title: Highly diastereoselective formation of C2-symmetric bis-thioglycoside Pd(II) complexes: the role of the exo anomeric effect.
abstract: Treatment of several C(2) symmetric bis-thioglycosides with Pd(CH(3)CN)(2)Cl(2) always leads to a single diastereomeric Pd(II) complex as a consequence of the exo-anomeric effect.
authors.affiliation: Instituto de Investigaciones Químicas, C.S.I.C-Universidad de Sevilla, c/. Américo Vespucio, s/n., Isla de la Cartuja, 41092 Seville, Spain. khiar@cica.es
authors.forename: Noureddine
authors.initials: N
authors.lastname: Khiar
authors.forename: Cristina S
authors.initials: CS
authors.lastname: Araujo
authors.forename: Bélen
authors.initials: B
authors.lastname: Suárez
authors.forename: Eleuterio
authors.initials: E
authors.lastname: Alvarez
authors.forename: Inmaculada
authors.initials: I
authors.lastname: Fernández
mesh_terms: D002236:Carbohydrate Conformation; D006031:Glycosylation; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism; D013865:Thioglycosides / Q000737:chemistry*
chemical_list: D009942:Organometallic Compounds; D013865:Thioglycosides; D010165:Palladium