Chemical evolution and meteorites: an update.
Carbonaceous chondrites are a primitive group of meteorites, which contain abundant organic material and provide a unique natural record of prebiotic chemical evolution. This material comprises a varied suite of soluble organic compounds that are similar, sometimes identical, to those found in the biosphere, such as amino acids, carboxylic acids, and sugar derivatives. Some amino acids of this suite also show L-enantiomeric excesses, and suggest the possibility they may have contributed to terrestrial homochirality by direct input of meteoritic material to the early Earth. This optical activity appears to be limited to the subgroup of alpha-methyl amino acids which, although not common in the extant biosphere, would have been well suited to provide the early earth with both enantiomeric excesses and means for their amplification by subsequent chemical evolution. We can also envision this exogenous delivery of carbonaceous material by meteorites and comets as having coincided with the endogenous formation of prebiotic precursors and influenced their evolution by complementary reactions or catalysis.
Pizzarello
Sandra
S
Arizona State University, Tempe, AZ 85287, USA. pizzar@asu.edu
D019110:Meteoroids; D013237:Stereoisomerism