title: Isolation, dynamic NMR study and X-ray characterisation of a bis sulfonium zirconocene-ate dimer.
abstract: The novel dimer [Cp(2)Zr[upper bond start]([minus sign in circle])S([plus sign in circle])CH(Ph)CH[double bond]C[upper bond end]PPh(2)](2), the first example of a structurally characterised sulfur-bridged binuclear zirconathiolane complex, was prepared, characterised by NMR spectroscopy and X-ray crystallography, and some aspects of its solution behaviour were studied.
authors.affiliation: Laboratoire de Synthèse et Electrosynthèse Organométalliques associé au CNRS (UMR 5188), Université de Bourgogne, Faculté des Sciences Gabriel, 6 boulevard Gabriel, 21000 Dijon, France.
authors.forename: Esteban
authors.initials: E
authors.lastname: Ortega
authors.forename: Nadine
authors.initials: N
authors.lastname: Pirio
authors.forename: Philippe
authors.initials: P
authors.lastname: Meunier
authors.forename: Bruno
authors.initials: B
authors.lastname: Donnadieu