Extractive phase vanishing reactions with dichloromethane, perfluorohexanes, and dibromoethane: slow addition in a test tube.
[reaction: see text] Partition coefficient measurements and experiments with a dye show that a new fluorous "phase vanishing reaction" described by Jana and Verkade occurs by an extractive mechanism. This mechanism is contrasted with the original diffusive phase-vanishing reactions introduced by Ryu and co-workers.
Curran
Dennis P
DP
Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA. curran@pitt.edu
Werner
Stefan
S
D001391:Azo Compounds; D003377:Countercurrent Distribution; D004058:Diffusion; D015946:Ethylene Dibromide / Q000737:chemistry*; D005466:Fluorocarbons / Q000737:chemistry*; D007202:Indicators and Reagents; D008752:Methylene Chloride / Q000737:chemistry*; D012997:Solvents / Q000737:chemistry*; D013997:Time Factors
D001391:Azo Compounds; D005466:Fluorocarbons; D007202:Indicators and Reagents; D012997:Solvents; D015946:Ethylene Dibromide; D008752:Methylene Chloride; C046548:fat red 7B; C078626:perflexane