(1E)-2-(Diacetylamino)-1-methylprop-1-enyl acetate.
The analysis of the title compound, C10H15NO4, firmly establishes the configuration of the double bond as E, a stereochemistry that had been assigned tentatively by other methods. The diacetylamine and acetate substituents are approximately coplanar to one another, but approximately perpendicular to the planar ethene core. H atoms of the ethene methyl substituents are found within the ethene plane, indicating that hyperconjugation does not play an important role in stabilizing the double bond.
Olesen
Bjorn
B
Department of Chemistry, Southeast Missouri State University, Cape Girardeau, MO 63701, USA. bolesen@semo.edu
Bond
Marcus R
MR
D000085:Acetates / Q000737:chemistry*; D000409:Alanine / Q000031:analogs & derivatives*; D018360:Crystallography, X-Ray; D015394:Molecular Structure; D011725:Pyridines / Q000737:chemistry; D013237:Stereoisomerism
C496845:2-(diacetylamino)-1-methylprop-1-enyl acetate; D000085:Acetates; D011725:Pyridines; C023666:pyridine; D000409:Alanine