N-Acyl derivatives of Asn, new bacterial N-acyl D-amino acids with surfactant activity.
New N-acyl D-amino acids were isolated from Bacillus pumilus IM 1801. Their structures were determined by chemical analysis and mass spectrometry. The lipid part was identified as a mixture of fatty acids with 11, 12, 13, 15, and 16 carbon atoms in the iso, anteiso or n configuration linked by an amide bond with a D-asparagine. They exhibited surfactant properties.
Peypoux
F
F
Laboratoire de Biochimie Analytique et Synthèse Bioorganique, Université Claude Bernard, Lyon 1, 43 Boulevard du 11 novembre 1918, 69622 Villeurbanne Cedex, France. peypoux@cismsun.univ-lyon1.fr
Laprévote
O
O
Pagadoy
M
M
Wallach
J
J
D000596:Amino Acids / Q000737:chemistry* / Q000302:isolation & purification; D001216:Asparagine / Q000031:analogs & derivatives* / Q000737:chemistry*; D001407:Bacillus / Q000737:chemistry*; D002851:Chromatography, High Pressure Liquid; D005227:Fatty Acids / Q000737:chemistry; D021241:Spectrometry, Mass, Electrospray Ionization / Q000379:methods; D013501:Surface-Active Agents / Q000737:chemistry* / Q000302:isolation & purification; D013997:Time Factors
D000596:Amino Acids; D005227:Fatty Acids; D013501:Surface-Active Agents; D001216:Asparagine