Diverse redox-active molecules bearing O-, S-, or Se-terminated tethers for attachment to silicon in studies of molecular information storage.
A molecular approach to information storage employs redox-active molecules tethered to an electroactive surface. Attachment of the molecules to electroactive surfaces requires control over the nature of the tether (linker and surface attachment group). We have synthesized a collection of redox-active molecules bearing different linkers and surface anchor groups in free or protected form (hydroxy, mercapto, S-acetylthio, and Se-acetylseleno) for attachment to surfaces such as silicon, germanium, and gold. The molecules exhibit a number of cationic oxidation states, including one (ferrocene), two [zinc(II)porphyrin], three [cobalt(II)porphyrin], or four (lanthanide triple-decker sandwich compound). Electrochemical studies of monolayers of a variety of the redox-active molecules attached to Si(100) electrodes indicate that molecules exhibit a regular mode of attachment (via a Si-X bond, X = O, S, or Se), relatively homogeneous surface organization, and robust reversible electrochemical behavior. The acetyl protecting group undergoes cleavage during the surface deposition process, enabling attachment to silicon via thio or seleno groups without handling free thiols or selenols.
Balakumar
Arumugham
A
Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695-8204, USA.
Lysenko
Andrey B
AB
Carcel
Carole
C
Malinovskii
Vladimir L
VL
Gryko
Daniel T
DT
Schweikart
Karl-Heinz
KH
Loewe
Robert S
RS
Yasseri
Amir A
AA
Liu
Zhiming
Z
Bocian
David F
DF
Lindsey
Jonathan S
JS