Vibrational analysis and normal coordinate analysis of trimethylphosphane.
Raman spectra of trimethylphosphine {P(CH(3))(3)} as liquid have been recorded with parallel and perpendicular polarization. Vibrational assignments are given by means of a normal coordinate analysis. The skeletal modes of the phosphoruscarbon-core and their interactions with the methyl groups, its force field and potential energy distribution are discussed.
Pikl
R.
R
Institut für Physikalische Chemie, Universität Würzburg, Marcusstrasse 9-11, D-97070, Würzburg, Germany.
Fickert
C.
C
Kiefer
W.
W