title: 19F and 1H NMR spectra of halocarbons.
abstract: 19F NMR chemical shifts and coupling constants are reported for 215 compounds. For 77 of these compounds, 1H NMR spectral data are also given. Long-range couplings, including 8J(F,F) and 5J(F,H), are reported. The complexity of halocarbon spectra owing to the presence of rotational isomers, asymmetric centers, long-range couplings, and chlorine isotope effects are illustrated, and the methods used for analyzing such complex spectra are briefly discussed.
authors.affiliation: DuPont Central Research & Development, Corporate Center for Analytical Science, Wilmington, Delaware 19880, USA. forchem@earthlink.net
authors.forename: Anthony
authors.initials: A
authors.lastname: Foris
mesh_terms: D000465:Algorithms; D003198:Computer Simulation; D005462:Fluorine Radioisotopes; D006846:Hydrocarbons, Halogenated / Q000032:analysis* / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D008956:Models, Chemical; D008958:Models, Molecular; D011522:Protons
chemical_list: D005462:Fluorine Radioisotopes; D006846:Hydrocarbons, Halogenated; D011522:Protons