Stabilization of enhanced chirality from pyrene-containing l-glutamide lipid in methyl methacrylate by photo-induced polymerization.
Enhanced CD spectra based on chirally-oriented structures of pyrene-containing L-glutamic acid-derived lipid were observed in polymerizable monomers and CD strength was maintained after photo-induced polymerization of the monomer solvents.
Takafuji
Makoto
M
Department of Applied Chemistry and Biochemistry, Kumamoto University, 2-39-1 Kurokami, Kumamoto, Japan. takafuji@chem.kumamoto-u.ac.jp
Ishiodori
Arata
A
Yamada
Taisuke
T
Sakurai
Toshihiko
T
Ihara
Hirotaka
H
D002942:Circular Dichroism; D018698:Glutamic Acid / Q000737:chemistry*; D008055:Lipids / Q000737:chemistry*; D015394:Molecular Structure; D019904:Polymethyl Methacrylate / Q000737:chemistry* / Q000528:radiation effects*; D011721:Pyrenes / Q000737:chemistry*; D013696:Temperature; D014466:Ultraviolet Rays
D008055:Lipids; D011721:Pyrenes; D018698:Glutamic Acid; D019904:Polymethyl Methacrylate; C030984:pyrene