Straightforward synthesis of gem-phosphonate-phosphate containing compounds via one-pot reaction of thioesters with diethyl phosphite.
A convenient straightforward, three step, one-pot reaction of diethyl phosphite with thioesters in the presence of catalytic amounts of potassium tert-butoxide in toluene or DMF as solvent provided various phosphonate-phosphate containing compounds in excellent yields.
Pachamuthu
Kandasamy
K
Universitat Konstanz, Fachbereich Chemie, Fach M 725, 78457 Konstanz, Germany.
Schmidt
Richard R
RR