title: Thioacylation reactions for the surface functionalization of phosphorus-containing dendrimers.
abstract: The functionalization of phosphorus-containing dendrimers was easily achieved through thioacylation reactions involving new dendrimers capped with dithioester end groups and various functionalized amines. These reactions were successfully applied to the first generation (12 end groups) and the third generation of the dendrimer (48 end groups) and allowed their functionalization by various primary or secondary amines, alcohols, glycols, and azides. [reaction: see text]
authors.affiliation: Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 4, France.
authors.forename: Patrice
authors.initials: P
authors.lastname: Marchand
authors.forename: Laurent
authors.initials: L
authors.lastname: Griffe
authors.forename: Anne-Marie
authors.initials: AM
authors.lastname: Caminade
authors.forename: Jean-Pierre
authors.initials: JP
authors.lastname: Majoral
authors.forename: Mathias
authors.initials: M
authors.lastname: Destarac
authors.forename: Frédéric
authors.initials: F
authors.lastname: Leising
mesh_terms: D000215:Acylation; D000438:Alcohols / Q000737:chemistry; D000588:Amines / Q000737:chemistry; D001386:Azides / Q000737:chemistry; D006018:Glycols / Q000737:chemistry; D015394:Molecular Structure; D010758:Phosphorus / Q000737:chemistry*; D011108:Polymers / Q000138:chemical synthesis*; D013438:Sulfhydryl Compounds / Q000737:chemistry*; D013854:Thioamides / Q000138:chemical synthesis
chemical_list: D000438:Alcohols; D000588:Amines; D001386:Azides; D006018:Glycols; D011108:Polymers; D013438:Sulfhydryl Compounds; D013854:Thioamides; D010758:Phosphorus