Dynamic helicity inversion by achiral anion stimulus in synthetic labile cobalt(II) complex.
The helical chirality of a Co(II) complex with a chiral tetradentate ligand is completely inverted from Lambda to Delta by the addition of achiral NO3- anion as an external stimulus.
Miyake
Hiroyuki
H
Department of Chemistry, Graduate School of Science, Osaka City University, Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan. miyake@sci.osaka-cu.ac.jp
Yoshida
Kana
K
Sugimoto
Hideki
H
Tsukube
Hiroshi
H