title: Organochlorine pesticides in the air around the Taihu Lake, China.
abstract: Organochlorine (OC) pesticides have been used broadly in China's past, yet very little is known about their atmospheric concentrations and transport. In this work, air samples were collected in the Taihu Lake Region, China, from July 23 to August 11, 2002, to measure concentrations of OC pesticides in air. The average concentrations of alpha and gamma- hexachlorocyclohexane (HCH), hexachlorobenzene (HCB), heptachlor (HEPT), alpha-endosulfan, p,p'-DDT, p,p'-DDE, p,p'-DDD, and o,p'-DDT in the air were 74 and 46, 47, 53, 307, 124, 212, 36, and 767 pg m(-3), respectively. It was interesting to note that the concentrations of p,p'-DDT, p,p'-DDE, and o,p'-DDT were all very high, even though the use of technical DDT has been banned in China since 1983. Moreover, the average concentration ratios of o,p'-DDT/p,p'-DDT and p,p'-DDE/p,p'-DDT were as high as 6.3 and 1.8. This suggested that there could be an unknown source of DDT-related compounds (DDTs), especially o,p'-DDT and p,p'-DDE. It is very likely that this unknown source was the application of dicofol, an acaricide manufactured from technical DDT and used mainly on cotton fields to treat mites in China. Backward trajectory analysis also provided consistent evidence that the high air concentrations of DDTs were related to trajectories from the area north of the Yangtze River, where cotton fields account for a significant fraction of land use.
authors.affiliation: State Key Joint Laboratory for Environmental Simulation and Pollution Control, College of Environmental Sciences, Peking University, Beijing 100871, China.
authors.forename: Xinghua
authors.initials: X
authors.lastname: Qiu
authors.forename: Tong
authors.initials: T
authors.lastname: Zhu
authors.forename: Jing
authors.initials: J
authors.lastname: Li
authors.forename: Hansheng
authors.initials: H
authors.lastname: Pan
authors.forename: Quanlin
authors.initials: Q
authors.lastname: Li
authors.forename: Guofang
authors.initials: G
authors.lastname: Miao
authors.forename: Jicheng
authors.initials: J
authors.lastname: Gong
mesh_terms: D000383:Agriculture; D000393:Air Pollutants / Q000032:analysis*; D002681:China; D004784:Environmental Monitoring; D006843:Hydrocarbons, Chlorinated; D007306:Insecticides / Q000032:analysis*; D014881:Water Supply
chemical_list: D000393:Air Pollutants; D006843:Hydrocarbons, Chlorinated; D007306:Insecticides