Time resolved spectroscopic NMR imaging using hyperpolarized 129Xe.
We have visualized the melting and dissolution processes of xenon (Xe) ice into different solvents using the methods of nuclear magnetic resonance (NMR) spectroscopy, imaging, and time resolved spectroscopic imaging by means of hyperpolarized 129Xe. Starting from the initial condition of a hyperpolarized solid Xe layer frozen on top of an ethanol (ethanol/water) ice block we measured the Xe phase transitions as a function of time and temperature. In the pure ethanol sample, pieces of Xe ice first fall through the viscous ethanol to the bottom of the sample tube and then form a thin layer of liquid Xe/ethanol. The xenon atoms are trapped in this liquid layer up to room temperature and keep their magnetization over a time period of 11 min. In the ethanol/water mixture (80 vol%/20%), most of the polarized Xe liquid first stays on top of the ethanol/water ice block and then starts to penetrate into the pores and cracks of the ethanol/water ice block. In the final stage, nearly all the Xe polarization is in the gas phase above the liquid and trapped inside the pores. NMR spectra of homogeneous samples of pure ethanol containing thermally polarized Xe and the spectroscopic images of the melting process show that very high concentrations of hyperpolarized Xe (about half of the density of liquid Xe) can be stored or delivered in pure ethanol.
Han
S
S
Max-Planck Institute for Polymer Research, Ackermannweg 10, D-55128, Mainz, Germany.
Kühn
H
H
Häsing
F W
FW
Münnemann
K
K
Blümich
B
B
Appelt
S
S
D045424:Complex Mixtures / Q000032:analysis / Q000737:chemistry; D004058:Diffusion; D000431:Ethanol / Q000737:chemistry*; D005615:Freezing; D006358:Hot Temperature; D007089:Image Enhancement / Q000379:methods*; D008279:Magnetic Resonance Imaging / Q000379:methods*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D009862:Online Systems; D011312:Pressure; D012996:Solutions; D014867:Water / Q000737:chemistry*; D014979:Xenon Isotopes / Q000032:analysis* / Q000145:classification*
D045424:Complex Mixtures; D012996:Solutions; D014979:Xenon Isotopes; D014867:Water; D000431:Ethanol