Unprecedented photochemical induced cascading rearrangement of the 3-azabicyclo[3.3.1]nonane skeleton.
Certain 3-azabicyclo[3.3.1]nonane derivatives undergo unprecedented stereospecific skeletal cleavage when subjected to light affording a novel heterotricyclic skeleton.
Chemistry Department, School of Molecular and Microbial Sciences, University of Queensland, St. Lucia, 4072, Queensland, Australia. c.williams3@mailbox.uq.edu.au
Craig M
CM
Williams
Ralf
R
Heim
Douglas J
DJ
Brecknell
Paul V
PV
Bernhardt
D000473:Alkanes / Q000737:chemistry*; D001372:Aza Compounds / Q000737:chemistry*; D019086:Bridged Bicyclo Compounds, Heterocyclic / Q000737:chemistry*; D001952:Bridged-Ring Compounds / Q000737:chemistry*; D015394:Molecular Structure; D010777:Photochemistry; D013237:Stereoisomerism
D000473:Alkanes; D001372:Aza Compounds; D019086:Bridged Bicyclo Compounds, Heterocyclic; D001952:Bridged-Ring Compounds; C017573:nonane