Hexakis(isopropylthio)-1,5-hexadien-3-yne and its fluorescent Ag(I) coordination polymers: assembly of helicates with thioether sites.
A new thioether-rich ligand with a conjugated dienyne backbone and its fluorescent Ag(I) coordination networks have been synthesized and characterized by single crystal X-ray diffraction studies, which reveal that the supramolecular architectures of the networks contain assembled helicates with thioether sites.
Fu
Yuan-Te
YT
Department of Chemistry and Biochemistry, The University of Texas at Austin, Austin, Texas 78712, USA.
Lynch
Vincent M
VM
Lagow
Richard J
RJ