Two mixed-valence copper(I,II) imidazolate coordination polymers: metal-valence tuning approach for new topological structures.
A new metal-valence tuning synthetic approach has been utilized to generate two new mixed-valence Cu(I,II) coordination polymers Cu(2)(im)(3) and Cu(3)(im)(4)(Him = imidazole), which are an unprecedented uninodal 4-connected 4.8(5) topological net and a 4-connected (4,4) net, respectively.
Huang
Xiao-Chun
XC
School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.
Zhang
Jie-Peng
JP
Lin
Yan-Yong
YY
Yu
Xiao-Lan
XL
Chen
Xiao-Ming
XM