Allylic tantalums as highly imine-selective reagents.
A practical method for the allylation of low electrophilic N-aliphatic imines was established by allylic tantalum. This is a superior methodology compared with conventional ones in terms of wide applicability to imines.
Shibata
Ikuya
I
Department of Molecular Chemistry, Science and Technology Center for Atoms, Molecules and Ions Control, Graduate School of Engineering, Osaka University, Osaka, Japan. shibata@chem.eng.osaka-u.ac.jp
Nose
Kyo
K
Sakamoto
Kazuya
K
Yasuda
Makoto
M
Baba
Akio
A