title: Toward single-site, immobilized molecular catalysts: site-isolated Ti ethylene polymerization catalysts supported on porous silica.
abstract: A new, general patterning methodology that may allow for the preparation of site-isolated organometallic catalysts on a silica surface is reported. The technique is demonstrated with Group 4 polymerization catalysts. The catalysts synthesized via the patterning method have up to a 10-fold increase in activity as compared to materials prepared by traditional techniques. In addition to supporting Group 4 polymerization catalysts, the patterned aminosilica is a possible support for other metal complexes, allowing for the synthesis of a wide array of immobilized single-site organometallic catalysts.
authors.affiliation: School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, 311 Ferst Drive, Atlanta, Georgia 30332, USA.
authors.forename: Michael W
authors.initials: MW
authors.lastname: McKittrick
authors.forename: Christopher W
authors.initials: CW
authors.lastname: Jones