title: Relative importance of hydrogen bonding and coordinating groups in modulating the zinc-water acidity.
abstract: The presence of second-sphere -NH(2) groups in the proximity of a zinc(ii)-bound water molecule enhances its acidity by ca. 2 pK(a) units.
authors.affiliation: School of Chemistry, The University of Edinburgh, King's Buildings, West Mains Road, Edinburgh, U.K.EH9 3JJ. juan.mareque@ed.ac.uk
authors.forename: Juan C
authors.initials: JC
authors.lastname: Mareque-Rivas
authors.forename: Ravi
authors.initials: R
authors.lastname: Prabaharan
authors.forename: Rafael Torres Martín
authors.initials: RT
authors.lastname: de Rosales