Highly diastereoselective formation of C2-symmetric bis-thioglycoside Pd(II) complexes: the role of the exo anomeric effect.
Treatment of several C(2) symmetric bis-thioglycosides with Pd(CH(3)CN)(2)Cl(2) always leads to a single diastereomeric Pd(II) complex as a consequence of the exo-anomeric effect.
Khiar
Noureddine
N
Instituto de Investigaciones Químicas, C.S.I.C-Universidad de Sevilla, c/. Américo Vespucio, s/n., Isla de la Cartuja, 41092 Seville, Spain. khiar@cica.es
Araujo
Cristina S
CS
Suárez
Bélen
B
Alvarez
Eleuterio
E
Fernández
Inmaculada
I
D002236:Carbohydrate Conformation; D006031:Glycosylation; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism; D013865:Thioglycosides / Q000737:chemistry*
D009942:Organometallic Compounds; D013865:Thioglycosides; D010165:Palladium