title: Unexpected features of stretched Si-H...Mo beta-agostic interactions.
abstract: Coupling of silanes with the imido group of (Ar'N)2Mo(PMe3)3 gives either the silanimine dimer (ArN-SiHCl)2 or Si-H agostic silylamido complexes which do not exhibit the commonly expected correlation between the nature of the substituents on silicon, the degree of Si-H addition and the value of the Si-H coupling constant.
authors.affiliation: University of Nizhnii Novgorod, 23 Gagarin Avenue, Nizhnii Novgorod 603600, Russia.
authors.forename: Stanislav K
authors.initials: SK
authors.lastname: Ignatov
authors.forename: Nicholas H
authors.initials: NH
authors.lastname: Rees
authors.forename: Stuart R
authors.initials: SR
authors.lastname: Dubberley
authors.forename: Alexei G
authors.initials: AG
authors.lastname: Razuvaev
authors.forename: Philip
authors.initials: P
authors.lastname: Mountford
authors.forename: Georgii I
authors.initials: GI
authors.lastname: Nikonov