Highly stereoselective synthesis of (1E)-2-methyl-1,3-dienes by palladium-catalyzed trans-selective cross-coupling of 1,1-dibromo-1-alkenes with alkenylzinc reagents.
Zeng
Xingzhong
X
Herbert C. Brown Laboratories of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, IN 47907-2084, USA.
Qian
Mingxing
M
Hu
Qian
Q
Negishi
Ei-Ichi
E
D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry; D000900:Anti-Bacterial Agents / Q000138:chemical synthesis; D000970:Antineoplastic Agents / Q000138:chemical synthesis; D002338:Carotenoids / Q000138:chemical synthesis; D007202:Indicators and Reagents; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism; D015032:Zinc / Q000737:chemistry
D000475:Alkenes; D000900:Anti-Bacterial Agents; D000970:Antineoplastic Agents; D007202:Indicators and Reagents; D002338:Carotenoids; D010165:Palladium; D015032:Zinc