Unexpected features of stretched Si-H...Mo beta-agostic interactions.
Coupling of silanes with the imido group of (Ar'N)2Mo(PMe3)3 gives either the silanimine dimer (ArN-SiHCl)2 or Si-H agostic silylamido complexes which do not exhibit the commonly expected correlation between the nature of the substituents on silicon, the degree of Si-H addition and the value of the Si-H coupling constant.
Ignatov
Stanislav K
SK
University of Nizhnii Novgorod, 23 Gagarin Avenue, Nizhnii Novgorod 603600, Russia.
Rees
Nicholas H
NH
Dubberley
Stuart R
SR
Razuvaev
Alexei G
AG
Mountford
Philip
P
Nikonov
Georgii I
GI