Crystalline molecular alloys.
The dicationic tecton 1-2H(+) leads in the presence of anionic M(CN)(6)(3-) complexes to two almost identical crystalline systems A (M = Fe) and B (M = Co) composed of 2-D H-bonded networks and water molecules. The epitaxial growth of B on A used as seed or A on B generates crystalline molecular alloys.
Ferlay
Sylvie
S
Laboratoire de Chimie de Coordination Organique, Universite Louis Pasteur, F-67000, Strasbourg, France.
Hosseini
Wais
W