Reactivity of beta-lactamido N-sulfonyl radicals.
[reaction: see text] A new class of N-substituted radical has been studied. Obtained from the corresponding chlorides, beta-lactamido N-sulfonyl radicals were allylated and added onto electron-rich olefins. It has been shown that the radicals do not undergo desulfonylation and are electrophilic in nature.
Montermini
Florian
F
Laboratoire de Chimie Organique, UMR CNRS 7611, Université Pierre et Marie Curie, Case 229, 4 Place Jussieu, 75005 Paris, France.
Lacôte
Emmanuel
E
Malacria
Max
M