Two-dimensional molecular ordering of Os(II) complexes in organo-clay hybrid ultrathin films.
An ordered structure of [OsL(3)](2+)(L = 2, 2'-bipyridine or 1, 10-phenanthroline) layer in an ultrathin film composed of the complex cations, clay nanosheets and alkylammonium cations is reported on the basis of its in-plane X-ray diffraction and polarized electronic spectral data.
Umemura
Yasushi
Y
Department of Applied Chemistry, National Defense Academy, Yokosuka, Kanagawa 239-8686, Japan. umemura@nda.ac.jp
Shinohara
Emi
E