Molecular beam studies of gas-liquid interfaces.
Molecular beam scattering experiments provide a way to disentangle the elementary steps involved in energy transfer and chemical reactions between gases and liquids. After surveying the history and recent progress in this field, we review studies of the kinematics of gas-liquid collisions and proton exchange of HCl, DCl, and HBr with supercooled sulfuric acid and liquid glycerol. These experiments help to clarify the role of the surface region in controlling trapping and interfacial- and bulk-phase reactions.
Nathanson
Gilbert M
GM
Department of Chemistry, University of Wisconsin-Madison, Madison, Wisconsin 53706-1322, USA. nathanson@chem.wisc.edu