title: Intramolecular reductive nitrosylation: reaction of nitric oxide and a copper(II) complex of a cyclam derivative with pendant luminescent chromophores.
abstract: The base-catalyzed reaction of nitric oxide with the Cu(II) complex Cu(DAC)2+ (DAC = 1,8-bis(9-anthracyl-methyl)-(1,4,8,11-tetraazacyclotetradecane)) leads to reduction of the metal center and the unexpected intramolecular nitrosylation of a secondary amine.
authors.affiliation: Department of Chemistry and Biochemistry, University of California - Santa Barbara, Santa Barbara, California 93106-9510, USA.
authors.forename: Kiyoshi
authors.initials: K
authors.lastname: Tsuge
authors.forename: Frank
authors.initials: F
authors.lastname: DeRosa
authors.forename: Mark D
authors.initials: MD
authors.lastname: Lim
authors.forename: Peter C
authors.initials: PC
authors.lastname: Ford
mesh_terms: D000873:Anthracenes / Q000737:chemistry; D003300:Copper / Q000737:chemistry*; D006571:Heterocyclic Compounds / Q000737:chemistry*; D008163:Luminescent Measurements; D015394:Molecular Structure; D009569:Nitric Oxide / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry; D010084:Oxidation-Reduction
chemical_list: D000873:Anthracenes; D006571:Heterocyclic Compounds; D009942:Organometallic Compounds; C024560:cyclam; D009569:Nitric Oxide; D003300:Copper