Dichloro(dodeca-2,6,10-triene-1,12-diyl)ruthenium(IV): a highly efficient catalyst for the isomerization of allylic alcohols into carbonyl compounds in organic and aqueous media.
The catalytic activity of the bis(allyl)-ruthenium(iv) complex [Ru([small eta](3):[small eta](2):[small eta](3)-C(12)H(18))Cl(2)] in the transposition of allylic alcohols into carbonyl compounds, both in THF and H(2)O as solvent, is reported.
Cadierno
Victorio
V
Departamento de Química Orgánica e Inorgánica, Instituto Universitario de Química Organometálica Enrique Moles(Unidad Asociada al CSIC), Facultad de Química, Universidad de Oviedo, 33071, Oviedo, Spain. vcm@sauron.quimica.uniovi.es
García-Garrido
Sergio E
SE
Gimeno
José
J