title: Determination of antimony, arsenic, bismuth and copper by inductively coupled plasma atomic emission spectrometry in the electrorefining of copper.
abstract: Inductively coupled plasma atomic emissionspectrometry (ICP-AES) has been applied as a rapid and routine method for the analysis of process electrolytes in the electrorefining of copper. Antimony, arsenic, bismuth and copper have been selected as major electrolyte constituents. For these elements profound statistical studies of spectral and interelement effects have been carried out. For As, Bi and Sb two analyte wavelengths have been selected, and for Cu one relatively insensitive analyte line has been chosen due to the high Cu concentration in samples. Best analytical lines were: As at 193.759 nm, Bi at 306.772 nm, Sb at 206.833 nm and Cu at 216.953 nm. Multiple linear regression proved to be very capable in the search of the best analytical wavelength and identifying interfering elements. Using simple acid based standards all elements investigated can be determined separately in complicated matrices with satisfactory results. Differences between true values and measured values can be partly eliminated by appropriate calculational methods.
authors.affiliation: Department of Chemistry, University of Jyväskylä, PO Box 35, 40351, Jyväskylä, Finland.
authors.forename: T
authors.initials: T
authors.lastname: Piippanen
authors.forename: J
authors.initials: J
authors.lastname: Tummavuori