H2O outgassing from silica-filled polysiloxane TR55.
Temperature-programmed desorption/decomposition (TPD) was employed to obtain the moisture content and outgassing kinetics of TR55, a silica-filled cross-linked polysiloxane. The total moisture content of TR55 in the as-received state and after 20-30 min of vacuum pumping in the load-lock prior to TPD was measured to be on the order of 0.35 wt%. Physisorbed H(2)O and chemisorbed H(2)O account for about 13.2 and 86.8%, respectively, of the 0.35 wt% measured moisture content. H(2)O outgassing models based on the kinetics measured from TPD experiments suggest that loosely bound chemisorbed water outgasses in a dry environment slowly but continuously over many decades at or a little above room temperature. However, physisorbed water can be easily pumped out in a matter of hours at around 400 K.
Dinh
L N
LN
Chemistry and Materials Science Directorate, Lawrence Livermore National Laboratory, Livermore, CA 94551, USA. dihn1@llnl.gov
Schildbach
M A
MA
Maxwell
R S
RS
Siekhaus
W J
WJ
Balazs
B
B
McLean
W
W