Synthetic approach to kendomycin: preparation of the C-glycosidic core.
Synthesis of the C13-C19 C-glycoside portion of kendomycin was achieved via oxidative pyran cyclization and Claisen rearrangement to construct the fully functionalized aromatic ring.
Sengoku
Tetsuya
T
Department of Chemistry, Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan.
Arimoto
Hirokazu
H
Uemura
Daisuke
D
D006027:Glycosides; D009005:Monosaccharides / Q000138:chemical synthesis*; D017828:Rifabutin / Q000031:analogs & derivatives* / Q000138:chemical synthesis*
C438934:C-glycoside; D006027:Glycosides; D009005:Monosaccharides; C485395:kendomycin; D017828:Rifabutin