The first ligand-modulated oxidative Heck vinylation. Efficient catalysis with molecular oxygen as palladium(0) oxidant.
The discovery of the first ligand-supported Pd(ii) catalysed oxidative Heck reaction with molecular oxygen as reoxidant and the scope with diverse arylboronic acids and olefins using only 1-2% of catalyst are reported.
Andappan
Murugaiah M S
MM
Box 574, Organic Pharmaceutical Chemistry, Department of Medicinal Chemistry, BMC, Uppsala, SE-75123, Sweden.
Nilsson
Peter
P
Larhed
Mats
M