title: Determination of shapes and maximums of analyte peaks based on solute mobilities in capillary electrophoresis.
abstract: In capillary electrophoresis, the relative orders of mobilities of analyte, additive, and the complex formed determine the analyte peak shape in a way similar to the way the binding isotherms determine the peak shapes in chromatography. The three mobilities allow six possible orders; each produces a characteristic peak shape in CE. Equations describing the analyte migration in a CE system with the presence of mobility-changing additives can be implemented into computer programs to predict the migration times of the analyte peak maximums, and the predicted migration times agree well with the experimental results.
authors.affiliation: Department of Chemistry, University of British Columbia, Vancouver, British Columbia, Canada V6T 1Z1.
authors.forename: Ning
authors.initials: N
authors.lastname: Fang
authors.forename: Eon
authors.initials: E
authors.lastname: Ting
authors.forename: David D Y
authors.initials: DD
authors.lastname: Chen