Hopping of a single hole in hexakis[4-(1,1,2-triphenyl-ethenyl)phenyl]benzene cation radical through the hexaphenylbenzene propeller.
A versatile synthesis of a dendritic structure (5) is described in which six tetraphenylethylene moieties are connected to a central benzene ring in such a way that one of the phenyl rings of each tetraphenylethylene is also part of the propeller of the hexaphenylbenzene core. Observation of multiple oxidation waves in its cyclovoltammogram as well as an intense charge-resonance transition in the near-IR region in its cation radical spectrum suggests that a single hole delocalizes via electron transfer over six identical redox-active centers. [structure--see text]
Rathore
Rajendra
R
Department of Chemistry, Marquette University, P.O. Box 1881, Milwaukee, WI 53201, USA. rajendra.rathore@marquette.edu
Burns
Carrie L
CL
Abdelwahed
Sameh A
SA