title: AgBF4-impregnated poly(vinyl phenyl ketone): an ethylene sensing film.
abstract: Incorporation of silver tetrafluoroborate (AgBF4) into poly(vinyl phenyl ketone) (PVPK) renders the photoluminescent polymer responsive to ethylene. Polymer films prepared with a 2:1 ratio of Ag+ ions to polymer acetophenone groups responded with a quench of photoluminescence. Conditioned films showed a luminescence quench that was proportional to ethylene concentration before saturation occurred. Stern-Volmer analysis of the photoluminescence response suggested the presence of sites that were accessible and sites that were inaccessible to ethylene. Perturbations in polymer-metal interactions were monitored with infrared spectroscopy, revealing changes upon Ag+ incorporation, polymer film conditioning, and exposure to ethylene.
authors.affiliation: Department of Chemistry, University of Wisconsin, Madison, Wisconsin 53706, USA.
authors.forename: Omar
authors.initials: O
authors.lastname: Green
authors.forename: Nickolaus A
authors.initials: NA
authors.lastname: Smith
authors.forename: Arthur B
authors.initials: AB
authors.lastname: Ellis
authors.forename: Judith N
authors.initials: JN
authors.lastname: Burstyn
mesh_terms: D001881:Borates / Q000737:chemistry*; D005030:Ethylenes / Q000737:chemistry*; D007202:Indicators and Reagents; D008163:Luminescent Measurements; D008567:Membranes, Artificial; D011145:Polyvinyls / Q000737:chemistry*; D018030:Silver Compounds / Q000737:chemistry*; D013055:Spectrophotometry, Infrared
chemical_list: D001881:Borates; D005030:Ethylenes; D007202:Indicators and Reagents; D008567:Membranes, Artificial; D011145:Polyvinyls; D018030:Silver Compounds; C488580:poly(vinyl phenyl ketone); C064097:silver tetrafluoroborate