The infinite one-dimensional chain polymer catena-poly[[bis[micro-1,1'-ethane-1,2-diylbis(1,2,4-triazole)-kappa(2)N(4):N(4')]bis[azidozinc(II)]]-di-micro-azido-kappa(4)N(1):N(1)].
In the crystal structure of the title complex, [Zn(N(3))(2)(C(6)H(8)N(6))](n) or [Zn(N(3))(2)(bte)](n), where bte is micro-1,2-bis(1,2,4-triazol-1-yl)ethane, each Zn atom is pentacoordinated in a distorted trigonal-bipyramidal coordination environment involving two N atoms from two bte ligands and three N atoms from three azide ligands. The Zn atoms are bridged by micro-1,1-azide groups and bte ligands around a centre of inversion, forming an infinite one-dimensional chain containing both four-membered Zn(micro-1,1-N(3))(2)Zn and 18-membered Zn(gauche-bte)(2)Zn rings.
Zhu
Xia
X
College of Chemistry and Chemical Engineering, The Key Laboratory of Organic Synthesis of Jiangsu Province, Suzhou University, Suzhou 215006, People's Republic of China.
Li
Bao Zong
BZ
Zhou
Jun Hui
JH
Li
Bao Long
BL
Zhang
Yong
Y