Bis[tetrakis(triphenylphosphine-kappaP)silver(I)] di-mutrifluoroacetato-kappa4O:O'-bis[bis(trifluoroacetato-kappaO)stannate(IV)].
The crystal structure of the title compound, [Ag(C18H15P)4]2[Sn2(CH3)4(CF3CO2)6], consists of discrete tetrahedral cations and trans-C2SnO4 octahedral dianions [C-Sn-C = 154.6 (2) degrees ]. The dianion lies about a center of inversion and the two Sn atoms are linked unevenly by the carboxylate unit [Sn-O = 2.291 (3) A and Sn <-- O = 2.818 (3) A].
Department of Chemistry and State Key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen 361005, People's Republic of China.
Shi Yao
SY
Yang
Zhao Xiong
ZX
Xie
Seik Weng
SW
Ng