[Ag6(PMo10V2O40](CH3COO).8H2O: A 3D macrocationic polyoxometallic Keggin complex.
Silver atoms and strongly interlinking Keggin units ensure the tridimensionnal macrocationic structure of [Ag(6)(PMo(10)V(2)O(40))](CH(3)COO).8H(2)O, which catalyzes O(2)-based oxidation of p-methoxytoluene in acetic acid by air.
Liu
Feng-Xian
FX
Institut de Réactivité, Electrochimie et Microporosités, UMR CNRS 8637, Université de Versailles-St Quentin-en-Yvelines, Bâtiment Lavoisier, 45, Avenue des Etats-Unis, 78035 Versailles Cedex, France.
Marchal-Roch
Catherine
C
Bouchard
Philippe
P
Marrot
Jérôme
J
Simonato
Jean-Pierre
JP
Hervé
Gilbert
G
Sécheresse
Francis
F