title: Dynamic headspace: a single-step extraction for isotopic analysis of microg/L concentrations of dissolved chlorinated ethenes.
abstract: In this study a dynamic headspace method was developed to measure the carbon isotope values of dissolved chlorinated ethenes at microg/L concentrations. A gas chromatograph/combustion/isotope ratio mass spectrometer (GC/C/IRMS) was modified to include a headspace extraction system followed by a cryogenic trap. Extracting headspace from a 160 mL vial with 80 mL of aqueous solution and 40 g of NaCl for 8-12 min resulted in accurate and reproducible delta13C values for trichloroethene (TCE) and cis-1,2-dichloroethene (cDCE) at concentrations of 50-75 microg/L. Based on these results a conservative lower limit of quantitation of 38 microg/L can be calculated for these compounds. For more volatile compounds such as tetrachloroethene (PCE) and vinyl chloride (VC), field data analyzed using this method indicate a lower limit of quantitation in the tens of microg /L range.
authors.affiliation: Department of Geology, Stable Isotope Laboratory, University of Toronto, 22 Russell St., Toronto, ON M5S 3B1, Canada.
authors.forename: Penny L
authors.initials: PL
authors.lastname: Morrill
authors.forename: Georges
authors.initials: G
authors.lastname: Lacrampe-Couloume
authors.forename: Barbara Sherwood
authors.initials: BS
authors.lastname: Lollar
mesh_terms: D002247:Carbon Isotopes / Q000737:chemistry*; D004000:Dichloroethylenes / Q000032:analysis; D008401:Gas Chromatography-Mass Spectrometry / Q000295:instrumentation / Q000379:methods*; D006843:Hydrocarbons, Chlorinated / Q000032:analysis*; D015203:Reproducibility of Results; D013750:Tetrachloroethylene / Q000032:analysis; D014241:Trichloroethylene / Q000032:analysis; D014752:Vinyl Chloride / Q000032:analysis
chemical_list: D002247:Carbon Isotopes; D004000:Dichloroethylenes; D006843:Hydrocarbons, Chlorinated; D014241:Trichloroethylene; D013750:Tetrachloroethylene; D014752:Vinyl Chloride; C035384:1,2-dichloroethylene