4-[(2-Chlorophenyl)diazenyl]-6-methoxy-2-[[tris(hydroxymethyl)methyl]aminomethylene]cyclohexa-3,5-dien-1(2H)-one.
The structure of the title compound, C(18)H(20)ClN(3)O(5), displays the characteristic features of azobenzene derivatives. Intramolecular N-H.O, weak intramolecular C-H.O, and intermolecular O-H.O and C-H.O interactions influence the conformation of the molecules and the crystal packing. Intermolecular hydrogen bonds link the molecules into infinite chains, and the title compound adopts the keto-amine tautomeric form. The azobenzene moiety of the molecule has a trans configuration. The molecule is not planar, and the dihedral angle between the two phenyl rings is 35.6 (2) degrees.
Ersanli
Cem Cüneyt
CC
Department of Physics, Faculty of Arts and Sciences, Ondokuz Mayis University, 55139 Kurupelit Samsun, Turkey. ccersan@omu.edu.tr
Albayrak
Cigdem
C
Odabaşoglu
Mustafa
M
Thöne
Carsten
C
Erdönmez
Ahmet
A