title: Towards local rheology of emulsions under Couette flow using Dynamic Light Scattering.
abstract: We present local velocity measurements in emulsions under shear using heterodyne Dynamic Light Scattering. Two emulsions are studied: a dilute system of volume fraction phi = 20% and a concentrated system with phi = 75%. Velocity profiles in both systems clearly show the presence of wall slip. We investigate the evolution of slip velocities as a function of shear stress and discuss the validity of the corrections for wall slip classically used in rheology. Focussing on the bulk flow, we show that the dilute system is Newtonian and that the concentrated emulsion is shear-thinning. In the latter case, the curvature of the velocity profiles is compatible with a shear-thinning exponent of 0.4 consistent with global rheological data. However, even if individual profiles can be accounted for by a power law fluid (with or without a yield stress), we could not find a fixed set of parameters that would fit the whole range of applied shear rates. Our data, thus, raise the question of the definition of a global flow curve for such a concentrated system. These results show that local measurements are a crucial complement to standard rheological tools. They are discussed in the light of recent works on soft glassy materials.
authors.affiliation: Centre de Recherche Paul Pascal, Avenue Schweitzer, 33600 Pessac, France. salmon@crpp.u-bordeaux.fr
authors.forename: J-B
authors.initials: JB
authors.lastname: Salmon
authors.forename: L
authors.initials: L
authors.lastname: Bécu
authors.forename: S
authors.initials: S
authors.lastname: Manneville
authors.forename: A
authors.initials: A
authors.lastname: Colin
mesh_terms: D004548:Elasticity; D004655:Emulsions / Q000737:chemistry*; D005990:Glycerol / Q000737:chemistry*; D017078:Laser-Doppler Flowmetry / Q000379:methods*; D008027:Light; D008956:Models, Chemical; D009038:Motion; D000644:Quaternary Ammonium Compounds / Q000737:chemistry*; D012031:Refractometry / Q000379:methods*; D012212:Rheology / Q000379:methods; D012542:Scattering, Radiation; D033081:Shear Strength; D012833:Siloxanes / Q000737:chemistry*; D013314:Stress, Mechanical; D013501:Surface-Active Agents / Q000737:chemistry*; D050337:Trimethyl Ammonium Compounds; D014783:Viscosity
chemical_list: D004655:Emulsions; D000644:Quaternary Ammonium Compounds; D012833:Siloxanes; D013501:Surface-Active Agents; D050337:Trimethyl Ammonium Compounds; D005990:Glycerol; C009410:tetradecyltrimethylammonium