A novel ligand-unsupported 3D framework polymer of trimeric copper(I) and its NLO property.
A novel 3-D coordination polymer with trimeric copper (I) unit, [Cu(3)(CN)(IN)(2)](n)(IN = isonicotinate), was hydrothermally synthesized by the reaction of Cu(NO(3))(2).3H(2)O with isonicotinic and terephthalic acids. The structure was characterized to be a twofold interpenetrated 3-D coordination network polymer with two-coordinated copper(I). It has a powder SHG efficiency about that of KDP.
Kang
Yao
Y
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China.
Yao
Yuan-Gen
YG
Qin
Ye-Yan
YY
Zhang
Jian
J
Chen
Yu-Biao
YB
Li
Zhao-Ji
ZJ
Wen
Yi-Hang
YH
Cheng
Jian-Kai
JK
Hu
Rui-Feng
RF