title: Molecular sieving in a nanoporous b-oriented pure-silica-zeolite MFI monocrystal film.
abstract: The molecular sieving property of a continuous b-oriented pure-silica-zeolite (PSZ) MFI monocrystal film was demonstrated in a zeolite-modified electrode (ZME) configuration using redox molecules of different sizes. Ru(NH3)63+ (diameter approximately 5.5 A) was able to traverse the film, while Co(phen)32+ (diameter approximately 13.0 A) was completely excluded. This film has excellent adhesion to the electrode and is stable in strong acidic conditions.
authors.affiliation: Department of Chemical and Environmental Engineering, University of California, Riverside, California, USA.
authors.forename: Shuang
authors.initials: S
authors.lastname: Li
authors.forename: Xin
authors.initials: X
authors.lastname: Wang
authors.forename: Derek
authors.initials: D
authors.lastname: Beving
authors.forename: Zhongwei
authors.initials: Z
authors.lastname: Chen
authors.forename: Yushan
authors.initials: Y
authors.lastname: Yan