title: Two mixed-valence copper(I,II) imidazolate coordination polymers: metal-valence tuning approach for new topological structures.
abstract: A new metal-valence tuning synthetic approach has been utilized to generate two new mixed-valence Cu(I,II) coordination polymers Cu(2)(im)(3) and Cu(3)(im)(4)(Him = imidazole), which are an unprecedented uninodal 4-connected 4.8(5) topological net and a 4-connected (4,4) net, respectively.
authors.affiliation: School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.
authors.forename: Xiao-Chun
authors.initials: XC
authors.lastname: Huang
authors.forename: Jie-Peng
authors.initials: JP
authors.lastname: Zhang
authors.forename: Yan-Yong
authors.initials: YY
authors.lastname: Lin
authors.forename: Xiao-Lan
authors.initials: XL
authors.lastname: Yu
authors.forename: Xiao-Ming
authors.initials: XM
authors.lastname: Chen