Synthesis of poly(para-phenylenevinylene) rotaxanes by aqueous Suzuki coupling.
PPV-based polyrotaxanes have been prepared by coupling vinyl boronic acids to aryl iodides in the presence of cyclodextrins, and the crystal structure of a [2]rotaxane of this type has been determined.
Terao
Jun
J
Department of Chemistry, University of Oxford, Dyson Perrins Laboratory, South Parks Road, Oxford, UKOX1 3QY.
Tang
Andrew
A
Michels
Jasper J
JJ
Krivokapic
Alexander
A
Anderson
Harry L
HL