The regio- and stereoselective one-pot catalytic preparation of beta-selenyl acrylamides.
Pd(PPh(3))(4) is found to catalytically assemble sulfenamides, terminal aliphatic alkynes, carbon monoxide, and diphenyl diselenides regio- and stereoselectively in a single-pot reaction to produce good yields of beta-selenyl acrylamides. [reaction: see text]
Department of Chemistry, University of Pittsburgh. Pittsburgh, PA 15213, USA.
Daniel J
DJ
Knapton
Tara Y
TY
Meyer