title: Synthesis of tertiary propargylamines by sequential reactions of in situ generated thioiminium salts with organolithium and -magnesium reagents.
abstract: Sequential reactions of thioiminium salts generated from thioamides and methyl triflate with organolithium and -magnesium reagents proceed smoothly to give tertiary propargylamines in moderate to high yields. In all cases, two different organometallic reagents are incorporated into the starting thioamides.
authors.affiliation: Department of Chemistry, Faculty of Engineering, Gifu University, Yanagido, Gifu 501-1193, Japan. mtoshi@cc.gifu-u.ac.jp
authors.forename: Toshiaki
authors.initials: T
authors.lastname: Murai
authors.forename: Yuichiro
authors.initials: Y
authors.lastname: Mutoh
authors.forename: Yukiyasu
authors.initials: Y
authors.lastname: Ohta
authors.forename: Masahiro
authors.initials: M
authors.lastname: Murakami