Intramolecular reductive nitrosylation: reaction of nitric oxide and a copper(II) complex of a cyclam derivative with pendant luminescent chromophores.
The base-catalyzed reaction of nitric oxide with the Cu(II) complex Cu(DAC)2+ (DAC = 1,8-bis(9-anthracyl-methyl)-(1,4,8,11-tetraazacyclotetradecane)) leads to reduction of the metal center and the unexpected intramolecular nitrosylation of a secondary amine.
Tsuge
Kiyoshi
K
Department of Chemistry and Biochemistry, University of California - Santa Barbara, Santa Barbara, California 93106-9510, USA.
DeRosa
Frank
F
Lim
Mark D
MD
Ford
Peter C
PC
D000873:Anthracenes / Q000737:chemistry; D003300:Copper / Q000737:chemistry*; D006571:Heterocyclic Compounds / Q000737:chemistry*; D008163:Luminescent Measurements; D015394:Molecular Structure; D009569:Nitric Oxide / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry; D010084:Oxidation-Reduction
D000873:Anthracenes; D006571:Heterocyclic Compounds; D009942:Organometallic Compounds; C024560:cyclam; D009569:Nitric Oxide; D003300:Copper