Mineralomimetic sodalite- and muscovite-type coordination frameworks. Dynamic crystal-to-crystal interconversion processes sensitive to ion pair recognition.
A flexible sodalite-type metal organic framework [Cu(pyrimidine-2-olate)2]n (1R) is obtained in a self-assembly process involving Cu2+ ions and pyrimidine-2-olate ligands. 1R suffers a series of sequential and reversible structural changes upon solid-liquid sorption processes of metal nitrates. The 1C-to-1O transformation occurs only with large cations.
Barea
Elisa
E
Departamento de Química Inorgánica, Universidad de Granada, Avenida Fuentenueva S/N, E-18071 Granada, Spain.
Navarro
Jorge A R
JA
Salas
Juan M
JM
Masciocchi
Norberto
N
Galli
Simona
S
Sironi
Angelo
A