Tributyltin in environmental samples from the Former Derecktor Shipyard, Coddington Cove, Newport RI.
Tributyltin (TBT) was detected in all 24 surface sediment (top 2 cm) samples collected from Coddington Cove, Newport, RI. TBT surface sediment concentrations ranged from 32 to 372 ng Sn/g with a mean concentration of 146 ng Sn/g. Analyses of selected core sections detected TBT in at least the top 18 cm at all 7 stations where cores were collected. No consistent TBT concentration trends with depth for these cores suggest mixing is an important process in the sediment column. In one core (station 28), TBT was found in the 76-86 cm section at a concentration of 141 ng Sn/g; thus sediments are a significant sink for TBT. However, sediment mixing processes can enhance releases of bioavailable TBT. Mussels, clams and fish from Coddington Cove contain TBT at concentrations ranging from 9.2 to 977 ng Sn/g. TBT concentrations in lobsters were below the detection limit (<6 ng Sn/g). Based on available screening criteria, TBT concentrations in Coddington Cove sediment is likely to be having an adverse effect on the biota at some locations.
Wade
Terry L
TL
Texas A&M University, Geochemical and Environmental Research Group, 833 Graham Rd, College Station TX 77845, USA. terry@gerg.tamu.edu
Sweet
Stephen T
ST
Quinn
James G
JG
Cairns
Robert W
RW
King
John W
JW
D000818:Animals; D001682:Biological Availability; D004784:Environmental Monitoring / Q000379:methods; D004785:Environmental Pollutants / Q000032:analysis*; D019015:Geologic Sediments / Q000737:chemistry; D008669:Metallurgy; D008975:Molluscacides / Q000032:analysis*; D012237:Rhode Island; D012758:Shellfish / Q000032:analysis; D014220:Trialkyltin Compounds / Q000032:analysis*
D004785:Environmental Pollutants; D008975:Molluscacides; D014220:Trialkyltin Compounds; C011559:tributyltin