Oligomeric tetrathiafulvalenes: a new route toward conjugated TTF dimers and trimers.
The synthesis of bis-TTF 1 and tris-TTF 2, linked by an ethenyl spacer, is described using new useful Wittig-type reagents with the introduction of phosphonate functionality on 1,3-dithiole and TTF frameworks. Electrochemical and spectroscopic studies show intramolecular electronic interactions between conjugated TTF units.
Gautier
Nicolas
N
Chimie, Ingénierie Moléculaire et Matériaux d'Angers, UMR CNRS 6200, 2 Bd Lavoisier, 49045 Angers, France.
Samuel
Reichel
R
Sahin
Yücel
Y
Levillain
Eric
E
Leroy-Lhez
Stéphanie
S
Hudhomme
Piétrick
P