title: Synthetic approach to kendomycin: preparation of the C-glycosidic core.
abstract: Synthesis of the C13-C19 C-glycoside portion of kendomycin was achieved via oxidative pyran cyclization and Claisen rearrangement to construct the fully functionalized aromatic ring.
authors.affiliation: Department of Chemistry, Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan.
authors.forename: Tetsuya
authors.initials: T
authors.lastname: Sengoku
authors.forename: Hirokazu
authors.initials: H
authors.lastname: Arimoto
authors.forename: Daisuke
authors.initials: D
authors.lastname: Uemura
mesh_terms: D006027:Glycosides; D009005:Monosaccharides / Q000138:chemical synthesis*; D017828:Rifabutin / Q000031:analogs & derivatives* / Q000138:chemical synthesis*
chemical_list: C438934:C-glycoside; D006027:Glycosides; D009005:Monosaccharides; C485395:kendomycin; D017828:Rifabutin