title: Impact of edible oil injection on the permeability of aquifer sands.
abstract: Recent laboratory and field studies have shown that food-grade edible oils can be injected into the subsurface for installation of in-situ permeable reactive barriers. However to be effective, the oil must be distributed out away from the oil injection points without excessive permeability loss. In this work, we examine the distribution of soybean oil in representative aquifer sediments as non-aqueous phase liquid oil (NAPL oil) or as an oil-in-water emulsion. Laboratory columns packed with sands or clayey sands were flushed with either NAPL oil or a soybean emulsion followed by plain water, while monitoring permeability loss and the final oil residual saturation. NAPL oil can be injected into coarse-grained sands. However NAPL injection into finer grained sediments requires high injection pressures which may not be feasible at some sites. In addition, NAPL injection results in high oil residual saturations and moderate permeability losses. In contrast, properly prepared emulsions can be distributed through sands with varying clay content without excessive pressure buildup, low oil retention and very low to moderate permeability loss. For effective transport, the emulsion must be stable, the oil droplets must be significantly smaller than the mean pore size of the sediment and the oil droplets should have a low to moderate tendency to stick to each other and the aquifer sediments. In our work, oil retention and associated permeability loss increased with sediment clay content and with the ratio of droplet size to pore size. For sandy sediments, the permeability loss is modest (0-40% loss) and is proportional to the oil residual saturation.
authors.affiliation: North Carolina State University Campus Box 7908, Raleigh, NC 27695, USA.
authors.forename: Kapo M
authors.initials: KM
authors.lastname: Coulibaly
authors.forename: Robert C
authors.initials: RC
authors.lastname: Borden
mesh_terms: D000538:Aluminum Silicates; D001421:Bacteria, Anaerobic; D000077215:Clay; D004655:Emulsions; D004784:Environmental Monitoring; D010539:Permeability; D012989:Soil Pollutants / Q000032:analysis*; D013024:Soybean Oil; D014873:Water Pollutants / Q000032:analysis*; D014881:Water Supply
chemical_list: D000538:Aluminum Silicates; D004655:Emulsions; D012989:Soil Pollutants; D014873:Water Pollutants; D013024:Soybean Oil; D000077215:Clay