New data on the mobility of Pt emitted from catalytic converters.
The mobility and speciation of Pt was investigated in dust deposited in highway tunnels and in gully sediments. For this, a sequential extraction technique was used in combination with a microwave digestion procedure, followed by detection of Pt with high resolution ICP-MS. A digestion procedure using HNO(3)/HCl/H(2)O(2) was developed and its efficiency tested for environmental materials. Total Pt contents ranged from approximately 100 to 300 microg/kg. The high share of chemically mobile Pt in the tunnel dust (up to about 40%) indicates that Pt is predominantly emitted in a mobile form from the converter. The absence of a mobile fraction in the gully sediment is explained by the elution of Pt by run-off. Except for the mobile and easily mobilised fractions none of the other fractions of the sequential extraction contains Pt, neither in the dust samples nor in the gully sediment.
Fliegel
Daniel
D
Institut für Mineralogie und Geochemie, Universität Karlsruhe, Karlsruhe, Germany. fliegel@inorg.chem.ethz.ch
Berner
Zsolt
Z
Eckhardt
Detlef
D
Stüben
Doris
D
D004391:Dust / Q000032:analysis; D004785:Environmental Pollutants / Q000032:analysis*; D006851:Hydrochloric Acid; D006861:Hydrogen Peroxide; D017942:Nitric Acid; D010984:Platinum / Q000032:analysis*; D015203:Reproducibility of Results; D012989:Soil Pollutants / Q000032:analysis; D013054:Spectrophotometry, Atomic / Q000379:methods; D001335:Vehicle Emissions / Q000032:analysis
D004391:Dust; D004785:Environmental Pollutants; D012989:Soil Pollutants; D001335:Vehicle Emissions; D017942:Nitric Acid; D010984:Platinum; D006861:Hydrogen Peroxide; D006851:Hydrochloric Acid