Temperature and pressure effects on the bending modulus of monolayers in a ternary microemulsion.
We performed small-angle neutron scattering and neutron spin echo experiments on a ternary microemulsion composed of ionic surfactant AOT, water, and decane. Thermal fluctuations of monolayers have been investigated as a function of temperature and pressure. The amphiphilic monolayers become more flexible with increasing temperature and more rigid with increasing pressure. These results are consistent with the microscopic picture that the head-head repulsion of the AOT molecules is enhanced at high temperature while an attractive interaction between the hydrophobic tails of the AOT molecules increases at high pressure.
Kawabata
Y
Y
Department of Chemistry, Faculty of Science, Tokyo Metropolitan University, Tokyo 192-0397, Japan. youheik@comp.metro-u.ac.jp
Nagao
M
M
Seto
H
H
Komura
S
S
Takeda
T
T
Schwahn
D
D
Yamada
N L
NL
Nobutou
H
H