title: Determination of inorganic ionic mercury down to 5x10(-14) mol l(-1) by differential-pulse anodic stripping voltammetry.
abstract: A new method is described for the reliable and ultrasensitive determination of inorganic ionic mercury, using differential-pulse anodic stripping voltammetry on a glassy carbon electrode. It has been possible to determine mercury down to a concentration of 5x10(-14) mol l(-1) (the lowest detection limit ever reported for a voltammetric method). This success was achieved by using a thiocyanate electrolyte and relatively long deposition times. The mercury ions are stabilized in the solution by the formation of strong thiocyanate complexes. This leads to a highly reproducible cathodic plating and anodic dissolution of mercury. A speciation analysis allowing to distinguish between dissolved atomic and ionic mercury in water is possible.
authors.affiliation: Fachinstitut für Angewandte Analytik und Umweltchemie Institut für Chemie, Humboldt-Universität, Hessische Strasse 1-2, D-10115, Berlin, Germany.
authors.forename: S
authors.initials: S
authors.lastname: Meyer
authors.forename: F
authors.initials: F
authors.lastname: Scholz
authors.forename: R
authors.initials: R
authors.lastname: Trittler