Steroidal alkaloid glycosides from tomato (Lycopersicon esculentum).
Three new steroidal alkaloid glycosides, lycoperosides F-H (1-3), were isolated from tomato fruits (Lycopersicon sculentum) along with lycoperosides A-D, esculeoside A, and rutin. The structures of these glycosides were characterized as the 3-O-beta-lycotetraosides of 23(R)-23-acetoxy-27-hydroxy-27-O-beta-d-glucopyranosyltomatidine (1), (23S,24R)-23-acetoxy-24-O-beta-d-glucopyranosylsoladulcidine-24-ol (2), and 22-isopimpifolidine (3), by means of their spectroscopic data. Also obtained was the new natural product lycoperodine-1 (4).
Yahara
Shoji
S
Medicinal Plant Garden, Graduate School of Pharmaceutical Sciences, Kumamoto University, Kumamoto 862-0973, Japan. yaharas1@gpo.kumamoto-u.ac.jp
Uda
Noriko
N
Yoshio
Eri
E
Yae
Emiko
E
D000470:Alkaloids / Q000737:chemistry / Q000302:isolation & purification*; D006027:Glycosides / Q000737:chemistry / Q000302:isolation & purification*; D007564:Japan; D018551:Solanum lycopersicum / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism; D013256:Steroids / Q000737:chemistry / Q000302:isolation & purification*
D000470:Alkaloids; D006027:Glycosides; D013256:Steroids; C485035:lycoperoside F; C485036:lycoperoside G; C485037:lycoperoside H