Novel oxygen storage mechanism based on redox of sulfur in lanthanum oxysulfate/oxysulfide.
A sulfur redox cycle between La(2)O(2)SO(4)(S(6+)) and La(2)O(2)S(S(2-)) phases was found for the first time to achieve the oxygen storage of 2 mol O(2) mol(-1), which is eight times larger than that of the conventional CeO(2)-ZrO(2) system.
Machida
Masato
M
Department of Applied Chemistry and Biochemistry, Faculty of Engineering, Kumamoto University, 2-39-1 Kurokami, Kumamoto 860-8555. machida@chem.kumamoto-u.ac.jp
Kawamura
Kiyotaka
K
Ito
Kazuhiro
K