A self-assembled supramolecular optical sensor for NiII, CdII, and CrIII.
A new chromogenic supramolecular sensor for transition metals is reported. It is based on a newly designed phenanthroline-containing molecule that self-assembles via an organometallic "clip" into a supramolecular optical sensor for metals. [reaction: see text]
Department of Chemistry, University of Utah, 315 S. 1400 E., Salt Lake City, UT 84112, USA.
Marino J E
MJ
Resendiz
Juan C
JC
Noveron
Hendrick
H
Disteldorf
Sonja
S
Fischer
Peter J
PJ
Stang
D002104:Cadmium / Q000032:analysis* / Q000737:chemistry; D002857:Chromium / Q000032:analysis* / Q000737:chemistry; D015336:Molecular Probe Techniques; D009532:Nickel / Q000032:analysis* / Q000737:chemistry; D010618:Phenanthrolines / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry*
C487222:3,8-bis(pyridin-4-ylethynyl)-1,10-phenanthroline; D010618:Phenanthrolines; D011725:Pyridines; D002104:Cadmium; D002857:Chromium; D009532:Nickel