Spectroscopic and electrochemical study of Rose Bengal in aqueous solutions of cyclodextrins.
The interaction of Rose Bengal (RB) in aqueous solution of LiClO4 0.1 M with alpha-cyclodextrin (alpha-CD), hydroxypropyl-beta-cyclodextrins (HP-beta-CD) and hydroxypropyl-gamma-cyclodextrins (HP-gamma-CD) were studied by spectrophotometric measurements. The presence of Induced Circular Signals and the results of the analysis of the modifications in the absorbance spectra of RB produced by the presence of CDs in solution indicate that RB forms inclusion complexes only with HP-beta-CD and with HP-gamma-CD.
Fini
P
P
Istituto per i Processi Chimico Fisici (IPCF) CNR, sez. Bari, Via Orabona 4, 70126 Bari, Italy. p.fini@area.ba.cnr.it
Longobardi
F
F
Catucci
L
L
Cosma
P
P
Agostiano
A
A
D002942:Circular Dichroism / Q000379:methods; D003505:Cyclodextrins / Q000737:chemistry* / Q000528:radiation effects*; D019281:Dimerization; D004563:Electrochemistry / Q000379:methods*; D008027:Light; D046911:Macromolecular Substances; D011485:Protein Binding / Q000528:radiation effects; D012395:Rose Bengal / Q000737:chemistry* / Q000528:radiation effects*; D012996:Solutions; D013057:Spectrum Analysis / Q000379:methods*; D014867:Water / Q000737:chemistry*
D003505:Cyclodextrins; D046911:Macromolecular Substances; D012996:Solutions; D014867:Water; D012395:Rose Bengal