title: Electrophilic amination of 4-fluorophenol with diazenes: a complete removal of the fluorine atom.
abstract: The electrophilic amination of 2-fluorophenol, 4-fluorophenol, and 2-chlorophenol was observed to occur as a result of their treatment with diazenes 1-4 under mild reaction conditions in the presence of ZrCl(4). The products originating from the 2-fluorophenol or 2-chlorophenol can be considered as "normal" products of amination. On the other hand, the 2-chloro-4-amino-substituted phenols obtained from the 4-fluorophenol seem to be formed in a process that involves an ipso amination, the complete removal of the fluorine atom, and the introduction of the chlorine atom.
authors.affiliation: Faculty of Chemistry and Chemical Technology, University of Ljubljana, Askerceva 5, SI-1000 Ljubljana, Slovenia.
authors.forename: Sergeja
authors.initials: S
authors.lastname: Bombek
authors.forename: Franc
authors.initials: F
authors.lastname: Pozgan
authors.forename: Marijan
authors.initials: M
authors.lastname: Kocevar
authors.forename: Slovenko
authors.initials: S
authors.lastname: Polanc