Phosphasilaferracyclopropane: an activator of small molecules having polarized single, double, and aromatic unsaturated bonds.
Irradiation of Cp*(CO)2FeSiMe2PPh2 resulted in the formation of phosphasilaferracyclopropane 2, which readily reacted with small organic molecules with polarized bonds to yield 3-5.
Okazaki
Masaaki
M
Department of Chemistry, Graduate School of Science, Tohoku University, Sendai, Japan. mokazaki@mail.tains.tohoku.ac.jp
Jung
Kyeong A
KA
Satoh
Kazuyuki
K
Okada
Hiroshi
H
Naito
Junpei
J
Akagi
Tadahiro
T
Tobita
Hiromi
H
Ogino
Hiroshi
H