Ti-Mo heterobimetallic thiacalix[4]arene complex containing an unusual alpha-agostic micro2-eta5:eta2-cyclopentadienyl ligand.
A stepwise reaction of p-tert-butylthiacalix[4]arene (TC4A-(OH)(4)) with [CpTiCl3]-NEt(3) and cis-[Mo(N(2))(2)(PMe(2)Ph)(4)] afforded a new Ti-Mo heterobimetallic complex [TC4A-(O)(4)Ti(micro2-C(5)H(5))MoH(PMe(2)Ph)(2)] which shows an unusual alpha-agostic micro2-eta5:eta2-coordination of a cyclopentadienyl ligand.
Takemoto
Shin
S
Department of Materials Science and Technology, Faculty of Industrial Science and Technology, Tokyo University of Science, Noda, Chiba 278-8510, Japan.
Tanaka
Shinpei
S
Mizobe
Yasushi
Y
Hidai
Masanobu
M