Triethylammonium tetraphenylborate dichloromethane solvate.
The crystal structure of the title compound, C6H16N+.C24H20B-.CH2Cl2, displays an N-H...pi interaction between the triethylammonium cation and a phenyl ring of the tetraphenylborate anion. The distance between the ammonium H atom and the edge of this phenyl ring is 2.40 (3) A. The ammonium group and the aryl moiety are nearly perpendicular, forming an intramolecular dihedral angle of 90.4 degrees. A C-H...pi interaction between the disordered dichloromethane solvate molecule and a phenyl ring of the tetraphenylborate anion is also present.
Department of Chemistry, University of Minnesota, 207 Pleasant St. SE, Minneapolis, MN 55455-0431, USA.
Daron E
DE
Janzen
Kent R
KR
Mann