title: Superoxide-stable ionic liquids: new and efficient media for electrosynthesis of functional siloxanes.
abstract: The electrogeneration of diorganylsilanones from difunctional precursors Y(CH(2))(3)(Me)SiX(2) and Ph(2)SiX(2)(Y = NH(2), CF(3), CN; X = Cl, OEt, OMe), performed in the presence of hexamethyldisiloxane or hexamethylcyclotrisiloxane (D(3)) in the ionic liquids [C(5)H(5)NC(8)F(18)].NTf(2), [C(5)H(5)NC(18)H(38)].NTf(2) and Me(3)BuN.NTf(2), which reveal high solubility of oxygen and are inert toward superoxide anion, allows functionalized siloxanes to be produced selectively in good isolated yields.
authors.affiliation: Departmento de Química Orgánica, Universidad de Murcia, Spain.
authors.forename: Bruno
authors.initials: B
authors.lastname: Martiz
authors.forename: Robert
authors.initials: R
authors.lastname: Keyrouz
authors.forename: Said
authors.initials: S
authors.lastname: Gmouh
authors.forename: Michel
authors.initials: M
authors.lastname: Vaultier
authors.forename: Viatcheslav
authors.initials: V
authors.lastname: Jouikov