Total synthesis of (+)-acanthodoral by the use of a Pd-catalyzed metal-ene reaction and a nonreductive 5-exo-acyl radical cyclization.
D000818:Animals; D000900:Anti-Bacterial Agents / Q000032:analysis / Q000138:chemical synthesis*; D002384:Catalysis; D003500:Cyclization; D003509:Cyclohexanecarboxylic Acids / Q000737:chemistry; D007202:Indicators and Reagents; D015394:Molecular Structure; D008974:Mollusca / Q000737:chemistry*; D019906:Nuclear Magnetic Resonance, Biomolecular; D010165:Palladium / Q000737:chemistry*; D012717:Sesquiterpenes / Q000032:analysis / Q000138:chemical synthesis*; D013237:Stereoisomerism
D000900:Anti-Bacterial Agents; D003509:Cyclohexanecarboxylic Acids; D007202:Indicators and Reagents; C489771:S-2,2-dimethyl-6-methylenecyclohexanecarboxylic acid; D012717:Sesquiterpenes; C489770:acanthodoral; D010165:Palladium