Design, synthesis, and crystallographic studies of neutral platinum-based macrocycles formed via self-assembly.
A series of neutral, platinum-based macrocycles was synthesized from rigid oxygen donor building blocks via self-assembly. The combination of a platinum-based 60 degrees acceptor unit 1 with several linear and angular dicarboxylate bridging ligands afforded hitherto unknown neutral platinum-based supramolecular triangles and rhomboids. In addition, a similar reaction of the diplatinum molecular clip 6 and three different linear dicarboxylates led to the formation of neutral molecular rectangles. Most of the macrocycles were characterized by X-ray single-crystal structure analysis, and, in all cases, NMR spectra were consistent with the formation of single highly symmetrical species.
Mukherjee
Partha Sarathi
PS
Department of Chemistry, University of Utah, 315 South 1400 East, Room 2020, Salt Lake City, Utah 84112, USA. stang@chem.uth.edu
Das
Neeladri
N
Kryschenko
Yury K
YK
Arif
Atta M
AM
Stang
Peter J
PJ
D001580:Benzopyrenes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D003500:Cyclization; D046911:Macromolecular Substances; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D015394:Molecular Structure; D009944:Organoplatinum Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D010984:Platinum / Q000737:chemistry; D013818:Thermogravimetry
D001580:Benzopyrenes; D046911:Macromolecular Substances; D009944:Organoplatinum Compounds; D010984:Platinum; C001575:anthanthrene