4-Chloro-N-(trimethylammonio)benzamide chloride monohydrate.
The structure of the cation in the ylide hydrochloride [Me(3)NNHC(O)C(6)H(4)-Cl-p]Cl.H(2)O, or C(10)H(14)ClN(2)O(+).Cl(-).H(2)O, is compared with that of the free ylide. Protonation lengthens the N-C(O) bond but shortens the C=O and N-N bonds by approximately 0.03 A and increases the dihedral angle between the phenyl and ylide planes.
Muir
Kenneth W
KW
Department of Chemistry, University of Glasgow, Glasgow G12 8QQ, Scotland. ken@chem.gla.ac.uk
Morris
David G
DG
Chii
Cindy OngWoei
CO