The production of oxidants in Europa's surface.
The oxidants produced by radiolysis and photolysis in the icy surface of Europa may be necessary to sustain carbon-based biochemistry in Europa's putative subsurface ocean. Because the subduction of oxidants to the ocean presents considerable thermodynamic challenges, we examine the formation of oxygen and related species in Europa's surface ice with the goal of characterizing the chemical state of the irradiated material. Relevant spectral observations of Europa and the laboratory data on the production of oxygen and related species are first summarized. Since the laboratory data are incomplete, we examine the rate equations for formation of oxygen and its chemical precursors by radiolysis and photolysis. Measurements and simple rate equations are suggested that can be used to characterize the production of oxidants in Europa's surface material and the chemical environment produced by radiolysis. Possible precursor molecules and the role of radical trapping are examined. The possibility of oxygen reactions on grain surfaces in Europa's regolith is discussed, and the earlier estimates of the supply of O(2) to the atmosphere are increased.
Johnson
R E
RE
Engineering Physics, University of Virginia, Charlottesville, Virginia 22904, USA. rej@virginia.edu
Quickenden
T I
TI
Cooper
P D
PD
McKinley
A J
AJ
Freeman
C G
CG
D002244:Carbon; D019281:Dimerization; D005609:Free Radicals; D006859:Hydrogen; D007053:Ice; D007477:Ions; D018538:Jupiter; D007700:Kinetics; D008027:Light; D008956:Models, Chemical; D016877:Oxidants; D010100:Oxygen / Q000737:chemistry; D010545:Peroxides / Q000737:chemistry; D013696:Temperature; D013816:Thermodynamics
D005609:Free Radicals; D007053:Ice; D007477:Ions; D016877:Oxidants; D010545:Peroxides; D002244:Carbon; D006859:Hydrogen; D010100:Oxygen