Tetra-mu-benzoato-kappa8O:O'-bis([1-[(3,4-dimethoxyphenyl)methyl]-6,7-dimethoxyisoquinoline-kappaN]zinc(II)): the first crystal structure with papaverine as a ligand.
The title complex, [Zn(2)(C(7)H(5)O(2))(4)(C(20)H(21)NO(4))(2)], forms dimers of the paddle-wheel cage type located at crystallographic inversion centres. The two Zn atoms [Zn.Zn = 3.0533 (4) A] are connected by four syn-syn benzoate ligands. The apical positions of the square-pyramidal zinc coordination polyhedra are occupied by the N atoms of the papaverine ligand. Upon coordination, the mutual orientation of the phenyl and isoquinoline rings in papaverine is changed compared with that in the uncoordinated ligand.
Zelenák
Vladimír
V
Institute of Chemical Science, Faculty of Science, P. J. Safárik University, Moyzesova 11, SK-041 54 Kosice, Slovak Republic. zelenak@kosice.upis.sk
Sabo
Michal
M
Massa
Werner
W
Cernák
Juraj
J
D018360:Crystallography, X-Ray; D008024:Ligands; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry* / Q000378:metabolism; D010208:Papaverine / Q000737:chemistry* / Q000378:metabolism; D014665:Vasodilator Agents / Q000737:chemistry* / Q000378:metabolism
D008024:Ligands; D009942:Organometallic Compounds; D014665:Vasodilator Agents; C487158:tetra-mu-benzoato-kappa(8)O-O'-bis((1-((3,4-dimethoxyphenyl)methyl)-6,7-dimethoxyisoquinoline-kappaN)zinc(II)); D010208:Papaverine