Spin trapping of nitric oxide with the iron-dithiocarbamate complex: chemistry and biology.
This brief review describes chemical and biological aspects concerning spin trapping of nitric oxide (NO) with the iron-dithiocarbamate (Fe-DTC) complex as a spin trap. Knowledge on basic properties of the Fe-DTC complex would help in understanding the applicability and limitation of the Fe-DTC-based NO spin-trapping method when it is employed in viable biological systems.
Yoshimura
Tetsuhiko
T
Institute for Life Support Technology, Yamagata Public Corporation for the Development of Industry, Yamagata, Japan.
Kotake
Yashige
Y
D001120:Arginine / Q000737:chemistry; D002956:Citrulline / Q000737:chemistry; D004578:Electron Spin Resonance Spectroscopy; D005296:Ferrous Compounds / Q000737:chemistry*; D007501:Iron / Q000737:chemistry; D008956:Models, Chemical; D009569:Nitric Oxide / Q000737:chemistry / Q000378:metabolism*; D009589:Nitrogen Oxides / Q000737:chemistry; D019097:Spin Trapping / Q000379:methods*; D013859:Thiocarbamates / Q000737:chemistry*
D005296:Ferrous Compounds; D009589:Nitrogen Oxides; D013859:Thiocarbamates; C110934:dithiocarbamate-Fe(II); D002956:Citrulline; D009569:Nitric Oxide; D001120:Arginine; D007501:Iron