Polyhapto-aromatic interactions in lead(II) coordination.
In its crystalline form, the Pb(II) complex of 1,3-diphenylpropane-1,3-dionate (dibenzoylmethanide, DBM(-)) can be regarded as containing polymeric chains of centrosymmetric, dimeric Pb(2)(DBM)(4) units linked through hexahapto interactions of the Pb atoms with phenyl groups from adjacent units. Each Pb atom also appears to be involved in intraunit dihapto-aromatic interactions, thus attaining a total hapticity of thirteen. Comparison with the analogous Sn(II) compound indicates that the unusually high coordination number may reflect the capacity of Pb(II) to act as both a Lewis acid and a Lewis base.
Harrowfield
Jack M
JM
Chemistry, School of Biomedical and Chemical Sciences, University of Western Australia, 35 Stirling Highway, Crawley, WA 6009, Australia. cages@chem.uwa.edu.au
Maghaminia
Saeed
S
Soudi
Ali A
AA