Building block syntheses of site-isolated vanadyl groups in silicate oxides.
Cross-linking of the cubic silicate building block, Si8O20 with vanadyl chloride leads to porous solids in which a homogeneous dispersion of isolated vanadyl groups is maintained throughout the matrix even at high loadings of vanadium.
Ghosh
Narendra N
NN
University of Tennessee, Department of Chemistry, Knoxville, TN 37996-1600, USA.
Clark
Jason C
JC
Eldridge
Geoffrey T
GT
Barnes
Craig E
CE