DNA-templated catalysis using a metal-cleavable linker.
Catalytic release of carboxylates from their 8-hydroxyquinoline esters by Cu(II) complexes, both attached to peptide nucleic acid strands, is triggered by complementary DNA.
Zelder
Felix H
FH
Anorganisch-Chemisches Institut, Universitat Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany.
Brunner
Jens
J
Krämer
Roland
R
D002264:Carboxylic Acids / Q000737:chemistry; D002384:Catalysis; D002413:Cations, Divalent / Q000737:chemistry; D003300:Copper / Q000737:chemistry; D004247:DNA / Q000737:chemistry*; D004952:Esters / Q000737:chemistry; D008670:Metals / Q000737:chemistry* / Q000494:pharmacology; D008956:Models, Chemical; D015125:Oxyquinoline / Q000737:chemistry; D020135:Peptide Nucleic Acids / Q000737:chemistry
D002264:Carboxylic Acids; D002413:Cations, Divalent; D004952:Esters; D008670:Metals; D020135:Peptide Nucleic Acids; D015125:Oxyquinoline; D003300:Copper; D004247:DNA