title: Critical effect of cubic phase on aging in 3mol% yttria-stabilized zirconia ceramics for hip replacement prosthesis.
abstract: The isothermal tetragonal-to-monoclinic transformation of 3Y-TZP ceramics sintered at two different temperatures (1450 degrees C and 1550 degrees C) and duration (2 and 5h) is investigated at 134 degrees C in steam. Particular attention is paid to the presence of a cubic phase and its effect on isothermal aging. Sintering at 1550 degrees C can result in a significant amount of large cubic grains in the specimens, that have a detrimental impact on aging resistance, especially for the first stage of the aging process. Cubic grains appear to be enriched in yttrium, which in turn leads to a depletion of yttrium in the neighboring tetragonal grains. These grains will act as nucleation sites for tetragonal-to-monoclinic transformation. Even for specimens sintered at lower temperature, i.e. 1450 degrees C, the presence of a cubic phase is expected from the phase diagram, leading to a significant effect on aging sensitivity.
authors.affiliation: Department of Research into the Metallurgy and Physical Properties of Materials, National Institute of Applied Sciences, Associate Research Unit 5510, 69621 Villeurbanne Cedex, France. jerome.chevalier@insa-lyon.fr
authors.forename: Jérôme
authors.initials: J
authors.lastname: Chevalier
authors.forename: Sylvain
authors.initials: S
authors.lastname: Deville
authors.forename: Etienne
authors.initials: E
authors.lastname: Münch
authors.forename: Romain
authors.initials: R
authors.lastname: Jullian
authors.forename: Frédéric
authors.initials: F
authors.lastname: Lair
mesh_terms: D002516:Ceramics / Q000737:chemistry*; D003080:Cold Temperature; D006622:Hip Prosthesis; D007700:Kinetics; D018625:Microscopy, Atomic Force; D008855:Microscopy, Electron, Scanning; D015019:Yttrium / Q000737:chemistry*; D015040:Zirconium / Q000737:chemistry*
chemical_list: D015019:Yttrium; D015040:Zirconium