Three new norditerpenoid alkaloids from Consolida orientalis.
The structures of three new norditerpenoid alkaloids named dehydrodeltatsine (1), 14-O-acetyltakaosamine (2), 18-demethoxypubescenine (3) isolated from the aerial parts of Consolida orientalis (GAY) SCHROD., were elucidated by 1D and 2D NMR spectroscopy and HR-EIMS. Twelve known norditerpenoid alkaloids (type lycoctonine) and the diterpenoid alkaloid ajaconine have been isolated. Several assignments of (13)C-NMR data for delbonine (4) were revised and the complete assignment for 18-hydroxy-14-O-methylgadesine (5) was realized.
Alva
Alenguer
A
Instituto de Productos Naturales y Agrobiología, Consejo Superior de Investigaciones Científicas, Tenerife, Spain.
Grandez
Maritza
M
Madinaveitia
Alberto
A
de la Fuente
Gabriel
G
Gavín
José
J
D000470:Alkaloids / Q000737:chemistry / Q000302:isolation & purification*; D004224:Diterpenes / Q000737:chemistry / Q000302:isolation & purification*; D035261:Plant Components, Aerial; D010936:Plant Extracts / Q000737:chemistry / Q000302:isolation & purification; D029626:Ranunculaceae
D000470:Alkaloids; D004224:Diterpenes; D010936:Plant Extracts