Synthesis, X-ray structure, and self-assembly of functionalized bis(2,2':6',2' '-terpyridinyl)arenes.
meta-Bis(terpyridinyl)phenol has been synthesized from O-benzyl-3,5-di(formyl)phenol in three steps. Its alkylation afforded a series of bisterpyridinylarenes, which can be self-assembled to afford the corresponding hexametallomacrocycles possessing Fe(II), Zn(II), or Ru(II) connectivity. [structure: see text]
Wang
Pingshan
P
Departments of Polymer Science and Chemistry, Goodyear Polymer Center, The University of Akron, Akron, OH 44325-4717, USA.
Moorefield
Charles N
CN
Newkome
George R
GR
D000478:Alkylation; D001672:Biocompatible Materials / Q000138:chemical synthesis; D018360:Crystallography, X-Ray; D007501:Iron / Q000737:chemistry; D008956:Models, Chemical; D010636:Phenols / Q000138:chemical synthesis; D011725:Pyridines / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry; D015032:Zinc / Q000737:chemistry
D001672:Biocompatible Materials; D010636:Phenols; D011725:Pyridines; D012428:Ruthenium; D007501:Iron; D015032:Zinc