title: Vibrational analysis and normal coordinate analysis of trimethylphosphane.
abstract: Raman spectra of trimethylphosphine {P(CH(3))(3)} as liquid have been recorded with parallel and perpendicular polarization. Vibrational assignments are given by means of a normal coordinate analysis. The skeletal modes of the phosphoruscarbon-core and their interactions with the methyl groups, its force field and potential energy distribution are discussed.
authors.affiliation: Institut für Physikalische Chemie, Universität Würzburg, Marcusstrasse 9-11, D-97070, Würzburg, Germany.
authors.forename: R.
authors.initials: R
authors.lastname: Pikl
authors.forename: C.
authors.initials: C
authors.lastname: Fickert
authors.forename: W.
authors.initials: W
authors.lastname: Kiefer