Density functional theory for nearest-neighbor exclusion lattice gases in two and three dimensions.
To speak about fundamental measure theory obliges us to mention dimensional crossover. This feature, inherent to the systems themselves, was incorporated in the theory almost from the beginning. Although at first it was thought to be a consistency check for the theory, it rapidly became its fundamental pillar, thus becoming the only density functional theory which possesses such a property. It is straightforward that dimensional crossover connects, for instance, the parallel hard cube system (three dimensional) with that of squares (two dimensional) and rods (one dimensional). We show here that there are many more connections which can be established in this way. Through them we deduce from the functional for parallel hard (hyper)cubes in the simple (hyper)cubic lattice the corresponding functionals for the nearest-neighbor exclusion lattice gases in the square, triangular, simple cubic, face-centered-cubic, and body-centered-cubic lattices. As an application, the bulk phase diagram for all these systems is obtained.
Lafuente
Luis
L
Grupo Interdisciplinar de Sistemas Complejos, Departamento de Matemáticas, Universidad Carlos III de Madrid, Avenida de la Universidad 30, 28911 Leganés, Madrid, Spain. llafuent@math.uc3m.es
Cuesta
José A
JA