Supramolecular stereocontrol of octahedral metal-centered chirality. Ligand modulation.
By associating chiral labile [FeL3](2+) complexes with TRISPHAT anions, a stereocontrol of the metal-centered chirality is feasible; the sense of the stereoselective induction and its magnitude strongly depends upon the structure of the diimine ligands (L: bpy, phen).
Jodry
Jonathan J
JJ
Département de Chimie Organique, Université de Genève, quai Ernest-Ansermet 30, CH-1211 Genèva 4, Switzerland.
Frantz
Richard
R
Lacour
Jérôme
J