title: Building block syntheses of site-isolated vanadyl groups in silicate oxides.
abstract: Cross-linking of the cubic silicate building block, Si8O20 with vanadyl chloride leads to porous solids in which a homogeneous dispersion of isolated vanadyl groups is maintained throughout the matrix even at high loadings of vanadium.
authors.affiliation: University of Tennessee, Department of Chemistry, Knoxville, TN 37996-1600, USA.
authors.forename: Narendra N
authors.initials: NN
authors.lastname: Ghosh
authors.forename: Jason C
authors.initials: JC
authors.lastname: Clark
authors.forename: Geoffrey T
authors.initials: GT
authors.lastname: Eldridge
authors.forename: Craig E
authors.initials: CE
authors.lastname: Barnes