Extended hypervalent 5c-6e interactions: linear alignment of five C-Se---O---Se-C atoms in anthraquinone and 9-methoxyanthracene bearing arylselanyl groups at the 1,8-positions.
The structures of 1,8-bis(phenylselanyl)anthraquinone (1a), 1,8-bis(phenylselanyl)-9-methoxyanthracene (2a), and 1,8-bis(phenylselanyl)anthracene (3a) are determined by X-ray crystallographic analysis, together with the derivatives. The Se-C(i) (Ph) bonds in 1a are placed on the anthraquinone plane (both type B) and the phenyl planes are perpendicular to the anthraquinone plane. The structure around the Se atoms in 2a is very close to that of 1a: the conformations of the PhSe groups are both type B. Consequently, the five C(i)-Se- - -O- - -Se-C(i) atoms in 1a and 2a align linearly. The nonbonded Se- - -O distances in 1a and 2a are 2.673-2.688 and 2.731-2.744 A, respectively, which are about 0.7 A shorter than the sum of van der Waals radii of the atoms. The extended hypervalent sigma*(C(i)-Se)- - -n(p)(O)- - -sigma*(Se-C(i)) 5c-6e interactions are strongly suggested for the origin of the linear alignment of the five atoms in 1a and 2a. The 5c-6e must be constructed by the connection of the two hypervalent n(p)(O)- - -sigma*(Se-C(i)) 3c-4e interactions through the central n(p)(O). The five C(i)-Se- - -H- - -Se-C(i) atoms never align linearly in 3a. To reveal the nature of 5c-6e in 1a and 2a, QC calculations are performed on H(a)H(b)(A)Se- - -O([double bond]CH(2))- - -(B)SeH(a')H(b') (model a) and H(a)H(b)(A)Se- - -OH(2)- - -(B)SeH(a')H(b') (model b) with the B3LYP/6-311++G(3df,2pd) method, where the nonbonded Se- - -O distances are fixed at 2.658 A. Four conformers, a (AA-cis), a (AA-trans), a (AB), and a (BB), are optimized to be stable for model a, where a (AA) shows both type A for the (A)Se-H(b) and (B)Se-H(b') bonds in model a. Three conformers, b (AA-cis), b (AB), and b (BB), are stable for model b. The bonding models in AA, AB, and BB correspond to 3c-6e, 4c-6e, and 5c-6e, respectively. The models become more stable by 42 +/- 5 kJ mol(-1), if the type A conformation of each Se-H bond changes to type B. No noticeable saturation is observed in the stabilization for each change. QC calculations are also performed on 1a-3a at the B3LYP level. Three conformers are evaluated to be stable for 1a and 2a. The relative energies of 1a (AA-trans), 1a (AB), and 1a (BB) are 0.0, -31.5, and -60.6 kJ mol(-1), respectively, and those of 2a (AA-cis), 2a (AB), and 2a (BB) are 0.0, -24.4, and -36.5 kJ mol(-1), respectively. These results demonstrate that the origin of the linear alignment of the five C-Se- - -O- - -Se-C atoms in 1a and 2a is the energy lowering effect by the extended hypervalent 5c-6e interactions of the sigma*(C-Se)<--n(p)(O)-->sigma*(Se-C) type. The pi-conjugation between pi(C[double bond]O) and n(pz)(Se) through the pi-framework of anthraquinone must also contribute to stabilize the BB structure of 1a, where z is the direction perpendicular to the anthraquinone plane.
Department of Chemistry and Material Science, Faculty of Systems Engineering, Wakayama University, 930 Sakaedani, Wakayama 640-8510, Japan. nakanisi@sys.wakayama-u.ac.jp
Warô
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Nakanishi
Satoko
S
Hayashi
Norio
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Itoh