric detection in selected ion monitoring mode contributes to the lower detection limit and good sensibility obtained with this method.
Díez
Juan
J
Departamento Técnico, Osborne y Cía, S.A., Fernan Caballero 3, 11500 El Puerto de Santa Maria, Cádiz, Spain.
Domínguez
Cristina
C
Guillén
Dominico A
DA
Veas
Rafael
R
Barroso
Carmelo G
CG
D002849:Chromatography, Gas / Q000379:methods; D010636:Phenols / Q000032:analysis*; D015203:Reproducibility of Results; D012680:Sensitivity and Specificity; D014835:Volatilization; D014920:Wine / Q000032:analysis*
D010636:Phenols