A quadrupole-quadrupole stacking synthon in (2,3,5,6-tetrafluorobenzenethiolato-kappaS)(triphenylphosphine-kappaP)gold(I).
The title compound, [Au(C6HF4S)(C18H15P)], with both aromatic and fluorinated aromatic rings in its molecular system, shows dimerization through a quadrupole-quadrupole stacking synthon. The dimer further aggregates through intermolecular pi-pi stacking and C-H...pi interactions, giving a supramolecular three-dimensional network.
Osaka Municipal Technical Research Institute, 1-6-50 Morinomiya, Joto-ku, Osaka 536-8553, Japan.
Seiji
S
Watase
Takayuki
T
Kitamura
Nobuko
N
Kanehisa
Masami
M
Nakamoto
Yasushi
Y
Kai
Shozo
S
Yanagida