Structural and optical characterization of pyrolytic carbon derived from novolac resin.
The structural and optical properties of technologically interesting pyrolytic carbons formed from cured novolac resin and cured novolac/biomass composites were studied by X-Ray Diffraction Analysis (XRD), and Fourier Transform Infrared (FTIR), Raman and Photoluminescence (PL) spectroscopy. Pyrolysis of the cured materials took place at temperatures in the range 400-1000 degrees C. The most important weight loss, shrinkage and structural changes of pyrolyzed composites are observed at temperatures up to 600 degrees C due to the olive stone component. In the same temperature range, the changes in pyrolyzed novolac are smaller. The spectroscopic analysis shows that novolac pyrolyzed up to 900 ( degrees )C has less defects and disorder than the composites. However, above 900 ( degrees )C, pyrolyzed novolac becomes more disordered compared to the pyrolyzed composites. It is concluded that partial replacement of novolac by olive stone in the composite materials leads to the formation of a low cost, good quality product.
Theodoropoulou
S
S
School of Chemical Engineering, National Technical University of Athens, 9-Heroon Polytechniou str., Zografou Campus, 15773 Athens, Greece.
Papadimitriou
D
D
Zoumpoulakis
L
L
Simitzis
J
J
D018533:Biomass; D002244:Carbon / Q000032:analysis* / Q000737:chemistry*; D005390:Fires; D011108:Polymers / Q000737:chemistry*; D017550:Spectroscopy, Fourier Transform Infrared; D013057:Spectrum Analysis; D013059:Spectrum Analysis, Raman
D011108:Polymers; D002244:Carbon