title: Preparation of ZnS/CdS composite nanoparticles by coprecipitation from reverse micelles using CO2 as antisolvent.
abstract: The possibility of simultaneously recovering ZnS and CdS particles from reverse micelles by dissolving antisolvent CO2 into the micellar solution was investigated by high-pressure UV-Vis spectra. It was found that all the ZnS and CdS particles in the reverse micelles could be precipitated by compressed CO2 at suitable pressures. The phase structures and morphologies of the obtained composites were characterized by X-ray diffraction and transmission electronic micrographs. The results illustrate that the smaller molar ratio of water to surfactant of the reverse micelles and higher pressure of CO2 are favorable for producing smaller particles. This method has many potential advantages for the production of composite nanoparticles.
authors.affiliation: Center for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China.
authors.forename: Jianling
authors.initials: J
authors.lastname: Zhang
authors.forename: Ming
authors.initials: M
authors.lastname: Xiao
authors.forename: Zhimin
authors.initials: Z
authors.lastname: Liu
authors.forename: Buxing
authors.initials: B
authors.lastname: Han
authors.forename: Tao
authors.initials: T
authors.lastname: Jiang
authors.forename: Jun
authors.initials: J
authors.lastname: He
authors.forename: Guanying
authors.initials: G
authors.lastname: Yang