EPMA of interfaces applied to the solid oxide fuel cell.
Chemical interactions at the phase boundaries of materials applied for the solid oxide fuel cell (SOFC) have been studied by EPMA. The chemical reactivity at the interface of La(y-x)Sr(x)MnO(3)/ZrO(2)-Y(2)O(3) is dependent on the stoichiometry (y) and the Sr content (x) of the perovskite. Typical reaction products (zirconates) and a diffusion zone in the ZrO(2)-Y(2)O(3) have been observed. The extension of cation release (Mn) is related to the increasing chemical activity of Mn oxide in the perovskite by the Sr substitution for La. The wettability of the metal/oxide interface in the anode cermet (Ni/ZrO(2)-Y(2)O(3)) has been found to be influenced by chemical reactions resulting from the applied reducing atmosphere with high carbon activity. The disintegration of ZrO(2)-Y(2)O(3) in contact with molten Ni or Ni-Ti and Ni-Cr alloys leads to the redeposition of Y(2)O(3)-enriched oxides and also to Zr-rich intermetallic compounds and eutectics.
Grübmeier
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Institute for Materials in Energy Systems, IWE 1, Research Centre Jülich, D-52425, Jülich, Germany.
Naoumidis
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A
Stochniol
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G
Tsoga
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A