Azido[1,1'-bis(diphenylphosphino)ferrocene](pentamethylcyclopentadienyl)rhodium(III) hexafluorophosphate.
In the title compound, azido-2kappaN-bis[micro-(1eta(5):2kappaP)-diphenylphosphinocyclopentadienyl][2(eta(5))-pentamethylcyclopentadienyl]iron(III)rhodium(III) hexafluorophosphate, [[Rh(C(10)H(15))(N(3))][Fe(micro-C(17)H(14)P)(2)]]PF(6) or [FeRh(C(10)H(15))(micro-C(17)H(14)P)(2)(N(3))]PF(6), the coordination sphere of Rh(III) can be described as pseudo-tetrahedral, composed of two P atoms from a 1,1'-bis(diphenylphosphino)ferrocene (dppf) ligand, an azido N atom and the centroid of the ring of a C(5)Me(5) (Cp*) ligand. The two cyclopentadienyl rings in the dppf moiety adopt an eclipsed conformation. The Rh.Fe distance is 4.340 (2) A.
Han
Won Seok
WS
Department of Chemistry (BK21), Institute of Basic Science, Sungkyunkwan University, Natural Science Campus, Suwon 440-746, South Korea.
Lee
Soon W
SW