19F and 1H NMR spectra of halocarbons.
19F NMR chemical shifts and coupling constants are reported for 215 compounds. For 77 of these compounds, 1H NMR spectral data are also given. Long-range couplings, including 8J(F,F) and 5J(F,H), are reported. The complexity of halocarbon spectra owing to the presence of rotational isomers, asymmetric centers, long-range couplings, and chlorine isotope effects are illustrated, and the methods used for analyzing such complex spectra are briefly discussed.
Foris
Anthony
A
DuPont Central Research & Development, Corporate Center for Analytical Science, Wilmington, Delaware 19880, USA. forchem@earthlink.net
D000465:Algorithms; D003198:Computer Simulation; D005462:Fluorine Radioisotopes; D006846:Hydrocarbons, Halogenated / Q000032:analysis* / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D008956:Models, Chemical; D008958:Models, Molecular; D011522:Protons
D005462:Fluorine Radioisotopes; D006846:Hydrocarbons, Halogenated; D011522:Protons