Thioacylation reactions for the surface functionalization of phosphorus-containing dendrimers.
The functionalization of phosphorus-containing dendrimers was easily achieved through thioacylation reactions involving new dendrimers capped with dithioester end groups and various functionalized amines. These reactions were successfully applied to the first generation (12 end groups) and the third generation of the dendrimer (48 end groups) and allowed their functionalization by various primary or secondary amines, alcohols, glycols, and azides. [reaction: see text]
Marchand
Patrice
P
Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 4, France.
Griffe
Laurent
L
Caminade
Anne-Marie
AM
Majoral
Jean-Pierre
JP
Destarac
Mathias
M
Leising
Frédéric
F
D000215:Acylation; D000438:Alcohols / Q000737:chemistry; D000588:Amines / Q000737:chemistry; D001386:Azides / Q000737:chemistry; D006018:Glycols / Q000737:chemistry; D015394:Molecular Structure; D010758:Phosphorus / Q000737:chemistry*; D011108:Polymers / Q000138:chemical synthesis*; D013438:Sulfhydryl Compounds / Q000737:chemistry*; D013854:Thioamides / Q000138:chemical synthesis
D000438:Alcohols; D000588:Amines; D001386:Azides; D006018:Glycols; D011108:Polymers; D013438:Sulfhydryl Compounds; D013854:Thioamides; D010758:Phosphorus