First example of high loaded polymer-stabilized nanoclusters immobilized on hydrotalcite: effects in alkyne hydrogenation.
Poly(N-vinyl-2-pyrrolidone)-stabilized Pd-nanoclusters, for the first time exclusively supported on the hydrotalcite lateral surface, showed a remarkable catalytic performance in the selective hydrogenation of 3-hexyn-1-ol, which can be ascribed to both the influence of the protecting polymer PVP as well as the nature of the support.
Roelofs
Jules C A A
JC
Engelhard De Meern b.v. Strijkviertel 67, 3454 ZG De Meern, The Netherlands. jules.roelofs@Engelhard.com
Berben
Peter H
PH